The state-of-the-art in electrochemical etching of charged particle track detectors

The state-of-the-art in the electrochemical etching (ECE) amplification of charged particle tracks in polymeric detectors and its applications in particular in radiation dosimetry are presented and discussed in this paper. During the past quarter of century, extensive efforts have been made on research and development in the world as well as at NRPD in AEOI on production of high voltage generators, construction of ECE chamber systems, optimization of ECE conditions, development of detectors, studies on basic physical and chemical phenomena, promotion of large-scale applications, etc. Quality high voltage generators can now be home made or are commercially available. The ECE chamber systems are advanced for special purposes as well as for large-scale applications (e.g. pressure chamber, triplet ECE or TECE chamber, etc. from NRPD). Many parameters have been optimized and new parameters such as internal heating, pressure, detector dimensions, etchant volume, chamber insulation, etc. have been recently discovered. Lexan polycarbonates (PC) and CR-39 have been shown to be the most successful detectors for ECE, while other detectors were also applied. The fundamental phenomena including “dielectric breakdown”, “dielectric loss”, “electro-osmosis”, “dielectrophoresis”, “electrostriction”, etc. although primarily proved to exist and studied, need to be further studied. The novel triplet ECE (TECE) method has provided a new approach for track amplification, firing tree production, fractal tree generation, etc. Also the novel dyed ECE track (DYECET) method enables one to study in more detail the structure of tracks, cracks, fractals, etc. Large-scale radon monitoring indoors and outdoors, large-scale neutron personnel dosimetry, low level radionuclide determination in environmental samples, autoradiography, beam profile determination, etc. are considered some successful applications. In this paper, the above were explored with emphasis on recent discoveries and inventions at NRPD in AEOI.     

Nuclear track radiography of “Hot” aerosol particles

Nuclear track radiography was applied to identify aerosol “hot” particles which contain elements of nuclear fuel and fallout after Chernobyl NPP accident. For the determination of the content of transuranium elements in radioactive aerosols the measurement of the -activity of “hot” particles by SSNTD was used in this work, as well as radiography of fission fragments formed as a result of the reactions (n,f) and (γ,f) in the irradiation of aerosol filters by thermal neutrons and high energy gamma quanta. The technique allowed the sizes and alpha-activity of “hot” particles to be determined without extracting them from the filter, as well as the determination of the uranium content and its enrichment by ²³⁵U, ²³⁹Pu and ²⁴¹Pu isotopes. Sensitivity of determination of alpha activity by fission method is 5×10⁻⁶ Bq per particle. The software for the system of image analysis was created. It ensured the identification of track clusters on an optical image of the SSNTD surface obtained through a video camera and the determination of size and activity of “hot” particles.     

Alternative procedure for LR 115 chemical etching and alpha tracks counting

An improved procedure for etching and analysis of alpha tracks induced in LR-115 detectors is proposed with the advantages of simplicity and its relatively low cost. A new type of detector holder was designed to etch and rinse efficiently up to 100 detectors. We develop a simple and reliable methodology with a semiautomatic track count using a Nikon digital camera coupled to a PC and employing software “SCION” freely available on the Internet. Track images are binarized prior the application of software “SCION” so that original track shapes are not distorted, space resolution is improved and track counting has low dependence on focus and illumination level. High discrimination for tracks is achieved when marks and rips perturb the detector surface. An image generator of nuclear tracks is included to study the effect of track overlapping effect on counting.     

Thermal spike analysis of low energy ion tracks

The theoretical track diameter of low energy ions in organic materials is usually estimated through the model of dose deposition by delta rays, with results remarkably lower than the experimental values obtained via a replica method and electron microscopy. The track detector used here is Makrofol-E and the ions studied have specific energies between 1.4 and 100 keV/n. To evaluate the problem from another point of view, thermal effects for track formation, a modified version of the “liquid drop model” for insulators was applied. The electronic as well as nuclear energy deposition by an individual ion are considered and the thermal spike evolution is studied. The model allows for the formation of ion tracks in a range of energies previously considered as “forbidden”. There still exists a discrepancy between the experimental data and the track diameters predicted by the model, and although this difference is smaller than the obtained with previous calculations, it suggests the necessity of further adjustments.     

Search for massive rare particles with the MACRO track-etch detector at Gran Sasso

Searches for massive penetrating particles in the cosmic radiation have been performed with the MACRO nuclear track detector used as a “stand alone” detector. The complete experimental procedure is presented. In absence of candidates, updated estimates of the flux upper limits both for the CR-39 “stand alone” detector and for the global MACRO detector are presented for magnetic monopoles, nuclearites and charged Q-balls.     

Hollow particle tracks in AgCI-detectors

In selected Cd-doped monocristalline silverchloride detectors we observe developed tracks from particles at LET values > 300 keV/μm AgCl and charge state values > 9, without a visible central region: the “hollow track”. The microdensitometric lateral profile shows a density decrease near the track axis, up to a radial extension of some microns from highly charged particles as Fe or U-ions of several MeV/u; the tracks of fast U- or Fe-projectiles, moreover, represent an entanglement of delta-electron tracks only. A recent reanalysis of this “hollow track”-effect is suggested to be caused by recombination effects and structural distortions. They occure in areas of high delta-electron density; together with the characteristic process of track formation in crystalline AgCl/Cd they enable us to vizualise and to measure the radial range of distortion and to evaluate the threshold of the energy density above which the destruction occurs.     

The evolution of track theory throughout the history of the international solid state detector conferences

This work is devoted to the 20th Anniversary of the international “Nuclear Tracks in Solids” conferences. Several principal stages of track theory evolution have been analyzed.     

Completeness of “good” Bethe ansatz solutions of a quantum-group-invariant Heisenberg model

The sl_q(2) quantum-group-invariant Heisenberg model with open boundary conditions is investigated by means of the Bethe ansatz. As is well known, quantum groups for q equal to a root of unity possess a finite number of “good” representations with non-zero q-dimension and “bad” ones with vanishing q-dimension. Correspondingly, the state space of an invariant Heisenberg chain decomposes into “good” and “bad” states. A “good” state may be described by a path of only “good” representations. It is shown that the “good” states are given by all “good” Bethe ansatz solutions with roots restricted to the first periodicity strip, i.e. only positive-parity strings (in the language of Takahashi) are allowed. Applying Bethe's string-counting technique completeness of the “good” Bethe states is proven, i.e. the same number of states is found as the number of all restricted paths on the sl_q(2) Bratteli diagram. It is the first time that a “completeness” proof for an anisotropic quantum-invariant reduced Heisenberg model is performed.     

Nuclear tracks in solids: registration physics and the compound spike

Observations of GeV heavy ion and MeV cluster-ion tracks in crystalline solids give us new insight into registration physics. Thermal and ion explosion spikes no longer compete; a ‘compound spike’ accounts for both. Ion explosion dominates for surface tracks (electronic sputtering). And there can also be transient plasma stopping in the bulk. For clusters there are ‘vicinage effects’—both electronic and nuclear—which can influence track dimensions and structure. Displacement cascades in large energetic clusters may lead to projectile “fission” and coherent flow into sub-tracks. The absence of tracks in certain targets, and their size/structure in others, leads to a model of projectile assisted prompt anneal (PAPA) in 10⁻¹¹s, either partial or complete, often by swift epitaxy, on elemental lattices (e.g. silicon) or on compound sublattices (e.g. fluorite). Phase transformations are important, but simple target amorphization is rare—the exception, not the rule. For many targets the thermal spike (macroscopic) fails, since ‘point’ defects (atomistic) characteristic of the target, their motion, and the electronic band structure, determine latent track detail. Circumstances in which the Bragg Rule of Additivity fails completely are revealed, and the kinetic threshold for constructive phase transitions in tracks described. This same track physics applies generally also to geothermometry—the opposite time extremum (10⁺¹¹s)—where annealing is due to defect assisted delayed anneal (DADA). Differences between etching rates of induced and spontaneous fission tracks can be explained. The geothermobarometric “Wendt/Vidal effect” (2002)—combined pressure, temperature and stress (with time) influences on fission track annealing (in e.g. apatite)—is briefly discussed.     

Acoustic Analyses of Developmental Changes and Emotional Expression in the Preverbal Vocalizations of Infants

The nonverbal vocal utterances of seven normally hearing infants were studied within their first year of life with respect to age- and emotion-related changes. Supported by a multiparametric acoustic analysis it was possible to distinguish one inspiratory and eleven expiratory call types. Most of the call types appeared within the first two months; some emerged in the majority of infants not until the 5th (“laugh”) or 7th month (“babble”). Age-related changes in acoustic structure were found in only 4 call types (“discomfort cry,” “short discomfort cry,” “wail,” “moan”). The acoustic changes were characterized mainly by an increase in harmonic-to-noise ratio and homogeneity of the call, a decrease in frequency range and a downward shift of acoustic energy from higher to lower frequencies. Emotion-related differences were found in the acoustic structure of single call types as well as in the frequency of occurrence of different call types. A change from positive to negative emotional state was accompanied by an increase in call duration, frequency range, and peak frequency (frequency with the highest amplitude within the power spectrum). Negative emotions, in addition, were characterized by a significantly higher rate of “crying,” “hic” and “ingressive vocalizations” than positive emotions, while positive emotions showed a significantly higher rate of “babble,” “laugh,” and “raspberry.”     

Smart Sensors

The term “Smart Sensors” refers to sensors which contain both sensing and signal processing capabilities with objectives ranging from simple viewing to sophisticated remote sensing, surveillance, search/track, weapon guidance, robotics, perceptronics and intelligence applications.

Recently this approach is achieving higher goals by a new and revolutionary sensors concept which introduced inside the sensor some of the basic functions of living eyes, such as dynamic stare, non-uniformity compensation, spatial and temporal filtering.

New objectives and requirements are presented for this type of new infrared smart sensor systems.

This paper is concerned with the front end of FPA microbolometers processing, namely, the enhancement of target-to-noise ratio by background clutter suppression and the improvement in target detection by “smart” and pattern correlation thresholding.     

Methane activation over Ag-exchanged ZSM-5 zeolites: A theoretical study

Methane activation catalyzed over Ag-exchanged ZSM-5 zeolites was investigated by using the density functional theory (DFT) with a cluster model. Two different pathways were taken into account in this work: the “alkyl” and the “carbenium” pathways. The activation barriers obtained are 34.09 and 66.63 kcal/mol for the “alkyl” and the “carbenium” pathway, respectively. The calculated results show that the activation barrier of the “alkyl” pathway is smaller than that of “carbenium” pathway. Consequently, the “alkyl” pathway is the preferential reaction pathway. A new mechanism of methane conversion in the presence of ethene was proposed. In the catalytic cycle, the initial step of methane activation proceeds with the “alkyl” pathway and the Ag⁺ cation acts as an acceptor of the methyl group, then ethene reacts with the Ag⁺CH₃⁻ group to form propene. In addition, it is found that the Ag⁺ cations play an important role in the methane activation, compared with the reaction of methane activation over H-ZSM-5.     

Cosmic history of the Bragin pallasite: evidence from the fission-track analysis

Chronology is rather a weak point in the investigation of pallasites, the stony-iron meteorites. No chronological data are known for the Bragin pallasite. Our attempt to reconstruct its cosmic history was based on the interpretation of fission-track analysis data. To apply this method only uranium-rich phosphates can be used. Extremely rare grains of stanfieldite were extracted from the silicate sawing residue and from the pallasite sample directly.

The researches pursued by us made it possible to find two populations of fossil tracks in stanfieldite grains. The tracks of these populations strongly differed both in size, shape and character of distribution. The first population, consisting of short (L2–6 μm instead of L8–12 μm for induced fission tracks), round-shaped tracks irregularly distributed, as we suppose, suffered an intense heating process, which caused a significant amount of partial annealing. The second population, consisting of longer (L8–12 μm), rhombic-shaped tracks homogeneously distributed, occurred after this thermal event. Only the second population track density was used for the fission-track age calculation.

After correction of the fossil track density, consisting of the second population tracks, for other possible track sources, the revealed tracks were unequivocally identified as those due to the spontaneous fission of ²⁴⁴Pu and ²³⁸U. The largest part of them was attributed to the spontaneous fission of ²⁴⁴Pu; ρ_Pu/ρ_U≈3. The model fission-track age of the studied pallasite turned out to be 4.20 Gyr. This value fix the time of the last shock/thermal event in the cosmic history of the Bragin pallasite, which had caused the partial annealing of tracks presented to that time and “fission-track clock” reset.     

Wireless retrospective gating: Application to cine cardiac imaging

A new “wireless” method of cardiac imaging is introduced, which, unlike ECG triggering, allows imaging the heart at end-diastole, and greatly reduces smearing artifacts in the phase-encoding direction. It is an improvement over ECG-driven retrospective gating, in that patients with poor ECGs can be imaged. This method extends the applicability of cardiac imaging, and since it requires no physiological monitoring hardware, can be implemented easily on any MR imager. The images produced by this method are superior to those from ECG triggering, especially when viewed in a “cine” loop. The technique described herein is, furthermore, extendable to any area where periodic or quasi-periodic motion is a problem.     

Formation model of bulk etching rate for polymer detectors

Any detector is composed of an enormous number of sensitive microscopic volumes (SMV) mainly in the state “NO” (Katz 1970. Unified Track Theory. In: Seventh International Colloquium on Corpuscular Photography and Visual Solid Detectors. Barcelona, pp. 1–29.). Irradiation evokes some spatial distribution of SMV in the state “Yes”. It can be described by the many-hit model of the SMV response (Ditlov, 1980. Theory of spatial calculation of primary action of d-electrons in track detectors with account of multiple scattering. In: Francois, H., et al. (Eds.), Solid State Nuclear Track Detectors. Pergamon Press, Oxford, pp. 131–141.). It appears that the process of etching can be described by its own many-hit model too, when the etching molecule attacks SMV in the state “Yes”. As a first our step of research, only the bulk rate V_b was considered.     

On the low-frequency limit of the Schönfeld pulse 1/f law

On the basis of propositions of the common fluctuation theory, peculiarities of small fluctuations in real physical systems with limited sizes are analyzed. It is established that small fluctuations should necessarily be divided into two types of fluctuations: “small” and “very small”. It is shown that the damping process of “small” fluctuations has relaxation character, while the damping process of “very small” fluctuations is of random character, i.e., it represents a random rectangular signal. The probability density of “very small” fluctuations is shown to be Gaussian. The agreement of the obtained results with experimental data acquired from semiconductor-based devices is analyzed. A relation between the generation–recombination noise and phonon number fluctuations in semiconductors is studied. On the basis of this consideration it is shown that the Schönfeld pulse spectrum preserves its well-known 1/f form only in the range of intermediate frequencies; at lower frequencies the spectrum gets saturated. An expression for the low-frequency limit of Schönfeld pulse 1/f law is obtained.     

About some physical mechanisms of statistics of radiation-induced effects formation and non-linear cell response in low dose area

A new cascade-stochastic approach to solve the direct and inverse problems of radiation-induced effect statistics in track biodetectors is presented in this paper. The analysis of the experimental data has made it possible to establish a non-linear nature of the “dose–effect” dependence in low dose area. For the first time, a new determination of the relative biological efficiency and quality coefficient of ionizing radiation in area of low doses are proposed.     

Uniformity in radon exhalation from construction materials using can technique

The uniformity in radon exhalation rates for 46 tiles of granite, marble and ceramic used as construction materials were determined using “Can Technique” employing CR-39 nuclear track detectors (NTDs). On each tile, two sealed cans, each enclosing one NTD fixed at the center of the tile surface area covered by the can, were mounted at two different locations of each individual tiles. The track production rates on the NTDs representing radon exhalation rates were measured. The radon exhalation rates from the surface of individual tiles showed uniform exhalations within the calculated uncertainties of the measured values. This makes Can Technique an alternative simple method to measure radon exhalation rates. Calibration required to convert track production rates into radon exhalation rates for the used can and NTD was done using an active technique. The correlation between the measurements by the two techniques shows a good linear correlation coefficient (0.83).