Kinetic theory of adsorption and desorption

In this paper we use stochastic methods to discuss adsorption and desorption. The paper derives generalized coefficients of sticking and accomodation depending on surface temperatureT _s and gas temperatureT _g and shows, that for additive Markov processes, these kinetic coefficients are identical. Furthermore, exact solutions of the kinetic equations for certain simple transition probabilitiesP(, ) are found and an approximation method for more complicatedP(, ) is given. The comparison of the theory with experimental results for noble gas-metal systems indicate a quadratic relationship between the first moment of the transition probabilityP(, ) and the well depth of the physisorption system.     

Static and dynamic properties of XY systems with extended defects in cubic anisotropic crystallines

Static and dynamic critical behavior ofXY systems in cubic anisotropic crystallines, with extended defects (or quenched nonmagnetic impurities) strongly correlated along _d -dimensional space and randomly distributed ind – _d dimensions, were studied. These extended defects make the systems coordinate anisotropic, resulting in unique critical behavior due to competition between the cubic anisotropy and the coordinate anisotropy. The systems were analyzed by an ^1/2 (4 – d) type of expansion with double expansion parameters based on a renormalization-group (RG) approach. Critical exponents were calculated near the second-order phase transition point and the behavior of the first-order transition was evaluated near the tricritical point.     

Lattice and continuum wavelets and the block renormalization group

We obtain a resolution of the identity operator, for functions on a latticeZ ^d, which is derived from the block renormalization group. We use eigenfunctions of the terms of the decomposition to form a basis forl ₂(Z^d) and show how the basis is generated from lattice wavelets. The lattice spacing is taken to zero and continuum wavelets are obtained.     

Kinetic limits of the HPP cellular automaton

We study the Boltzmann-Grad limit in various versions of the two-dimensional HPP cellular automaton. In the completely deterministic case we prove convergence to an evolution that is not of kinetic type, a well-known phenomenon after Uchyiama's paper on the Broadwell gas, whereas the limiting equation becomes of kinetic type in the model with random collisions. The main part of the paper concerns the case where the collisions are deterministic and the randomness comes from inserting, between any two successive HPP updatings, ^- stirring updatings, <1 being any fixed positive number and a parameter which tends to 0. The initial measure is a product measure with average occupation numbers of the order of (low-density limit) and varying on distances of the order of ^–1. The limit as 0 of the system evolved for times of the order of ^-1- corresponds to the Boltzmann-Grad limit. We prove propagation of chaos and that the renormalized average occupation numbers (i.e., divided by) converge to the solution of the Broadwell equation. Convergence is proven at all times for which the solution of the Broadwell equation is bounded.     

Natural boundaries for area-preserving twist maps

We consider KAM invariant curves for generalizations of the standard map of the form (x, y)=(x+y, y+f(x)), wheref(x) is an odd trigonometric polynomial. We study numerically their analytic properties by a Padé approximant method applied to the function which conjugates the dynamics to a rotation +. In the complex plane, natural boundaries of different shapes are found. In the complex plane the analyticity region appears to be a strip bounded by a natural boundary, whose width tends linearly to 0 as tends to the critical value.     

A limit theorem for stochastic acceleration

We consider the motion of a particle in a weak mean zero random force fieldF, which depends on the position,x(t), and the velocity,v(t)= (t). The equation of motion is (t)=F(x(t),v(t), ), wherex(·) andv(·) take values in ^d ,d3, and ranges over some probability space. We show, under suitable mixing and moment conditions onF, that as 0,v (t)v(t/²) converges weakly to a diffusion Markov processv(t), and ² x (t) converges weakly to , wherex=lim ² x (0).     

P-polarized nonlinear surface polaritons near the surface of a saturable self-defocusing medium: Threshold case

We have obtained the solution of the stationary problem for P-polarized nonlinear surface polaritons (NLSP) near the interface of two media, one of which is optically linear and the other having an optical nonlinearity with saturation and a dielectric function of the form: =_xx=_zz=₀+a|E|²/(1+b|E|²), where E is the amplitude of the electric field. On this basis the NLSP energy and propagation properties, the polarization structure and the localization depth of the NLSP field as well as the physically allowed region in the parameter space have been investigated for the case in which the parameter ₀ is positive, b is non-negative, and a and ₁ are negative (₁ is the dielectric function of the linear medium); ₀>|₁|.     

Finite size critical behavior for Dirichlet boundary conditions

The behavior, near the upper critical dimensiond=4, of finite size properties at bulk criticality forn-vector models is shown to dependqualitatively on the type of boundary condition (bc). Contrary to the more complicated behavior which holds for periodic bc's, there exists an =4–d expansion for Dirichlet (or free) bc's with only integer powers in . Several universal finite size amplitude ratios are calculated for systems with Dirichlet bc's and spherical shape. This concerns ratios at bulk criticality as well as ratios related to the crossover into the region above the bulk critical temperature where the bulk correlation length is small compared to the diameter of the system and where the same simple type of -expansion holds. The general finite size scaling form of the free energy for Dirichlet bc's is compared with conjectures by Privman and Fisher.     

Effective Dynamics for Bloch Electrons: Peierls Substitution and Beyond

We consider an electron moving in a periodic potential and subject to an additional slowly varying external electrostatic potential, (x), and vector potential A(x), with x ^d and 1. We prove that associated to an isolated family of Bloch bands there exists an almost invariant subspace of L ² ( ^d ) and an effective Hamiltonian governing the evolution inside this subspace to all orders in . To leading order the effective Hamiltonian is given through the Peierls substitution. We explicitly compute the first order correction. From a semiclassical analysis of this effective quantum Hamiltonian we establish the first order correction to the standard semiclassical model of solid state physics.     

Retardation of electromagnetic waves by helices of large diameters

This paper is devoted to the study of the wave retardation by helices of large diameters, when the lengthL of one turn of the helix is larger than the vacuum wavelength, i.e.L/>1. The dispersion equation of the tape helix wound up on a dielectric cylinder was derived and the dependence of the phase velocity of slowed-down waves on the diameter of helix was calculated. The theory was verified experimentally at a frequencyf=2·385 GHz. Helices were wound up on polyfoam (=1·04) and plexiglass (=2·55) cylinders of various diameters. For the helix wound up on plexiglass cylinders it was found that the wave retardation depends on the form of conductor from which the helix is made. The retardation of waves is determined by an effective dielectric constant _ef which is equal either ( _i + _e)/2 for the tape helix or ( _{i e}) for the helix made from a wire of the circular cross-section; here _i is the dielectric constant of inner dielectric rod and _e is that of outer space.     

Spectral behavior of quasi periodic potentials

Spectral properties of Schrödinger operators of the typeH =–+V, where is the Laplacian,V a quasiperiodic potential and a coupling constant, are developed.V is taken to be finite sum of exponentials with generic frequencies. For small a strong stability is shown. On the other hand, examples (in the finite diffeence case) are given, for which a transition in the type of spectrum occurs, as is increased.Research supported in part by grant NSF MCS 7900813     

Boltzmann–Grad Limits for Stochastic Hard Sphere Models

We study a d-dimensional stochastic particle system in which the particles travel deterministically in between stochastic collisions. The collisions are elastic and occur with a probability of order when two particles are at a distance less than . When the number of particles N goes to infinity and Nd^+–1 goes to a nonzero constant, we show that the particle density converges to a solution of the Boltzmann equation provided that d+1.Research supported in part by NSF Grant DMS-00-72666.     

Simulation calculation of dielectric constants: Comparison of methods on an exactly solvable model

A mean spherical model of classical dipoles on a simple cubic lattice of sideM=2N+1 sites is considered. Exact results are obtained for finite systems using periodic boundary conditions with an external dielectric constant and using reaction field boundary conditions with a cutoff radiusR _c N and an external dielectric constant. The dielectric constant in the disordered phase is calculated using a variety of fluctuation formulas commonly implemented in Monte Carlo and molecular dynamics simulations of dipolar systems. The coupling in the system is measured by the parametery=4 ²/9kT, where ² is the fixed mean square value of the dipole moments on the lattice. The system undergoes a phase transition aty2.8, so that very high dielectric constants cannot be obtained in the disordered phase. The results show clearly the effects of system size, cutoff radius, external dielectric constant, and different measuring techniques on a dielectric constant estimate. It is concluded that with periodic boundary conditions, the rate of approach of the dielectric constant estimate to its thermodynamic limit is asN ^–2/3 and depends only weakly on. Methods of implementing reaction field boundary conditions to give rapid convergence to the thermodynamic limit are discussed.     

The Statistics of the Trajectory of a Certain Billiard in a Flat Two-Torus

We consider a billiard in the punctured torus obtained by removing a small disk of radius >0 from the flat torus ², with trajectory starting from the center of the puncture. In this case the phase space is given by the range of the velocity only. Let (), and respectively R(), denote the first exit time (length of the trajectory), and respectively the number of collisions with the side cushions when ² is being identified with [0,1)². We prove that the probability measures on [0, ) associated with the random variables and R are weakly convergent as 0⁺ and explicitly compute the densities of the limits. Research partially supported by ANSTI grant C6189/2000.     

Asymptotic theory of multidimensional chaos

A delay-differential equationu(t)+u(t)=f(u(t–1)), 0t < , and its generalization are investigated in the limit 0, when the attractor's dimension increases infinitely. It is shown that a number of statistical characteristics are asymptotically independent of. As for the attractor, it can be regarded as a direct product ofO(1/) equivalent subattractors, their statistical characteristics being asymptotically independent of . The results enable one to predict some characteristics of the attractor with fractal dimensionD 1 for the case 1, when they are inaccessible numerically. The approach developed seems to be applicable for a wide class of spatiotemporal systems.     

An investigation of finite-size scaling for systems with long-range interaction: The spherical model

A method is suggested for the derivation of finite-size corrections in the thermodynamic functions of systems with pair interaction potential decaying at large distancesr asr ^{–d –} , whered is the space dimensionality and>0. It allows for a unified treatment of short-range (=2) and long-range (<2) interaction. The asymptotic analysis is illustrated by the mean spherical model of general geometryL ^d–d× ^d subject to periodic boundary conditions. The Fisher-Privman equation of state is generalized to arbitrary real values ofd, 0d. It is shown that the-expansion may be used to study the breakdown of standard finite-size scaling at the borderline dimensionalities.     

Equation of state and dynamical properties near the Yang-Lee edge singularity

Statics and dynamics of the Yang-Lee edge singularity are investigated by field theoretic renormalization group techniques. Exploiting a continuous symmetry under a shift of the order parameter we calculate the static critical exponent to order ²=(6–d)², in accordance with previous results; in addition, we derive the equation of state and its asymptotic behaviour. The dynamic scaling exponentz is calculated to order ² from a purely relaxational model with non-conserved order parameter; joining the -expansion to an exact result ford=0 in a [2/1] Padè approximant we estimatez=1.81 ford=3.     

Effect of quenching temperature on the components of the permeability tensor and the complex dielectric constant of microwave magnesium ferrites

We report an investigation of the effect of the quenching temperature (from 900 °C, 700 °C, and for self-cooling) on the components of the permeability tensor and on the complex dielectric constant * of magnesium-aluminum, magnesium-chromium and magnesium-manganese, ferrites of fixed composition. The measuring apparatus and measurement procedure are described and an estimate of the errors is given. It is shown that due to quenching the gyrotropic properties of the ferrites are increased ( falls and _a increases), while the dielectric constant is unchanged. Quenching leads to an increase in the magnetic and dielectric losses.Translated from Izvestiya VUZ. Fizika, Vol. 11, No. 11, pp. 41–47, November, 1968.     

One-dimensional harmonic lattice caricature of hydrodynamics

We derive the hydrodynamic (Euler) approximation for the harmonic time evolution of infinite classical oscillator system on one-dimensional lattice ¹ It is known that equilibrium (i.e., time-invariant attractive) states for this model are translationally invariant Gaussian ones, with the mean 0, which satisfy some linear relations involving the interaction quadratic form. The natural parameter characterizing equilibrium states is the spectral density matrix function (SDMF)F(), [– , ). Time evolution of a space profile of local equilibrium parameters is described by a space-time SDMFF(t;x, ) t, xR ¹. The hydrodynamic equation forF(t; x, ) which we derive in this paper means that the normal mode profiles indexed by are moving according to linear laws and are mutually independent. The procedure of deriving the hydrodynamic equation is the following: We fix an initial SDMF profileF(x, ) and a familyP ,>0 of mean 0 states which satisfy the two conditions imposed on the covariance of spins at various lattice points: (a) the covariance at points close to the value ^–1 x in the stateP is approximately described by the SDMFF(x, ); (b) The covariance (on large distances) decreases with distance quickly enough and uniformly in. Given nonzerotR ¹, we consider the states P _–1 ,>0, describing the system at the time moments ^–1 t during its harmonic time evolution. We check that the covariance at lattice points close to ^–1 x in the state P _–1 is approximately described by a SDMFF(t;x, ) and establish the connection betweenF(t; x, ) andF(x,).     

An upgraded analysis of ɛ′/ɛ at the next-to-leading order

An upgraded analysis of ,x _d and /, using the latest determinations of the relevant experimental and theoretical parameters, is presented. Using the recent determination of the top quark mass,m _t =(174±17) GeV, our best estimate is /=(3.1±2.5)×10^–, which lies in the range given by E731. We describe our detemination of / and make a comparison with other similar studies. A detailed discussion of the matching of the full theory to the effective Hamiltonian, written in terms of lattice operators, is also given.