共查询到20条相似文献,搜索用时 78 毫秒
1.
We have studied photoluminescence and thermoluminescence (PL and TL) in CaGa2Se4:Eu crystals in the temperature range 77–400 K. We have established that broadband photoluminescence with maximum at 571 nm
is due to intracenter transitions 4f6 5d–4f7 (8S7/2) of the Eu2+ ions. From the temperature dependence of the intensity (log I–103/T), we determined the activation energy (E
a = 0.04 eV) for thermal quenching of photoluminescence. From the thermoluminescence spectra, we determined the trap depths:
0.31, 0.44, 0.53, 0.59 eV. The lifetime of the excited state 4f6 5d of the Eu2+ ions in the CaGa2Se4 crystal found from the luminescence decay kinetics is 3.8 μsec.
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 76, No. 1, pp. 112–116, January–February, 2009. 相似文献
2.
V. I. Gerasimova A. A. Antoshkov Yu. S. Zavorotny D. A. Lemenovskii 《Journal of Applied Spectroscopy》2012,79(2):203-210
Optical properties (photoluminescence and absorption) of Eu(bta)3(B) n (B = H2O or 1,10-phenanthroline) polycrystalline powders and fluoroacrylate polymers (FAPs) impregnated with these compounds using supercritical CO2 (SC CO2) were investigated. It was established that impregnation of Eu(bta)3phen into the FAPs using an SC CO2 solution was difficult to achieve. The type of B (ancillary ligand) and the polymer matrix were shown to influence the temperature quenching of photoluminescence of Eu3+ ions in the range 25–100°C. A comparative analysis of quantum yields (λex = 300 and 380 nm) and photoluminescence decay times (λex = 337.1 nm) for Eu(bta)3B n and for Eu(bta)3B n -doped FAPs was performed. 相似文献
3.
Spectroscopic properties of praseodymium ions-doped erbium oxalate (Er2(C2O4)3 · nH2O) crystals have been investigated. The crystals were grown by hydro silica gel method under suitable pH conditions and by
single diffusion method. The well-grown crystals are bright and transparent. The dark green colour of these crystals changes
with the variation of the concentrations of the dopant ions. The absorption spectra have been measured in the region 200–800
nm at room temperature. Judd–Ofelt intensity parameters for f–f transitions of the Pr3+ ions have been determined as Ω2 = 166.7, Ω4 = 1.103 and Ω6 = 2.898. Analyses of the absorption spectra also show a possible energy transfer from the host material to the dopant. 相似文献
4.
A. V. Mudryi A. V. Ivanyukovich M. V. Yakushev R. Martin A. Saad 《Journal of Applied Spectroscopy》2007,74(3):415-420
The effect of a strong magnetic field (induction up to 10 T) on free and bound excitons in CuInS2 single crystals is studied. A diamagnetic shift to higher energies is observed in the luminescence and reflectance spectra
for free-exciton lines ALPB ≈ 1.5348 eV, AUPB ≈ 1.5361 eV, and BC ≈ 1.557 eV. The diamagnetic shifts of free-exciton lines ALPB, AUPB, and BC provide a basis for estimating the exciton reduced masses
= 0.131m0,
= 0.13 4m0, and μBC = 0.111m0, respectively. Bound-exciton lines in luminescence spectra are split under the influence of the magnetic field. The magnitude
of the Zeeman effect (g-factor of the magnetic splitting) is estimated.
__________
Translated from Zhurnal Prikladnoi Spektroskopii Vol. 74, No. 3, pp. 373–377, May–June, 2007. 相似文献
5.
The [N(CH3)4][N(C2H5)4]ZnCl4 compound has been synthesized by a solution-based chemical method. The X-ray diffraction study at room temperature revealed
an orthorhombic system with P21212 space group. The complex impedance has been investigated in the temperature and frequency ranges 420–520 K and 200 Hz–5 MHz,
respectively. The grain interior and grain boundary contribution to the electrical response in the material have been identified.
Dielectric data were analyzed using the complex electrical modulus M
* for the sample at various temperature. The modulus plots can be characterized by full width at half height or in terms of
a non-exponential decay function ϕ(t) = exp[(−t/τ)
β
]. The detailed conductivity study indicated that the electrical conduction in the material is a thermally activated process.
The variation of the AC conductivity with frequency at different temperatures obeys the Almond and West universal law. 相似文献
6.
M.?Cristina?Gon?alves Verónica?de?Zea Bermudez M.?M.?Silva M.?J.?Smith Enrique?Morales Rute?A.?Sá Ferreira Luís?D.?Carlos 《Ionics》2010,16(3):193-201
Variable chain length di-urethane cross-linked poly(oxyethylene) (POE)/siloxane hybrid networks were prepared by application
of a sol-gel strategy. These materials, designated as di-urethanesils (represented as d-Ut(Y′), where Y′ indicates the average
molecular weight of the polymer segment), were doped with lithium triflate (LiCF3SO3). The two host hybrid matrices used, d-Ut(300) and d-Ut(600), incorporate POE chains with approximately 6 and 13 (OCH2CH2) repeat units, respectively. All the samples studied, with compositions ∞ > n ≥ 1 (where n is the molar ratio of (OCH2CH2) repeat units per Li+), are entirely amorphous. The di-urethanesils are thermally stable up to at least 200 °C. At room temperature the conductivity
maxima of the d-Ut(300)- and d-Ut(600)-based di-urethanesil families are located at n = 1 (approximately 2.0 × 10−6 and 7.4 × 10−5 Scm−1, respectively). At about 100 °C, both these samples also exhibit the highest conductivity of the two electrolyte systems
(approximately 1.6 × 10−4 and 1.0 × 10−3 Scm−1, respectively). The d-Ut(600)-based xerogel with n = 1 displays excellent redox stability. 相似文献
7.
The layered LiNi0.5Mn0.47Al0.03O2 was synthesized by wet chemical method and characterized by X-ray diffraction and analysis of magnetic measurements. The
powders adopted the α-NaFeO2 structure. This substitution of Al for Mn promotes the formation of Li(Ni0.472+Ni0.033+Mn0.474+Al0.033+)O2 structures and induces an increase in the average oxidation state of Ni, thereby leading to the shrinkage of the lattice
unit cell. The concentration of antisite defects in which Ni2+ occupies the (3a) Li lattice sites in the Wyckoff notation has been estimated from the ferromagnetic Ni2+(3a)–Mn4+(3b) pairing observed below 140 K. The substitution of 3% Al for Mn reduces the amount of antisite defects from 7% to 6.4–6.5%.
The analysis of the magnetic properties in the paramagnetic phase in the framework of the Curie–Weiss law agrees well with
the combination of Ni2+ (S = 1), Ni3+ (S = 1/2) and Mn4+ (S = 3/2) spin-only values. Delithiation has been made by the use of K2S2O8. According to this process, known to be softer than the electrochemical one, the nickel ions in the (3b) sites are converted into Ni4+ in the high spin configuration, while Ni2+(3a)–Mn4+(3b) ferromagnetic pairs remain, as the Li+(3b) ions linked to the Ni2+(3a) ions in the antisite defects are not removed. The results show that the antisite defect is surrounded by Mn4+ ions, implying the nonuniform distribution of the cations in agreement with previous NMR and neutron experiments. 相似文献
8.
Good-quality hexagonal NbSe2 single crystals were prepared. In 2H-NbSe2, superconducting and charge density wave (CDW) transitions were found at T
s = 7.4 K and T
c = 35 K respectively as reported previously. We have noticed that these two transitions are changed to T
c = 42 K and T
s = 6.5 K, in 4H-NbSe2. Thermopower has shown clear anomaly at CDW transitions. The anisotropic upper critical field was calculated as ~3 and 6.3
for 2H- and 4H-single crystals around t = 0.81, where t = T/T
s, from resistivity and explained in terms of coherence length. From the relation, Hc2 (T)=Hc2 (0)[1-t2]H_{\rm c2} (T)=H_{\rm c2} (0)[1-t^2], Hc2l (0)H_{\rm c2}^l (0) was calculated as ~8.15 T and 16.98 T at t = 0.84 in 2H-NbSe2 and 4H-NbSe2 respectively. However, Hc2t (0) = 2.68H_{\rm c2}^t (0) = 2.68T for both single crystals. 相似文献
9.
The Ac electrical conductivity and the dielectric relaxation properties of the [(C3H7)4N]2Cd2Cl6 polycrystalline sample have been investigated by means of impedance spectroscopy measurements over a wide range of frequencies
and temperatures, 209 Hz–5 MHz and 361–418 K, respectively. The purpose is to make a difference between the electrical and
dielectric properties of the polycrystalline sample and single crystal. Besides, a detailed analysis of the impedance spectrum
suggests that the electrical properties of the material are strongly temperature-dependent. Plots of (Z" versus Z') are well
fitted to an equivalent circuit model consisting of a series combination of grains and grains boundary elements. Moreover,
the temperature dependence of the electrical conductivity in the different phases follows the Arrhenius law and the frequency
dependence of σ (ω) follows the Jonscher’s universal dynamic law. Furthermore, the modulus plots can be characterized by full
width at half height or in terms of a nonexperiential decay function φ(t) = exp(t/t)β. Finally, the imaginary part of the permittivity constant is analyzed with the Cole–Cole formalism. 相似文献
10.
There has been an increasing interest towards the incorporation of nanosize ceramic fillers in polymer electrolytes. Solid
polymer electrolytes based on polyvinylidene fluoride (PVDF), silver triflate (AgCF3SO3), and x wt% of aluminum oxide (Al2O3) nanopowders (where x = 1, 3, 5, and 10, respectively) have been prepared using solution casting technique. The structural characteristics of these
thin film specimens were studied using Fourier transform infrared (FTIR) and X-ray diffraction (XRD) patterns at room temperature.
The appearance of new absorption bands and gradual shifts observed in some characteristic peaks confirmed the complex formation
between polyvinylidene fluoride and silver triflate. Furthermore, the addition of nanosized filler Al2O3 has also indicated the interaction of the filler with the polymer salt complex. The XRD patterns obtained for all these samples
in the 2θ range 10° to 70° showed the amorphous nature of these samples.
Paper presented at the Third International Conference on Ionic Devices (ICID 2006), Chennai, Tamilnadu, India, December 7–9,
2006. 相似文献
11.
Mingfu Zhang Hengzhi Chen Bin Yang Wenwu Cao 《Applied Physics A: Materials Science & Processing》2009,97(4):741-744
Layered-perovskite ferroelectric Bi2.85La0.15TiNbO9 (LBTN) optical waveguiding thin films were grown on fused silica substrates by pulsed laser deposition (PLD). X-ray diffraction
(XRD) revealed that the film is highly (00l) textured. We observed sharp and distinct transverse electric (TE) and transverse magnetic (TM) multimodes and measured the
refractive indices of LBTN thin films at 632.8 nm. The ordinary and extraordinary refractive indices were calculated to be
n
TE=2.358 and n
TM=2.464, respectively. The film homogeneity and the film-substrate interface were analyzed using an improved version of the
inverse Wentzel–Kramer–Brillouin (iWKB) method. The refractive index of the film remains constant at n
0 within the waveguiding layer. The average transmittance of the film is 70% in the wavelength range of 400–1400 nm and the
optical waveguiding properties were evaluated by the optical prism coupling method. Our results showed that the LBTN films
are very good electro-optical active material. 相似文献
12.
The synthesis and functionalization of carbon nanoparticles with PEG200 and mercaptosuccinic acid, rendering fluorescent carbon dots, is described. Fluorescent carbon dots (maximum excitation and
emission at 320 and 430 nm, respectively) with average dimension 267 nm were obtained. The lifetime decay of the functionalized
carbon dots is complex and a three component decay time model originated a good fit with the following lifetimes: τ
1 = 2.71 ns; τ
2 = 7.36 ns; τ
3 = 0.38 ns. The fluorescence intensity of the carbon dots is affected by the solvent, pH (apparent pK
a of 7.4 ± 0.2) and iodide (Stern-Volmer constant of 78 ± 2 M−1). 相似文献
13.
H. Tian Z. Zhou D. Gong H. Wang D. Liu Y. Jiang 《Applied physics. B, Lasers and optics》2008,91(1):75-78
We report the successful growth of an electroholographic crystal, potassium sodium tantalate niobate (KNTN), by a top-seeded
solution growth method. Both blue and colorless crystals were obtained. The structure, optical absorption, and refractive
dispersion properties of the as-grown crystals have been investigated. Furthermore, the Kerr coefficients R11 and R12 of paraelectric K0.95Na0.05Ta0.61Nb0.39O3 single crystal were determined by using an automated scanning Mach–Zehnder interferometer. The crystal has large Kerr coefficients
with R11= 2.8×10-16 m2/V2 and R12= -0.3×10-16 m2/V2 at the wavelength of 632.8 nm near its cubic–tetragonal phase boundary.
PACS 81.10.Dn; 42.70.Nq 相似文献
14.
Photoluminescence spectra from a single-crystalline AgGaSe2 ternary compound grown by the Bridgman-Stockbarger method from a nonstoichiometric melt are studied in the temperature interval
8–300 K under various excitation levels. The spectra contain emission bands associated with donor-acceptor recombination,
as well as with bound and free excitons. The exciton binding energy and the energy gap of the AgGaSe2 crystals are evaluated. The temperature dependence of the energies of bound and free excitons, as well as of the energy gap
of the crystals, is constructed. 相似文献
15.
I. I. Polovinko S. V. Rykhlyuk V. B. Koman I. D. Karbovnyk 《Journal of Applied Spectroscopy》2009,76(1):116-120
We propose a new method for obtaining K2Co
x
Ni1–x
(SO4)2⋅6H2O (x = 0, 0.4, 0.8, 1) crystals, involving the use of the chlorides (CoCl2⋅6H2O and NiCl2⋅6H2O) in an aqueous solution instead of the widely used sulfates. We have studied the transmission spectra of the grown single
crystals in the range λ = 200–900 nm and the IR reflectance spectra in the 2.5–20 μm region. We have observed a change in
the position and intensity of the absorption bands as a function of the composition of the crystals. Based on the Tanabe–Sugano
diagrams, we determined the crystal field splitting (Dq) and its dependence on the nickel concentration.
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 76, No. 1, pp. 126–130, January–February, 2009. 相似文献
16.
The lead pyrophosphate, Pb2P2O7, compound was prepared by conventional solid-state reaction and identified by X-ray powder diffractometer. Pb2P2O7 has a triclinic structure whose electrical properties were studied using impedance spectroscopy technique. Both impedance
and modulus analysis exhibit the grain and grain boundary contribution to the electrical response of the sample. The temperature
dependence of the bulk and grain boundary conductivity were found to obey the Arrhenius law with activation energies E
g = 0.66 eV and E
gb = 0.67 eV, respectively. The scaling behavior of the imaginary part of the complex impedance suggests that the relaxation
describes the same mechanism at various temperatures. 相似文献
17.
CuInS2 films were deposited by the single-step pulse electrodeposition technique at different duty cycles in the range of 6–50%
at 80 °C using conducting glass and titanium substrates. The films exhibited a single-phase tetragonal structure. Optical
transmission spectra exhibited interference fringes. A direct band gap value of 1.42 eV was obtained. The refractive index
value calculated by the envelope method was 1.2. Electrical resistivity of the films was in the range of 15–33 Ω cm. Photoelectrochemical
cells made with the as deposited films yielded low photo output. After post-heat treatment in argon atmosphere at different
temperatures, the films yielded higher photo output compared to earlier reports. 相似文献
18.
LiCoO2 thin films were prepared by electron beam evaporation technique using LiCoO2 target with Li/Co ratio 1.1 in an oxygen partial pressure of 5 × 10−4 mbar. The films prepared at substrate temperature T
s < 573 K were amorphous in nature, and the films prepared at T
s > 573 K exhibited well defined (104), (101), and (003) peaks among which the (104) orientation predominates. The X-ray photoelectron
spectroscopy (XPS) and inductively coupled plasma (ICP) data revealed that the films prepared in the substrate temperature
range 673–773 K are nearly stoichiometric. The grain size increases with an increase of substrate temperature. The Co–eg absorption bands, are empty and their peak position lies at around 1.7 eV above the top to the Co–t2g bands. The fundamental absorption edge was observed at 2.32 eV. The films annealed at 1,023 K in a controlled oxygen environment
exhibit (104) out plane texture with large grains.
Paper presented at the Third International Conference on Ionic Devices (ICID 2006), Chennai, Tamilnadu, India, Dec. 7–9, 2006 相似文献
19.
The ionic conductivity of PVC–ENR–LiClO4 (PVC, polyvinyl chloride; ENR, epoxidized natural rubber) as a function of LiClO4 concentration, ENR concentration, temperature, and radiation dose of electron beam cross-linking has been studied. The electrolyte
samples were prepared by solution casting technique. Their ionic conductivities were measured using the impedance spectroscopy
technique. It was observed that the relationship between the concentration of salt, as well as temperature, and conductivity
were linear. The electrolyte conductivity increases with ENR concentration. This relationship was discussed using the number
of charge carrier theory. The conductivity–temperature behaviour of the electrolyte is Arrhenian. The conductivity also varies
with the radiation dose of the electron beam cross-linking. The highest room temperature conductivity of the electrolyte of
8.5 × 10−7 S/cm was obtained at 30% by weight of LiClO4. The activation energy, E
a and pre-exponential factor, σ
o, are 1.4 × 10−2 eV and 1.5 × 10−11 S/cm, respectively. 相似文献
20.
Summary Single crystals of copper indium disulfide (CuInS2) have been grown by chemical-vapour transport technique (CVT) using iodine as the transporting agent. The obtained phase
was checked by X-ray diffractometry and the presence of copper, indium and sulfur in the grown crystals was confirmed by Energy-Dispersive
Spectrum Analysis (EDSA). The mechanical properties of the grown crystals were studied using microindentation analysis. Optical-transmission
measurements were done to determine the energy gap of the grown crystals. The four-probe technique was used to measure the
electrical properties of the grown crystals. The as-grown crystals were found to bep-type conducting and they were converted ton-type by suitable annealing treatment. The electrical parameters of bothn- andp-type crystals were measured. 相似文献