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含碲唑杂环部花青的合成 总被引:2,自引:0,他引:2
含碲唑杂环部花青的合成罗学红,刘秀芳,徐汉生(武汉大学化学系,430072)部花青(又称份菁,merocyanines)是一类重要的功能染料。它不仅可以作为感蓝或感绿的光谱增感剂应用于照相化学领域 ̄[1],也可作为光盘染料用于其它信息记录 ̄[2]。这... 相似文献
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李可及 《理化检验(化学分册)》2020,56(2):236-239
作为重要的"三稀"矿产资源,碲在半导体制冷、特种合金、薄膜太阳能电池等领域有着不可替代的作用[1],四川石棉大水沟碲铋硫铁矿是迄今为止有报道的唯一碲原生独立矿床[2]。然而,由于此类矿床的稀缺性,相关分析方法研究尚少[2-3],当前对岩矿、化工样品中高含量碲的测定或采用重量法(YS/T 1227.1-2018《粗碲化学分析方法第1部分:碲量的测定重量法》)或酸溶后稀释测定,铋则采用容量法(GB/T 15926-2010《铋矿石化学分析方法铋量测定》),前处理方法难以统一,影响分析效率。 相似文献
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沉淀分离ICP-AES法测定高纯阴极铜中铅铋碲 总被引:7,自引:0,他引:7
研究了用虱氧化铁共沉淀分离富集高纯阴极铜中铅、铋和碲的最佳条件与ICP-AES法的最佳工作条件。在选定的最佳条件下测铅、铋和碲的检出限分别为0.0034,0.013和0.0077μg·ml-1,回收率分别为97.8%-100.8%、95.5%-106.5%和98.5-100.5%。测定高纯阴极铜中铅、铋和碲,结果满意。 相似文献
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本文对富碲铋矿中碲铋的分离条件进行了详细研究。在pH8~12范围内,当Fe>10mg时,Te、Bi与Fe共沉淀完全而与其它杂质元素分离,沉淀用10%KOH溶解Te而与Bi、Fe分离,溶液经酸化后用K2Cr2O7法滴定Te。平行测定10次碲铋矿粉和矿渣,RSD为1.07%。 相似文献
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Nafion修饰金电极阳极溶出伏安法测定痕量碲 总被引:4,自引:0,他引:4
本文用Nafion修饰金盘电极,在0.04mol/LLiCl和PH2的H2SO4底液中,阳极溶出伏安法测定痕量碲,研究了富集溶出过程的特性和优化条件,碲浓度在0.2-15ng/mL范围内与溶出峰电流呈良好的线性关系。本法灵敏度高,选择性好,用于测定小麦粉和玉米粉中痕量碲,测定标准偏差小于0.07μg/g,与ICP测定结果比较其相对误差小于16%。 相似文献
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1990年Kratschmer[1,2]等人实现了C60和C70的宏观量制备后,有关fullerene的化学研究迅速展开[3-5].业已发现C60具有极为丰富的化学性质.在对C60化学性质的认识过程中,气相离子化学一直起着重要的作用[6].Roth等人[7]在ICR质谱仪中,制得了C60外部键合金属的衍生物C60M+;Caldwell及合作者[8]在质谱仪上,利用高动能的C60与轻气体(He,Ne,H2,D2)碰撞,得到了笼内包含轻气体原子的C60;Bohme[9,10]等人在流动后辉光质谱仪上,系统地研究了C60的单、双、三电荷离子与多种有机物的反应,获得了相应的C60加合… 相似文献
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用溶胶-凝胶法以磷钼酸(MPA)的镍盐溶液水解钛酸四丁酯制备了NiPMo/TiO2催化剂.使用ICP、 XRD、 TG-DTA、 IR、 TPD-MS和微反应技术研究了催化剂的化学组成、热稳定性、化学吸附性质和催化反应性能.杂多钼酸盐与TiO2通过O2-在TiO2表面发生了键合.在623 K下,杂多阴离子仍保持原有的Keggin结构.CO2在Lewis酸位Ni(Ⅱ)和Lewis碱位Ni-O-Mo的桥氧协同作用下生成CO2卧式吸附态Ni(Ⅱ)←O-(CO)←(O--Ni).丙烯有多种吸附态在催化剂上吸附.在563 K、 1 MPa和空速1500 h-1的反应条件下,丙烯的摩尔转化率为3.2%,产物MAA选择性为95%. 相似文献
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Different approaches for the synthesis of 1-benzyloxypyrazin-2(1H)-one derivatives from simple amino acids have been investigated. A library of 33 precursors for the preparation of N-hydroxy pyrazinones was obtained in moderate to good yields. 相似文献
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Toward new camptothecins. Part 6: Synthesis of crucial ketones and their use in Friedländer reaction
Laurent Gavara Thomas Boisse Jean-Pierre Hénichart Adam Daïch Philippe Gautret 《Tetrahedron》2010,66(38):7544-5571
In the context of the preparation of camptothecin and luotonin A analogs, the synthesis of some key keto-precursors and their use in Friedländer condensation are described. This paper also focuses on the stability of these keto intermediates and emphasizes the major differences between indolizinones and pyrroloquinazolinones series. Noteworthy is also the report of some original structures isolated as by-products of some experiments. 相似文献
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The Langevin paramagnetic theory can’t describe the relation between magnetization of ferrofluids and applied magnetic field. The structuralization of ferrofluids, which is considered the main influence factor of the magnetization, is regarded. The part of magnetization works is deposited when the structure is forming. This action influences the magnetization of ferrofluids directly or indirectly. On the base of the “compressing” model, the Langevin function that usually describes the magnetization of ferrofluid is modified, and a well-fitted curve is obtained. An equation of the relation between the equivalent volume fraction after being “compressed” and the intensity of magnetic field is discovered, which approximately describes the process of magnetization. The relation between the approximate initial susceptibility and the volume fraction can be obtained from modified formula. 相似文献
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Rebecca J. Burton Mandy L. CrowtherNeal J. Fazakerley Shaun M. FilleryBarry M. Hayter Jason G. KettleCaroline A. McMillan Paula PerkinsPeter Robins Peter M. SmithEmma J. Williams Gail L. Wrigley 《Tetrahedron letters》2013
The highly regioselective Buchwald–Hartwig amination at C-2 of the cheap and readily accessible reagent, 2,4-dichloropyridine with a range of anilines and heterocyclic amines is described. This new methodology is robust and provides a facile access to 4-chloro-N-phenylpyridin-2-amines on 0.25 mol scale. These intermediates undergo a further Buchwald–Hartwig amination at higher temperature to enable rapid exploration of the chemical space at C-4 and to provide a library of 2,4-bisaminopyridines. 相似文献
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KMnO4-mediated oxidative CN bond cleavage of tertiary amines producing secondary amine was introduced, which was trapped by electrophiles (acyl chloride and sulfonyl chloride) to form amides and sulfonamides. The reaction could take place at mild condition, tolerating a wide range of function groups and affording products in moderate to excellent yields. 相似文献
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N. A. Nedolya 《Chemistry of Heterocyclic Compounds》2008,44(10):1165-1219
The review contains a concise historical account and information on the most significant researches undertaken by the staff
at the A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences on the Chemistry
of Heterocyclic Compounds.
Dedicated to Academician of the Russian Academy of Sciences B. A. Trofimov on his 70th jubilee.
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 10, pp. 1443–1502, October, 2008. 相似文献
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A general synthesis of previously unknown semicarbazone-based α-amidoalkylating reagents, 4-(tosylmethyl)semicarbazones, has been developed. The synthesis involved three-component condensation of semicarbazones of aliphatic or aromatic aldehydes with the same or other aldehydes and p-toluenesulfinic acid. The scope and limitations of this reaction were investigated. The compounds obtained were demonstrated to be an efficient α-(4-semicarbazono)alkylating agents. They were reacted with H- (sodium borohydride), O- (sodium methylate), S- (sodium phenylthiolate), N- (pyrrolidine, sodium succinimide), P- (trialkyl phosphites), and C-nucleophiles (sodium diethyl malonate) to give the corresponding products of the tosyl group substitution, 4-substituted semicarbazones, including analogues of nitrofurazone. Among the prepared compounds tested in vitro for antibacterial and antifungal activity, three nitrofuryl-containing semicarbazones exhibited high biological activities with minimum inhibitory concentration (MIC) values of 8–32 μg/mL. 相似文献
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Regiospecific and direct imidation of the methyl C(sp3)–H bond of thioanisoles is realized under mild and metal-free conditions with N-fluorobis(benzenesulfonyl)imide as an oxidant and nitrogen source. Proposed mechanism suggests that thionium ion intermediates and a Pummerer-type reaction are involved. The imidation has advantages such as high step-economy, excellent functionality tolerance, and regiospecificity, giving structurally diverse imidation products. 相似文献
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A small library of new chiral bidentate hydroxyalkyl-imidazolium salts 1 is conveniently synthesized on multi-gram scale from inexpensive and commercially available chiral pool amino acids. The corresponding carbenes, generated by deprotonation of imidazolium salts 1, in combination with palladium(II) chloride were tested in the Mizoroki–Heck coupling reaction. The most significant results in terms of yields and reactivities were achieved with low catalyst loading. The catalytic activities of these imidazolium salts were also investigated in the asymmetric addition of diethylzinc to benzaldehyde. The use of MgO nanoparticles as an additive in conjunction with these ligands played a crucial role in increasing the efficiency of these reactions. 相似文献