共查询到20条相似文献,搜索用时 31 毫秒
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Manuela Gaab Stéphane Bellemin‐Laponnaz Dr. Lutz H. Gade Prof. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2009,15(22):5450-5462
Trapped in a “tea bag” : Membrane bags, fabricated from a dialysis membrane, have been employed as semipermeable containers for dendrimer‐immobilised oxazoline–copper(II) Lewis acid catalysts. Dipping them into reactant solutions leads to the catalytic conversion of the substrates, which penetrate the membrane as does the product in the reverse direction (see scheme).
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Serpil Boz Meike Stöhr Dr. Umut Soydaner Marcel Mayor Prof. 《Angewandte Chemie (International ed. in English)》2009,48(17):3179-3183
Like pearls on a string , molecular building blocks have been preorganized and then interlinked on a surface (see STM images). In this way both the supramolecular self‐assembly of the reactants as well as the subsequent thermal activation to release the protecting group are controlled.
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Jing Tan Xianxiu Xu Dr. Lingjuan Zhang Yifei Li Qun Liu Prof. 《Angewandte Chemie (International ed. in English)》2009,48(16):2868-2872
Up to four adjacent stereocenters can be formed stereoselectively in the construction of a pyrrolizidine unit through a novel organocatalytic reaction that involves treatment of various dienones with ethyl isocyanoacetate (see scheme; DBU=1,8‐diazabicyclo[5.4.0]undec‐7‐ene). Mechanisms for this atom‐economic, one‐pot synthesis have been proposed.
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Rocío Ponce Ortiz Dr. Juan Casado Prof. Víctor Hernández Prof. Juan T. López Navarrete Prof. Joseph A. Letizia Dr. Mark A. Ratner Antonio Facchetti Prof. Tobin J. Marks Prof. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2009,15(20):4959-4959
Molecular semiconductors in the guise of three diazine‐functionalized oligothiophenes have been synthesized and their structural, optical, vibrational, electrochemical, and semiconductor properties studied. In their Full Paper on page 5023 ff. , J. T. López Navarrete, A. Facchetti, T. J. Marks et al. describe how these diazine‐functionalized oligothiophenes are reasonably efficient hole transporters.
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Thomas K. Wood Warren E. Piers Brian A. Keay Masood Parvez 《Angewandte Chemie (International ed. in English)》2009,48(22):4009-4012
2009: A boraanthracene odyssey : General routes to boraanthracene derivatives—long proposed, but never observed—are disclosed, along with the structural and photophysical properties of these compounds and their remarkable reactivity towards oxygen.
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Soluble InP and GaP Nanowires: Self‐Seeded,Solution–Liquid–Solid Synthesis and Electrical Properties
Zhaoping Liu Kai Sun Dr. Wen‐Bin Jian Prof. Dr. Dan Xu Yen‐Fu Lin Jiye Fang Prof. Dr. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2009,15(18):4546-4552
A facile, self‐seeded , solution–liquid–solid growth of soluble InP and GaP nanowires with a very low amount of native point defects with respect to the carrier concentrations have been synthesized (see scheme) and characterized. They are potentially promising building blocks in optoelectronic applications.
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Gregory A. Chass Dr. Christopher J. O'Brien Dr. Niloufar Hadei Dr. Eric Assen B. Kantchev Dr. Wei‐Hua Mu De‐Cai Fang Prof. Alan C. Hopkinson Prof. Imre G. Csizmadia Prof. Michael G. Organ Prof. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2009,15(17):4281-4288
Why bigger is better : A “steric wall” created by the N‐(2,6‐diisopropylphenyl) substituent on the bulky NHC ligand IPr (1,3‐bis(2,6‐diisopropylphenyl)imidazol‐2‐ylidene) guides the reactants to and from the Pd center through weak, fleeting (IPr)H–Pd interactions that help the oxidative addition intermediate escape “the anti‐trap”. The alternative “side” approach leads to transmetalation (the rate‐limiting step) for which a novel Pd–Zn interaction was identified.
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Ruihu Wang Dr. Yong Guo Dr. Zhuo Zeng Dr. Brendan Twamley Dr. Jean'ne M. Shreeve Prof. Dr. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2009,15(11):2625-2634
Insensitive energetic salts : A series of furazan‐functionalized tetrazolate‐based energetic salts (see figure) were synthesized and characterized. All of the salts exhibit excellent thermal stabilities and high positive heats of formation.
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Junghan Lee Youngseon Choi Dr. Junwon Kim Dr. Eunjung Park Rita Song Dr. 《Chemphyschem》2009,10(5):806-811
Selective DNA detection: The fluorescence, from stable cationic QDs, is quenched by 90% on complexation with modified DNA molecules. The QD–DNA probe is capable of detecting pathogenic DNA fragments at concentrations as low as 200 nM in solution and shows selective fluorescence recovery in the presence of target DNA (see spectrum c in figure) vs noncomplementary DNA (spectrum d).
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Johann Elbaz Michal Moshe Bella Shlyahovsky Itamar Willner Prof. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2009,15(14):3411-3418
Self‐assembly line : In the presence of a DNA analyte or low‐molecular‐weight substrates, multicomponent nucleic acids self‐assemble into cooperatively stabilized functional nanostructures (see scheme) that activate DNAzyme cascades.
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Ji‐Ho Yoon Prof. Yun‐Je Lee Jeasung Park Dr. Taro Kawamura Dr. Yoshitaka Yamamoto Dr. Takeshi Komai Dr. Satoshi Takeya Dr. Sang Sup Han Dr. Jong‐Won Lee Prof. Yongjae Lee Prof. 《Chemphyschem》2009,10(2):352-355
Easy come, easy go: Hydroquinone forms a channel structure of cages with hydrogen‐bonded hexagons. These may provide an ideal route for the fast inclusion and facile release of hydrogen molecules (see figure), which can lead to reversible hydrogen storage under mild conditions.