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介绍聚合物分散液晶和应变液晶概念,给出聚合物分散液晶调光玻璃的"正压光效应"、"负压光效应"和"反式压光效应"三种效应定义.实验制备出负压光效应和反式压光效应新型应变调光玻璃样品,测试样品散射态雾度90%以上,半透明态透光率接近30%.用偏光显微术研究压光效应原理,表明对样品施加垂面按压或拉伸的应力诱导作用会引起液晶微滴中液晶分子具有某些特殊排列方式,导致样品光学性质发生显著变化.建立垂面拉伸液晶微滴模型,计算模拟所绘出的图形与偏光显微镜照片独特花样十分相似,进而合理解释了实验现象.应变液晶压光效应研究具有聚合物分散液晶基础研究意义和开发非电控调光玻璃的实际应用价值. 相似文献
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聚合物分散液晶增强散射的理想模型 总被引:7,自引:0,他引:7
介绍聚合物分散液晶技术新进展,应用光学原理对液晶微滴增强散射问题进行研究,提出液晶微滴最佳间距判据,液晶微滴间隔处聚合物材料光学厚度满足增反膜条件;提出液晶微滴最佳直径判据,液晶微滴直径满足双折射相消干涉条件;提出聚合物与液晶最佳配比的计算方法,应用晶体学原子堆积致密度知识给出最佳配比的计算结果.建立一种聚合物分散液晶增强散射的理想模型,进而从更基本的光学原理出发对异常散射理论模拟计算和实验上确定的液晶微滴最佳直径和聚合物与液晶最佳配比问题给出十分简单明确的理论解释. 相似文献
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采用激光染料DCM、向列相液晶TEB30A、手性剂S-811、聚乙烯醇(PVA), 通过微胶囊法制备了聚合物分散胆甾相液晶薄膜, 测量激光辐射谱, 研究了其激光辐射机理和温度调谐特性. 利用正交偏光显微镜观察器件织构, 看到液晶微滴分散均匀, 尺寸较大, 约为80 μm, 并且微滴中液晶分子呈现平面态排列织构. 以532 nm的Nd:YAG固体激光器作为抽运源, 测得在634.5 nm和680.2 nm波长处出现了尖锐的激光辐射峰, 线宽分别约为0.25 nm, 0.29 nm. 并与染料掺杂胆甾相液晶激光器件进行比较. 升高器件温度, 其输出激光波长蓝移, 获得666.7 nm至643.9 nm共22.8 nm的调谐范围. 由实验结果分析得出, 激光辐射机理为光子禁带末端激光, 出射波长分别对应光子禁带的两个边沿. 相似文献
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基于分子两体势,用Monte Carlo方法计算向列相液晶微滴.两体势基于格点模型,是空间各向异性的且依赖于液晶的弹性常数.假定向列相液晶微滴具有自由表面,引入切向内禀强度定量描写表面引发的分子内禀易取向的强弱.通过各向异性势的两种方案,在低温下计算切向内禀强度和二阶序参数在微滴内不同区域的变化,与Lebwohl-Lasher模型作对比分析.结果表明:只有一种方案在微滴表面产生内禀易取向,且内禀强度值的大小与K33/K11值有关;空间不完整的向列相液晶使得微滴由内层到外层有序度越来越低. 相似文献
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应变液晶散射偏光片的试制 总被引:1,自引:0,他引:1
介绍了聚合物分散液晶(PDLC)和应变液晶(SLC)以及散射偏光片的概念,实验制备了应变液晶散射偏光片样品,样品由两张胶片夹层聚合物分散液晶膜在紫外光固化过程中施加剪切应力所形成。给出了样品偏光显微镜照片和可见光分光光度计偏光特性光谱分析。实验结果表明,应变液晶散射偏光片样品外观半透明,在正交偏光场中转动样品有颜色变化,通过样品观察液晶显示器屏幕,在不同角度下有透射和散射作用,在偏光显微镜中观察样品有衬垫料被拉动的痕迹,光谱分析显示样品在绿光550nm波长处最大透光率T∥≈50%,最小透光率T⊥≈5%,偏振度P≈82%。实验结果对于研制实用的拉伸液晶散射偏光片具有参考意义。 相似文献
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剪切液晶散射偏光玻璃的研制与应用 总被引:1,自引:0,他引:1
介绍了聚合物分散液晶、剪切液晶、散射偏光片以及透明投影屏幕等概念。实验制备了剪切液晶散射偏光玻璃样品,样品由两张玻璃夹层聚合物分散液晶膜在紫外光固化过程中施加剪切应力制成。实验给出了样品偏光显微镜照片和透光率以及雾度随透光轴与入射偏振光偏振方向夹角的变化曲线。剪切液晶散射偏光玻璃外观半透明,存在透光轴。散射偏光玻璃与吸收偏光片组合具有调光窗功能,与单片液晶投影机或单片硅上液晶投影机配套还能用作背投影成像效果十分清晰的透明投影屏幕。 相似文献
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提出了把液晶波片作为电控补偿器,使用偏光显微镜的白光照射条件下测试液晶器件光程差二维分布的方法,建立了液晶器件在正交偏光下测试二维光程差分布的验证系统。使用该系统测试了液晶电控波片的光程差分布,将测试数据与传统的1/4波片法的测试结果进行了标定,误差在3%以内。在此基础上,使用上述系统完成了液晶光楔、紫外光寻址的透过式液晶空间光调制器二维光程差分布的测试,得到了二者的电控二维光程差分布规律。该方法的进一步优化,还可以用于液晶光学相控阵列的测试。研究意义在于,可以用偏光显微镜自带的白光照明系统来测试电控液晶器件在多个波长,包括近红外波段下光程差二维分布的显微结构,用于液晶光学相控阵列的驱动电压非线性校正、相位凹陷与回程区检测,还可用于液晶空间光调制器的光学寻址伽马校正等方面。 相似文献
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《Current Applied Physics》2015,15(3):292-297
Polymer dispersed liquid crystal was synthesized by combining a UV curable polymer and a nematic liquid crystal. Optimized conditions for the optical properties of the PDLC were found to be the concentration ratio of LC and polymer at 7:3, UV curing time of 18 min, and the thickness less than 25 μm. In the case of the high LC concentration (≥70%) sample, the amount of liquid crystal segregated in the polymerization process was enough to form a spherical shape of droplet, and the threshold driving voltage was reduced. The response time for the turn-on process was nearly independent of the concentration, while the turn-off process was almost proportional to the concentration. From microscopic image and UV–visible spectrum analysis, the relation between LC droplet morphology and optical properties were explained. 相似文献
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H. Stark J. Stelzer R. Bernhard 《The European Physical Journal B - Condensed Matter and Complex Systems》1999,10(3):515-523
Recently, it was observed that water droplets suspended in a nematic liquid crystal form linear chains [Poulin et al., Science 275, 1770 (1997)]. The chaining occurs, e.g., in a large nematic drop with homeotropic boundary conditions at all the surfaces. Between each pair of water droplets a
point defect in the liquid crystalline order was found in accordance with topological constraints. This point defect causes
a repulsion between the water droplets. In our numerical investigation we limit ourselves to a chain of two droplets. For
such a complex geometry we use the method of finite elements to minimize the Frank free energy. We confirm an experimental
observation that the distance d of the point defect from the surface of a water droplet scales with the radius r of the droplet like .When the water droplets are moved apart, we find that the point defect does not stay in the middle between the droplets,
but rather forms a dipole with one of them. This confirms a theoretical model for the chaining. Analogies to a second order
phase transition are drawn. We also find the dipole when one water droplet is suspended in a bipolar nematic drop with two
boojums, i.e., surface defects at the outer boundary. Finally, we present a configuration where two droplets repel each other without a
defect between them.
Received 11 December 1998 相似文献
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提高液晶波前校正器的响应速度是增加液晶自适应光学系统校正带宽的关键, 而研究设计低旋转黏度的液晶分子是提高液晶波前校正器响应速度的根本方法. 利用原子水平上的分子动力学方法获得了目标分子的液相、向列相以及近晶相, 给出了理论计算液晶分子序参数以及旋转黏度的方法. 与此同时, 结合实验方法, 提出利用混合液晶分子动力学模拟来比较液晶分子旋转黏度的大小, 通过多次模拟、多起始点数据处理最大限度消除了因边界尺寸效应带来的数据波动, 最后给出了两种高性能液晶分子的具体比较结果. 这种分子动力学模拟方法能够探查分子结构细微差别对液晶相态以及旋转黏度的影响, 为设计低旋转黏度的液晶分子提供了理论支持, 必将为快速响应液晶材料的设计提供帮助. 相似文献
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针对蓝相液晶显示器中的暗态漏光特性, 采用时域有限差分方法模拟计算了胆甾相液晶的平面态和焦锥态以及蓝相II态液晶的透射和反射特性, 得到了它们在正交和平行偏振片之间的漏光, 并提出了计算等效旋光能力的公式以比较它们的旋光能力. 通过对比焦锥态和蓝相液晶的旋光能力和漏光特性发现, 采用焦锥态替代蓝相液晶而得到良好的暗态特性是一种可行的方法. 通过研究它们的布拉格反射特性, 得知蓝相液晶的布拉格反射与平面态相似, 但反射强度小, 焦锥态无明显的布拉格反射特性. 相似文献
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二元光学液晶闪耀光栅的特性分析 总被引:11,自引:2,他引:9
在二元光学理论的基础上,结合波动光学理论和液晶指向矢的计算提出一种新的二元光学液晶闪耀光栅设计.对液晶光栅电极施加阶梯分布的电压使之形成相位阶梯形分布,推导出液晶闪耀光栅的衍射效率.结果表明,通过改变周期单元光栅电极数日而改变光栅常数,可以改变光衍射角度,一级衍射角度调节范围0°~10°;调节电极电压可以使特定级次衍射光效率达到90%以上,使该级次得到闪耀. 相似文献
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本文利用向列相液晶层作为激光偏振调控单元,涂覆于垂直腔面发射激光器(VCSEL)表面,测量并分析了不同温度下VCSEL正交线偏振光的阈值电流、峰值光功率和I-P特性. 实验结果表明:温度为293 K时,涂覆液晶后激光偏振第一跳变点和第二跳变点之间的电流值ΔI增大了2.2 mA,比无液晶时增大1倍. 温度为313 K、注入电流为3 mA时,两种正交线偏振光的光功率差ΔP由133.6 μW增大到248.8 μW,进一步增加了线偏振光的各向异性. 表面液晶层的引入有效地扩大了VCSEL的正交线偏振态稳定范围和光功率差,为实现液晶VCSEL高温单偏振稳定的设计和器件制备提供了理论和实验基础.
关键词:
垂直腔面发射激光器
向列相液晶
偏振态 相似文献
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A NEW METHOD TO ALIGN LIQUID CRYSTAL MOLECULES BY LINEAR PHOTO-POLYMERIZATION FOR LIQUID CRYSTAL DISPLAY
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A new technique to uniformly align liquid crystal molecules is presented. The technique is based on producing an anisotropic surface on the glass substrate coated with photo-polymers by photo-polymerization of linear polarized UV-light. The orientation of liquid crystal molecules is governed by the direction of the polarized vector of UV-light. Using this method, we have studied the photo-polymer PSi-CM aligning LC 6710A molecules. The liquid crystal microscopic texture between crossed polarizers, optical retardation from liquid crystal layers and electro-optical properties of twisted nematic liquid crystal display cell are obtained, which was prepared with one side -photo-alignment and the other side-rebbed substrate. 相似文献
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The formation of regular colloid patterns in free-standing smectic films at the transition from the smectic-C to the isotropic
or nematic phase is well known experimentally. The self-organization of isotropic or nematic droplets is caused by their mutual
interaction, mediated by elastic distortions of the local director in the surrounding liquid crystal. These distortions are
related to the anchoring conditions of the director at the droplet border. We describe analytically the energetics of the
liquid crystal environment of a single droplet in one-constant approximation. A method of complex analysis, Conformal Mapping,
is employed. Following a suggestion of Dolganov et al. (Phys. Rev. E. 73, 041706 (2006)), energetics of chain and grid patterns built from the colloids are investigated numerically in order to explain
experimentally observed formations and their director fields. 相似文献