共查询到20条相似文献,搜索用时 437 毫秒
1.
聚氯乙烯(PVC)的有机辅助稳定剂包括含N有机稳定剂、含P有机稳定剂、含O有机稳定剂、含S有机稳定剂等四种类型。其中含O有机稳定剂和含S有机稳定剂对改善PVC初期着色和长期稳定性效果显著,是PVC的有机辅助稳定剂发展的重要方向。文章介绍了PVC的有机辅助稳定剂的作用机理及应用进展。 相似文献
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钐试剂在有机合成中的应用 总被引:4,自引:0,他引:4
钐试剂在有机合成中的应用是近年来有机合成方法学研究中的热点之一。综述了十余年来本课题组在钐试剂应用于有机合成方面所开展的有关工作:(1)二碘化钐作为偶联剂和还原剂在有机合成中的应用;(2)金属钐直接应用于有机合成;(3)三碘化钐作为路易斯酸应用于有机合成;(4)有机钐试剂在有机合成中的应用。 相似文献
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There has been extensive research on the development of organic optoelectronic devices, such as organic light‐emitting diodes, organic field‐effect transistors, and organic solid‐state lasers from various viewpoints, ranging from basic studies to practical applications. As organic materials are used as solids in these devices, the importance of organic chromophores that exhibit intense emissions of visible light in the solid state is greatly increasing in the field of organic electronics. However, highly efficient emission from organic solids is very difficult to attain because most organic emitting materials strongly tend to cause concentration quenching of the luminescence in the condensed phase. Therefore, in order to generate and improve organic optoelectronic devices, it is necessary to design novel chromophores that exhibit superior solid‐state emission performance. This Focus Review covers the recent development of highly emissive organic small molecules whose photoluminescence quantum yields in the solid state have been reported. Following the introduction, the photophysical processes of excited molecules are briefly reviewed. Subsequently, organic solid fluorophores are described with an emphasis on the characteristics of their molecular structures. 相似文献
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Sanyo Hamai 《Journal of inclusion phenomena and macrocyclic chemistry》2009,63(1-2):77-86
The interactions of an organic anion, 1-pyrenesulfonate (PS), with γ-cyclodextrin (γ-CD) and organic cations such as quaternary ammonium compounds (or organic anions such as 1-decanesulfonate) have been examined by means of absorption and fluorescence spectroscopy. At a low concentration of PS, γ-CD forms a 1:1 inclusion complex with PS. PS forms organic cation–organic anion complexes with quaternary ammonium compounds. The organic cation–organic anion complexes of PS form ternary inclusion complexes with γ-CD. Equilibrium constants for the formation of these complexes have been evaluated from the fluorescence intensity change. As an alkyl chain in the quaternary ammonium compound is lengthened, the equilibrium constant for the formation of the ternary inclusion complex is increased. Although PS does not form complexes with organic anions such as 1-decanesulfonate, the organic anions are bound to the γ-CD cavity accommodating a PS molecule to form ternary inclusion complexes. However, the equilibrium constants for the organic anions (1-decanesulfonate etc.) are significantly less than those for the quaternary ammonium compounds. The small equilibrium constants for the organic anions can be ascribed to the electrostatic repulsion between PS and the organic anions. 相似文献
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Yujing Liu Guoyuan Sun Xiaohan Cai Fan Yang Cong Ma Min Xue Xinyong Tao 《Journal of Energy Chemistry》2021,(3)
Pursuing material development for next-generation batteries,organic electrode materials have shown great potential for lithium-ion batteries.However,their widespread adopting is plagued by intrinsic problems such as poor electronic conductivity,high dissolution inside electrolytes and unstable chemical peculiarity.Recently,nanostructured-strategies promoted organic electrodes with exotic properties for enhancing electron and ion transport together with the stability during electrochemical process,have received increasing attention and have been extensive applied in boosting the organic lithium-ion based energy storage.In this review,we summarize the applications of nanostructures to improve the performance of both organic anodes and cathodes,including(i)nanoscale design of zero-dimensional organic electrode materials,(ii)strategies of one-dimensional nanostructured organic electrode materials,(iii)construction of two-dimensional nanosized organic composite electrodes,and(iv)three-dimensional exploration of nanosized organic electrodes.We hope to stimulate high-quality applied research on understanding and handling the relationship between the nanostructure and performance of organic lithium-ion batteries that might speed up the commercialization of organic lithium ion batteries. 相似文献
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Dr. Julie Broggi Prof. Dr. Thierry Terme Prof. Dr. Patrice Vanelle 《Angewandte Chemie (International ed. in English)》2014,53(2):384-413
One‐electron reduction is commonly used in organic chemistry for the formation of radicals by the stepwise transfer of one or two electrons from a donor to an organic substrate. Besides metallic reagents, single‐electron reducers based on neutral organic molecules have emerged as an attractive novel source of reducing electrons. The past 20 years have seen the blossoming of a particular class of organic reducing agents, the electron‐rich olefins, and their application in organic synthesis. This Review gives an overview of the different types of organic donors and their specific characteristics in organic transformations. 相似文献
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《The Chemical Engineering Journal》1992,48(3):167-172
A group contribution method for the prediction of the molar volume at the normal boiling point has been developed. The method can be used for organic and inorganic compounds. It cannot be used for elements and diatomic molecules. Group contributions are shown for a wide variety of hydrocarbons, organic halogen compounds, organic oxygen compounds, organic nitrogen compounds, organic sulfur compounds, organic boron compounds, organic silicon compounds, miscellaneous organics, and many inorganic compounds.Contrary to the corresponding states methods for the prediction of molar volumes, knowledge of critical properties, acentric factors, and reference volumes is not needed. 相似文献
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SUN QiuJian DONG GuiFang WANG LiDuo & QIU Yong Key Laboratory of Organic Optoelectronics & Molecular Engineering of Ministry of Education 《中国科学B辑(英文版)》2011,(7)
Organic optocoupler(OOC) or organic photocoupler,optical coupler is a novel and one of the most promising organic optoelectronic devices for its well electrical isolation and anti-jamming ability in long-distance and real-time digital communications.The performance parameters of OOC were greatly raised during the past decade,and its development was strongly associated with basic organic devices such as organic light emitting diodes(OLED),organic photodiodes(OPD) and organic phototransistors(OPT) etc.Here we... 相似文献
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This paper intends to provide an overview for using corannulene derivatives in organic electronics such as organic field-effect transistors (OFETs), organic solar cells (OSCs), and organic light-emitting diodes (OLEDs). We highlight the rational design strategies, tuning molecular orbital energy levels and arrangement in single crystals of corannulenes. The topological structure and properties of corannulene make it a unique candidate for organic electronics. 相似文献
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Characterisation and quantification of organic phosphorus and organic nitrogen components in aquatic systems: a review 总被引:5,自引:0,他引:5
Worsfold PJ Monbet P Tappin AD Fitzsimons MF Stiles DA McKelvie ID 《Analytica chimica acta》2008,624(1):37-58
This review provides a critical assessment of knowledge regarding the determination of organic phosphorus (OP) and organic nitrogen (ON) in aquatic systems, with an emphasis on biogeochemical considerations and analytical challenges. A general background on organic phosphorus and organic nitrogen precedes a discussion of sample collection, extraction, treatment/conditioning and preconcentration of organic phosphorus/nitrogen from sediments, including suspended particulate matter, and waters, including sediment porewaters. This is followed by sections on the determination of organic phosphorus/nitrogen components. Key techniques covered for organic phosphorus components are molecular spectrometry, atomic spectrometry and enzymatic methods. For nitrogen the focus is on the measurement of total organic nitrogen concentrations by carbon hydrogen nitrogen analysis and high temperature combustion, and organic nitrogen components by gas chromatography, high-performance liquid chromatography, gel electrophoresis, mass spectrometry, nuclear magnetic resonance spectrometry, X-ray techniques and enzymatic methods. Finally future trends and needs are discussed and recommendations made. 相似文献
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Xiaolong Liu Dr. Kang Wang Ang Ren Tongjin Zhang Shizhe Ren Prof. Jiannian Yao Prof. Haiyun Dong Prof. Yong Sheng Zhao 《Angewandte Chemie (International ed. in English)》2023,62(40):e202309386
Stimulated Raman scattering offers an alternative strategy to explore continuous-wave (c.w.) organic lasers, which, however, still suffers from the limitation of inadequate Raman gain in organic material systems. Here we propose a metal-linking approach to enhance the Raman gain of organic molecules. Self-assembled microcrystals of the metal linked organic dimers exhibit large Raman gain, therefore allowing for c.w. Raman lasing. Furthermore, broadband tunable Raman lasing is achieved in the organic dimer microcrystals by adjusting excitation wavelengths. This work advances the understanding of Raman gain in organic molecules, paving a way for the design of c.w. organic lasers. 相似文献
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Porous materials with well‐defined pore structures have received considerable attention in the past decades due to their unique structures and wide applications. Most porous materials such as zeolites, metal‐organic frameworks, covalent organic frameworks, and porous organic polymers are extended to infinite frameworks or networks by robust covalent or coordination bonds. Porous molecular cages composed of discrete molecules with permanent cavities are an emerging class of porous material and the discrete molecules assemble into solids by weak intermolecular interaction. In comparison to porous extended solids such as metal‐organic frameworks and covalent organic frameworks, porous molecular cage solids are generally soluble in organic solvents thus allowing solution processing, making them more convenient to apply in many fields. This review mainly focuses on the recent advances of application of porous molecular cages (porous organic cages and metal‐organic cages) for enantioselective recognition and separation from 2010 to present, including gas chromatography, capillary electrochromatography, chiral fluorescent recognition, chiral potentiometric sensing, and enantioselective adsorption. Furthermore, the two important family members of porous molecular cages, porous organic cages and metal‐organic cages, are also discussed. 相似文献
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有机化学涉及的有机反应类型繁多,反应机理复杂,理论性强,难以理解和掌握。而大学有机化学的教学模式基本以教师为中心,以课堂讲授为主,这在某种程度上束缚了学生的创造思维和积极性。融入科研的有机化学教学法的尝试,可以破解有机化学授课的困惑,调动了学生对有机化学的兴趣及精准掌握。科研渗透的教学可以拓宽学生知识视野,激发学习兴趣,实现理论联系科研、实际生产,能够加强学生对有机化学知识的掌握。 相似文献
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End-product identification of organic pollutants during oxidation water treatments is of environmental concern due to their potential toxicity. In this work the coupling of ion chromatography (IC), equipped with a membrane ion suppressor, and electrospray ionization mass spectrometry (ESI-MS) has been successfully exploited for the identification of novel low molecular weight organic acids formed as final by-products of 2,4-dichloro-phenol (DCP) degradation by Fenton's reagent, an oxidation method widely employed to degrade recalcitrant organic pollutants in industrial wastewater. The IC-ESI-MS analytical set-up not only allowed the detection of known organic acids but also the identification of 13 new low molecular weight organic acids as a result of extensive oxidation of the parent organic pollutant. Some of the novel organic acids were shown to be chlorine containing by-products and, consequently, of environmental concern. The analytical set-up could be used for characterizing the unknown organic carbon fraction arising from oxidation water treatments. 相似文献
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Organic electronic devices and their functional interfaces. 总被引:1,自引:0,他引:1
Norbert Koch 《Chemphyschem》2007,8(10):1438-1455
A most appealing feature of the development of (opto)electronic devices based on conjugated organic materials is the highly visible link between fundamental research and technological advances. Improved understanding of organic material properties can often instantly be implemented in novel device architectures, which results in rapid progress in the performance and functionality of devices. An essential ingredient for this success is the strong interdisciplinary nature of the field of organic electronics, which brings together experts in chemistry, physics, and engineering, thus softening or even removing traditional boundaries between the disciplines. Naturally, a thorough comprehension of all properties of organic insulators, semiconductors, and conductors is the goal of current efforts. Furthermore, interfaces between dissimilar materials-organic/organic and organic/inorganic-are inherent in organic electronic devices. It has been recognized that these interfaces are a key for device function and efficiency, and detailed investigations of interface physics and chemistry are at the focus of research. Ultimately, a comprehensive understanding of phenomena at interfaces with organic materials will improve the rational design of highly functional organic electronic devices. 相似文献
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Julien Warnan Erwin Reisner 《Angewandte Chemie (International ed. in English)》2020,59(40):17344-17354
From the understanding of biological processes and metalloenzymes to the development of inorganic catalysts, electro‐ and photocatalytic systems for fuel generation have evolved considerably during the last decades. Recently, organic and hybrid organic systems have emerged to challenge the classical inorganic structures through their enormous chemical diversity and modularity that led earlier to their success in organic (opto)electronics. This Minireview describes recent advances in the design of synthetic organic architectures and promising strategies toward (solar) fuel synthesis, highlighting progress on materials from organic ligands and chromophores to conjugated polymers and covalent organic frameworks. 相似文献