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Buncha Pulpoka Jong Sueng Kim Seung Hwan Yang Jacques Vicens 《Journal of heterocyclic chemistry》2001,38(6):1383-1385
Two novel calix[4]cryptands were synthesized from 1,3‐alternate calix[4]bis‐azacrown. “Mappemonde II” consists of one 1,3‐calix[4]bis‐azacrown wrapped by a benzo‐crown ether loop. “Mill II” is composed of two 1,3‐calix[4]bis‐azacrowns linked by two benzo‐crown ether strands. 相似文献
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Raphael Bextermller Hartmut Redlich Klaus Schnieders Sven Thormhlen Roland Frhlich 《Angewandte Chemie (International ed. in English)》1998,37(18):2496-2500
As spiro sugars is an apt way of considering perhydroxylated 1,7-dioxaspiro[5.5]undecanes–a class of compounds which has not been found in nature up to now. The crystal structure of such a spiroacetal, in which the two pyran rings show the β-D -manno configuration, is depicted. Note that the all-trans arrangement of C-6, C,-5, Opyr, Cspiro, Opyr′, C-5′, and C-6′ does not allow any of the stereoelectronic effects that are typical of carbohydrates. 相似文献
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Michael A. Zirnstein Heinz A. Staab 《Angewandte Chemie (International ed. in English)》1987,26(5):460-461
So far, “proton sponges” have been defined as bis(dialkylamino)arenes whose dialkylamino groups are in close spatial proximity.[1] The unusual basicity of these compounds is ascribed to the destabilizing overlap of the lone electron pairs on the nitrogen atoms, to the formation of especially strong hydrogen bonds in the monoprotonated diamines, and to the hydrophobic shielding of these hydrogen bonds. In order to differentiate and assess the relative importance of these factors, we were interested in quino[7,8-h]quinoline 1 , whose nitrogen atoms exhibit a mutual orientation similar to that in 1,8-bis(dimethylamino)naphthalene 2 (“proton sponge”). In contrast to 2 , however, 1 lacks the hydrophobic shielding of the hydrogen bonds of its monoprotonated derivative. This shielding is considered to be responsible for the low rates of proton transfer, which make the “proton sponges” reported so far unsuitable as auxiliary bases in chemical reactions. 相似文献
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“Truncated” [1.1.1.1] pagodanes like the [1.1.0.0] and [0.0.0.0] homologues3 and 4 (EStr = 146.1 – 171.5 kcal mol?1, MM2) are potential precursors of unusual unsaturated homoconjugated radical cations and σ-bishomoaromatic dications. Attempts are presented toward the synthesis of 3 - starting out from [1.1.1.1] pagodane-4,9-dione 9 and diaza [2.2.1.1] pagodadiene 11 by cycloelimination (unsuccessful) and by Favorskii-type ring contraction methodologies. Control experiments with the model diketone 19 documented the limitations for α,α′-difunctionalization of 9 as the prerequisite for one-pot double Favorskii-type ring contraction. A de novo synthesis for such α,α′-disubstituted derivatives of 9(54) was not sufficiently expeditious to open a practical access to 3. Sequential double bridgehead hydroxylation of 9, successfully practized with model 19, similarly suffered from inherent cage effects and allowed only limited yields of [1.1.1.0] pagodanone 10, the intermediate on the way to 3. 相似文献
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From Packed “Sandwich” to “Russian Doll”: Assembly by Charge‐Transfer Interactions in Cucurbit[10]uril 下载免费PDF全文
Wanjun Gong Xiran Yang Peter Y. Zavalij Prof. Lyle Isaacs Dr. Zhiyong Zhao Prof. Simin Liu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(49):17612-17618
As the host possessing the largest cavity in the cucurbit[n]uril (CB[n]) family, CB[10] has previously displayed unusual recognition and assembly properties with guests but much remains to be explored. Herein, we present the recognition properties of CB[10] toward a series of bipyridinium guests including the tetracationic cyclophane known as blue box along with electron‐rich guests and detail the influence of encapsulation on the charge‐transfer interactions between guests. For the mono‐bipyridinium guest (methylviologen, MV 2+), CB[10] not only forms 1:1 and 1:2 inclusion complexes, but also enhances the charge‐transfer interactions between methylviologen and dihydroxynaphthalene ( HN ) by mainly forming the 1:2:1 packed “sandwich” complex (CB[10] ? 2 MV 2+ ?HN ). For guest 1 with two bipyridinium units, an interesting conformational switching from linear to “U” shape is observed by adding catechol to the solution of CB[10] and the guest. For the tetracationic cyclophane‐blue box, CB[10] forms a stable 1:1 inclusion complex; the two bipyridinium units tilt inside the cavity of CB[10] according to the X‐ray crystal structure. Finally, a supramolecular “Russian doll” was built up by threading a guest through the cavities of both blue box and CB[10]. 相似文献
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