共查询到20条相似文献,搜索用时 15 毫秒
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Investigations are made to get the experimental conditions for obtaining periodic crystallisation of magnesium hydroxide in agar-agar gel. A detailed study is made on the dependence of the velocity constant (K), the spacing coefficient \documentclass{article}\pagestyle{empty}\begin{document}$ \left( {p = \frac{{x_{n + 1} }}{{x_n }}} \right)'$\end{document} the length of the continuous precipitate and the width of the rings on the concentrations of the inner and outer electrolytes. Using SHINOHARA 's revised coagulation theory, the flocculation value F is calculated. F = Γ + C30, where Γ is the characteristic concentration of the outer electrolyte for which the flocculation starts and C30 is the reduced concentration of the reaction product. The value of the concentration of the outer electrolyte for which the flocculation stops (γ) is calculated. The dependence of F on the concentrations of the reactants is also discussed. Observation of a coneshaped precipitation is also reported. 相似文献
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The investigation of the gel structure and properties influence upon the crystallization processes have been carried out and are reported in this paper. The gel acidity and nucleation centers distribution are chosen as the parameters describing this process. The analytical approximations for the nucleation and precipitation density along the gel column are proposed. It has been shown that in the view of the parameters chosen it is impossible separately to determine the gel structure and proton concentration effects on crystallization processes. 相似文献
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L. Kramer 《Liquid Crystals Today》2013,22(3-4):17-18
Abstract This event marked the 10th anniversary of the first workshop on this topic in Bayreuth, which initiated a bi-annual series on pattern formation in complex systems which took place in Kitakyushu, Santa Fe, Copenhagen and Budapest. Some of the topics discussed are reported below (see also www.phy.uni-bayreuth.de/-ptlc/). 相似文献
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K. Mohanan Pillai V. K. Vaidyan M. A. Ittyachan 《Crystal Research and Technology》1982,17(12):1529-1534
Influence of different parameters like concentration of the outer electrolyte, age of the gel and impurities added to the outer electrolyte on the periodic precipitation of lead carbonate crystals in silica gel are presented. Increase of outer electrolyte concentration has the effect of increasing x2/t value while it decreases with increase of the gel age. Impurities added to the outer electrolyte delay the time of formation of the rings. All these observed results are explained. 相似文献
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从负离子配位多面体生长基元模型出发,根据大维度生长基元的结构特性,讨论了人工可控氢氧化镁晶须生长,主要介绍了多元醇法及镁盐过饱和度法.多元醇法的实质是醇中的羟基在一定条件下与大维度生长基元中的羟基发生假联结(即吸附),使得与多元醇发生了假联结的晶面生长速率大大减小或甚至停止生长,而其他晶面仍然保持原有的速率生长以致形成晶须.镁盐过饱和度法就是使得生长基元[Mg-Ax](x-2)-(A≠OH-)的浓度很大,且要远比[Mg-(OH)x](x-2)-组分浓度大4倍以上,以先形成碱式镁盐晶须,碱式镁盐晶须再与适当的碱液反应,即可制备得氢氧化镁晶须. 相似文献
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The observation of periodic bands and macroscopic deposits, when suspensions of silver and arsenious trisulphide are allowed to interact in a gel medium may be due to a chemical instability of autocatalytic reaction mechanism of colloid growth and nucleation. 相似文献
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Qualitative and semiquantitative study of the Liesegang rings formed by the reaction of oxalic acid and cadmium chloride in the acidic range of pH in silica hydrogel is made. The behaviour of Jablczynski's space constant and Morce-Pierce's time constant at various temperatures, pH and concentration of outer electrolyte is studied. The possible mechanisms for the above observed behaviour are suggested. The deviations from Isemura's general obserations are interprerted by considering two particular aspects, viz., comparatively larger crystals constituting the rings and the irreversibility of inner and outer electrolytes. 相似文献
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A. G. Saraf K. B. Saraf P. A. Wani S. V. Bhoraskar 《Crystal Research and Technology》1986,21(4):449-452
Dendritic growth of Ammonium tartrate single crystals in silica gel at 30 °C is reported. Main stem parallel to the ‘C’ axis is observed. Dendritic growth in initial and final stages with its surface structures are illustrated and described. Growth features are correlated to the growing conditions and reacting components. 相似文献
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Synthesis of single crystals of calcium iodate by gel method is described. Fairly transparent crystals of reasonably large size with different habits obtained here are illustrated. Crystals grown are identified and characterized by electron microprobe, chemical, X-ray, thermogravimetric and infra-red analysis. 相似文献
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Influence of technological factors on growth and photosensitivity of CdS single crystals prepared by sublimation in an argon flow has been studied. A conclusion is drawn that crystal growth occurs in the non-stoichiometric medium with an excess in Cd. 相似文献
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以NaTeO3为碲源,还原型谷胱甘肽(GSH)为稳定剂,一步合成CdTe量子点.研究了参与反应回流的镉与碲摩尔比和Cd2+浓度对CdTe量子点生长速率的影响,并用荧光光谱、X射线衍射光谱及透射电子显微镜对其性能进行表征.结果表明:GSH稳定的CdTe量子点具有闪锌矿结构、球形形貌;在pH =8.5,n(Cd2+)∶ n(GSH)=1∶1.2,C(Cd2)=0.67 mmol/L,n(Cd)∶ n(Te)=6∶1时,CdTe量子点荧光量子效率最高可达51.53;,并且量子点生长的速率在初期的1h内达到最高点,并随着时间的延长呈下降趋势. 相似文献
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J. M. Garcia-Ruiz J. L. Martin-Vivaldi Caballero 《Crystal Research and Technology》1982,17(10):1209-1215
Single and transparent crystals of potassium sulphate up to 30 × 3 × 3 mm in size have been grown by silica gel technique, using various methods (two-layers three-layers and hybrid gel technique) which are described. The effects of the three differents alcohols (used as top solutions) upon the quality and nucleation of crystals are also reported. The “growth and equilibrium” morphologies and microstructures of the habit faces are discussed. 相似文献
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