共查询到19条相似文献,搜索用时 93 毫秒
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采用热极化技术对掺锗玻璃条形光波导进行极化,通过光纤连接 (单模) 的Mach Zehnder Interferometer 系统测量条形波导内诱导出的电光效应,系统地研究了大气环境下极化条件(极化温度、极化时间、极化电压)对电光效应的影响.结果表明:在最佳极化条件下(406℃、-2.4 kV、20 min),波导内的电光系数为rTM=0.059±0.001 pm/V, rTE=0.053±0.001 pm/V,且波导结构中存在一个较低的阈值极化电压(100 V)和阈值极化温度(80℃),此时在波导样品内仍能被激发出可观察的电光效应;实验还发现采用负极化诱导方式产生的电光系数较正极化提高15%左右. 相似文献
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低阈值极化电压玻璃光波导电光效应的研究(英文) 总被引:1,自引:1,他引:0
采用热极化技术对掺锗玻璃条形光波导进行极化,通过光纤连接(单模)的Mach ZehnderInterferometer系统测量条形波导内诱导出的电光效应,系统地研究了大气环境下极化条件(极化温度、极化时间、极化电压)对电光效应的影响.结果表明:在最佳极化条件下(406℃、-2.4kV、20min),波导内的电光系数为rTM=0.059±0.001pm/V,rTE=0.053±0.001pm/V,且波导结构中存在一个较低的阈值极化电压(100V)和阈值极化温度(80℃),此时在波导样品内仍能被激发出可观察的电光效应;实验还发现采用负极化诱导方式产生的电光系数较正极化提高15%左右. 相似文献
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M-Z型极化DANS聚合物电光波导强度调制器研究 总被引:1,自引:1,他引:0
研究了Mach-Zehnder型极化聚合物电光波导强度调制器的制备工艺.器件采用DANS (4-dimethylamino-4′nitro-stlibene)聚合物为电光波导材料,由电光波导层、上下介质缓冲层、上下金属电极层构成五层波导结构.对五层光波导各层之间的光学、化学以及微加工工艺的相互兼容性进行了深入研究.采用紫外光漂白方法制备出侧壁光滑的条波导,采用钨丝电晕极化方法对DANS聚合物波导进行有效极化,使其具有电光特性.通过优化器件制备工艺,研制出工作波长为1300 nm的M-Z型电光波导强度调制器原型器件.实验测得器件半波电压约为10 V,调制带宽约为1 GHz. 相似文献
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针对SiO2光波导声光布拉格器件,计算了SiO2非对称平板波导TE模式的横向场分布;给出了SiO2/ZnO/Air层状介质结构的性能方程、运动方程和麦克斯韦方程,推导出这种层状结构的特征方程,并结合所满足的边界条件,得到了各层介质的位移及电磁场分布;计算了声表面波所引起的光学相对介质隔离率张量的变化,最后讨论了声光衍射效率和光场与声场的重叠积分、声功率、声频率、声孔径和光波导参数之间的关系。结果表明,在低频范围内光场与声表面波场重叠良好;低阶模的重叠积分始终大于高阶模重叠积分,最低阶模与声表面波相互作用最强,所需声功率最小;当声功率一定时,增加声孔径可以提高衍射效率。 相似文献
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本文首次报道了在SBN:60(Sr_(0.6)Ba_(0.4)Nb_2O_6)单晶上观察到DC(直流)电光诱导光波导的形成,以及当反转上述DC极性时光由电极间隙下低折射率区折向衬底的现象,并根据上述现象演示了一种不同于以光相位调制为基础的新的低压高调制度的电光光强调制器。 相似文献
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采用反应磁控溅射法制备了一系列不同SiO2层厚度的AlN/SiO2纳米多层膜,利用X射线衍射仪、高分辨透射电子显微镜和微力学探针表征了多层膜的微结构和力学性能,研究了SiO2层在多层膜中的晶化现象及其对多层膜生长方式及力学性能的影响. 结果表明,由于受AlN六方晶体结构的模板作用,溅射条件下以非晶态存在的SiO2层在其厚度小于0.6 nm时被强制晶化为与AlN相同的六方结构赝晶体并与AlN形成共格外延生长. 由于不同模量的两调制层存在晶格错配度,多层膜中产生了拉、压交变的应力场,使得多层膜产生硬度升高的超硬效应. SiO2随层厚的进一步增加又转变为以非晶态生长,多层膜的外延生长结构受到破坏,其硬度也随之降低.
关键词:
2纳米多层膜')" href="#">AlN/SiO2纳米多层膜
赝晶化
应力场
超硬效应 相似文献
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Two-layer ZrO2/SiO2 and SiO2/ZrO2 films were deposited on K9 glass substrates by sol–gel dip coating method. X-ray photoelectron spectroscopy (XPS) technique was used to investigate the diffusion of ZrO2/SiO2 and SiO2/ZrO2 films. To explain the difference of diffusion between ZrO2/SiO2 and SiO2/ZrO2 films, porous ratio and surface morphology of monolayer SiO2 and ZrO2 films were analyzed by using ellipsometry and atomic force microscopy (AFM). We found that for the ZrO2/SiO2 films there was a diffusion layer with a certain thickness and the atomic concentrations of Si and Zr changed rapidly; for the SiO2/ZrO2 films, the atomic concentrations of Si and Zr changed relatively slowly, and the ZrO2 layer had diffused through the entire SiO2 layer. The difference of diffusion between ZrO2/SiO2 and SiO2/ZrO2 films was influenced by the microstructure of SiO2 and ZrO2. 相似文献
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The influence of SiO2 on the dielectric properties of barium titanate ceramics was investigated. SiO2 had been doped solely and together with BaO into barium titanate before calcination. X-ray diffraction showed that all the ceramics were of a pure perovskite phase after sintering at 1275 °C for 2 h. For SiO2-doping, there was about 2.5 °C increase in Curie temperature per molar percentage of doping and the leakage current was obviously increased, especially at low voltages for relatively high doping levels. While for the co-doping of SiO2 and BaO, there was little change in Curie temperature. The point defects formed through the dopings were proposed responsible for the effects. It was suggested that SiO2 is important to barium titanate ceramics not only for sintering but also for modifying their properties. 相似文献
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Novel egg-shell structured monometallic Pd/SiO2 and bimetallic Ca-Pd/SiO2 catalysts were prepared by an impregnation method using porous hollow silica (PHS) as the support and PdCl2 and Ca(NO3)2·4H2O as the precursors. It was found from transmission electron microscope (TEM), scanning electron microscope (SEM), energy dispersive spectroscopy (EDS) and X-ray diffraction (XRD) that Pd was loaded on PHS with a particle size of 5-12 nm in Pd/SiO2 samples and the Pd particle size in Ca-Pd/SiO2 was smaller than that in Pd/SiO2 since Ca could prevent Pd particles from aggregating. X-ray photoelectron spectroscopy (XPS) analyses exhibited that Pd 3d5/2 binding energies of Pd/SiO2 and Ca-Pd/SiO2 were 0.2 and 0.9 eV lower than that of bulk Pd, respectively, as a result of the shift of the electron cloud from Pd to oxygen in Pd/SiO2 and to both oxygen and Ca in Ca-Pd/SiO2. The activity of Ca-Pd/SiO2 egg-shell catalyst for CO hydrogenation and the selectivity to methanol, with a value of 36.50 mmolCO mol−1Pd s−1 and 100%, respectively, were much higher than those of the catalysts prepared with traditional silica gel as the support, owing to the porous core-shell structure of the PHS support. 相似文献
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The structure of Au/Si/SiO2/p-Si has been fabricated using the magnetron sputtering technique. It has a very good rectifying behaviour. Visible electroluminescence (EL) has been observed from the Au/Si/SiO2/p-Si structure at a forward bias of 5V or larger. A broad band with one peak around 650-660 nm appears in all the EL spectra of the structure. The effects of the thickness of the Si layer in the Si/SiO2 films and of the input electrical power on EL spectra are studied systematically. 相似文献
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Aminated-CoFe2O4/SiO2 magnetic nanoparticles (NPs) were prepared from primary silica particles using modified StÖber method. By optimizing the preparation conditions, monodisperse CoFe2O4/SiO2 NPs with high amino groups’ density were obtained, which is necessary for enzyme immobilization. TEM confirm that the sample is a core/shell structure. These aminated-CoFe2O4/SiO2 NPs have narrow size distributions with a mean size of about 60 nm. Moreover, the aminated-CoFe2O4/SiO2 NPs can be easily dispersed in aqueous medium. The experimental results also show that the NPs have superparamagnetism, indicating that the aminated-CoFe2O4/SiO2 NPs can be used as an effective carrier for the enzyme immobilization. 相似文献
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采用溶胶-凝胶(sol-gel)工艺制备0.1 mol% Er3+掺杂Al2O3体系和SiO2-Al2O3复合体系粉末. 实验结果表明:5 mol%的SiO2复合加入Al2O3抑制γ→θ和θ→α相转变. 掺0.1 mol%Er3+:Al2O3体系粉末,900℃烧结,在1.47—1.63μm波段内光致发光(PL)谱为中心波长1.53 μm、半高宽56 nm的单一宽峰,1000—1200℃烧结,劈裂为多峰PL谱. 掺0.1 mol%Er3+:SiO2-Al2O3复合体系粉末,在高达1200℃烧结,仍保持中心波长1.53 μm的单一宽峰PL谱,由于—OH更完全的脱除,PL强度较900℃烧结Al2O3体系,SiO2-Al2O3复合体系均提高1个数量级.
关键词:
2-Al2O3复合体系')" href="#">SiO2-Al2O3复合体系
掺铒
溶胶-凝胶工艺
光致发光 相似文献
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Room temperature photoluminescence (PL) at around 600 nm from magnetron-sputtered SiO2 films co-doped with Ge is reported. The PL signal is observed in pure SiO2, however, its intensity increases significantly in the presence of Ge-nanocrystals (Ge-nc). The PL intensity has been optimized by varying the temperature of heat treatment, type of gas during heat treatment, concentration of Ge in the SiO2 films, and gas pressure during deposition. Maximum intensity occurs when Ge-nc of around 3.5 nm are present in large concentration in SiO2 layers deposited at fairly high gas pressure. Based on time resolved PL, and PL measurements after α-particle irradiation or H passivation, we attribute the origin of the PL to a defect in SiO2 (probably an O deficiency) that is excited through an energy transfer from Ge-nc. There is no direct PL from the Ge-nc; however, there is a strong coupling between excitons created in the Ge-nc and the SiO2 defect. 相似文献