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1.
Zusammenfassung Im System Hafnium-Quecksilber wurde im Temperaturbereich zwischen 500° C und 800° C nur eine Verbindung Hf2Hg gefunden. Für diese Verbindung wird eine tetragonale Elementarzelle mita=3,345 Å,c=11,496 Å,c/a=3,436, Raumgruppe D 4h 17 –I 4/mmm vom MoSi2-Typ vorgeschlagen.
Investigations in the system hafnium—mercury have shown the existence of only one intermetallic compound Hf2Hg. The structure is supposed to be tetragonal of the MoSi2-type,a=3.345 Å,c=11.496 Å,c/a=3.436, belonging to the space group D 4h 17 –I 4/mmm.
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2.
Zusammenfassung Im Zweistoff: Zr–Al bzw. Hf–Al werden zwei neue Kristallarten Zr2Al und Hf2Al mit CuAl2-Struktur nachgewiesen; die Parameter sind:a=6,840 bzw. 6,762 undc=5,490 bzw. 5,374 kX·E. In den Dreistoffen: Zr–Al–Si und Hf–Al–Si besteht jeweils ein lückenloser Übergang zwischen den isotypen Phasen Zr2Al und Zr2Si bzw. Hf2Al und Hf2Si.  相似文献   

3.
The crystal structure of LiEu3O4 which represents a new structure type was solved by usual methods with the aid of integrated WEISSENBERG photographs (MoKα radiation, 787 reflexions) and refined to a reliability index of 4.3%. In LiEu3O4 just as in the first known europium(II, III)-oxide, Eu3O4, a clear distinction is possible between the divalent and trivalent europium ions. The given assignment which is based on crystal chemical arguments has been verified indirectly by means of the isostructural compound LiSr2EuO4, the cation distribution of which was established experimentally. The structure of LiEu3O4 is discussed in connection with the related oxides EuO and Eu3O4. The geometrical relations to the latter are of special interest, as LiEu3O4 undergoes a topotactical transformation into Eu3O4 by heating it in a high vacuum. There is an astonishing close structural relationship between LiEu3O4 and Yb3S4: except for lithium all the atoms are correlated as for isostructural compounds.  相似文献   

4.
The crystal structure of the hexagonal Ag3Co(CN)6 (a = 7.03 Å, c = 7.13 Å, Z = 1) has been determined by X-ray powder methods. The structure factor calculations based on the space group D lead to a reliability index R of 0.062, the R̃-value from F2-sums of systematically coinciding reflections being 0.064. The cobalt atoms are located in the position 1 a (0,0,0), the silver atoms in 3g (1/2,0,1/2;0,1/2,1/2;1/2,1/2,1/2). The carbon and nitrogen atoms occupy the position 6k. The interatomic distance are: Co-C = 1.89 Å, C-N = 1.14 Å, Ag-N = 2.06 Å. The angle C-N-Ag is 157.3º.  相似文献   

5.
The crystal structure of Ru2Ge3 has been determined and refined by Fourier synthesis using pseudo-tetragonal X-ray data resulting from twinned crystals. The true symmetry is orthorhombic with space group Pnca-D 2h 14 and the lattice parameters are:a=5.718,b=11.436 andc-9.240 Å. Ru2Ge3 is a member of the Mn11Si19 structure family which is characterized by the occurrence of different compositions in the rangeTB 2?x (x≤0.75,T=transition metal andB=group III or IV metal). The compounds Ru2Si3, Os2Si3, Os2Ge3, and Ir2(Ga0.6Ge0.4)3 are isostructural.  相似文献   

6.
Li2SnO3 crystallises monoclinic, C, with a = 5.295, b = 9.184, c = 10.032 Å and β = 100.13°; Z = 8. The positions of Sn were obtained from PATTERSON maps and the positions of O and Li by FOURIER difference method. Parameters were refined by least squares-method [1462 reflexes (h 01)–(h 71); R = 10.5%]. The average distances of Li? O are 2.07 Å, and 2.20 Å for Sn? O. The Li2SnO3 structure can be derived from the NaCl type: in a cubic closest packing of oxygen 2/3 of the octahedral holes are occupied by lithium and 1/3 by tin.  相似文献   

7.
The crystal structure of Ru2Si3 has been refined by leastsquares using three-dimensional X-ray data from a twinned crystal (1355 reflections,R=5.8%). Ru2Si3 is isostructural with Ru2Ge3 and like this compound a member of the Mn11Si19 structure family. The lattice parameters of the orthorhombic unit cell (Pnca—D 14 2h ) are:a=5.530 (1),b=11.060 (2) andc=8.952 (2) Å.

Mit 1 Abbildung  相似文献   

8.
9.
The crystal structure of the hexagonal H3Co(CN)6 (a = 6.43 Å, c = 5.70 Å, Z = 1) has been determined by X-ray powder methods. The space group is D (at least pseudo), the cobalt atoms being in (0, 0, 0). Structure factor calculations lead to a final R-value of 13.2%, based on F2-sums of coinciding reflections. The carbon and nitrogen atoms are located at the vertices of a slightly distorted octahedron around the cobalt atom; the angle Co? C? N is 177°. The interatomic distances are: Co? C = 1.89 Å, Co? N = 2,98 Å, C? N = 1.09 Å. The pseudo-octahedral units of Co(CN)6 are linked together by N? H? N bridges. Infrared spectra show that the most probable linkage is the one with a N? H? N-bond length of 2.7 Å.  相似文献   

10.
Crystal Structure of Li2TeO3 Crystals of Li2TeO3 were prepared from melts. Li2TeO3 crystallizes in the monoclinic system, space group C2/c. The lattice parameters are a = 5.069, b = 9.566, c = 13.727 Å, β = 95.4°. The formular unit is 8. The crystal structure has been determined by Patterson and threedimensional differential Fourier synthesis refined by least squares using isotropic temperature corrections. The final R-value of 772 observed reflections is 0.101. Li2TeO3 forms a layer lattice consisting of trigonal TeO3 pyramids and deformed LiO4 tetrahedrons. The TeO3 pyramids are only connected with the corners of LiO4 groups, which are linked one with another by common corners and edges.  相似文献   

11.
12.
Zusammenfassung Die Kristallstruktur von Li2GeO3 wird mit Hilfe dreidimensionalerFourier-Synthesen und nach der Methode der kleinsten Quadrate bestimmt. Li2GeO3 ist isotyp mit Li2SiO3 und enthält [GeO3]2–-Ketten (Zweiereinfachkette). Die Gitterparameter der rhombischen Elementarzelle (C 2v 12 –Cmc21) betragen:a=9,630,b=5,465 undc=4,850 Å. Als mittlere interatomare Abstände wurden erhalten: Ge–O=1,74 und Li–O=2,01 Å.
The crystal structure of Li2GeO3 has been determined by means of 3-dimensional Fourier syntheses and least-squares method. Li2GeO3 is isostructural with Li2SiO3, containing [GeO3]2–-chains (Zweiereinfachkette). The lattice parameters of the orthorhombic cell (C 2v 12 –Cmc21) are:a=9,630;b=5,465 andc=4,850 Å. The average interatomic distances are found to be: Ge–O=1,74 and Li–O=2,01 Å.


Mit 3 Abbildungen  相似文献   

13.
Zusammenfassung In den Dreistoffen: Uran–T (Ti,V,Cr,Mn,Co,Nb,W)–{Si,Al} werden Legierungen auf dem Schnitt U(T,Si)2 bzw. U(T,Al)2 aus den Komponenten hergestellt und röntgenographisch identifiziert*. Es bestehen die ternären Verbindungen U2Cr3Si, U4Mn5Si3 und U2Co3Si, die sich als mit MgZn2 isotyp erweisen.  相似文献   

14.
Zusammenfassung Die Struktur einer ternären Phase im System Fe–Zr–P wurde mit Hilfe von Einkristallaufnahmen bestimmt und verfeinert. Die Kristallart entspricht der vonVogel undDobbener aufgefundenen Phase Fe4ZrP2 und hat eine Idealzusammensetzung von Fe12Zr2P7. Die Gitterparameter der hexagonalen Kristallart sinda=9,0002 undc=3,5920 Å, die Raumgruppe ist . Die Struktur ist mit jener von Fe2P verwandt.
The crystal structure of a ternary phase in the system Fe–Zr–P has been determined and refined by means of singlecrystal X-ray methods. The phase, already described byVogel andDobbener as Fe4ZrP2, has the ideal composition Fe12Zr2P7. The cell dimensions are found to be:a=9,0002 andc=3,5920 Å, the space group is . The crystal structure of Fe12Zr2P7 is related to Fe2P.


Mit 3 Abbildungen  相似文献   

15.
Crystal Structure of BaTeO3 Crystals of BaTeO3 were prepared from melts. BaTeO3 is isotropic with KClO3 and crystallizes in the monoclinic system, space group P21/m. The lattice parameters are a = 4.633, b = 5.952, c = 7.308 Å, β = 111.2°. The formula unit is 2. The crystal structure was determined by Patterson synthesis, refined by least squares and confirmed by (Fo — Fc) synthesis. Using isotropic temperature corrections the R-value of 1072 observed reflections calculated as 0.748, and anisotropic the R-value as 0.702. In BaTeO3 tellurium forms with three oxygen atoms pyramidal TeO3-groups, barium has to oxygen atoms the coordination 7+2. The TeO3 groups are not linked one with another, but with the BaO9 polyhedrons by common corners and edges, the latter are linked one with another only by common edges.  相似文献   

16.
Zusammenfassung Im System: Th-Ga wird die Phase ThGa2 mit -ThSi2-Typ aufgefunden, im System: Ru-In werden die Phasen RuIn3 mit CoGa3-Struktur sowie eine Ru-reiche Phase mit hexagonal dichter Packung machgewiesen.Herrn Professor Dr.Erich Hayek zum 60. Geburtstag.  相似文献   

17.
The Crystal Structure of α-CaCr2O4 Single crystals of the high temperature modifikation α-CaCr2O4 were investigated by X-Ray goniometer data. (a = 11.059, b = 5.836, c = 5.114 Å, space group D–Pmmn). α-CaCr2O4 is isotypic with SrCr2O4.  相似文献   

18.
Crystal Structure of AlI3 · 2 PI3:P2I5+ AlI4? The crystal structure of the title compound was determined from single crystal X-ray data. P2I5+AlI4? crystallizes in the orthorhombic space group Pbca, a = 1 088.3, b = 1 827.3, c = 2 031.6 pm, V = 4040 · 106 pm3, Z = 8. The P2I5+ and AlI4? ions are connected by weak iodine-iodine bonds (I? I distances between 343.5 and 376.3 pm). The mean P? I and Al? I bond lengths were found to be 240.9 and 252.9 pm respectively.  相似文献   

19.
Zusammenfassung Die Kristallstruktur des Lithiumorthosilicats wurde mittels dreidimensionaler Fourier-Synthesen und nach der Methode der kleinsten Quadrate bestimmt. Die Gitterparameter der monoklinen Elementarzelle (C 2h 2 –P21/m) betragen:a=5,14;b=6,10;c=5,30 Å und =90,5°. Die Struktur enthält isolierte [SiO4]-Tetraeder, welche durch [LiO n ]-Polyeder (n=4, 5, 6) verknüpft sind. Hervorzuheben ist, daß sämtliche Lithiumlagen nur partiell besetzt sind. Als mittlerer Si–O-Abstand wurde 1,632 Å erhalten; als Mittelwerte der Li–O-Abstände für die verschiedenen Koordinationszahlen ergeben sich: 1,975 [4]; 2,099 [5] und 2,247 [6] Å.
The crystal structure of lithium orthosilicate has been determined by means of three-dimensional Fourier syntheses and the least squares method. The lattice parameters of the monoclinic unit cell (P21/m–C 2h 2 ) are:a=5.14;b=6.10;c=5.30 Å and =90.5°. The crystal structure contains isolated [SiO4]-tetrahedra being connected by [LiO n ]-polyhedra (n=4, 5, 6). The positions of the lithium atoms are partially occupied only. The average interatomic Si–O distance is found to be 1.632 Å. The averaged values for Li–O distances given for the different coordination numbers are: 1.975 [4]; 2.099 [5] and 2.247 [6] Å.


Mit 4 Abbildungen  相似文献   

20.
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