共查询到20条相似文献,搜索用时 31 毫秒
1.
A. B. Siqueira C. T. Carvalho E. Y. Ionashiro G. Bannach E. C. Rodrigues M. Ionashiro 《Journal of Thermal Analysis and Calorimetry》2008,92(3):945-951
Solid-state Ln(L)3 compounds, where Ln stands for trivalent Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu and Y and L is 2-methoxybenzoate have been synthesized. Simultaneous thermogravimetry and differential thermal analysis (TG-DTA), differential
scanning calorimetry (DSC), X-ray powder diffractometry, infrared spectroscopy and complexometry were used to characterize
and to study the thermal behaviour of these compounds. The results provided information on the composition, dehydration, coordination
mode, structure, thermal behaviour and thermal decomposition. 相似文献
2.
Patrícia R. Dametto Beatriz Ambrozini Adriano B. Siqueira Cláudio T. Carvalho Massao Ionashiro 《Journal of Thermal Analysis and Calorimetry》2009,97(2):765-768
Solid-state Ln–C8H7O3 compounds, where Ln stands for Eu(III) and Gd(III) and C8H7O3 is 3-methoxybenzoate, have been synthesized. Simultaneous thermogravimetry and differential thermal analysis (TG-DTA), differential
scanning calorimetry (DSC), X-ray powder diffractometry, infrared spectroscopy, elemental analysis and complexometry were
used to characterize and to study the thermal behaviour of these compounds. The results led to information about the composition,
dehydration, thermal stability and decomposition of the isolated compounds. 相似文献
3.
A. B. Siqueira G. Bannach E. C. Rodrigues C. T. Carvalho M. Ionashiro 《Journal of Thermal Analysis and Calorimetry》2008,91(3):897-902
Solid-state LnL3 compounds, where L is 2-methoxybenzoate and Ln is light trivalent lanthanides, have been synthesized. Thermogravimetry (TG), differential scanning calorimetry (DSC), X-ray
powder diffractometry, infrared spectroscopy and elementary analysis were used to characterize and to study the thermal behaviour
of these compounds. The results led to information on the composition, dehydration, thermal stability and thermal decomposition
of the isolated compounds. On heating these complexes decompose in three (Ce, Pr) or five (La, Nd, Sm) steps with the formation
of the respective oxide: CeO2, Pr6O11 and Ln2O3 (Ln=La, Nd, Sm) as final residues. The theoretical and experimental spectroscopic study suggests predominantly the ionic bond
between the ligand and metallic center. 相似文献
4.
F. J. Caires L. S. Lima C. T. Carvalho A. B. Siqueira Oswaldo Treu-Filho M. Ionashiro 《Journal of Thermal Analysis and Calorimetry》2012,107(1):335-344
Synthesis, characterization, and thermal behavior of transition metal oxamates, M(NH2C2O3)2·nH2O (M = Mn(II), Fe(II), Co(II), Ni(II), Cu(II), Zn(II)), as well as the thermal behavior of oxamic acid and its sodium salt
(NaNH2C2O3) were investigated employing simultaneous thermogravimetry and differential scanning calorimetry (TG-DSC), experimental and
theoretical infrared spectroscopy, TG-DSC coupled to FTIR, elemental analysis and complexometry. The results led to information
about the composition, dehydration, thermal stability, thermal decomposition, as well as of the gaseous products evolved during
the thermal decomposition of these compounds in dynamic air and N2 atmospheres. 相似文献
5.
E. Schnitzler G. Bannach O. Treu-Filho C. T. Carvalho M. Ionashiro 《Journal of Thermal Analysis and Calorimetry》2011,106(3):643-649
Solid-state compounds of general formula ThL4·nH2O, where L represents 2-methoxybenzylidenepyruvate and 2-methoxycynamylidenepyruvate, were synthesized. Complexometric titrations
with EDTA, thermogravimetry (TG), differential thermal analysis (DTA), X-ray powder diffractometry, elemental analysis (EA),
and infrared spectroscopy have been employed to characterize and to study the thermal behavior of these compounds in dynamic
air atmosphere. The results led to informations about the composition, dehydration, crystallinity, and thermal decomposition
of the isolated compounds. The performed molecular calculations in this study were done using the Gaussian 03 routine. Theoretical
calculations help in interpretations of FT-IR spectra supplying structural and physicochemical parameters. 相似文献
6.
M. L. S. De Melo N. A. Santos R. Rosenhaim A. G. Souza P. F. Athayde Filho 《Journal of Thermal Analysis and Calorimetry》2011,105(3):831-836
Solid state Ln2–L3 compounds, where Ln stands for light trivalent lanthanides (lanthanum to gadolinium), except promethium, and L is folate
(C19H17N7O6), have been synthesized. Simultaneous thermogravimetry and differential thermal analysis (TG-DTA), differential scanning
calorimetry (DSC), X-ray powder diffractometry, infrared spectroscopy (FTIR), TG coupled to FTIR, elemental analysis and complexometry
were used to characterize and to study the thermal behaviour of these compounds. The results provided information concerning
the stoichiometry, crystallinity, ligand’s denticity, thermal stability, thermal behaviour and identification of the gaseous
products evolved during the thermal decomposition of these compounds. 相似文献
7.
P. R. Dametto B. Ambrozini A. B. Siqueira C. T. Carvalho M. Ionashiro 《Journal of Thermal Analysis and Calorimetry》2010,101(3):933-939
Solid-state Ln(L)3 compounds, where Ln stands for trivalent Tb, Dy, Ho, Er, Tm, Yb, Lu and Y, and L is 3-methoxybenzoate, have been synthesized.
X-ray powder diffractometry, infrared spectroscopy, complexometry and elemental analysis were used to characterize the compounds.
In order to study the thermal behaviour of these compounds simultaneous thermogravimetry and differential thermal analysis
(TG-DTA) and differential scanning calorimetry (DSC) were used. The results provided information on the composition, dehydration,
polymorphic transformation, thermal stability and thermal decomposition of the synthesized compounds. 相似文献
8.
F. S. Alves L. H. Bembo F. J. Caires E. Y. Ionashiro 《Journal of Thermal Analysis and Calorimetry》2013,113(2):739-744
Solid-state heavier lanthanides fumarates compounds have been synthesized, and the compounds were characterized by employing simultaneous thermogravimetry and differential thermal analysis (TG–DTA), differential scanning calorimetry (DSC), Fourier transform infrared spectroscopy (FTIR), TG coupled to FTIR, elemental analysis, and complexometry. On heating, the dehydration occurs in a single and two consecutive steps and the thermal decomposition of the anhydrous compounds occurs in consecutive and/or overlapping steps, with formation of the respective oxides: Tb4O7 and Ln2O3 (Ln=Dy to Lu). The results also led to information about composition, thermal behavior, and the type of coordination of the isolated compounds. 相似文献
9.
G Bannach E Schnitzler O Treu
Filho V H S Utuni M Ionashiro 《Journal of Thermal Analysis and Calorimetry》2006,83(1):233-240
Solid-state
compounds of general formula LnL3⋅nH2O,
where Ln represents heavier lanthanides
and yttrium and L is 2-chlorobenzylidenepyruvate,
have been synthesized. Chemical analysis, simultaneous thermogravimetry-differential
analysis (TG-DTA), differential scanning calorimetry (DSC), X-ray powder diffractometry,
elemental analysis and infrared spectroscopy have been employed to characterize
and to study the thermal behaviour of these compounds in dynamic air atmosphere.
On heating these compounds
decompose in four (Gd, Tb, Ho to Lu, Y) or five (Eu, Dy) steps. They lose
the hydration water in the first step and the thermal decomposition of the
anhydrous compounds up to 1200°C occurs with the formation of the respective
oxide, Tb4O7 and Ln2O3
(Ln=Eu, Gd, Dy to Lu and Y) as final residue.
The dehydration enthalpies found for these compounds (Eu, to Lu and Y) were:
65.77, 55.63, 86.89, 121.65, 99.80, 109.59, 131.02, 119.78, 205.46 and 83.11
kJ mol-1, respectively. 相似文献
10.
Szunyogová E. Györyová K. Kováşová J. Juhászová E. 《Journal of Thermal Analysis and Calorimetry》2003,71(3):967-976
Four new complex compounds were prepared by reaction of zinc carboxylate and methyl-3-pyridyl carbamate. The synthesized complex
compounds of the general formula (RCOO)2ZnL2 (RCOO-= HCOO- (form), CH3COO- (ac), CH3CH2CH2COO- (but), (CH3)2CHCOO- (isobut), L= methyl-3-pyridyl carbamate (mpc)) were characterized by chemical analysis, IR spectroscopy and studied by methods of thermal
analysis (TG/DTG, DTA). CH2O, CO2, (CH3)2CO, (C3H7)2CO were found as volatile products of thermal decomposition. ZnO was found as final product of thermal decomposition of the
prepared complexes heated up to 700°C. Mass spectroscopy, X-ray powder diffraction method, IR spectra and chemical analysis
were used for the determination of the thermal decomposition products.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
11.
Neeraj Sharma Amit Pathania Mala Sharma 《Journal of Thermal Analysis and Calorimetry》2012,107(1):149-154
Thermal behaviour of newly synthesized niobium(V) aryloxides of composition [NbCl5−n
(OC6H4CH(CH3)2-4)
n
] (where n = 1 → 5) synthesized by the reactions of niobium pentachloride with 4-isopropylphenol in predetermined molar ratios in carbon
tetrachloride has been studied by thermogravimetric (TG) and differential thermal analysis (DTA) techniques. The results showed
that thermal decomposition of complex of composition [NbCl4(OC6H4CH(CH3)2-4)] resulted in the formation of NbOCl3 as the ultimate decompositional product while all other complexes yielded Nb2O5 as the final product of thermal decomposition. From the mathematical analysis of TG data, the kinetic and thermodynamic parameters
viz. energy of activation, frequency factor, entropy of activation, etc. have been evaluated using Coats–Redfern equation. 相似文献
12.
A new one‐dimensional phase, CsGaSe3 has been synthesized and characterized by single crystal X‐ray diffraction, differential thermal analysis, and single crystal UV/Vis spectroscopy. The structure contains infinite chain anions, [GaSe(Se2)]— separated by Cs cations. The Ga3+ cation is in a distorted tetrahedral environment coordinated by each two Se2— and Se22— ions. The red crystals of CsGaSe3 absorb visible light at energies above 2.25 eV. Differential thermal analysis revealed that the compound does not melt below 1000 °C. Crystal data: CsGaSe3, monoclinic, space group P21/c (No 14), a=7.727(1), b=13.014(3), c=6.705(1), β=106.39(3)°, Z=4, R1=0.0469. 相似文献
13.
E. Y. Ionashiro G. Bannach A. B. Siqueira C. T. de Carvalho E. C. Rodrigues M. Ionashiro 《Journal of Thermal Analysis and Calorimetry》2008,92(3):953-959
Solid-state Ln(2-MeO-BP) compounds, where Ln stands for trivalent Eu to Lu and Y(III) and 2-MeO-BP (which is 2-methoxybenzylidenepyruvate) have been synthesized. Simultaneous thermogravimetry and differential thermal analysis (TG-DTA), differential scanning calorimetry (DSC), X-ray powder diffraction, infrared spectroscopy and other methods of analysis were used to characterize and to study these compounds. On the base of the obtained results an Ln(2MeO-BP)3·nH2O general formula can be established. 相似文献
14.
Petra Šulcová Jan Večeřa Pavel Bystrzycki 《Journal of Thermal Analysis and Calorimetry》2012,108(2):525-529
New environmentally inorganic pigments based on Bi2O3 doped by metal ions, such as Zr4+ and Dy3+ have been developed and characterized using the methods thermal analysis, X-ray powder diffraction, and spectral reflectance
data. The compounds having formula Bi2−x
Dy
x/2Zr3x/8O3 (x = 0.2, 0.6, 1.0, and 1.2) were prepared by the solid state reaction. Methods of thermal analysis were used for determination
of the temperature region of the pigment formation and thermal stability of compounds. The incorporation of doped ions in
Bi2O3 changes the color from yellow to orange and also contributes to a growth of their thermal stability. This property gives
a direction for coloring ceramic glazes. 相似文献
15.
B. Ambrozini P. R. Dametto M. Ionashiro 《Journal of Thermal Analysis and Calorimetry》2011,105(3):867-871
Solid state Ln2-L3 compounds, where Ln stands for heavy trivalent lanthanides (terbium to lutetium) and yttrium, and L is tartrate [(C4H4O6)?2] have been synthesized. Simultaneous thermogravimetry and differential thermal analysis, differential scanning calorimetry, X-ray powder diffractometry, infrared spectroscopy, elemental analysis and complexometry were used to characterize and to study the thermal behaviour of these compounds. The results provided information concerning the stoichiometry, crystallinity, ligand??s denticity, thermal stability and thermal behaviour of these compounds. 相似文献
16.
Z. Rzączyńska A. Kula J. Sienkiewicz-Gromiuk A. Szybiak 《Journal of Thermal Analysis and Calorimetry》2011,103(1):275-281
The complexes of rare earth elements with 2,3-naphthalenedicarboxylic acid of the formula: Ln2(C12H6O4)3·nH2O, where Ln = La(III)-Lu(III) and Y(III); n = 3 for La(III), Ce(III); n = 6 for Pr(III)-Yb(III) and Y(III) and n = 5 for Lu(III) have been synthesized and characterized by elemental analysis, IR spectroscopy, thermal analysis (TG, DTG,
DTA and TG-FTIR) and X-ray analysis. They are sparingly soluble in water and stable at room temperature. During heating in
air atmosphere, they lose all water molecules in several steps, generally in two or three steps, except for the La(III) and
Ce(III) complexes which lose all water molecules in one step. The anhydrous compounds are stable up to about 773 K and then
decompose to corresponding oxides. The thermal decomposition is connected with the release of water molecules (443 K), carbon
dioxide (713 K) and hydrocarbons. 相似文献
17.
Thechano Merry Prabhakar Maddela Kiran Devaraya Anand K. Kondapi Chullikkattil P. Pradeep 《Journal of heterocyclic chemistry》2019,56(9):2469-2478
A series of anthracenyl pyrazoline derivatives ( 3a – o ) were synthesized with an aim to evaluate their in vitro anticancer activities. Anthracenyl pyrazoline compounds were prepared by the reaction between various anthracenyl chalcones ( 1a – o ) and hydrazine hydrate ( 2 ). The reactions were carried out under reflux in the presence of triethylamine and ethanol for 24 h, and the obtained yields were from good to excellent (90–97%). The structure of each compound is well characterized by IR, 1H‐NMR, 13C‐NMR, elemental analyses, and mass spectroscopic technics, and the molecular structures of compounds 3d and 3e were solved by single‐crystal X‐ray crystallographic methods. The newly synthesized compounds ( 3a – o ) were evaluated for their in vitro cytotoxic studies against four human cancer cell lines MCF‐7 (breast cancer cell lines), SK‐N‐SH (neuroblastoma cancer cell lines), HeLa (cervical cancer cell lines), and HepG2 (liver cancer cell lines), and the screening results show strong cytotoxic effects for most of the synthesized compounds against the three cell lines except SK‐N‐SH cells. Notably, compounds 3a , 3j , 3l , 3m , 3n , and 3o showed a highly potential activity against HeLa cells (IC50: 0.22, 0.3, 0.3, 0.10, 0.25, and 0.25 μM), while compounds 3i , 3k , 3l , and 3m showed a significant cytotoxic activity in HepG2 cells (IC50: 0.22, 0.44, 0.40, and 0.22 μM), whereas compounds 3a , 3b , 3d , and 3e exhibit a promising cytotoxicity against MCF‐7 cells (IC50: 0.73, 0.495, 0.493, and 0.66 μM). 相似文献
18.
Lijie He Hongming Yuan Keke Huang Chen Yan Guanghua Li Qiaoru He Yang Yu Shouhua Feng 《Journal of solid state chemistry》2009,182(8):2208-2212
The single crystals of perovskite fluorides (NH4)2NaVF6 and Na3VF6 were synthesized under mild hydrothermal conditions. The structures of the compounds were determined by means of single-crystal and powder X-ray diffraction analyses, respectively. (NH4)2NaVF6 has a cubic elpasolite-type structure and crystallizes in the space group with lattice constant a=8.495(0) Å. Rietveld refinement indicates that Na3VF6 has a monoclinic structure and is in space group P21/n. The compounds were characterized by scanning electron microscopy, thermogravimetric and differential thermal analysis, and variable temperature magnetic susceptibility. With the temperature decreasing, the magnetic studies of the compounds showed the magnetic ordering was related to the crystallographic features and isolated magnetic units. 相似文献
19.
Lucica Viorica Ababei Angela Kriza Adina Magdalena Musuc Cristian Andronescu Elena Adina Rogozea 《Journal of Thermal Analysis and Calorimetry》2010,101(3):987-996
New complexes of 2-benzoyl-pyridil-isonicotinoylhydrazone (L) with Cu(II), Co(II), Ni(II) and Mn(II), having formula of type
[ML2] SO4·xH2O (M = Cu2+, Co2+, Ni2+, x = 2 and M = Mn2+, x = 3), have been synthesised and characterised. All complexes were characterised on the basis of elemental analyses, IR spectroscopy,
UV–VIS–NIR, EPR, as well as thermal analysis and determination of molar conductivity and magnetic moments. The thermal behaviour
of complexes was studied using thermogravimetry (TG), differential thermal analysis (DTA) and differential scanning calorimetry
(DSC). The structure of L hydrazone was established by X-ray study on single crystal. The ligand works as tridentate NNO,
being coordinated through the azomethine nitrogen, the pyridine nitrogen and carbonylic oxygen. Heats of decomposition, ΔH, associated with the exothermal effects were also determined. 相似文献
20.
Shitong Ren Fangjing Tian Shaoheng Zhang Weicong Zhou Yonggang Du 《Journal of polymer science. Part A, Polymer chemistry》2022,60(9):1492-1500
Developing thermosets derived from renewable sources is of great importance. In this work, a fully bio-based benzoxazine monomer, 3,6-bis((3-(furan-2-ylmethyl)-3,4-dihydro-2H-benzo[e][1,3]oxazin-6-yl)methyl)piperazine-2,5-dione (TCDPF), is conveniently synthesized from L-tyrosine cyclic dipeptide (TCDP), furfurylamine and paraformaldehyde. The chemical structure of TCDPF is confirmed by nuclear magnetic resonance spectroscopy and Fourier transform infrared spectroscopy (FT-IR) techniques. The curing behavior of TCDPF is investigated by differential scanning calorimetry and in situ FT-IR techniques. After temperature-programmed curing, the thermomechanical property and thermal stability of the resulting TCDPF polymer (PTCDPF) are evaluated by dynamic mechanical analysis and thermogravimetric analysis techniques, respectively. It is found that PTCDPF have excellent comprehensive performance such as high glass transition temperature (Tg = 322 °C), high thermal degradation temperature (T5% = 342 °C, T10% = 395 °C in N2 atmosphere), and high char yield (CY = 51.3% at 800 °C in N2 atmosphere). The results demonstrate that L-tyrosine is a promising bio-based raw material for preparing high performance polybenzoxazines. 相似文献