Laser emission under flashlamp pumping of a new crystal: Nd-doped strontium-lanthanum-aluminate (Nd:ASL)

1-x Nd_yLa_x-yMg_xAl_12-xO₁₉) is a new material, tunable in the 1–1.1 μm band. We present the first results of pulsed laser emission of this crystal under flashlamp pumping. We obtain a slope efficiency of 3.3% with a maximum average power of 40 W at 40 Hz in free-lasing regime. Nd:Cr codoping of ASL is also tested, but with much lower efficiency. Received: 12 June 1998/Revised version: 30 September 1998     

Laser operation of the new stoichiometric crystal KYb(WO4)2

We demonstrate for the first time laser operation with the monoclinic stoichiometric crystal KYb(WO₄)₂ (hereafter KYbW). Lasing on the ² F _5/2 ?² F _7/2 transition of Yb³⁺ at room temperature has been achieved near 1074 nm with >41% slope efficiency (>26% maximum conversion efficiency) using a 0.5-mm-thick plate of KYbW. This new laser material holds great promise for diode-pumped high-power lasers, thin-disk and waveguide designs as well as for ultrashort (ps/fs) pulse laser systems. Received: 10 October 2001 / Revised version: 19 November 2001 / Published online: 17 January 2002     

New green self-frequency-doubling diode-pumped Nd:Ca4GdO(BO3)3 laser

3+ :Ca₄GdO(BO₃)₃ (Nd:GdCOB). 21 mW of green cw laser emission for an absorbed pump power of 820 mW were achieved under laser diode-pumping. 64 mW of green cw laser output were obtained with 1 W of absorbed pump power under titanium-sapphire pumping. Its availability in large-size crystals with good optical quality makes Nd:GdCOB a true challenger to the best SFD laser crystal reported so far: Nd:YAl₃(BO₃)₄ (Nd:YAB or NYAB). Received: 2 March 1998/Revised version: 20 May 1998     

Slope efficiency of up to 73% for Yb:Ca4YO(BO3)3 crystal laser pumped by a laser diode

Yb:Ca₄YO(BO₃)₃ (Yb:YCOB) crystal with good quality and large size has been grown by the Czochralski method. The polarization absorption and fluorescence spectra have been measured. The laser action of the Yb:YCOB crystal has been demonstrated when it is pumped by a fiber-coupled laser diode (LD) at the wavelength of 976.4 nm. The pumping threshold is 55 mW, the light-light conversion efficiency is 58.7%, and a slope efficiency of up to 73% is thus calculated. Received: 16 December 1998 / Revised version: 4 February 1999 / Published online: 7 April 1999     

Vacuum ultraviolet gain measurements in optically pumped LiYF4:Nd3+

 We present measurements of the net-induced gain on the 5d–4f transition at 186 nm in LiYF₄ : Nd³⁺ optically pumped by radiation from a molecular fluorine laser. It is found that for LiYF₄ : Nd³⁺, one of a series of potential continuously tunable VUV lasers, relatively strong excited-state absorption results in net-induced loss. The prospects for VUV laser operation being realised in other rare-earth-doped fluorides is discussed. Received: 4 March 1996/Revised version: 10 July 1996     

Crystalline structure and optical spectroscopy of Er3+-doped KGd(WO4)2 single crystals

4 )₂ single crystals doped with Er³⁺ have been grown by the flux top-seeded-solution growth method. The crystallographic structure of the lattice has been refined, being the lattice constants a=10.652(4), b=10.374(6), c=7.582(2) Å, β=130.80(2)°. The refractive index dispersion of the host has been measured in the 350–1500 nm range. The optical absorption and photoluminescence properties of Er³⁺ have been characterised in the 5–300 K temperature range. At 5 K, the absorption and emission bands show the (2J+1)/2 multiplet splittings expected for the C₂ symmetry site of Er in the Gd site. The energy positions and halfwidths of the 72 sublevels observed have been tabulated as well as the cross sections of the different multiplets. Six emission band sets have been observed under excitation of the ⁴F_7/2 multiplet. The Judd–Ofelt (JO) parameters of Er³⁺ in KGW have been calculated: Ω₂=8.90×10^-20 cm², Ω₄=0.96×10^-20 cm², Ω₆=0.82×10^-20 cm². Lifetimes of the ⁴S_3/2, ⁴F_9/2, and ⁴I_11/2 multiplets have been measured in the 5–300 K range of temperature and compared with those calculated from the JO theory. A reduction of the ⁴S_3/2 and ⁴I_11/2 measured lifetimes with increasing erbium concentration has been observed, moreover the presence of multiphonon non-radiative processes is inferred from the temperature dependence of the lifetimes. Received: 15 December 1997/Revised version: 10 July 1998     

Excited state absorption and stimulated emission of Nd3+ in crystals. Part 2: YVO4, GdVO4, and Sr5(PO4)3F

3+ ion in the crystals YVO₄, GdVO₄, and Sr₅(PO₄)₃F. The measurements were performed in the spectral region of the main laser transitions ⁴F_3/2→⁴I_9/2, ⁴F_3/2→⁴I_11/2, and ⁴F_3/2→⁴I_13/2by a continuous wave pump and probe technique. The calibrated gain and ESA spectra are presented and possible implications of ESA on the laser performance are estimated. It is shown that ESA can be a small loss factor to the laser emission near 1060 nm but does considerably diminish the effective emission cross sections near 1340 nm especially in Nd:YVO₄ and Nd:GdVO₄. Received: 29 January 1998/Revised version: 8 May 1998     

Continuous-wave tunable Cr2+:ZnS laser

We report the first continuous-wave tunable over ∼280 nm around 2.3 μm room-temperature operation of a chemical vapor transport-grown and diffusion-doped Cr²⁺:ZnS laser, pumped by a Co:MgF₂ laser at 1.67 μm and generating over 100 mW of output power at 16% slope efficiency. The self-consistent results of the laser and spectroscopic analysis demonstrate a large potential of this crystal as an active medium for diode-pumped tunable mid-infrared sources. Received: 7 January 2002 / Revised: 14 March 2002 / Published online: 2 May 2002     

Comparison of cw laser performance of Nd:KGW, Nd:YAG, Nd:BEL, and Nd:YVO4 under laser diode pumping

4 crystals under low-power laser diode end-pumping. Output power dependencies on the pump power and the pump wavelength of these diode-pumped solid state lasers were investigated. The high Nd³⁺ concentration of the Nd:KGW samples used in our measurements as well as up-conversion and exited-state absorption processes in Nd:KGW cause the reduced laser output power dependence on the pump wavelength which was experimentally observed. At pump levels up to 270 mW a slope efficiency of η_sl≈46% was reached for the Nd:KGW laser. Nd:KGW microchip laser operation with a slope efficiency of η_sl≈50% was demonstrated. Thermal lensing in Nd:KGW at pump powers up to 3 W was measured. Received: 4 August 1997     

Excited state absorption and stimulated emission of Nd3+ in crystals III: LaSc3(BO3)4, CaWO4, and YLiF4

3+ ions in CaWO₄, LaSc₃(BO₃)₄, and YLiF₄ crystals are presented. The spectra were measured by a continuous-wave pump and probe technique. It is shown that ESA is a negligible loss mechanism in cw lasers emitting at 1.06 μm. In contrast, the effective emission cross sections in Nd:CaWO₄ and Nd:LaSc₃(BO₃)₄ around 1.35 μm are considerably diminished. Received: 8 May 1998/Revised version: 7 September 1998     

Determination of the Auger upconversion rate in fiber-coupled diode end-pumped Nd:YAG and Nd:YVO4 crystals

An analytical model is developed to study the influence of the Auger upconversion process on the thermal loading under lasing and nonlasing conditions. With the developed model, Auger upconversion rates can be determined by comparing theoretical calculations with experimental results for the ratio of the thermal loading under lasing and nonlasing conditions. The upconversion rates obtained with the present method are compared with the results measured from the fluorescence decay experiment. Received: 7 June 1999 / Revised version: 3 August 1999 / Published online: 30 November 1999     

cw dual-wavelength operation of a diode-end-pumped Nd:YVO4 laser

A dual-wavelength continuous wave (cw) diode-end-pumped Nd:YVO₄ laser that generates simultaneous laser action at the wavelengths 1064 nm and 1342 nm is demonstrated. The optimum oscillation condition for the simultaneous dual-wavelength operation in a diode-end-pumped solid-state laser has been derived. The relationship between the laser cavity and the output stability is also studied. Experimental results show that the stability of the output power at the two wavelengths could be enhanced by use of a three-mirror cavity. Received: 26 August 1999 / Revised version: 11 October 1999 / Published online: 23 February 2000     

Self-starting five optical cycle pulse generation in Cr<Superscript>4+</Superscript>:YAG laser

We report stable self-starting near-transform-limited 26-fs pulses at 250-mW output power from a Kerr-lens mode-locked (KLM) Cr⁴⁺:YAG laser using chirped mirrors in combination with prisms. The highest output power achieved in KLM regime was 600 mW at 55-fs pulse duration. The experimental results agree well with the results of theoretical analysis with respect to KLM self-starting ability and stability against continuous-wave and multi-pulse operation. Parameter ranges for stable transform-limited KLM pulses as well as the shortest achievable pulse durations are established. Using an InGaAs-InP semiconductor saturable absorber mirror we could obtain self-starting 57-fs pulses at the average output power of 200 mW. Two-photon absorption was found to be the main mechanism favoring the multiple-pulse operation. Received: 2 May 2002 / Revised version: 16 July 2002 / Published online: 8 January 2003 RID="*" ID="*"Corresponding author. Fax: +43-1/58801-38799, E-mail: sorokina@tuwien.ac.at     

Laser action in a cw diode-pumped Nd:Ca3Sc2Ge3O12 crystal

CW diode-pumped laser operation of Nd³⁺ in Ca₃Sc₂Ge₃O₁₂ (CaSGG) single garnet crystal has been demonstrated for the first time. We measured an 18% slope efficiency and 2.7-nm tunability with two different laser cavities. A spectroscopic characterization of our sample has also been performed including the absorption cross section in the 800-nm region and the emission cross section and radiative lifetime of the upper laser level. Received: 7 December 1999 / Revised version: 6 February 2000 / Published online: 27 April 2000     

Efficient and highly photostable solid-state dye lasers based on modified dipyrromethene.BF2 complexes incorporated into solid matrices of poly(methyl methacrylate)

We report on the laser action of modified dipyrromethene.BF₂ complexes both dissolved in poly(methyl methacrylate) and copolymerized with methyl methacrylate. All recently synthesized dyes have the chromophore core of laser dye pyrromethene 567, differing in the substituent in position 8. The new dyes showed important and most significant increases in both lasing efficiency and photostability. When the laser samples were pumped transversely at 534 nm, laser emission was obtained with efficiencies of over 30% in most cases, to be compared with a lasing efficiency of 12% exhibited by reference dye pyrromethene 567 under the same experimental conditions. Some of the materials exhibited highly photostable laser action, with no sign of degradation in the laser output after 60000 pump pulses at the same position of the sample at a repetition rate of 10 Hz, whereas the laser emission of reference dye pyrromethene 567 dropped to zero after less than 40000 pump pulses. Received: 19 November 2002 / Revised version: 20 February 2003 / Published online: 9 April 2003 RID="*" ID="*"Corresponding author. Fax: +34-91/564-2431, E-mail: acostela@iqfr.csic.es     

Nonlinear absorption properties of Co2+:MgAl2O4 crystal

The differential absorption spectra of Co²⁺: MgAl₂O₄ (MALO) crystal were studied with a picosecond pump-probe technique under excitation of the ⁴A₂→⁴T₁(⁴P) and ⁴A₂→⁴T₁(⁴F) transitions of the tetrahedral Co²⁺ ion. The difference spectra of stimulated emission (SE) and excited state absorption (ESA) were derived from the measured differential absorption spectra. The ⁴T₁(⁴P)→⁴A₂ SE band around 660 nm was observed. The ESA bands were assigned to the ⁴T₂→⁴T₁(⁴P) transition and to transitions from the thermally populated ²E(²G) excited state to doublet levels arising from the ²F free-ion level of the tetrahedrally coordinated Co²⁺ ion. Absorption saturation measurements were performed at 1.34 μm and 1.54 μm. Passive Q-switching of 1.34-μm Nd³⁺:YAlO₃ and 1.54-μm Er³⁺:glass lasers was realized using the Co²⁺:MALO crystal as saturable absorber. The Q-switched laser pulses of 38 ns (110 ns) in duration and up to 2.7 mJ (10 mJ) in energy at 1.54 μm (1.34 μm) were obtained. Received: 3 March 1999 / Revised version: 30 June 1999 / Published online: 30 November 1999     

Type-I non-critically phase-matched second-harmonic generation in Gd1-xYxCa4O(BO3)3

Second-harmonic generation was z-cut observed Gd_1-xY_xCa₄O(BO₃)₃ (Gd_1-xY_xCOB) and the dependence of the phase-matching wavelength on the mixing ratio x has been investigated. The dependence on both temperature and angle tuning was examined as well. We found the suitable composition for noncritical frequency doubling at 930 nm, which is the lasing wavelength of Nd:YAlO₃ on the ⁴F_3/2?⁴I_9/2 transition. Received: 19 April 1999 / Published online: 5 May 1999     

Excited state absorption and stimulated emission of Nd3+ in crystals. Part I: Y3Al5O12, YAlO3, and Y2O3

4 F_3/2 excited state of the Nd³⁺ ion in Y₃Al₅O₁₂, YAlO₃, and Y₂O₃ were measured in a continuous wave pump- and probe experiment in a wide spectral range from 850 nm (780 nm for Y₃Al₅O₁₂) to 1500 nm. The cross sections were determined from a comparison with the emission spectra and the simultaneously measured ground state absorption bleaching. The strongest excited state absorption transitions were found in the 1220–1400 nm spectral region due to transitions to the ²G_9/2 and ⁴G_7/2 levels. The spectral positions of the measured transitions are in good agreement with the theoretically expected transitions calculated from the known Stark-level splittings. Received: 4 December 1997/Revised version: 8 May 1998     

Polarized spectroscopic properties of Nd-doped KGd(WO4)2 single crystal

The polarized absorption spectra, infrared fluorescence spectra, upconversion visible fluorescence spectra, and fluorescence decay curve of orientated Nd³⁺:KGd(WO₄)₂ crystal were measured at room-temperature. Some important spectroscopic parameters were investigated in detail in the framework of the Judd-Ofelt theory and the Fuchtbauer-Ladenburg formula. The effect of the crystal structure on the spectroscopic properties of the Nd³⁺ ions was analyzed. The relation among the spectroscopic parameters and the laser performances of the Nd³⁺:KGd(WO₄)₂ crystal was discussed.     

Efficient laser operation and continuous-wave diode pumping of Cr2+:ZnSe single crystals

Efficient continuous-wave laser operation of Cr²⁺:ZnSe was demonstrated with an output power of 1400 mW at an absorbed pump power of 1900 mW from a Tm:YAG laser. Under continuous-wave diode pumping at 1.54 μm an output power of 15 mW was obtained from a Cr⁺²:ZnSe laser. Excited state absorption is shown to be negligible in the pump and laser spectral region. Received: 12 October 2000 / Published online: 30 November 2000