共查询到20条相似文献,搜索用时 625 毫秒
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本文在室温到300℃的温度范围内研究了Li4SiO4-Li3VO4和Li4GeO4-Li4SiO4-Li3VO4体系中的离子导电性,发现γII相固溶体Li3+xV1-xSixO4是好的锂离子导体。所研究的成分中Li3.3V0.7Si0.3O4的离子电导率最高,室温下为1×10-5Ω-1·cm-1,在42—192℃的电导激活能为0.36eV,电子电导率可以忽略,因而这是迄今所发现的最好的锂离子导体之一。粗略确定了Li4GeO4-Li4SiO4-Li3VO4三元系中电导率高的范围,发现在Li3.5V0.5Ge0.5O4中Si部分取代Ge可以使电导率进一步提高,Li3.5V0.5Ge0.4Si0.1O4的室温电导率可达1.3×10-5Ω-1·cm-1,电导激活能为0.40eV。
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本文综述了近年来关于横场伊辛链模型及量子E8可积模型研究工作的一系列理论及实验进展.在针对横场伊辛链的研究工作中,理论上发现格林艾森比率(热或磁胀系数与比热之比)在此模型中独特的奇异量子临界行为,并实质性地扩展了能涌现横场伊辛链普适类的微观模型.这些理论进展成功地推进了一系列合作实验在准一维反铁磁材料BaCo2V2O8及SrCo2V2O8中首次实现横场伊辛链普适类.在针对量子E8可积模型的研究工作中,理论上严格计算了该系统的低温局域动力学行为及在零转移动量之时的动力学结构因子,并在动力学结构因子的连续谱区域得到了级联幂次发散的奇性谱边激发.这些理论进展在结合详细的量子临界标度行为分析及大规模iTEBD数值计算之后,成功促成了包括太赫兹谱学测量、非弹性中子散射、核磁共振等系列实验,在BaCo2V2O8中首次实现量子E8可积模型.... 相似文献
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用X射线衍射和磁测量手段研究了Ni部分替代Fe对具有ThMn12结构的Rfe11.3Nb0.7(R=Gd,Tb,Dy,Ho,Er和Y)化合物的结构与磁性的影响.研究表明,Ni部分替代Fe不改变晶体结构,但引起了晶胞体积收缩.随着Ni含量的增加,居里温度TC迅速上升,而饱和磁化强度Ms则单调减小.Ni部分替代Fe还导致了Fe次晶格的轴各向异性的迅速降低和RF11.3Nb0.7(R=Tb,Dy,Er)化合物中自旋重取向温度Tsr的变化.Tsr与Ni含量的关系用晶场理论给出了定性的解释.
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用水热法新工艺在温度为200—220℃,pH值为6—9条件下合成出Mn2V2O7粉晶.利用X射线衍射(XRD)、扫描电子显微镜(SEM)、能谱分析(EDS)、透射电子显微镜(TEM)、高分辨透射电镜(HRTEM)和电子衍射(SAED)分析了其物相、形貌及微结构,结果表明:合成产物均为单斜晶系的钪钇石型β-Mn2V2O7;当合成温度为200℃时,pH值为6—7时合成产物的形貌为
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水热法
2V2O7')" href="#">β-Mn2V2O7
结构与形貌
反铁磁性 相似文献
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MAGNETIC PROPERTIES OF NEW SERIES R-Mo-Fe NITRIDES WITH THE ThMn12-TYPE STRUCTURE AT A LOWER Mo CONTENT
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A systematic study has been made on formation condition, crystallographic structure and magnetic properties of RMo1.5Fe10.5Nx, where R=Y, Ce, Pr, Nd, Sm, Gd, Tb, Dy, Ho, Er. The interstitial nitrogen atom effects on Curie temperature, saturation magnetization and magneto-crystalline anisotropy have been investigated. Two important preliminary results have been obtained. (1) A single phase crystallized in the ThMn12-type structure was stabilized with a smaller content of molybdenum, thus, the compounds possess a higher Curie temperature and a larger spontaneous magnetization. (2) A complete system of compounds with 1:12 type structure containing the light rare earth cerium and praseodymium was synthesized, which will be favorable for developing new rare earth hard magnetic materials. 相似文献
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Debabrata Mishra P. Saravanan A. Srinivasan 《Journal of magnetism and magnetic materials》2009,321(24):4097-4102
The temperature and field dependent magnetic properties of melt-spun amorphous Fe89−x−yZr11Bx(Co,Mn)y (x=5, 10 and 0≤y≤10) alloys in the temperature range 5-1200 K are reported. The Curie temperature and saturation magnetization at room temperature increase (decrease) almost linearly with Co (Mn) addition. With increasing Co concentration, the room temperature coercivity increases at the rate of 2.26 (0.28) A/m per at% for the x=5 (10) samples. The high-field magnetic susceptibility and local magnetic anisotropy decrease (increases) rapidly with increasing Co (Mn) concentration. The thermomagnetic curves show a marked increase in magnetization above 850 K corresponding to the crystallization of α-FeCo (α-Fe) phase in samples containing Co (Mn). The Curie temperature of the crystalline phase increases (remains same) with increasing Co (Mn) concentration with the formation of α-FeCo (α-Fe). Addition of Co up to 10 at% in Fe-Zr-B improves the room temperature saturation magnetization from 0.56 to 1.2 T, and Curie temperature from 315 to 476 K. Also, the coercivity increases with Co addition from 1.27 to 23.88 A/m for x=5 and from 7.64 to 10.35 A/m for x=10 alloy. The non-collinear spin structures that characterize Fe rich Fe-Zr-B amorphous alloys have been used to describe the observed results. 相似文献
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T.J.A. Popma A.M. van Diepen P.F. Bongers 《Journal of Physics and Chemistry of Solids》1974,35(2):201-205
The behaviour of the magnetization, Curie temperature, Mössbauer spectra, and lattice parameter is studied in the garnet series Bi0·8Ca2.χT2·2-2.χFe5-χVχ]O12. The shape of magnetization vs temperature curves shows only a minor dependence on x. The hyperfine field at the octahedral 57Fe nuclei at 5°K decreases linearly with x (12·5kOe per substituted V neighbour), while that at the tetrahedral 57Fe nuclei is not affected. The dependence of the Curie temperatures and hyperfine fields on x is discussed in relation to the Fe-O-V-O-Fe exchange. The influence of Bi substitution is consistent with the idea of a geometric effect. 相似文献
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In this work, we have investigated the effect of the substitution of Gd for Pr on the crystal structure and magnetic properties of the Pr1−xGdxCo4B compounds for 0?x?1 using X-ray powder diffraction, magnetic measurements, and differential scanning calorimetry (DSC). These compounds have hexagonal CeCo4B-type structure with the space group P6/mmm. The substitution of Gd for Pr leads to a decrease of the unit-cell parameters a and the unit-cell volume V, while the unit-cell parameter c increases slightly. Magnetic measurements indicate that all samples are ordered magnetically below room temperature. The Curie temperatures determined by DSC technique increase as Pr is substituted by Gd. The saturation magnetization at 5 K decreases upon Gd substitution up to x=0.6, and then increases again. 相似文献
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The crystal and magnetic properties of the Nd1−xGdxCo4B compounds for 0?x?1 have been studied by X-ray powder diffraction, magnetization and differential scanning calorimetry (DSC) measurements. These compounds crystallize in a hexagonal CeCo4B-type structure with the P6/mmm space group. The substitution of Gd for Nd leads to a decrease of the unit-cell parameter a and the unit-cell volume V, while the unit-cell parameter c remains almost constant. Magnetic measurements indicate that all samples are ordered magnetically below room temperature. The Curie temperatures determined by the DSC technique increase linearly as Nd is substituted by Gd. The saturation magnetization at 5 K decreases upon the Gd substitution up to x=0.6, and then increases again. 相似文献
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S. Mizusaki N. Kawamura Y. Nagata A. Sato H. Samata 《Journal of magnetism and magnetic materials》2010,322(13):L19
The single crystal of the new ternary compound Sm12Fe14Al5 was grown and its crystallographic and magnetic properties were investigated. Sm12Fe14Al5 has a hexagonal structure of the space group p-3m1 and shows ferromagnetism with a Curie temperature of 245 K. The easy direction of magnetization is parallel to the c-axis at temperatures between 245 and 85 K; however, it changes to the c-plane below 85 K through a first-order-like phase transition. No saturation is observed in the magnetization curve even under the applied field of 55 kOe at 5 K. Sm12Fe14Al5 seems to have a large coercive field at very low temperatures. The anisotropy field was estimated at 5 and 120 K and the saturation magnetization of low temperature phase is explained assuming a ferromagnetic coupling between Fe and Sm sublattices. 相似文献
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本文报道非晶态Fe13Ni67.2P4.5B15.3合金的磁化强度与温度和磁场关系的测量结果。在居里温度附近样品的磁特性符合二级相变规律,得到临界指数β=0.39±0.02,γ=1.56±0.06,δ=5.20±0.1,样品的居里温度Tc=(180.4±0.2)K。在实验误差范围内,临界指数β,γ,δ满足γ=β(δ-1)关系,在168—192K温度范围,实验数据满足二级相变的磁状态方程。当T>270K时,样品顺磁磁化率服从居里-外斯定律,由居里-外斯常数c计算出有效顺磁磁矩Peff=3.19 μB。
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We report the observation of excellent hard magnetic properties on purely single phase ErCo7−xCux compounds with x=0.3, 0.5, 0.8 and 1. Cu substitution leads to a decrease in the saturation magnetization, but enhances the uniaxial anisotropy in this system. The large anisotropy field (∼100 kOe) is attributed to the Er and the Co sublattices. Domain wall pinning effect seems to play a crucial role in determining the temperature and field dependences of magnetization in these compounds. The hard magnetic properties obtained at room temperature (RT) are comparable to the best results obtained in other RCo7 based materials. 相似文献
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B.S. WangC.C. Li S. LinJ.C. Lin L.J. LiP. Tong W.J. LuX.B. Zhu Z.R. YangW.H. Song J.M. DaiY.P. Sun 《Journal of magnetism and magnetic materials》2011,323(15):2017-2022
We report the effects of Al doping on the structure, magnetic properties, and magnetocaloric effect of antiperovskite compounds Ga1−xAlxCMn3 (0≤x≤0.15). Partial substitutions of Al for Ga enhance the Curie temperature (from 250 K for x=0.0 to 312 K for x=0.15) and the saturation magnetization. On increasing the doping level x, the maximum values of the magnetic entropy change (−ΔSM) decreases while the temperature span of −ΔSM vs. T plot broadens. Furthermore, the relative cooling power (RCP) is also studied. For 20 kOe, the RCP value tends to saturate at a high doping level (for x=0.12, 119 J/kg at 296 K). However, at 45 kOe, the RCP value increases quickly with increasing x (for x=0.15, 293 J/kg at 312 K). Considering the relatively large RCP and inexpensive raw materials, Ga1−xAlxCMn3 may be alternative candidates for room-temperature magnetic refrigeration. 相似文献