Microwave electrodynamics of electron-doped cuprate superconductors

We report microwave cavity perturbation measurements of the temperature dependence of the penetration depth, lambda(T), and conductivity, sigma(T) of Pr(2-x)Ce(x)CuO(4-delta) (PCCO) crystals, as well as parallel-plate resonator measurements of lambda(T) in PCCO thin films. Penetration depth measurements are also presented for a Nd(2-x)Ce(x)CuO(4-delta) (NCCO) crystal. We find that Deltalambda(T) has a power-law behavior for T相似文献   

EPR spectroscopy of fullerene adducts

EPR spectroscopy has been used to identify and characterize the paramagnetic adducts of small free radicals with C₆₀ through measurements of the hyperfine interactions of protons and¹³C nuclei. The initially formed mono-radical adducts (RC₆₀) have unpaired spin density localized near the point of attachment of the radical. Generally, they are in thermal equilibrium with their diamagnetic dimer, and have a surprisingly large barrier to internal rotation about the new bond. The tri- and penta-radical adducts have electronic structures similar to those of allyl and cyclopentadienyl radicals, respectively.NRCC No. 35262     

Millimeter and submillimeter EPR spectroscopy

For a long time, the electron paramagnetic resonance (EPR) spectrometers have been operated in X and Q bands with wavelengths of microwave radiation about 3 cm and 8 mm. Increasing the operating frequency improves the basic parameters of an EPR spectrometer. In view of this, there has recently been rapid development of high-frequency EPR spectroscopy, including the submillimeter-wave range, related to significant progress in the millimeter-and submillimeterwave technique. This paper discusses characteristic features, application areas, and the state of the art of the experimental technique of EPR spectroscopy in the millimeter-wave range and the short-wavelength region of the millimeter-wave range. The design features of the high-frequency EPR spectrometer operated in the frequency range 65–1500 GHz, which was created at the E. K. Zavoisky Physico-Technical Institute of the Kazan’ Scientific Center of the Russian Academy of Sciences, are presented. The results of studying the structure of the paramagnetic centers formed by impurity Ho³⁺ ions in synthetic forsterite (Mg₂SiO₄), obtained by the method of tunable high-frequency EPR spectroscopy, are reported.     

Laser hyperacoustic spectroscopy of single crystal germanium

Using a photothermal laser deflection technique the profiles of laser-induced hyperacoustic pulses in single crystal germanium were studied at a subnanosecond time resolution. It is shown that the hyperacoustic pulses are excited due to an electron-deformation interaction of photogenerated carriers with the crystal lattice, which is much more effective than the thermoelastic mechanism of the acoustic wave generation. Evolution of the hyperacoustic pulse profiles related to the diffraction and acoustic absorption effects was studied. An analysis of the hyperacoustic signal profiles allowed us to estimate the coefficient of ambipolar diffusion of the photogenerated charge carriers and the coefficient of hyperacoustic wave damping. It is established that the front of the electron-hole plasma laser-excited in germanium at room temperature propagates at a supersonic velocity.     

EPR of the lithium ion-dangling bond complex in germanium containing dislocations

We have observed a new EPR spectrum in a lithium-diffused germanium crystal N_D-N_A ≈ 10¹³ cm^-3) containing dislocations. The principal g values are 1.917 ± 0.002, 1.896 ± 0.002, and 0.855 ± 0.010 along the axes <1$\text{1}$0>, <11$\text{2}$>, and <111>, plus equivalent sets. As this new spectrum is seen in lieu of the dislocation dangling bond spectrum, we attribute it to a lithium ion- dislocation dangling bond complex.     

Pseudo field modulation in EPR spectroscopy

This paper develops methodology for computer simulation of the effect on an experimental EPR spectrum that would occur if an additional field modulation were applied followed by eventual phase sensitive detection at the modulation frequency or at one its harmonics. The algorithm, which is called pseudomodulation, transforms the digitized spectrum and also filters the noise. If a second harmonic spectrum is desired in order to make subtle changes in curvature more apparent, it is shown that it is always preferable to obtain an experimental second harmonic spectrum. The signals are identical, but because of the filtering properties of the pseudomodulation algorithm, the noise is lower. Pseudomodulation should be applied to simulated spectra prior to fitting a model to data in order more precisely to simulate the experimental signal. It is argued that such fits ought to involve not only first harmonics but also higher harmonics, since the various harmonics are sensitive in different ways to input parameters in the spin Hamiltonian. Application of pseudomodulation to the EPR spectrum of the blue copper-protein azurin is described.     

Microwave modulated polarization spectroscopy

Complex sub-Doppler spectra can be simplified by the application of microwave modulated polarization spectroscopy (MMPS). This new laser spectroscopy technique is based on a combination of Doppler free laser polarization spectroscopy with microwave optical polarization spectroscopy (MOPS). The method has been used to label particular optical lines in the B²σ-X²σ spectrum of SrF.     

Angle-resolved photoemission spectroscopy of electron-doped cuprate superconductors: isotropic electron-phonon coupling

We have performed high resolution angle-resolved photoemission (ARPES) studies on electron-doped cuprate superconductors Sm2-xCexCuO4 (x=0.10, 0.15, 0.18), Nd2-xCexCuO4 (x=0.15), and Eu2-xCexCuO4 (x=0.15). Imaginary parts of the electron removal self energy show steplike features due to an electron-bosonic mode coupling. The steplike feature is seen along both nodal and antinodal directions but at energies of 50 and 70 meV, respectively, independent of the doping and rare earth element. Such energy scales can be understood as being due to preferential coupling to half- and full-breathing mode phonons, revealing the phononic origin of the kink structures. Estimated electron-phonon coupling constant lambda from the self energy is roughly independent of the doping and momentum. The isotropic nature of lambda is discussed in comparison with the hole-doped case where a strong anisotropy exists.     

Microwave spectroscopy of novel superconductors

A hollow dielectric resonator technique has been developed for accurate measurements of the complex microwave surface impedance of novel superconductors from 2 to 20 GHz down to 100 mK. Illustrative measurements of the antiferromagnetic ordering and spin-dynamics of Gd ions in GdBa₂Cu₃O₇ and of microwave penetration and losses in MgB₂ wires and high quality single crystals of Sr₂RuO₄ are presented. Measurements on Sr₂RuO₄ imply an unchanged electron relaxation time τ on entering the superconducting state, a power law temperature dependence of the normal state fraction implying nodes in the superconducting order parameter, and residual low temperature losses on increasing frequency.     

锗薄片内飞秒光偏转波谱技术

本文报道一种高灵敏飞秒时间分辨光偏转波谱技术。利用这一技术我们探测到锗薄片内超快的声子激发并精确测量了声脉冲的波形。我们观测到了光激发的电子—空穴等离子的超声传播。从实验数据我们推算出等离子的传播速度是锗内纵向声速的4倍。     

Signature of twin planes in Mössbauer spectroscopy of cuprate superconductors

One of the four quadrupole doublets (A, B, C, and D) observed in Mössbauer spectra of orthorhombic (Y or RE)₁Ba₂(Cu_1-xFe_x)30_7-δ(δ≈0) samples is identified with Fe dopant replacing a Cu site in twin planes. The site in question, labelled as D, is characterized by a quadrupole splitting Δ_D in the range 1.6±0.1 mm/s. The D-site intensity is found to approach zero when the 1-2-3, material is driven tetragonal, either upon oxygen desorption, upon oxygen loading, or upon increasing the Fe-dopant concentration.     

Amplitude modulated transversal and longitudinal EPR spectroscopy

The amplitude modulated EPR spectroscopy is analyzed both in the time and the frequency domain. The results of numerical calculations and analytical approximate treatments indicate that the signal lineshape is differently affected by relaxation mechanisms when transversal or longitudinal detection is used in spectroscopies with variable frequencies of modulation. Measurements of longitudinally detected electron-spin double resonance obtained in dependence on the frequency of modulation confirm the lineshape expected by the theoretical analysis.     

EPR spectroscopy and imaging of TEMPO-labeled magnetite nanoparticles

The article presents results of a study of TEMPO-labeled polymer coated superparamagnetic iron(II,III) oxide nanoparticles using both Electron Paramagnetic Resonance (EPR) spectroscopy and Electron Paramagnetic Resonance imaging technique (EPRI). The X-band (9.4 GHz) EPR spectroscopy was used to investigate the behavior of TEMPO-labeled polymer coated magnetite nanoparticles in different conditions (temperature and orientation in magnetic field). The broad line, which comes from the core of Fe₃O₄ nanoparticles, shows anisotropy. This signal broadens with decreasing temperature, its intensity increases with increasing temperature and the g factor decreases with increasing temperature. The shape of the signal from nitroxide radical strongly depends on temperature. When temperature is higher than 200 K, a narrow triplet appears, but when it is lower than 200 K the signal consists of broad asymmetric lines. Analysis of the signal allowed characterization of the motion of the spin label attached to nanoparticles. Values of anisotropy parameter ɛ and rotational correlation time τ_c were calculated for TEMPO in the fast rotation regime.The ability of TEMPO-labeled PEG coated magnetite nanoparticles to diffuse within the hydrogel medium was also investigated. The EPR imaging of nanoparticles diffusion in hydrogel was made at room temperature using an EPR L-band (1 GHz) spectrometer. EPRI has been proved effective for evaluation of changes in the spatial distribution of nanoparticles in the sample.     

Multifrequency CW EPR spectroscopy of extraterrestrial carbonaceous matter

In this work, the carbonaceous matter of Orgueil, Murchison and Tagish Lake carbonaceous meteorites and a reference coal is studied by multifrequency continuous-wave electron paramagnetic resonance (EPR) spectroscopy from 4 to 285 GHz. It is found that the shape of the EPR line of the radicals in meteoritic carbonaceous matter is Lorentzian in all the frequency range, while the line shape of the coal is Lorentzian only below 95 GHz and becomes inhomogeneously broadened at higher frequency, as previously observed for coals by other authors. This points to strong exchange interactions in meteoritic carbonaceous matter, resulting from a pronounced spin clustering that does not occur in biogenic carbonaceous matter (coals). The temperature dependence of the EPR line width has been studied in detail at X- and W-bands for the Orgueil meteorite. It confirmed our previous model of the presence of radicals with thermally accessible triplet states (TATS) in meteorites. These TATS, which were attributed to diradicaloids moieties on the basis of molecular quantum DFT calculations (L. Binet, D. Gourier, S. Derenne, F. Robert, I. Ciofini: Geochim. Cosmochim. Acta 68, 881–891, 2004) do not exist in biogenic carbonaceous matter. This analysis also precised the strength of the clustering effect in meteorites, yielding an estimated local spin concentrationN=5·10²⁰ spin/g, which is two orders of magnitude higher than the average spin concentration in the Orgueil meteorite. It is important to note that such spin clustering has also been observed by other authors in synthetic hydrogenated amorphous carbon. It seems that the clustering of radicals is a common feature of synthetic and extraterrestrial (abiotic) carbonaceous matters, while radicals are homogeneously distributed in biogenic carbonaceous matter.     

Tunneling spectroscopy and order parameter symmetry of hole- and electron-doped cuprate superconductors

In tunneling spectroscopy of superconductors the density of states close to the surface or the interface to an insulating tunneling barrier is probed. For d-wave superconductors the particle–hole coherence results in interesting new phenomena at surfaces such as the formation of bound surface states at the Fermi level by Andreev reflection due to a sign change of the order parameter field in different k -directions. The probing of these states represents a phase-sensitive experiment allowing the determination of the order parameter symmetry in superconductors. We summarize the present experimental status with respect to the study of high-temperature superconductors (HTS). We discuss theoretically predicted consequences of a dominating d-wave order parameter in the hole-doped HTS on their tunneling spectra as well as on the physics of high-temperature superconductor Josephson junctions. A comparison of the tunneling spectra obtained for hole- and electron-doped HTS leads to the conclusion that the former have a d-wave, whereas the latter most likely have an anisotropic s-wave order parameter. We also address some unsettled questions related to the presence of a state with broken time-reversal symmetry at surfaces and interfaces of d-wave HTS and discuss specific features of d-wave tunnel junctions that have been predicted theoretically but still not been confirmed in experiments.     

Core-level reflectance spectroscopy of germanium by means of synchrotron radiation

Reflectance spectra due to 3d core-levels of Ge have been measured in the photon-energy region from 29 to 38 eV by means of synchrotron radiation. Second-energy-derivative spectra have newly shown pairs of doublet structures with energy separation of the Ge $\text{3d}{}_{\mathrm{<mtext>5</mtext><mtext>2</mtext>}}\text{?}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}$ core-level splitting. The observed doublet structures are assigned to the transitions from the $\text{3d}{}_{\mathrm{<mtext>5</mtext><mtext>2</mtext>}}$ and $\text{3d}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}$ core-levels to the flat regions of the conduction band around the particular symmetry points of Δ₆^c and L(₃^c(L₆^c, L_4,5^c).