Four-wave mixing in CO via the C 1Σ+ (υ′=0) state

Coherent vacuum ultraviolet (VUV) radiation was generated by four-wave difference frequency mixing (_VUV=2₁–₂) of pulsed dye laser radiation in carbon monoxide (CO). The frequency ₁ was tuned to the C ¹⁺(=0)X ¹⁺(=0) two-photon transition, while the dye laser frequency ₂ was scaned around 17650 cm^–1 which corresponds to the A ¹(=7)«C ¹⁺(=0) transition energy. The VUV intensity was found to be strongly wavelength dependent. The analysis of the spectrum revealed (i) that the VUV intensity was enhanced by the rotational levels of the A ¹(=7) state and (ii) that the off-resonance excitation in the C ¹⁺(=0)X ¹⁺(=0) two-photon transition greatly contributed to the present four-wave mixing process. The effects of pumping laser detuning, saturation and foreign gases are briefly discussed.     

Properties of Quantum Languages

The class of quantum languages Q() over an alphabet is the class of languages accepted by quantum automata. We study properties of Q() and compare Q() with the class of regular languages R(). It is shown that Q() is closed under union, intersection, and reversal but is not closed under complementation, concatenation, or Kleene star. It is also shown that Q() and R() are incomparable. Finally, we prove that L Q() if and only if L admits a transition amplitude function satisfying a certain property and a similar characterization is given for R().     

Gas‐Kinetic Temperature of Planar High‐Frequency Capacitive Discharge Plasma in N2/CO2/He Gas Mixtures

Using methods of emission spectroscopy, we have determined the gaskinetic temperature fields of planar highfrequency capacitive discharge plasma in N₂/CO₂/He gas mixtures depending on the excitation frequency, discharge current, pressure, and chemical composition of the mixture. It is shown that the dominant contribution to the neutral component heating in the center of the discharge chamber is made by the processes of V–T relaxation of vibrationally excited molecules N₂(X ¹, V) and CO₂(X ¹, V), whereas in the zones near the electrodes an important role in the heating is played, along with the V–T relaxation of the N₂(X ¹, V) and CO₂(X ¹, V) molecules, by the processes of deactivation of the metastable states A ³ of the N₂ molecule.     

Random aggregation and random-walking center of mass

Two random aggregation models are used in demonstrating the properties of the random displacementsr _i of the center of mass of aggregating particles. It is found that r _i is a randomly decreasing sequence that scales with the cluster size (steps)s and _i ^=1/s r _i s ^1/D , whereD is the fractal dimension. The center-of-mass random walk is a consistent representation of the dynamics of aggregation.     

Degenerate four-wave-mixing spectroscopy in NaH

We performed DFWM spectroscopy on X ^–1+–A ¹⁺ transitions in NaH produced in an indirect photochemical reaction between Na(3p) and H₂ and detected v=1, 2 and 3 ground state vibrational levels of NaH molecules, whereas with resonance enhanced CARS, we observed v=0 levels only. This different sensitivity can be explained by considering the Franck-Condon-factors and the relevant damping coefficients for the corresponding transitions in the NaH molecule. Time resolved DFWM spectroscopy showed that NaH(v=1) molecules effectively live much longer than Na(3p) atoms which merely follow the laser excitation pulse.     

Universal expansion of the powers of a derivation

We give the expansion of the powers of the Lie operator = ⁱ _i in any dimension, where is either a smooth function or a formal power series over an infinite set of commutatives indeterminates. We describe an algorithm for computer treatment and we give, as an example, a table for the orders 1 to 6.     

Hidden 467-1467-1467-1

Letn be an integer. Denote byA _n one of the following two graded vector spaces: (a) the space of all multilinear Poisson polynomials of degreen (with a grading described below), or (b) the cohomology of the space of alln-uples of complex numbersz ₁,..., z_n withz _iz_j forij. We prove that the natural action of _n on each homogeneous component ofA _n can be extented to an hidden _n+1 -action and we compute the corresponding character (the _n -character being already given by Klyaschko and Lehrer-Solomon formulas).     

Light Σ hypernuclei and Σ− atoms

The structures of ⁴ He and ⁷ Li are investigated within the frame of the [³H + ⁺] + + [³He + ^o] model and the microscopic cluster model +2N+, respectively. The different binding mechanism between ⁴ He and ⁷ Li is emphasized together with a brief discussion on the ⁴ Be hypernucleus. It is clarified that the ⁴ He hypernucleus is bound due to the cooperative contribution from the and terms of -N interaction, while the ⁷ Li hypernucleus is bound mainly due to the term of -N interaction. The combined analysis of ^– atoms and ⁴ He hypernucleus is shown to be useful to reveal the characteristic differences among the model D, model F and soft core versions of the Nijmegen OBE potentials.The authors would like to express their sincere thanks to J. ofka, O. Richter, M. Sotona, L. Majling, A. Cieply and other colleagues in Nuclear Physics Institute (e/Prague), and H. Band, Y. Yamamoto and T. Motoba, for collaboration and useful discussions. We dedicate this article to the memory of the excellent activities of the late Prof. Jan ofka.     

Faceting of Σ3 and Σ9 Grain Boundaries in Copper

Faceting is a well documented phenomenon known both for surfaces and interfaces, particularly, grain boundaries (GBs). Faceting can be considered as a phase transition when the original surface or GB dissociates onto flat segments whose energy is less than that of the original surface or GB. For the investigation of GB faceting a cylindrical Cu bicrystal with an island grain was grown by the Bridgman technique. Grain 1 in this bicrystal is completely surrounded by grain 2. The dissociation 9 3 + 3 proceeds during the growth of the bicrystal. The twins appear instead of {111}₁/{115}₂ or (110)_9CSL facet. GB faceting was studied at 1293 K, 1073 K, and 873 K. The profiles of the GB thermal groove were analysed by atomic force microscopy. Wulff-Herring plots and GB phase diagrams have been constructed for the 3, 9 and 9 + 3 GBs. With increasing temperature the facets with low-density CSL-planes disappear in the GB shape. GB roughening phase transition can be responsible for this phenomenon.     

Observation of structural units at symmetric [001] tilt boundaries in SrTiO3

Incoherent Z-contrast imaging in the scanning transmission electron microscope allows atom column positions to be deduced directly from the experimental image, including locations where the column separation is less than the resolution limit. Maximum entropy analysis applied to the incoherent image locates the high-Z columns to an accuracy of ±0.2 Å. Oxygen coordination at the boundary plane can be deduced by high spatial resolution electron energy loss spectroscopy, and approximate column positions determined by simple bond-valence sum calculations. Observations of 25° (=85), 36° (=5) and 67° (=13) [001] symmetric tilt grain boundaries in SrTiO₃ bicrystals show that half columns are a ubiquitous feature of grain boundary structural units. The observed structural units can be combined to produce structural models for symmetric tilt boundaries over a 0–90° range. The =17 (410), =5 (310), and =5 (210) are found to be favored boundaries and the structures of all the other tilt boundaries are comprised of these units combined with =1 (100) and =1 (110) structural units. All the proposed boundary models show continuity of grain boundary structure over the entire misorientation range. The =17 (410) structural unit is asymmetric which induces microfacetting on all boundaries less than the =5, 36.87° misorientation.Work Supported by the U.S. Department of Energy under contract DE-Ac05-84OR21400.     

The Landau-Lifshitz equation,elliptic curves and the ward transform

The Landau-Lifshitz (LL) equation is studied from a point of view that is close to that of Segal and Wilson's work on KdV. The LL hierarchy is defined and shown to exist using a dressing transformation that involves parameters ₁, ₂, ₃ that live on an elliptic curve . The crucial role of the groupK ₂ × ₂ of translations by the half-periods of and its non-trivial central extension is brought out and an analogue of Birkhoff factorisation for -equivariant loops in is given. This factorisation theorem is given two treatments, one in terms of the geometry of an infinite-dimensional Grassmannian, and the other in terms of the algebraic geometry of bundles over . Further, a Ward-like transform between a class of holomorphic vector bundles on the total spaceZ of a line-bundle over and solutions of LL is constructed. An appendix is devoted to a careful definition of the Grassmannian of the Frechet spaceC (S ¹).     

On the equivalence of different order parameters and coexistence of phases for Ising ferromagnet. II

We investigate Ising spin systems with general ferromagnetic, translation invariant interactions,H=–J _BB,J _B0. We show that the critical temperatureT _i for the order parameterp _i defined as the temperature below whichp _i>0, is independent of the way in which the symmetry breaking interactions approach zero from above. Furthermore, all the equivalent correlation functions have the same critical exponents asT T_i from below, e.g. for pair interactions all the odd correlations have the same critical index as the spontaneous magnetization. The number of fluid and crystalline phases (periodic equilibrium states) coexisting at a temperatureT at which the energy is continuous is shown to be related to the number of symmetries of the interactions. This generalizes previous results for Ising spins with even (and non-vanishing nearest-neighbour) ferromagnetic interactions. We discuss some applications of these results to the triangular lattice with three body interactions and to the Ashkin-Teller model. Our results give the answer to the question raised by R.J. Baxter et al. concerning the equality of some critical exponents.Supported by NSF Grant PHY 77-22302     

On weak and monotone σ-closures ofC*-algebras

It is proved that the monotone -closure of the self-adjoint part of anyC*-algebraA is the self-adjoint part of aC*-algebra . IfA is of type I it is proved that is weakly -closed, i.e. is a*-algebra. The physical importance of*-algebras was explained in [1] and [7].     

The C1 Σ +-B1-Σ + amplified spontaneous emission in CO

The first observation of the amplified spontaneous emission (ASE) from the RydbergC ^{1 +}( = 0) state of CO is reported. When theC ^{1 +}( = 0) state was populated through the two-photon excitation, infrared radiation near 2.0 m was ejected in forward as well as backward directions along the laser propagation. The assignment as theC ^{1 +}( = 0) B ^{1 +}( = 0) transition was confirmed. Several characteristics of ASE from theC ^{1 +}( = 0) state are presented.This work was supported by the Morino Foundation, a Grant-in-Aid (No. 07640697) and that on Priority-Area-Research Photoreaction Dynamics (No. 07228268) from the Ministry of Education, Science, Sports and Culture, Japan.     

Measurement of the reaction γp → K0Σat photon energies up to 2.6 GeV⋆

The reaction p K⁰⁺ was measured in the photon energy range from threshold up to 2.6 GeV with the SAPHIR detector at the electron stretcher facility, ELSA, in Bonn. Results are presented on the reaction cross-section and the polarization of the ⁺ as a function of the kaon production angle in the centre-of-mass system, cos^c.m._K, and the photon energy. The cross-section is lower and varies less with photon energy and kaon production angle than that of p K⁺⁰. The ⁺ is polarized predominantly at cos^c.m._K 0. The data presented here are more precise than previous ones obtained with SAPHIR and extend the photon energy range to higher values. They are compared to isobar model calculations.     

Chemically produced XeF (B→X) emission

Strong UV emission has been observed in the reactions of XeF₂+SiH₄+F₂ and XeF₂+B₂H₆+F₂. The emission spectra have been identified with the B ²X ² transition of XeF. Possible mechanisms of XeF(B) production are discussed.     

Mathematical properties of the vacuum polarization function

This paper is an investigation of certain mathematical properties of the vacuum polarization function (s). We show that (s) is a Herglotz function, has no complex zeroes, and belongs to the class of functions called typically real. In addition, we obtain upper bounds on the higher derivatives of (s), at s=0, given that we know the value of the first derivative at that point.Research supported in part by NASA Grant NSG-8035     

Lifshitz tails for periodic plus random potentials

We prove that the integrated density of states () for a potentialW =V _per +V has Lifshitz tails where V_per is a periodic potential with reflection symmetry andV is a random potential, e.g., of the formV =q _i ()f(x–i).research partially supported by DFG.research partially supported by USNSF under grant No. MCS-81-20833.     

Sigma-Boundary Statistics by Length and Number

This paper presents a rationale for comparative use of length fraction and number fraction statistics in grain boundary analysis from orientation maps generated by electron back-scatter diffraction (EBSD). The length and number fraction statistics for 3 ⁿ coincidence site lattice (CSL) boundaries were measured and compared. The length fraction of 3 boundaries was 0.48 whereas the number fraction was significantly less, 0.36. A simple model was generated to estimate both the length fraction and number fraction of annealing twins (a subset of 3). The model showed that the number fraction of twins is 0.68, 0.75, 0.79 and 0.82 of the length fraction for 1, 2, 3 and 4 twins-per-grain respectively. For the experimental data the number fraction was 0.76 of the length fraction, implying that there were on average two twins-per-grain. In contrast to the 3 case, the length fraction for 9 and 27 boundaries was less than the number fraction. There are more inaccuracies involved in obtaining the number fraction than in obtaining the length fraction from EBSD maps, therefore the length fraction should be recommended as the standard reporting method. However a knowledge of the distribution in the microstructure of 3 ⁿ segments is often crucial to the inquiry in addition to the length fraction.     

Quantum Hamiltonian for the Rigid Rotator

An excess term exists when using hermitian form of Cartesian momentum p _i (i = 1,2,3) in usual kinetic energy 1/(2) p ² _i for the rigid rotator, and the correct kinetic energy turns to be 1/(2) (1/f _i ) p _i f _i p _i where f _i are dummy factors in classical mechanics and nontrivial in quantum mechanics.