Separation of the alkaloids deoxypeganine,peganol, and deoxyvasicinone by the HPLC method

Institute of Chemistry of Plant Substances Academy of Sciences of the Uzbek SSR, Tashkent. Scientific Center for Chromatography, Academy of Sciences of the Uzbek SSR. Institute of the Chemistry and Physics of Polymers, Academy of Sciences of the Uzbek SSR, Tashkent. Iranslated from Khimiya Prirodnykh Soedinenii, No. 2, pp. 297–298, March–April, 1991.     

Molecular structure of 1-morpholino-3-phenyl-5,6,7,8-tetrachloro-1,2,4-benzothiadiazine

Institute of Organic Chemistry, Academy of Sciences of the Ukrainian SSR. Institute of Applied Physics, Academy of Sciences of the Moldavian SSR. Translated from Zhurnal Strukturnoi Khimii, Vol. 32, No. 2, pp. 172–174, March–April, 1991.     

Crystal structure of 3-[dimethyl-4-phenyl-3,5-dioxacyclohexyl)-methyl]-1,5,8,11-tetraoxacyclotridecane

Institute of Applied Physics, Academy of Sciences of the Moldavian SSR. Physical Chemistry Institute, Academy of Sciences of the Moldavian SSR. Translated from Zhurnal Strukturnoi Khimii, Vol. 32, No. 3, pp. 136–138, May–June, 1991.     

Electronic structure of the π-dianions and π-dications of porphyrins

Institute of Physics, Academy of Sciences of the Belorussian SSR. Institute of Physical Organic Chemistry and Coal Chemistry, Academy of Sciences of the Ukrainian SSR. Translated from Zhurnal Strukturnoi Khimii, Vol. 32, No. 5, pp. 42–51, September–October, 1991.     

Crystal and molecular structure of 2-hydroxy-5-methylphenyl cyclohexyl ketone

Physicotechnical Institute, Academy of Sciences of the Tadzhik SSR. Institute of Inorganic Chemistry, Siberian Branch, Academy of Sciences of the USSR. Translated from Zhurnal Strukturnoi Khimii, Vol. 31, No. 5, pp. 152–155, September–October, 1990.     

Molecular structure of N,N-(β-chloroethyl-β-cyanoethyl)-amidophosphoryldibenzo-17-crown-6

Institute of Organic Chemistry, Academy of Sciences of the Ukrainian SSR. Institute of Chemical Physics, Academy of Sciences of the USSR. Translated from Zhurnal Strukturnoi Khimii, Vol. 32, No. 2, pp. 175–179, March–April, 1991.     

Electronic structure of lanthanides in orthoborates with various structures

Institute of Chemistry, Ural Branch, Academy of Sciences of the USSR. A. V. Bogatskii Physicochemical Institute, Academy of Sciences of the Ukrainian SSR. Translated from Zhurnal Strukturnoi Khimii, Vol. 32, No. 1, pp. 26–33, January–February, 1991.     

Synthesis and membrane activity of new derivatives of 2,3-benzo-18-crown-6

The acylation of 2,3-benzo-18-crown-6 with carboxylic acids in the presence of polyphosphoric acid has given new acyl derivatives which have been reduced to the corresponding alkyl derivatives. The ionophoric activities of the compounds have been investigated on mitochondrial membranes.Institute of Biochemistry, Academy of Sciences of the Uzbek SSR, Tashkent. Institute of Bioorganic Chemistry, Academy of Sciences of the Uzbek SSR, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 5, pp. 634–637, September–October, 1983.     

X-ray structural investigation of alkaloids. II. Molecular structure and absolute configuration of (?)-pseudokopsinine

Summary By a complete x-ray structural investigation, the structural formula of (–)-pseudokopsinine has been refined and its absolute configuration has been determined.Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow. Institute of the Chemistry of Plant Substances, Academy of Sciences of the Uzbek SSR, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 2, pp. 197–206, March–April, 1976.     

Total synthesis of the racemic alkaloid diptocarpamine

A route for the synthesis of racemic diptocarpamine from hex-5-enoic acid has been developed.Institute of Chemistry, Bashkir Scientific Center of the Urals Branch, USSR Academy of Sciences, Ufa. Institute of the Chemistry of Plant Substances, Uzbek SSR Academy of Sciences, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 2, pp. 232–236, March–April, 1989.     

Synthesis of protected oligopeptides representing fragements of histone fraction HI

Summary Protected oligopeptides corresponding to sequences (31–40) of histone fraction HI of rabbit thymus and (34–41) of histone fraction HI of calf thymus and a number of their analogs have been synthesized.Institute of Molecular Biology, Academy of Sciences of the USSR, Moscow. Institute of Chemistry, Academy of Sciences of the Tadzhik SSR, Dushanbe. Translated from Khimiya Prirodnykh Soedinenii, No. 1, pp. 87–93, January–February, 1977.     

Synthesis of the racemic alkaloid diptocarpilidine

A convenient approach to the synthesis of the racemic alkaloid diptocarpilidine from the readily available l-hydroxy-7-thiaoctane has been developed.Institute of Chemistry, Bashkir Scientific Center, Urals Branch Academy of Sciences of the USSR, Ufa. Institute of Chemistry of Plant Substances, Academy of Sciences of the Ubzek SSR, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 2, pp. 261–263, March–April, 1991.     

Structure of stachysolone

Summary It has been shown that stachysolone — a bitter substance fromStachys annua L. — is a diterpenoid with a rearranged labdane hydrocarbon skeleton of the kolavane type. Structural formula (I) has been established for stachysoloneInstitute of Chemistry, Academy of Sciences of the Moldavian SSR. Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czechoslovakian SSR. Translated from Khimiya Prirodnykh Soedinenii, No. 3, pp. 295–299, May–June, 1972.     

The structure and stereochemistry of teucrin A

Summary The structure of teucrin A has been confirmed by spectral and chemical methods and the relative configurations at all the asymmetric centers have been shown.Institute of Chemistry, Academy of Sciences of the Moldavian SSR. Novosibirsk Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR. Translated from Khimiya Prirodnykh Soedinenii, No. 2, pp. 169–175, March–April, 1973.     

Isolation and antibiotic properties of cis-hexadeca-4,7,10,13-tetraenoic acid from the algaScenedesmus obliquus UA-2-6

Summary By the method of checking antibiotic activity, conditions have been selected for the isolation of cis-hexadeca-4,7,10,13-tetraenoic acid from the fatty-acid fractions of the lipids ofScenedesmus obliquus UA-2-6. Its structure has been confirmed and it has been established that this acid possesses a broad spectrum of antibiotic action.Institute of Microbiology, Academy of Sciences of the Uzbek SSR, Tashkent. Institute of the Chemistry of Plant Substances, Academy of Sciences of the Uzbek SSR, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 3, pp. 379–385, May–June, 1978.     

X-ray structural investigation of alkaloids. III. Molecular structure and absolute configuration of (+)-excelsine

Summary On the basis of a complete x-ray structural investigation, the structural formula of (+)-excelsine has been refined and its absolute configuration has been determined.Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow. Institute of the Chemistry of Plant Substances, Academy of Sciences of the Uzbek SSR, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 2, pp. 206–217, March–April, 1976.     

Difference-perturbation spectra of iodotyrosines and iodothyronines in polyethyleneglycols

The difference-perturbation absorption spectra of monoiodotyrosine, diiodotyrosine, triiodothyronine, and thyroxine with low- and high-molecular-mass polyethyleneglycols as perturbants have been measured and characterized. The SDP spectra, and their intensity and the position of the main maximum depend on the number of iodine atoms and the state of ionization of the hydroxyl in accordance with their electron-accepting properties.Institute of Physiology, Uzbek SSR Academy of Sciences, Tashkent. Institute of Biochemistry, Uzbek SSR Academy of Sciences, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, Vol. 6, pp. 840–845, November–December, 1989.     

Total synthesis of racemic diptocarpidine and diptocarpiline

Convenient methods for the synthesis of racemic diptocarpidine and racemic diptocarpiline have been proposed on the basis of the readily available 6-phthalimidohexyl bromide and hept-6-enoic acid.Institute of Chemistry, Bashkir Branch, Academy of Sciences of the USSR, Ufa. Institute of the Chemistry of Plant Substances, Academy of Sciences of the Uzbek SSR, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 1, pp. 76–82, January–February, 1988.     

Glucofructans of Cousinia polycephala

Institute of Organic Chemistry, Kirghiz SSR Academy of Sciences, Frunze. Institute of Plant Substances, Uzbek SSR Academy of Sciences, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 3, pp. 427–429, May–June, 1989.