基于偏振门的动态光散射颗粒测量法的研究

为了解决动态光散射纳米颗粒测量技术无法测量高浓度颗粒粒径的难题,提出了一种基于偏振门的动态光散射测量法。从动态光散射和Mie理论出发,理论分析了在高浓度溶液下多重散射效应对散射光偏振态和颗粒粒度测量结果的影响。根据散射光偏振特点,结合偏振门检测技术,改进了传统的动态光散射光学系统。实验研究了在低浓度和高浓度溶液时,不同偏振角度下的散射光强和粒度测量值,完善了散射光的偏振理论。采用90°偏振门检偏,通过各种浓度下的实验,证明了方法的可行性。该方法较之目前同类方法具有原理和结构简单,系统易于维护的特点。     

Modeling the light scattering by nanoparticles of complex shape using the generalized source method

The results of modeling the scattering of light by nanoparticles of complex shape using the generalized source method are presented. It is shown that the approach implementing direct solution of the implicit equation, which is derived by the generalized source method using the three-dimensional Green’s function, in conjunction with the fast Fourier transform significantly improves convergence of the method of volume integral equation and considerably extends the range of its applicability.     

Diffuse surface calibration method to improve accuracy and dynamic range of aerosol elastic light scattering measurements

A new method to calibrate detectors for elastic light scattering (ELS) measurement based on diffuse scattering from a Lambertian surface is presented. The method produces a calibration signal that is approximately seven orders of magnitude larger than a propane gas Rayleigh scattering calibration. The method also allows for calibration of detectors such as photodiodes, which are not sensitive enough to detect Rayleigh scattering for calibration but possess characteristics desirable for the measurement of soot ELS. Since the method is only suitable for backward scattering calibrations, transfer of calibration data from a backward- to a forward-oriented detector is accomplished with a secondary laser and integrating sphere. In demonstration experiments, calibration constants for photomultiplier tube (PMT) detectors obtained using both Rayleigh scattering and diffuse surface scattering agreed within experimental uncertainties as did measurements of in-flame scattering coefficients obtained with PMTs and photodiodes. However, achievable uncertainties with the diffuse-surface calibration approach were significantly reduced. More importantly, by enabling the use of photodiode detectors in ELS measurements, the new method facilitates operation at higher photon fluxes resulting in improved signal-to-noise ratios, reduced influence of photon shot noise, and the ability to achieve higher dynamic range in transient measurements.     

基于颗粒粒度信息分布特征的动态光散射加权反演

宽分布和双峰分布颗粒的准确反演是动态光散射技术至今未能有效解决的难题,尤其峰值位置比小于2:1且含有大粒径颗粒(350 nm)的双峰分布.造成这一难题的主要原因包括:1)单角度测量数据的粒度信息含量不足;2)常规反演方法对测量数据的噪声抑制以及粒度信息利用缺乏针对性.对测量数据(即光强自相关函数)的研究发现,数据噪声主要分布在长延迟时段,而粒度信息集中分布在衰减延迟时段.基于此,本文提出了采用粒度信息分布为底数、调节参数为指数的权重系数对自相关函数进行加权反演的约束正则化方法.由于采用了与粒度信息分布一致的权重系数,该方法既充分利用了衰减延迟时段的粒度信息,又有效地抑制了长延迟时段的数据噪声.不同噪声水平下,宽分布和双峰分布颗粒体系的反演结果表明,与常规反演方法相比,这一方法可以获得更为准确的宽分布和近双峰分布的反演结果.     

Boundary integral equation method for analysis of light scattering by 2D nanoparticles

The scattering of a plane electromagnetic wave by 2D nanoparticles is simulated using the boundary integral equation method. The accuracy and smoothness of the solution are improved by applying Hermitean interpolants for discretization. The accuracy of the numerical approach used in this paper is comparable to the Mie classical solution for scattering by a circular cylinder. It is shown that laser radiation incident on silver nanoparticles generates plasma resonances, giving rise to peak values of the extinction cross section and considerably enhancing the local electromagnetic field on the surface.     

基于布拉格声光衍射场的光强非均匀空间分布研究

为了保证合成孔径激光雷达测试中信号光的光束质量,从波动方程出发,推导出传统的衍射光源布拉格声光作用的耦合波方程。根据测试对光束质量的不同要求,借助有限差分方法分析衍射场光强的空间三维分布,发现声场振幅的不均匀分布会影响声光衍射场的光强分布,光强分布不均造成实验中信息光源的探测难度。通过光强空间分布研究增大有效通光孔径到3 mm,解决了声光调制器光束衍射质量问题,改进后的光束质量达到实验要求。该研究方法适用于改进声光器件工作参数。     

基于调制光束的空间相干性获得局域空心光束

 通过调制部分相干光的空间相干性,实现了局域空心光束的产生。理论上根据范西泰特-策尼克定理及标量衍射积分,构造出具有一定空间相干性的部分相干光,并研究其聚焦特性。实验上采用理论上要求的光学系统来构造具有特定空间相干性的部分相干光,并采用薄透镜聚焦部分相干光。研究表明,当构造出的部分相干光经透镜聚焦,可得到局域空心光束。研究了光学系统的参数及透镜焦距对产生局域空心光束的影响,结果显示：光阑的拦截比及透镜的焦距越大,获得的空心光束的尺寸就越大。     

基于调制光束的空间相干性获得局域空心光束

通过调制部分相干光的空间相干性,实现了局域空心光束的产生。理论上根据范西泰特-策尼克定理及标量衍射积分,构造出具有一定空间相干性的部分相干光,并研究其聚焦特性。实验上采用理论上要求的光学系统来构造具有特定空间相干性的部分相干光,并采用薄透镜聚焦部分相干光。研究表明,当构造出的部分相干光经透镜聚焦,可得到局域空心光束。研究了光学系统的参数及透镜焦距对产生局域空心光束的影响,结果显示：光阑的拦截比及透镜的焦距越大,获得的空心光束的尺寸就越大。     

Direct measurement of the spatial distribution of light intensity in a scattering medium

A direct nonperturbative measurement of the spatial distribution of the light intensity in a strongly scattering medium is performed using an optoacoustic method. It is shown that near a surface the intensity can be five times greater than the incident intensity, and the absolute maximum of the intensity is observed at a depth ℓ(1–R)(1–4.0R) determined by the photon transport mean free path ℓ and the effective light reflection coefficient R of the boundary separating the scattering and external media. Pis’ma Zh. éksp. Teor. Fiz. 70, No. 3, 187–191 (10 August 1999)     

Analysis of the biochemical composition of biological tissue in vivo by the diffuse light scattering method

We have studied possible options for improving the accuracy of biochemical analysis of the composition of biological tissue in vivo by using multifrequency diffuse light scattering spectroscopy with control of the optical thickness of the probed layer. We demonstrate the advantages of our technique for non-invasive measurements.     

A non-invasive method for the assessment of hemostasis in vivo by using dynamic light scattering

We present a new non-invasive method for assessing hemostasis in vivo. This method is based on the analysis of the movement characteristics of red blood cells (RBCs) during blood stasis condition. Stasis is intermittently induced by occlusion of arterial blood flow at the finger root. We assumed that under zero flow conditions, RBC movement is driven mostly by Brownian motion, and we characterized the RBC movement by utilizing the dynamic light scattering (DLS) technique in vivo. We found that during the stasis the RBCs diffusion coefficient in plasma decreases. We speculate that the RBC diffusion coefficient is most strongly related to endothelial and hemostatic activity. This assumption is supported by our findings that RBC movement, being expressed through the characteristics of the measured DLS signal, is correlative to the biological age and also is related to the coagulation factors. This new method can serve as a new diagnostic and research tool for the assessment of hemostasis and vascular function.     

Multiple layer formation of bovine serum albumin on silver nanoparticles revealed by dynamic light scattering and spectroscopic techniques

It is well known that when nanoparticles (NPs) are exposed to biological fluid, it results into formation of nanoparticle protein corona, which has been the subject of extensive studies for the development of targeted drug delivery. In this work, we demonstrated the dynamic light scattering, fluorescence, and UV-visible spectroscopy as quantitative and qualitative tools to monitor adsorption of BSA protein onto silver nanoparticles (AgNPs). The adsorption resulted in significant gradual increase in average hydrodynamic radius of BSA-AgNP corona from 24 to 35 nm and its attainment of equilibrium point (saturation) that correlated with albumin concentration enables condition for bound and unbound protein adsorption to be interpreted. Using DLS, the dissociation constant (K_D) was obtained for soft corona to be 2.09?±?0.30 μM. The UV-visible and fluorescence spectroscopy results were correlated with DLS. Loss of percent helicity in secondary structure of adsorbed BSA was monitored in both coronas as compared to native protein. Both coronas were found to be biocompatible with RBC membrane. Further, the results of adsorption isotherm model were used to validate the multilayer formation of albumin protein on silver nanoparticles. The obtained results would be relevant in the drug design development for tumor-targeted therapy.

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动态光散射检测电机转速的互信息函数分析

通过计算互信息函数,对动态光散射得到的电机转速的时间序列进行了分析。研究表明,互信息函数法能准确地测出电机转速。同时,由于互信息函数自身的优点———能实际地反映出数据之间的相互关联,因此,与自相关函数法比较,互信息函数法可反映出更多的动力学信息。对实验数据的时间序列作了二维的相空间重构,从重构图形发现系统有2周期行为,并呈现有一些新现象。     

Control of light scattering by nanoparticles with optically-induced magnetic responses

Conventional approaches to control and shape the scattering pattems of light generated by different nanostructures are mostly based on engineering of their electric response due to the fact that most metallic nanostructures support only electric resonances in the optical frequency range. Recently, fuelled by the fast development in the fields of metamaterials and plasmonics, artificial optically-induced magnetic responses have been demonstrated for various nanostructures. This kind of response can be employed to provide an extra degree of freedom for the efficient control and shaping of the scattering patterns of nanoparticles and nanoantennas. Here we review the recent progress in this research direction of nanoparticle scattering shaping and control through the interference of both electric and optically-induced magnetic responses. We discuss the magnetic resonances supported by various structures in different spectral regimes, and then summarize the original results on the scattering shaping involving both electric and magnetic responses, based on the interference of both spectrally separated （with different resonant wavelengths） and overlapped dipoles （with the same resonant wavelength）, and also other higher-order modes. Finally, we discuss the scattering control utilizing Fano resonances associated with the magnetic responses.     

Raman scattering as a probe of the tensile strain distribution in GaAs grown on Si(111) by molecular beam epitaxy

Epitaxial layers of GaAs grown on Si substrates, where the layer thickness greatly exceeds any critical thickness based on mismatch in lattice constant alone, have been shown to be under tensile strain for temperature at or below 300 K. This "thermal" strain arises from the difference in thermal expansion coefficients between GaAs and Si. We have performed Raman experiments on GaAs layers grown on both Si (001) and Si (111) substrates. We have observed a shift in the optical modes towards lower frequencies which is indicative of tensile strain in the GaAs layers, this is greater in the (111) growth direction than in the (001) one. In order to investigate the strain distribution as a function of distance from the GaAs/Si interface we have measured Raman spectra after successive removing of the epitaxial layer by chemical etching. We have found out that the strain decreases with increasing distance from the interface. We have developed the theory of Cerdeira et al. (1) to determine quantitatively the strain present in the heteroepitaxial layers. We have used, for the first time, polarization selection rules to separate the various components of the optical phonon modes. According to the theory we have observed that the doubly degenerate TO phonon line exhibits both a splitting and shift with strain, while only a shift is observed for the LO phonon line. In conformity with Cerdeira we have remarked that the strain dependence of the LO phonon is equal to that of the TO phonon mode observed in crossed polarization configuration.     

Effect of acoustooptic Bragg diffraction on the degree of spatial coherence of a light beam

The effect of acoustooptic (AO) Bragg diffraction on the degree of spatial coherence of an optical beam formed as the result of transmission of a Gaussian beam through a diffuser is studied. Experiments performed on the basis of the AO Bragg interaction in a single crystal of TeO₂ confirmed that the optical beam areas characterized by a higher spatial coherence diffract with a considerably higher efficiency than the low-coherence areas. In addition, the character of the speckle-structure distribution of the optical field of the diffracted beam is practically isotropic.