Multibubble sonoluminescence pulses from Na atoms in viscous liquid

Multibubble sonoluminescence pulses of Na and continuum emissions were measured from NaCl-ethylene glycol solution saturated with Xe at 28 kHz. The Na emission consisted of multiple-peak pulses and single pulses. The intrinsic pulse width estimated from single pulses was 0.37 ns, which differs from 10-165 ns obtained by previous work. High-speed shadowgraphs of bubble dynamics and high-speed movies (32000 fps) of sonoluminescence were observed. The observations suggest that the multiple-peak pulse is due to the superposition of single peaks resulting from bubbles fragmented from a characteristic bubble which repeats the fragmentation and coalescence. This phenomenon may be specific to viscous liquids.     

Water temperature dependence of single bubble sonoluminescence threshold

Water temperature dependence of single bubble sonoluminescence (SBSL) threshold has been experimentally measured to perform measurements at different temperatures on the very same bubble. Results show lower thresholds, i.e. an easier prime of mechanism, of sonoluminescence at lower water temperatures. Dependence is almost linear at lower temperatures while between 14 °C and about 20 °C the curve changes its slope reaching soon a virtual independence from water temperature above about 20 °C.     

Flow effects on phenol degradation and sonoluminescence at different ultrasonic frequencies

Current literature shows a direct correlation between the sonochemical (SC) process of iodide oxidation and the degradation of phenol solution. This implies phenol degradation occurs primarily via oxidisation at the bubble surface. There is no work at present which considers the effect of fluid flow on the degradation process. In this work, parametric analysis of the degradation of 0.1 mM phenol solution and iodide dosimetry under flow conditions was undertaken to determine the effect of flow. Frequencies of 44, 300 and 1000 kHz and flow rates of 0, 24, 228 and 626 mL/min were applied with variation of power input, air concentration, and surface stabilisation. Phenol degradation was analysed using the 4-aminoantipyrine (4-AAP) method, and sonoluminescence (SL) images were evaluated for 0.1, 20 and 60 mM phenol solutions. Flow, at all frequencies under certain conditions, could augment phenol degradation. At 300 kHz there was excellent correlation between phenol degradation and dosimetry indicating a SC process, here flow acted to increase bubble transience, fragmentation and radical transfer to solution. At 300 kHz, although oxidation is the primary phenol degradation mechanism, it is limited, attributed to degradation intermediates which reduce OH radical availability and bubble collapse intensity. For 44 and 1000 kHz there was poor correlation between the two SC processes. At 44 kHz (0.01 mM), there was little to suggest high levels of intermediate production, therefore it was theorised that under more transient bubble conditions additional pyrolytic degradation occurs inside the bubbles via diffusion/nanodroplet injection mechanisms. At 1000 kHz, phenol degradation was maximised above all other systems attributed to increased numbers of active bubbles combined with the nature of the ultrasonic field. SL quenching, by phenol, was reduced in flow systems for the 20 and 60 mM phenol solutions. Here, where the standing wave field was reinforced, and bubble localisation increased, flow and the intrinsic properties of phenol acted to reduce coalescence/clustering. Further, at these higher concentrations, and in flow conditions, the accumulation of volatile phenol degradation products inside the bubbles are likely reduced leading to an increase SL.     

Influence of bulk nanobubble concentration on the intensity of sonoluminescence

The present study mainly examined the effects of the volumetric concentration of nanobubbles (ultrafine bubbles) on the intensity of sonoluminescence (SL). The addition of nanobubbles at high acoustic amplitude enhanced the SL intensity for various bubble concentrations in comparison with that in pure water. This probably means that the resulting high amplitude is over the Blake threshold, and accordingly nanobubbles expand to some extent, leading to higher SL intensity. Therefore, nanobubbles have the potential to provide nucleation sites for sonochemistry. The influence of bubble size on the intensity of SL was also evaluated.     

利用声致发光成像技术的液体中超声场动态分布的实时测量方法

根据超声空化原理,运用声致发光成像技术测量超声在液体中的动态分布。利用高灵敏度的ICCD成像系统记录水在超声作用下的声致发光图像,并且分析了声致发光的分布和强度与作用超声的关系。结果表明,超声作用下的发光图像能够反映该作用超声在水中的分布情况,从而提出利用声致发光成像技术测量液体中超声场的分布是一种动态测量声场强度的新方法。     

Critical properties of binary liquid mixtures at different temperature modes

The coexistence curves (CC) of two binary mixtures, methanol-heptane (M-H) and perfluorodekaline-heptan (PFD-H), are measured for two temperature modes, namely heating and cooling. Distinctions in the behavior of the two systems in different temperature modes are revealed. For the M-H system this is likely to be attributed to the effects of surface processes and for the PFD-H systems, to the formation of colloidal structures. An additional signal related to the contribution of a meniscal layer is found and measured.     

HCl vibrational fundamental band: Line intensities and temperature dependence of self-broadening coefficients

Self-broadening in the vibrational fundamental of HCl is inversely proportional to the temperature for transitions which lie near the Boltzmann rotational maximum and becomes monotonically less temperature-dependent as the rotational quantum number increases. We have determined the rotationless transition moment to have the value of 5.57 ± 0.13 × 10^?3 (Debye)² and the first Herman-Wallis factor, C = ?2.543 ± 0.019 × 10^?2.     

The temperature and light intensity dependence of photorefraction in LiNbO3

In the paper the dependence of the photorefraction (PhR) in LiNbO₃ and LiNbO₃−Fe (0.1 wt%, 0.3wt%) crystals on light intensity (within 10¹⁶–10²³ quanta·cm⁻²·s⁻¹ at wavelengths 496.5 nm and 600 nm) and temperature (in the region 100–500 K) is studied. For all the crystals the limiting values of PhR are similar and atT=293 K Δn _sat ^lim ≈3·10⁻³. In LiNbO₃ the temperature dependence of PhR in the range 100–500 K requires to take into account at least two trapping centres.     

Application of high intensity air-borne ultrasound for debubbling liquid coating layers

In the coating processes, the formation of bubbles and microbubbles is relatively frequent inside the coating layer. Such bubbles, which are formed as a consequence of air retention, are difficult to remove and specifically in high-speed (quick-drying) industrial application where they cause permanent imperfections in the homogeneity of the layer. High-intensity air-borne ultrasound may represent a clean means to improve homogenization by quickly breaking the bubbles just when they are formed inside the coating film. This paper deals with the direct application of air-borne high-intensity ultrasonic radiation at a frequency of about 21 kHz over coating layers just immediately they have been deposited over wood substrates. Such novel process has been implemented and experimentally studied at laboratory and semi-industrial stages.     

基于电阻抗层析成像的高强度聚焦超声温度监测技术

作为一种对正常组织无损伤且不易引起癌细胞转移的非入侵肿瘤治疗手段,高强度聚焦超声(HIFU)治疗过程中焦域的温度监测是实现剂量精准控制的关键.本文基于生物组织的温度-电阻抗的关系,将电阻抗层析成像(EIT)和HIFU治疗相结合,提出了一种利用组织焦平面的表面电压实现电阻抗重构的检测技术.建立了HIFU治疗和EIT综合系统模型,在考虑组织的声吸收条件下,对三维Helmholtz方程在柱坐标下的声场计算进行了二维简化,并引入Pennes生物热传导方程来计算HIFU焦域的声压和温升分布特性;引入生物组织的温度-电阻抗关系,基于麦克斯韦电磁场理论,建立了具有温度分布HIFU焦域的电流和电压计算模型,利用恒流注入的边界条件实现电场计算,获得焦平面的表面电压分布.在数值计算中,利用实验聚焦换能器参数,模拟了在固定声功率下组织焦域的声场和温度场分布,以及中心和偏心聚焦条件下不同治疗时刻的电导率分布;然后通过对称电极的循环电流注入,计算了组织模型焦平面内的电流密度和电势分布,获得了焦平面圆周分布的表面电极电压;进一步采用修正的牛顿-拉夫逊算法,利用32×32的表面电极电压实现了焦平面内电导率分布的重建.结果表明,基于温度-电阻抗关系的EIT电导率重建技术不但能准确定位HIFU焦域中心,还能恢复HIFU治疗中焦域的温度分布,证明了EIT用于HIFU治疗中温度监测的可行性,为其疗效评估和剂量控制提供了一种无创电阻抗测量和成像新方法.     

Polymer electrolyte fuel cell performance degradation at different synchrotron beam intensities

The degradation of cell performance of polymer electrolyte fuel cells under monochromatic X‐ray irradiation at 13.5 keV was studied in galvanostatic and potentiostatic operation modes in a through‐plane imaging direction over a range of two orders of magnitude beam intensity at the TOMCAT beamline of the Swiss Light Source. The performance degradation was found to be a function of X‐ray dose and independent of beam intensity, whereas the degradation rate correlates with beam intensity. The cell performance was more sensitive to X‐ray irradiation at higher temperature and gas feed humidity. High‐frequency resistance measurements and the analysis of product water allow conclusions to be drawn on the dominating degradation processes, namely change of hydrophobicity of the electrode and sulfate contamination of the electrocatalyst.     

高强度聚焦超声间歇式治疗中焦域温度分布的仿真研究

探究不同治疗深度、组织类型和治疗模式对高强度聚焦超声焦域温度场的影响.采用有限元法建立高强度聚焦超声辐照组织的二维轴对称仿真模型,通过Westervelt方程和Pennes生物热传导方程计算高强度聚焦超声焦域的声场和温度场分布.仿真结果表明:随着治疗深度的增加,焦域内温度逐渐降低,有效温升面积减小;不同组织类型在相同条...     

Temperature measurements in plasmas generated by using lasers at different intensities

The temperature of laser-generated pulsed plasmas is an important property that depends on many parameters, such as the particle species and the time elapsed from the laser interaction with the matter and the surface characteristics.

Laser-generated plasmas with low intensity (<10¹⁰ W/cm²) at INFN-LNS of Catania and with high intensity (>10¹⁴ W/cm²) in PALS laboratory in Prague have been investigated in terms of temperatures relative to ions, electrons, and neutral species. Time-of-flight (ToF) measurements have been performed with an electrostatic ion energy analyzer (IEA) and with different Faraday cups, in order to measure the ion and electron average velocities. The IEA was also used to measure the ion energy, the ion charge state, and the ion energy distribution.

The Maxwell–Boltzmann function permitted to fit the experimental data and to extrapolate the ion temperature of the plasma core.

The velocity of the neutrals was measured with a special mass quadrupole spectrometer. The Nd:Yag laser operating at low intensity produced an ion temperature core of the order of 400 eV and a neutral temperature of the order of 100 eV for many ablated materials. The ToF of electrons indicates the presence of hot electron emission with an energy of ～1 keV.     

Experimental investigation on the ultrasonic impregnation of wood through measurements of the intensity of sonoluminescence

Ultrasonic impregnation is thought to be an effective way of permeation of liquid into material through the material-surface reforming with the attack by an ultrasonic cavitation jet or by the shock wave emitted from a collapsing bubble, or through dynamic transformation of material like a sponge. The action of a cavitation bubble can also provide penetration of liquid into the interior of the material. This paper investigates whether there is a correlation between the intensity of sonoluminescence (SL) measured at different positions and the increment in the mass of the wood material (cedar) after sonication with immersion into water in order to clarify the role of cavitation bubbles for ultrasonic impregnation. It was found that a high mass change was obtained for the material located at the position for high (the maximum) SL intensity. The number density of ultrasonic cavitation bubbles that are able to collapse leading to the emission of SL is correlated with the degree of ultrasonic impregnation.     

Interpreting the influence of liquid temperature on cavitation collapse intensity through bubble dynamic analysis

The violent collapse of inertial bubbles generates high temperature inside and emits strong impulsive pressure. Previous tests on sonoluminescence and cavitation erosion showed that the influence of liquid temperature on these two parameters is different. In this paper, we conducted a bubble dynamic analysis to explore the mechanism of the temperature effect and account for the above difference. The results show that the increase of vapor at higher liquid temperatures changes both the external compression pressure and the internal cushion and is responsible for the variation of bubble collapse intensity. The different trends of the collapsing temperature and emitted sound pressure are caused by the energy distribution during the bubble collapse. Moreover, a series of simulations are conducted to establish the distribution map of the optimum liquid temperature where the collapse intensity is maximized. The relationship between the collapse intensity and the radial dynamics of the bubble is discussed and the reliable indicator is identified. This study provides a clear picture of how the thermodynamic process changes cavitation aggressiveness and enriches the understanding of this complex thermal-hydrodynamic phenomenon.