From coherent to incoherent mismatched interfaces: A generalized continuum formulation of surface stresses

The equilibrium of coherent and incoherent mismatched interfaces is reformulated in the context of continuum mechanics based on the Gibbs dividing surface concept. Two surface stresses are introduced: a coherent surface stress and an incoherent surface stress, as well as a transverse excess strain. The coherent surface stress and the transverse excess strain represent the thermodynamic driving forces of stretching the interface while the incoherent surface stress represents the driving force of stretching one crystal while holding the other fixed and thereby altering the structure of the interface. These three quantities fully characterize the elastic behavior of coherent and incoherent interfaces as a function of the in-plane strain, the transverse stress and the mismatch strain. The isotropic case is developed in detail and particular attention is paid to the case of interfacial thermo-elasticity. This exercise provides an insight on the physical significance of the interfacial elastic constants introduced in the formulation and illustrates the obvious coupling between the interface structure and its associated thermodynamics quantities. Finally, an example based on atomistic simulations of Cu/Cu₂O interfaces is given to demonstrate the relevance of the generalized interfacial formulation and to emphasize the dependence of the interfacial thermodynamic quantities on the incoherency strain with an actual material system.     

Stress-driven interfacial instability of a bilayer structure: The interaction between free surface and interface

The morphological evolution of strained films is of technological importance to microelectronics and nanotechnology. The morphological instability of a bilayer system is analyzed, consisting of an elastic film and an elastic substrate with a misfit strain on the coherent interface. A kinetic model is derived by considering the morphological fluctuations of different perturbation amplitudes along both the free surface and the interface and the coupling effect between the film and the substrate. The couplings include the misfit strain, surface/interface energy, and surface/interface diffusion, which determine the morphological instability of the system. A quadratic dispersion relationship is established for the growth rate of the longitudinal surface and interfacial perturbations along the free surface and the interface, respectively. The propagation of the surface perturbations is revealed from the free surface to the interface, and the characteristic frequencies are identified for the initiation of the morphological instability.     

Irreversible thermodynamics of liquid crystal interfaces

A macroscopic theory for the dynamics of isothermal compressible interfaces between nematic liquid crystalline polymers and isotropic viscous fluids has been formulated using classical irreversible thermodynamics. The theory is based on the derivation of the interfacial rate of entropy production for ordered interfaces, that takes into account interfacial anisotropic viscous dissipation as well as interfacial anisotropic elastic storage. The symmetry breaking of the interface provides a natural decomposition of the forces and fluxes appearing in the entropy production, and singles out the symmetry properties and tensorial dimensionality of the forces and fluxes. Constitutive equations for the surface extra stress tensor and for surface molecular field are derived, and their use in interfacial balance equations for ordered interfaces is identified. It is found that the surface extra stress tensor is asymmetric, since the anisotropic viscoelasticity of the nematic phase is imprinted onto the surface. Consistency of the proposed surface extra stress tensor with the classical Boussinesq constitutive equation appropriate to Newtonian interfaces is demonstrated. The anisotropic viscoelastic nature of the interface between nematic polymers (NPs) and isotropic viscous fluids is demonstrated by deriving and characterizing the dynamic interfacial tension. The theory provides for the necessary theoretical tools needed to describe the interfacial dynamics of NP interfaces, such as capillary instabilities, Marangoni flows, wetting and spreading phenomena.     

Constitutive modeling of complex interfaces based on a differential interfacial energy function

An important theory on the dynamics of complex interfaces is the Doi and Ohta theory where the interfacial contribution to the Cauchy stress tensor is determined from an interfacial conformation tensor. For a uniform deformation field in the Eulerian framework, Doi and Ohta adopted a decoupling approximation to reduce a fourth-order tensor into two second-order tensors and derived a differential equation governing the evolution of the interfacial conformation tensor. In this paper, a different formulation is presented for establishing the Cauchy stress tensor based on a path-independent interfacial energy function. By differentiating this interfacial energy function against a Lagrangian strain tensor, a nearly closed-form solution for the stress tensor was determined, involving only elementary algebraic and matrix operations. From this process, the stress-conformation relation proposed by Doi and Ohta is also confirmed from a thermodynamic perspective. The testing cases with uniaxial elongation and simple shear further showed improved fitting to the analytical or exact solutions.     

Derivation of the general form of elasticity tensor of the transverse isotropic material by tensor derivate

SymbolsU--FunchonofstrainenergyQ--OrthonormaltensorE--StraintensorEar--ComponentsofthestraintensorE,i,j=l,2,3n--VectorofthesymmetricaamsofthetransverseisotropicmaterialU*,E.,n*--FormsofU,EandninanothercoordinatesystemJf--MaininvariantsofstraintensorE,i=l,2,3Jf'n--InvariantsofstraintensorEconnectingwithvectorn,i=4,5Ji--TheabbreviatedformsofJf,Jf,Jf,Jf,",Jf,",i=l,2,3,4,5fi--ConstantsindependentonE,n,i=l,2,3,4,5el,e"--Thecovariantandcontravariantofthonormalbasisoftheusedcoordinatesyste…     

A continuum description of partially coherent interfaces

A continuum model of a two-phase crystal-crystal system is constructed in which the structure of the interface between the phases is determined by energy minimization, rather than by being specified a priori. The interfacial structure is parameterized by a variable? corresponding to the jump in the surface deformation gradient (or strain) at the interface, so that coherence is defined locally by the condition? = 0. The energy of the system is taken to be the sum of the bulk and interfacial energies, where the interfacial energy densityf ^xs depends on?. In order to explore how the equilibrium interfacial structure depends on the functionf ^xs (?), a model system consisting of an elastic film on a rigid substrate is studied, and the interfacial energy density is taken to be nonconvex with a sharp minimum associated with coherence. In this case, it can be shown that the energy of the system is driven to its infimum by separating the interface into coherent and incoherent regions, which may be viewed as a continuum analog to a partially coherent interface. Further, this solution only appears above a certain critical thickness of the film, in agreement with misfit dislocation models of partially coherent interfaces.     

Modeling the interfacial effect on the yield strength and flow stress of thin metal films on substrates

It is shown in this paper that interfacial effects have a profound impact on the scale-dependent yield strength and strain hardening rates (flow stress) of metallic thin films on elastic substrates. This is achieved by developing a higher-order strain gradient plasticity theory based on the principle of virtual power and the laws of thermodynamics. This theory enforces microscopic boundary conditions at interfaces which relate a microtraction stress to the interfacial energy at the interface. It is shown that the film bulk length scale controls the size effect if a rigid interface is assumed whereas the interfacial length scale dominates if a compliant interface is assumed.     

New spatial curved beam and cylindrical shell elements of gradient-deficient Absolute Nodal Coordinate Formulation

Based on previous studies, a new spatial curved slender-beam finite element and a new cylindrical shell finite element are proposed in the frame of gradient-deficient Absolute Nodal Coordinate Formulation (ANCF). The strain energy of the beam element is derived by using the definition of the Green?CLagrange strain tensor in continuum mechanics so that the assumption on small strain can be relaxed. By using the differential geometry and the continuum mechanics, the angle between two base vectors of a defined local coordinate frame of the cylindrical shell element is introduced into the strain energy formulations. Therefore, the new shell element can be used to model parallelogram shells. The analytical formulations of elastic forces and their Jacobian for the above two finite elements of gradient-deficient ANCF are also derived via the skills of tensor analysis. The generalized-alpha method is used to solve the huge set of system equations. Finally, four case studies including both static and dynamic problems are given to validate the proposed beam and cylindrical shell elements of gradient-deficient ANCF.     

纤维复合材料界面横向拉伸分析

以单纤维十字型横向拉伸试验为研究对象,对纤维/基体界面采用弹性-软化双线性内聚力模型,建立了纤维复合材料在横向拉伸作用下界面法向失效过程的解析模型。得到了沿纤维/基体圆周界面的法向应力分布,纤维/基体界面的状态与界面承载力和单纤维复合材料承载力的关系,以及内聚力参数和试件几何尺寸对它们的影响。结果表明:纤维/基体圆周界面在脱粘前经历全部弹性及弹性+软化两种状态;当界面为弹性状态时,界面法向应力随界面强度线性增加;当界面为弹性+软化状态时,界面软化范围随界面裂纹萌生位移的增加而增大;界面初始脱粘位置与拉伸荷载方向重合;界面初始脱粘时的界面承载力随界面强度及界面裂纹萌生位移的增加而增加,随界面裂纹生成位移的增加而降低;单纤维复合材料的脱粘荷载受基体截面尺寸的影响,当纤维体积含量相同时,沿荷载方向截面尺寸的增大对提高脱粘荷载更显著。     

Shear and normal stress relaxation in polymer blends: stress predictions from interface velocity and Laplace pressure terms

We derived for the first time the relationships among shear stress and normal stress differences for ellipsoidal interfaces under large step shear strains considering interface velocity term and Laplace pressure term in the expression of the stress tensor for mixtures of two Newtonian fluids. In the derivation, orientation angle of the interface is assumed to be given by the affine deformation assumption and is independent of time based on experimental results for blends with 0.048 ≤ K ≤ 0.54 where K is the ratio of droplet viscosity to matrix viscosity. For ellipsoidal droplets, the shear stress is only proportional to the first normal stress difference. On the other hand, for spheroidal droplets, proportionality among the shear stress, the first and the second normal stress differences was derived, and the ratio of the second normal stress difference to the first normal stress difference was given as a function of step strain. The shear stress and the first normal stress difference obtained experimentally satisfy the derived relationship, indicating applicability of the stress expression for polymer blends.     

Modeling cylindrical waves in nonlinear elastic composites

A procedure of deriving nonlinear wave equations that describe the propagation and interaction of hyperelastic cylindrical waves in composite materials modeled by a mixture with two elastic constituents is outlined. Nonlinearity is introduced by metric coefficients, Cauchy-Green strain tensor, and Murnaghan potential. It is the quadratic nonlinearity of all governing relations. For a configuration (state) dependent on the radial coordinate and independent of the angular and axial coordinates, quadratically nonlinear wave equations for stresses are derived and a relationship between the components of the stress tensor and partial strain gradient is established. Four combinations of physical and geometrical nonlinearities in systems of wave equations are examined. Nonlinear wave equations are explicitly written for three of the combinations __________ Translated from Prikladnaya Mekhanika, Vol. 43, No. 6, pp. 63–72, June 2007.     

Contemporary perspectives in finite strain plasticity

From an internally consistent theory of finite strain plasticity in which are introduced a new stress tensor that includes rigid body rotation and a compatible finite strain tensor amenable to simple geometrical interpretation, a close correlation with experiment is obtained for stress paths of arbitrary composition and direction. Measured material constants are proportional to the elastic shear modulus, as indicated for dislocation theory. At large strain there exists a quantum mechanical structure for the continuum, in which are defined a series of relative reference configurations and second order transitions.     

Equilibrium of Phases with Interfacial Energy: A Variational Approach

The paper proves the existence of equilibrium two phase states with elastic solid bulk phases and deformation dependent interfacial energy. The states are pairs (y,E) consisting of the deformation y on the body and the region E occupied by one of the phases in the reference configuration. The bulk energies of the two phases are polyconvex functions representing two wells of the substance. The interfacial energy is interface polyconvex. The last notion is introduced and discussed below, together with the interface quasiconvexity and interface null Lagrangians. The constitutive theory and equilibrium theory of the interface are discussed in detail under appropriate smoothness hypotheses. Various forms of the interfacial stress relations for the standard and configurational (Eshelby) interfacial stresses are established. The equilibrium equations are derived by a variational argument emphasizing the roles of outer and inner variations.     

The effect of rotation and initial stress on the propagation of waves in a transversely isotropic elastic solid

In this paper the equations governing small amplitude motions in a rotating transversely isotropic initially stressed elastic solid are derived, both for compressible and incompressible linearly elastic materials. The equations are first applied to study the effects of initial stress and rotation on the speed of homogeneous plane waves propagating in a configuration with uniform initial stress. The general forms of the constitutive law, stresses and the elasticity tensor are derived within the finite deformation context and then summarized for the considered transversely isotropic material with initial stress in terms of invariants, following which they are specialized for linear elastic response and, for an incompressible material, to the case of plane strain, which involves considerable simplification. The equations for two-dimensional motions in the considered plane are then applied to the study of Rayleigh waves in a rotating half-space with the initial stress parallel to its boundary and the preferred direction of transverse isotropy either parallel to or normal to the boundary within the sagittal plane. The secular equation governing the wave speed is then derived for a general strain–energy function in the plane strain specialization, which involves only two material parameters. The results are illustrated graphically, first by showing how the wave speed depends on the material parameters and the rotation without specifying the constitutive law and, second, for a simple material model to highlight the effects of the rotation and initial stress on the surface wave speed.     

Transmission of a screw dislocation across a coherent, non-slipping interface

Current research on nanocrystalline metals and nanoscale multilayer thin films suggests extraordinary plastic strength is due to confinement of slip to individual grains or layers. To assess the magnitude of confinement, a Peierls model of slip transmission of a screw dislocation across a coherent, non-slipping interface is presented. The results reflect that large interfacial barriers to transmission are generated by rapid fluctuations in dislocation line energy near the interface due to elastic modulus mismatch, stacking fault energy mismatch, and antiphase boundary energy for transmission into an ordered phase. Coherency stress is predicted to dramatically alter the dislocation core configuration and impart additional strength regardless of the sign. Contributions to strength are not additive due to nonlinear coupling via the dislocation core configuration. The predicted barrier strength for a coherent (0 0 1) Cu/Ni interface is comparable to atomistic (EAM) results but larger than estimates from hardness data.     

On non-linear Beltrami-Mitchell equations

Beltrami-Mitchell equations for non-linear elasticity theory are derived using the first Piola-Kirchhoff stress and the deformation gradient tensors as field variables so as to yield linear equilibrium and compatibility equations, respectively. In the derivation it is assumed that a strain energy density and, correspondingly, a complementary strain energy density exist, and satisfy the axiom of objectivity. Substitution for the deformation gradient in the compatibility equations yields non-linear differential equations in terms of the first Piola-Kirchhoff stress tensor which may be regarded as the Beltrami-Mitchell equations of non-linear elasticity. The equations are also derived for “semi-linear” isotropic elastic materials and the theory is illustrated by three simple examples.     

A novel internal dissipation inequality by isotropy and its implication for inelastic constitutive characterization

In the present work a novel inelastic deformation caused internal dissipation inequality by isotropy is revealed. This inequality has the most concise form among a variety of internal dissipation inequalities, including the one widely used in constitutive characterization of isotropic finite strain elastoplasticity and viscoelasticiy. Further, the evolution term describing the difference between the rate of deformation tensor and the “principal rate” of the elastic logarithmic strain tensor is set, according to the standard practice by isotropy, to equal a rank-two isotropic tensor function of the corresponding branch stress, with the tensor function having an eigenspace identical to the eigenspace of the branch stress tensor. Through that a general form of evolution equation for the elastic logarithmic strain is formulated and some interesting and important results are derived. Namely, by isotropy the evolution of the elastic logarithmic strain tensor is embodied separately by the evolutions of its eigenvalues and eigenprojections, with the evolution of the eigenprojections driven by the rate of deformation tensor and the evolution of the eigenvalues connected to specific material behavior. It can be proved that by isotropy the evolution term in the present dissipation inequality stands for the essential form of the evolution term in the extensively applied dissipation inequality.     

Analysis of dynamic instability of interfacial slip waves based on the surface impedance tensor

A new method relying on the Stroh formulism and the theory of the surface impedance tensor was developed to investigate the dynamic instability of interfacial slip waves. The concept of the surface impedance tensor was extended to the case where the wave speed is of a complex value, and the boundary conditions at the frictionally contacting interface were expressed by the surface impedance tensor. Then the boundary value problem was transformed to searching for zeroes of a complex polynomial in the unit circle. As an example, the steady frictional sliding of an elastic half-space in contact with a rigid flat surface was considered in details. A quartic complex characteristic equation was derived and its solution behavior in the unit circle was discussed. An explicit expression for the instability condition of the interfacial slip waves was presented.