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1.
The preparation of poly(2,6‐dimethyl‐1,4‐phenylene ether)‐b‐poly(ethylene terephthalate) block copolymer was performed by the reaction of the 2‐hydroxyethyl modified poly(2,6‐dimethyl‐1,4‐phenylene ether) (PPE‐EtOH) with poly(ethylene terephthalate) (PET) by an in situ process, during the synthesis of the polyester. The yield of the reaction of the 2‐hydroxyethyl functionalized PPE‐EtOH with PET was close to 100%. A significant proportion of the PET‐b‐PPE‐EtOH block copolymer was found to have short PET block. Nevertheless, the copolymer structured in the shape of micelles (20 nm diameter) and very small domains with 50–200 nm diameter, whereas unmodified PPE formed much larger domains (1.5 μm) containing copolymer. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 3985–3991, 2008  相似文献   

2.
《先进技术聚合物》2018,29(6):1613-1619
Poly(2‐methyl‐1,5‐pentaneoxamide) ( PM52) with relative viscosity up to 3.3 were synthesized using 2‐methyl‐1,5‐pentanediamine (M52) and dibutyl oxalate via spray/melt polycondensation. The obtained polyoxamide was characterized by FTIR, 1H‐NMR, WAXD, DSC, and TGA. The Tm of PM52 was 200°C with a heat of fusion (ΔHf) of 59.7 J·g−1, crystallization temperature of 125°C, and a crystallization enthalpy (ΔHc) of 42.6 J·g−1. Isothermal crystallization studies revealed a 2‐dimensional crystallization phenomenon which didn't vary with change in crystallization temperature. TGA analysis revealed that the thermal stability of PM52 compared well with commercial PA6, and XRD studies revealed an α form of crystal structure and that the polymers possessed good crystallinity. Saturated water absorption of 4.6 wt% was recorded for the new polyoxamide synthesized as compared with 10.6 wt% for commercial PA6; such properties are good for applications in the food industry, plastics, and electronics industry where dimensional stability is a key requirement.  相似文献   

3.
Chain coherence length of rigid‐rod poly(p‐phenylene benzobisthiazole) (PBZT) and its derivatives in the solid state was determined from the wide‐angle X‐ray diffraction patterns of axially disordered crystal. The degree of the PBZT main chain extension was estimated from the coherence lengths and was compared to investigate the effects of side chain, orientation, heat treatment, and polymer solution concentration. Extremely small coherence length obtained from both highly oriented fibers and powder or bulk PBZT homopolymer suggested that a chain conformation deviated from the fully extended conceptual rigid‐rod, supporting the ribbon‐like conformation, as was previously predicted by molecular dynamic simulation. The deviation was also found to be highly dependent on the processing conditions. Fibers stretched during spinning exhibited much greater chain extension than the isotropic powder, the bulk, and fibers spun without tension. The chain extension was also dependent on the solution concentration prior to the processing. The PBZT produced from solution above the critical concentration exhibited higher chain extension than those from below the critical concentration. However, side chain attachment to the PBZT main chain or post‐heat treatments showed a minimal effect on the extension of the PBZT backbone. © 1999 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 37: 661–666, 1999  相似文献   

4.
Information on the crystalline structure and the properties of poly(butylene‐2,6‐naphthalene dicarboxylate) (PBN) has not been well reported until now, but it is known that there are two different crystal modifications in PBN, as follows: one is formed in isotropic samples by annealing (α form); another appears by annealing with tension (β form). The relation between the crystal modifications and the kinetics of isothermal crystallization for PBN was investigated using in‐situ Fourier transform infrared spectroscopy (FTIR) and wide‐angle X‐ray diffraction (WAXD). The melting behavior of each crystalline form was also studied by means of FTIR and differential scanning calorimetry (DSC) measurements. From the analysis of the melt‐crystallized PBN specimens, the two crystalline forms coexisted in the isotropic samples melt‐crystallized at 230°C, but only the α crystal modification was observed in the films annealed at lower temperatures. In addition, it was revealed that, at 230°C, the β modification was formed only in the primary crystallization process. © 1999 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 37: 561–574, 1999  相似文献   

5.
The influence of additives on the crystal modification and melting behavior of poly(ethylene‐2,6‐naphthalene dicarboxylate) (PEN) was investigated with wide‐angle X‐ray diffraction and differential scanning calorimetry (DSC). The addition of a nucleating promoter, Ceraflour 993, had no effect on the crystal modification and melting behavior of PEN crystallized under all chosen experimental conditions. However, the addition of a nucleating agent, sodium benzoate (SB), did affect the crystal modification and melting behavior of PEN when PEN/SB was crystallized at a higher temperature, but not at a lower temperature. A mixture of α and β modifications of PEN was obtained, and an overlapped dual melting peak was observed in DSC curves when PEN was crystallized at a higher temperature in the presence of SB, instead of a single crystal form and a single melting peak for the crystallization of pure PEN. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 296–301, 2004  相似文献   

6.
Wholly aromatic poly(azomethine)s with 1,5‐ or 2,6‐substituted naphthalene moiety in the main chains were prepared in aprotic polar solvents or m‐cresol under various reaction conditions. In the polymerization of 1,5‐diaminonaphthalene with terephthalaldehyde, the polymer that synthesized in (HMPA/DMSO) at room temperature for 24 h by adding 5 wt % of calcium chloride and a very small amount of p‐toluenesulfonic acid showed the highest reduced viscosity in all of the polymers from 1,5‐diaminonaphthalene. The reduced viscosity of poly(azomethine)s synthesized from 2,6‐diaminonaphthalene with 2,6‐diformylnaphthalene in m‐cresol and with terephthalaldehyde in HMPA/DMSO were ηred = 0.35 and 0.36, respectively. The thermal analysis showed the poly(azomethine)s had high thermal stability and the glass‐transition temperatures of these polymers are about 250 °C. The X‐ray diffraction showed that they are partially crystalline. They could be polymerized again by second stage polycondensation in polyphosphoric acid. The reduced viscosities of the obtained polymers were about 2–5 times as high as that of the pristine polymers. © 2000 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 38: 1064–1072, 2000  相似文献   

7.
Bis‐(3‐hydroxypropyl) 2,6‐naphthalenedicarboxylate (BHPN) was polymerized to poly(trimethylene 2,6‐naphthalenedicarboxylate) (PTN) in the presence of various catalysts. The order of the catalytic reactivity was Sb(III) < Zr(IV) < Sn(IV) < Ti(IV). The influence of temperature and catalyst concentration on the properties of PTN was studied with Ti(IV)butylate as a catalyst. The catalysis with titanium resulted in a yellowish polymer only if the polycondensation temperature exceeded 260 °C. PTN and its monomer BHPN were characterized by infrared spectroscopy. 1H NMR spectroscopy was employed to determine the quantity of bis‐(3‐hydroxypropyl)ether in PTN. The content of diolether was less than 1 mol %. © 2001 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 39: 620–629, 2001  相似文献   

8.
We prepared blends of poly(butylene‐2,6‐naphthalate) (PBN) and poly(ether imide) (PEI) by solution‐casting from dichloroacetic acid solutions. The miscibility, crystallization, and melting behavior of the blends were investigated with differential scanning calorimetry (DSC) and dynamic mechanical analysis. PBN was miscible with PEI over the entire range of compositions, as shown by the existence of single composition‐dependent glass‐transition temperatures. In addition, a negative polymer–polymer interaction parameter was calculated, with the Nishi–Wang equation, based on the melting depression of PBN. In nonisothermal crystallization investigations, the depression of the crystallization temperature of PBN depended on the composition of the blend and the cooling rate; the presence of PEI reduced the number of PBN segments migrating to the crystallite/melt interface. Melting, recrystallization, and remelting processes occurring during the DSC heating scan caused the occurrence of multiple melting endotherms for PBN. We explored the effects of various experimental conditions on the melting behavior of PBN/PEI blends. The extent of recrystallization of the PBN component during DSC heating scans decreased as the PEI content, the heating rate, the crystallization temperature, and the crystallization time increased. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 1694–1704, 2004  相似文献   

9.
Acrylamide was graft polymerized onto the surface of a chemically crosslinked and amorphous biodegradable polyester, poly(1,5‐dioxepan‐2‐one). Electron beam irradiation at a dose of 5 Mrad was used to generate the initiating species in the polyester. The degradation behavior in vitro at pH 7.4 and 37°C in a phosphate buffer solution was studied for untreated, irradiated, and acrylamide‐grafted polymer. Differences in weight loss performance were observed between virgin and treated polymers. The acrylamide‐grafted poly(1,5‐dioxepan‐2‐one) was totally degraded after 43 weeks as compared to 48 weeks for the irradiated and 55 weeks for the virgin polymer. On the other hand, the treated polymers showed a higher resistance to degradation in terms of weight loss during the intermediate part of the degradation, i.e., between about 5 and 35 weeks. After this period, the irradiated and particularly the acrylamide grafted poly(1,5‐dioxepan‐2‐one) degraded much more rapidly than the virgin polymer. © 1999 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 37: 1659–1663, 1999  相似文献   

10.
New star‐shaped and photocrosslinked poly(1,5‐dioxepan‐2‐one) (PDXO) has been synthesized through ring‐opening polymerization initiated by SnOct2/pentaerythritol. The star‐shaped PDXO was end‐functionalized by acrolyol chloride to form acrylate end groups. The end‐functionalized PDXO was photocrosslinked initiated by 2,2‐dimethoxy‐2‐phenylacetophenone. The gel content ranged from 80 to 99%, indicating a high degree of crosslinking. The thermal properties of the star‐shaped PDXO and the photocrosslinked PDXO were analyzed by differential scanning calorimetry. The glass‐transition temperature was determined to approximately ?32 °C for the crosslinked PDXO. The viscosity numbers were determined for star‐shaped PDXO, with reference to linear homologues. The star‐shaped PDXO had lower viscosity numbers than the linear counterparts. The crosslinked PDXO showed a rather hydrophilic surface as compared with other resorbable polyesters. The advancing contact angle was 64 ± 2, and the receding angle was 57 ± 4. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 40: 2049–2054, 2002  相似文献   

11.
The kinetics of the transesterification reaction between poly(ethylene terephthalate) (PET) and poly(ethylene 2,6‐naphthalate) (PEN) with and without the addition of a chain extender were studied with 1H NMR. Different kinetic approaches were considered, and a second‐order, reversible reaction was accepted for the PET/PEN reactive blend system. The addition of 2,2′‐bis(1,3‐oxazoline) (BOZ) promoted the transesterification reaction between PET and PEN in the molten state. The activation energy of the transesterification reaction for the PET/PEN reactive blend with BOZ (94.0 kJ/mol) was lower than that without BOZ (168.9KJ/mol). The rate constant k took an almost constant value for blend samples with different compositions mixed at 275 °C. © 2001 John Wiley & Sons, Inc. J Polym Sci Part B: Polym Phys 39: 2607–2614, 2001  相似文献   

12.
The complexes di‐n‐butyldi(2‐pyridinethiolato‐N‐oxide)tin(IV) (1), diphenyldi(2‐pyridinethiolato‐N‐oxide)tin(IV) ( 2 ) and dibenzyldi(2‐pyridinethiolato‐N‐oxide)tin(IV) ( 3 ) are synthesized and characterized by elemental analyses, IR, 1H, 13C, 119Sn NMR spectroscopy, and their structures are determined by X‐ray crystallography. In complex 1 the coordination geometry at tin is a skew‐trapezoidal bipyramid, with cisS,S and cisO,O atoms occupying the trapezoidal plane and two n‐butyl groups occupying the apical positions, which also exhibits strong π–π stacking interactions. In complexes 2 and 3 the geometry at tin is distorted cis‐octahedral, with cisO,O and cisC,C atoms occupying the equatorial plane and transS,S atoms occupying the apical positions. Their in vitro cytotoxicity against two human tumour cell lines, MCF‐7 and WiDr is reported. The ID50 values found are comparable to those found for cis‐platin, but lower than for many other diorganotin compounds. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

13.
14.
Morphology is presented as a powerful tool to control the in vitro degradation and drug release characteristics of novel drug delivery microspheres prepared from homopolymer blends of 1,5‐dioxepan‐2‐one, DXO, and L ‐lactide, L‐LA. Their performance in this respect was compared to analogous P(L‐LA‐co‐DXO) microspheres. Blends formed denser and less porous microspheres with a higher degree of matrix crystallinity than copolymers of corresponding L‐LA:DXO composition. The morphology differences of blends and copolymers, further adjustable by means of component ratio, are shown to have a vital impact on the in vitro performance. Sustained drug delivery was obtained from both copolymers and blends. Molecular weight loss was retarded and diffusion‐mediated release was inhibited in the latter case, further delaying the release process. The effects of storage on the physicochemical properties of these systems were evaluated under desiccated and moist conditions for 5 months. Storage‐induced physicochemical changes, such as matrix crystallization and molecular weight decrease, were accelerated at higher relative humidities. P(L‐LA‐co‐DXO) demonstrated higher moisture sensitivity than a PLLA‐PDXO blend of corresponding composition. The more crystalline and dense morphology of blend microspheres may thus be considered an improvement of the storage stability. © 2000 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 38: 786–796, 2000  相似文献   

15.
To check the previously proposed crystal structure of poly(p‐phenylene benzobisoxazole) [PBO], we performed an X‐ray structure analysis for single crystals of low molecular weight model compounds with the following chemical formulas: Both of these two model compounds show essentially the same molecular and subcell structures as those of PBO: the molecular chains take an almost perfect planar conformation and are packed together with a relative height between the adjacent chains of about 3 Å along the chain axis, although for the polymer the chains are shifted by the same value but in a disordered mode with respect to the direction of the shift (upward or downward), different from the regular packing in model compounds. These structural features are reproduced well with energy calculations. Structural ordering in PBO fibers caused by heat treatment at high temperatures, as clarified by X‐ray diffraction measurement, are interpreted on the basis of the energy calculations. © 2001 John Wiley & Sons, Inc. J Polym Sci Part B: Polym Phys 39: 1296–1311, 2001  相似文献   

16.
Mn(bzimpy)2(1)[bzimpy=2,6-bis(benzimidazol-2-yl)pyridine],a mononuclear manganese(Ⅱ)complex,was synthesized by the reaction of Mn(OOCMe)2 with bzimpy in absolute ethanol.The complex was structurally characterized by elemental analysis,cyclic voltammetry,and X-ray crystallography.In the complex,the manganese-nitrogen distances were different,and the geometry and the metal ion environment showed the distortion.The cyclic voltammetric measurements have been performed to assess its redox characteristics.The presence of oxidation wave at 0.62V and 0.081V vs.SCE or 0.8V and 1.0v vs.NHE suggested that this complex could catalyze the oxidation of water,therefore,simulate the water-oxidizing complex(WOC) of photosystem Ⅱ (PS Ⅱ).The measurements of photoreduction of 2,6-dichlorophenolindophenol (DCPIP),and oxygen evolution in the manganess-depleted and the comples 1-reconstituted PS Ⅱ preparations just support our conjecture.  相似文献   

17.
The lamellar‐level morphology of an extruded poly(ethylene terephthalate) (PET)/poly(ethylene‐2,6‐naphthalate) (PEN) blend was investigated with small‐angle X‐ray scattering (SAXS). Measurements were made as a function of the annealing time in the melt and the crystallization temperature. The characteristic morphological parameters at the lamellar level were determined by correlation function analysis of the SAXS data. At a low crystallization temperature of 120 °C, the increased amorphous layer thickness was identified in the blend, indicating that some PEN was incorporated into the interlamellar regions of PET during crystallization. The blend also showed a larger lamellar thickness than pure PET. A reason for the increase in the lamellar thickness might be that the formation of thinner lamellar stacks by secondary crystallization was significantly restricted because of the increased glass‐transition temperature. At high crystallization temperatures above 200 °C, the diffusion rates of noncrystallizable components were faster than the growth rates of crystals, with most of the noncrystallizable components escaping from the lamellar stacks. As a result, the blend showed an interfibrillar or interspherulitic morphology. © 2002 John Wiley & Sons, Inc. J Polym Sci Part B: Polym Phys 40: 317–324, 2002  相似文献   

18.
The melt structures of linear polyethylene and the isotactic vinyl polymers polypropylene, poly(1‐butene), and poly(4‐methyl‐1‐pentene), along with the corresponding methyl, ethyl, and isobutyl side chains, were studied with wide‐angle X‐ray diffraction. As the size of the side branch increases from zero (polyethylene) to methyl, ethyl, and isobutyl, a prepeak appears below the main diffraction peak in the total structure factor. The prepeaks become stronger and shift to lower scattering vectors with increasing bulkiness of the side chain. There is a strong correlation between the position of the prepeaks in the melt and the average nearest‐neighbor helix–helix packing distance in the crystals, implying similar helical conformations in the melts. © 2000 John Wiley & Sons, Inc.* J Polym Sci B: Polym Phys 38: 2480–2485, 2000  相似文献   

19.
A two‐dimensional MnII coordination polymer (CP), poly[bis[μ2‐2,6‐bis(imidazol‐1‐yl)pyridine‐κ2N3:N3′]bis(thiocyanato‐κN)manganese] [Mn(NCS)2(C11H9N5)2]n, (I), has been obtained by the self‐assembly reaction of Mn(ClO4)2·6H2O, NH4SCN and bent 2,6‐bis(imidazol‐1‐yl)pyridine (2,6‐bip). CP (I) was characterized by FT–IR spectroscopy, elemental analysis and single‐crystal X‐ray diffraction. The crystal structure features a unique two‐dimensional (4,4) network with one‐dimensional channels. The luminescence and nitrobenzene‐sensing properties were explored in a DMF suspension, revealing that CP (I) shows a strong luminescence emission and is highly sensitive for nitrobenzene detection.  相似文献   

20.
Two new diorganotin(IV) derivatives of 2,6‐pyridinedicarboxylic acid, {[Ph2Sn(2,6‐C5H3N)(COO)2][Na(2,6‐C5H3N)(COOH) (COO)(CH3OH)2]} ( 1 ) and [Me2Sn(2,6‐C5H3N)(COO)2(H2O)]H2O ( 2 ) were synthesized by the reaction of Ph3SnCl and PhMe2SnI with 2,6‐pyridinedicarboxylic acid, respectively in the presence of sodium methoxide or potassium iso‐propoxide. The prepared compounds were characterized by mass spectrometry, IR, 1H, 13C and 119Sn NMR spectroscopies. The molecular structures of both complexes were determined by a single‐crystal X‐ray analysis. The X‐ray structure revealed pentagonal bipyramidal geometry around the tin atom for compound 1, which is incorporated with a hexacoordinated monosodium derivative of 2,6‐pyridinedicarboxylic acid. Complex 2 adopts a monomeric structure with two carboxylate oxygen atoms coordinated to tin in monodenate form from equatorial positions, and the coordination number is raised to six as the oxygen of water and pyridine nitrogen occupies the other equatorial positions of octahedron. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

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