Influence of temperature on the electric,dielectric and AC conductivity properties of nano-crystalline zinc substituted cobalt ferrite synthesized by solution combustion technique

Cobalt–zinc nanoferrites with formulae Co $_{1-x}$ Zn $_{x}$ Fe $_{2}$ O $_{4}$ , where x = 0.0, 0.1, 0.2 and 0.3, have been synthesized by solution combustion technique. The variation of DC resistivity with temperature shows the semiconducting behavior of all nanoferrites. The dielectric properties such as dielectric constant ( $\varepsilon $ ’) and dielectric loss tangent (tan $\delta )$ are investigated as a function of temperature and frequency. Dielectric constant and loss tangent are found to be increasing with an increase in temperature while with an increase in frequency both, $\varepsilon $ ’ and tan $\delta $ , are found to be decreasing. The dielectric properties have been explained on the basis of space charge polarization according to Maxwell–Wagner’s two-layer model and the hopping of charge between Fe $^{2+}$ and Fe $^{3+}$ . Further, a very high value of dielectric constant and a low value of tan $\delta $ are the prime achievements of the present work. The AC electrical conductivity ( $\sigma _\mathrm{AC})$ is studied as a function of temperature as well as frequency and $\sigma _\mathrm{AC}$ is observed to be increasing with the increase in temperature and frequency.     

Mössbauer spectroscopy in the investigation of new mineral–related materials

New materials based on the composition of the mineral schafarzikite, FeSb $_{2}\textit {O}_{4}$ , have been synthesised. $^{57}$ Fe- and $^{121}$ Sb- Mössbauer spectroscopy shows that iron is present as Fe $^{2+}$ and that antimony is present as Sb $^{3+}$ . The presence of Pb $^{2+}$ on the antimony sites in materials of composition FeSb $_{1.5}$ Pb $_{0.5}\textit {O}_{4}$ induces partial oxidation of Fe $^{2+}_{}$ to Fe $^{3+}$ . The quasi-one-dimensional magnetic structure of schafarzikite is retained in FeSb $_{1.5}$ Pb $_{0.5}\textit {O}_{4}$ and gives rise to weakly coupled non-magnetic Fe $^{2+}$ ions coexisting with Fe $^{3+}$ ions in a magnetically ordered state. A similar model can be applied to account for the spectra recorded from the compound Co $_{0.5}$ Fe $_{0.5}$ Sb $_{1.5}$ Pb $_{0.5}\textit {O}_{4}$ .     

All-carbon detector with buried graphite pillars in CVD diamond

A diamond detector of 3D architecture without any metallization is developed for spectroscopy of ionizing radiation and single particles detection. The carbon electrode system was fabricated using a femtosecond infrared laser ( $\lambda $ = 1,030 nm) to induce graphitization on the surface and inside 4.0  $\times $  4.0  $\times $  0.4 mm $^{3}$ single-crystal chemical vapor deposition diamond slab, resulting in an array of 84 buried graphite pillars of 30  $\upmu $ m diameter formed orthogonally to the surface and connected by surface graphite strips. Sensitivity to ionizing radiation with $^{90}$ Sr $\upbeta $ -source has been measured for the 3D detector and high charge collection efficiency is demonstrated.     

Separation efficiency of the MASHA facility for short-lived mercury isotopes

The mass-separator MASHA built to identify Super Heavy Elements by their mass-to-charge ratios is described. The results of the off- and on-line measurements of its separation efficiency are presented. In the former case four calibrated leaks of noble gases were used. In the latter the efficiency was measured via 284 MeV $^{40}$ Ar beam and with using the hot catcher. The ECR ion source was used in both cases. The $\alpha $ -radioactive isotopes of mercury produced in the complete fusion reaction $^{40}$ Ar+ $^{144}$ Sm $\rightarrow ^{184-xn}$ Hg+xn were detected at the mass-separator focal plane. The half-lives and the separation efficiency for the short-lived mercury isotopes were measured. Potentialities of the MEDIPIX detector system have been demonstrated for future use at the mass-separator MASHA.     

BN thin film as thermal interface mateiral for high power LED: thermal resistance and optical analysis

Over heat in junction temperature of an LED can impact the luminous performance of the lighting system. The more heat extracted from the system, the easier the LEDs can be driven; resulting in more light output and possibly a reduction in the number of LEDs needed to achieve the desired level of light output. Consequently, thin film based thermal interface mateiral (TIM) has been suggested and BN thin film was prepared on Cu substrate which is used as TIM. The 3W green LED was tested with BN thin film interface and observed low $T_{J}$ and total thermal resistance (R $_\mathrm{th-tot})$ value at 700 mA. The $\Delta T_{J}$ was 3.79  $^\circ $ C which was high compared to bare Cu. Overall, BN thin films was performed well on maintaining both the $T_{J}$ and the optical output considerably and could be an alternative for commersial thermal paste.     

Structural evolution of nanopores and cracks as fundamental constituents of ultrashort pulse-induced nanogratings

We present an extensive study of the underlying structure of femtosecond laser-induced nanogratings in fused silica. To explore the evolution of the three-dimensional structure of the nanopores and cracks, of which the nanogratings consist, we performed small angle X-ray scattering measurements as well as focused ion beam milling and scanning electron microscopy. Our results show that cracks with dimensions of (280  $\times $  25  $\times $  380) nm $^{3}$ and nanopores with typical diameters of (30  $\times $  25  $\times $  75) nm $^{3}$ are formed independent of various illumination parameters. With increasing number of laser pulses the smaller pores fuse to larger structures. Furthermore, the data suggest a cross-sectional change of the pores from cuboidal to ellipsoidal.     

Laser nanoablation of graphite

Experimental data on laser ablation of highly oriented pyrolitic graphite by nanosecond pulsed UV ( $\lambda =193$  nm) and green ( $\lambda =532$  nm) lasers are presented. It was found that below graphite vaporization threshold $\approx $ 1 J/cm $^{2}$ , the nanoablation regime can be realized with material removal rates as low as 10 $^{-3}$  nm/pulse. The difference between physical (vaporization) and physical–chemical (heating + oxidation) ablation regimes is discussed. Special attention is paid to the influence of laser fluence and pulse number on ablation kinetics. Possibility of laser-induced graphite surface nanostructuring has been demonstrated. Combination of tightly focused laser beam and sharp tip of scanning probe microscope was applied to improve material nanoablation.     

Resonance Conversion as the Predominant Decay Mode of ^{229m}Th

Calculations performed within the advanced MCDF method show that the probability of decay of the 3.5-eV level of $^{229m}$ Th through the resonance electronic bridges exceeds the direct radiative nuclear decay width by a factor of around $5\cdot 10^3$ . Experimental consequences for detection of the delayed soft photons or $\alpha$ particles from the decay of the isomer are discussed.     

Asymptotic Behavior for a Version of Directed Percolation on the Triangular Lattice

We consider a version of directed bond percolation on the triangular lattice such that vertical edges are directed upward with probability $y$ , diagonal edges are directed from lower-left to upper-right or lower-right to upper-left with probability $d$ , and horizontal edges are directed rightward with probabilities $x$ and one in alternate rows. Let $\tau (M,N)$ be the probability that there is at least one connected-directed path of occupied edges from $(0,0)$ to $(M,N)$ . For each $x \in [0,1]$ , $y \in [0,1)$ , $d \in [0,1)$ but $(1-y)(1-d) \ne 1$ and aspect ratio $\alpha =M/N$ fixed for the triangular lattice with diagonal edges from lower-left to upper-right, we show that there is an $\alpha _c = (d-y-dy)/[2(d+y-dy)] + [1-(1-d)^2(1-y)^2x]/[2(d+y-dy)^2]$ such that as $N \rightarrow \infty $ , $\tau (M,N)$ is $1$ , $0$ and $1/2$ for $\alpha > \alpha _c$ , $\alpha < \alpha _c$ and $\alpha =\alpha _c$ , respectively. A corresponding result is obtained for the triangular lattice with diagonal edges from lower-right to upper-left. We also investigate the rate of convergence of $\tau (M,N)$ and the asymptotic behavior of $\tau (M_N^-,N)$ and $\tau (M_N^+ ,N)$ where $M_N^-/N\uparrow \alpha _c$ and $M_N^+/N\downarrow \alpha _c$ as $N\uparrow \infty $ .     

Analysis of the {3\over 2}^{+} heavy and doubly heavy baryon states with QCD sum rules

In this article, we study the ${3\over 2}^{+}$ heavy and doubly heavy baryon states $\varXi^{*}_{cc}$ , $\varOmega^{*}_{cc}$ , $\varXi^{*}_{bb}$ , $\varOmega^{*}_{bb}$ , $\varSigma_{c}^{*}$ , $\varXi_{c}^{*}$ , $\varOmega_{c}^{*}$ , $\varSigma_{b}^{*}$ , $\varXi_{b}^{*}$ and $\varOmega_{b}^{*}$ by subtracting the contributions from the corresponding ${3\over 2}^{-}$ heavy and doubly heavy baryon states with the QCD sum rules, and we make reasonable predictions for their masses.     

Charmonium rescattering effects in \psi(2S) \rightarrow \gamma \eta_{c}^{} decay

Charmonium rescattering effects in the M1 transition of $ \psi$ (2S) $ \rightarrow$ $ \gamma$ $ \eta_{c}^{}$ are investigated by modeling a $ \chi_{{cJ}}^{}$ or J/ $ \psi$ rescattering into a $ \eta_{c}^{}$ final state. The absorptive and dispersive part of the transition amplitudes for the rescattering loops of $ \eta$ $ \psi$ ( $ \gamma^{{\ast}}_{}$ ) and $ \gamma$ $ \chi$ ( $ \psi$ ) are separately evaluated. The numerical results show that the contribution from the $ \gamma$ $ \chi$ ( $ \psi$ ) rescattering process is negligible. Compared with the virtual D $ \bar{{D}}$ (D ^*) rescattering processes, the $ \eta$ $ \psi$ ( $ \gamma^{{\ast}}_{}$ ) process may be regarded as the next-leading order of the hadronic loop mechanism, which only offers the partial decay width of ～ 0.045 keV to the $ \psi$ (2S) $ \rightarrow$ $ \gamma$ $ \eta_{c}^{}$ .     

A realistic pattern of lepton mixing and masses from $$S_4$$ and CP

We calculate the combined angular-distribution functions of the polarized photons ( $\gamma _1$ and $\gamma _2$ ) and electron ( $e^-$ ) produced in the cascade process $\bar{p}p\rightarrow {^3{D_3}}\rightarrow {^3{P_2}}+\gamma _1 \rightarrow (\psi +\gamma _2)+\gamma _1\rightarrow (e^++e^-)+\gamma _1+\gamma _2$ , when the colliding $\bar{p}$ and $p$ are unpolarized. Our results are independent of any dynamical models and are expressed in terms of the spherical harmonics whose coefficients are functions of the angular-momentum helicity amplitudes of the individual processes. Once the joint angular distribution of ( $\gamma _1$ , $\gamma _2$ ) and that of ( $\gamma _2$ , $e^-$ ) with the polarization of either one of the two particles are measured, our results will enable one to determine the relative magnitudes as well as the relative phases of all the angular-momentum helicity amplitudes in the radiative decay processes ${^3{D_3}}\rightarrow {^3{P_2}}+\gamma _1$ and ${^3{P_2}}\rightarrow \psi +\gamma _2$ .     

Large N approach to Kaon decays and mixing 28 years later: \Delta I=1/2 rule, \hat{B}_K,and \Delta M_K

We review and update our results for $K\rightarrow \pi \pi $ decays and $K^0$ – $\bar{K}^0$ mixing obtained by us in the 1980s within an analytic approximate approach based on the dual representation of QCD as a theory of weakly interacting mesons for large $N$ , where $N$ is the number of colors. In our analytic approach the Standard Model dynamics behind the enhancement of $\hbox {Re}A_0$ and suppression of $\hbox {Re}A_2$ , the so-called $\Delta I=1/2$ rule for $K\rightarrow \pi \pi $ decays, has a simple structure: the usual octet enhancement through the long but slow quark–gluon renormalization group evolution down to the scales $\mathcal{O}(1\, {\hbox { GeV}})$ is continued as a short but fast meson evolution down to zero momentum scales at which the factorization of hadronic matrix elements is at work. The inclusion of lowest-lying vector meson contributions in addition to the pseudoscalar ones and of Wilson coefficients in a momentum scheme improves significantly the matching between quark–gluon and meson evolutions. In particular, the anomalous dimension matrix governing the meson evolution exhibits the structure of the known anomalous dimension matrix in the quark–gluon evolution. While this physical picture did not yet emerge from lattice simulations, the recent results on $\hbox {Re}A_2$ and $\hbox {Re}A_0$ from the RBC-UKQCD collaboration give support for its correctness. In particular, the signs of the two main contractions found numerically by these authors follow uniquely from our analytic approach. Though the current–current operators dominate the $\Delta I=1/2$ rule, working with matching scales $\mathcal{O}(1 \, {\hbox { GeV}})$ we find that the presence of QCD-penguin operator $Q_6$ is required to obtain satisfactory result for $\hbox {Re}A_0$ . At NLO in $1/N$ we obtain $R=\hbox {Re}A_0/\hbox {Re}A_2= 16.0\pm 1.5$ which amounts to an order of magnitude enhancement over the strict large $N$ limit value $\sqrt{2}$ . We also update our results for the parameter $\hat{B}_K$ , finding $\hat{B}_K=0.73\pm 0.02$ . The smallness of $1/N$ corrections to the large $N$ value $\hat{B}_K=3/4$ results within our approach from an approximate cancelation between pseudoscalar and vector meson one-loop contributions. We also summarize the status of $\Delta M_K$ in this approach.     

Analysis of the vertexes \Xi_{Q}^{*}′QV , \Sigma_{Q}^{*} \Sigma_{Q}^{}V and radiative decays \Xi_{Q}^{*} \rightarrow ′Q \gamma , \Sigma_{Q}^{*} \rightarrow \Sigma_{Q}^{} \gamma

In this article, we study the vertexes $ \Xi_{Q}^{*}$ ′_Q V and $ \Sigma_{Q}^{*}$ $ \Sigma_{Q}^{}$ V with the light-cone QCD sum rules, then assume the vector meson dominance of the intermediate $ \phi$ (1020) , $ \rho$ (770) and $ \omega$ (782) , and calculate the radiative decays $ \Xi_{Q}^{*}$ $ \rightarrow$ ′_Q $ \gamma$ and $ \Sigma_{Q}^{*}$ $ \rightarrow$ $ \Sigma_{Q}^{}$ $ \gamma$ .     

On Gravitational Effects in the Schrödinger Equation

The Schrödinger  equation for a particle of rest mass $m$ and electrical charge $ne$ interacting with a four-vector potential $A_i$ can be derived as the non-relativistic limit of the Klein–Gordon  equation $\left( \Box '+m^2\right) \varPsi =0$ for the wave function $\varPsi $ , where $\Box '=\eta ^{jk}\partial '_j\partial '_k$ and $\partial '_j=\partial _j -\mathrm {i}n e A_j$ , or equivalently from the one-dimensional  action $S_1=-\int m ds +\int neA_i dx^i$ for the corresponding point particle in the semi-classical approximation $\varPsi \sim \exp {(\mathrm {i}S_1)}$ , both methods yielding the equation $\mathrm {i}\partial _0\varPsi \approx \left( \frac{1}{2m}\eta ^{\alpha \beta }\partial '_{\alpha }\partial '_{\beta } + m + n e\phi \right) \varPsi $ in Minkowski  space–time  , where $\alpha ,\beta =1,2,3$ and $\phi =-A_0$ . We show that these two methods generally yield equations  that differ in a curved background  space–time   $g_{ij}$ , although they coincide when $g_{0\alpha }=0$ if $m$ is replaced by the effective mass $\mathcal{M}\equiv \sqrt{m^2-\xi R}$ in both the Klein–Gordon  action $S$ and $S_1$ , allowing for non-minimal coupling to the gravitational  field, where $R$ is the Ricci scalar and $\xi $ is a constant. In this case $\mathrm {i}\partial _0\varPsi \approx \left( \frac{1}{2\mathcal{M}'} g^{\alpha \beta }\partial '_{\alpha }\partial '_{\beta } + \mathcal{M}\phi ^{(\mathrm g)} + n e\phi \right) \varPsi $ , where $\phi ^{(\mathrm g)} =\sqrt{g_{00}}$ and $\mathcal{M}'=\mathcal{M}/\phi ^{(\mathrm g)} $ , the correctness of the gravitational  contribution to the potential having been verified to linear order $m\phi ^{(\mathrm g)} $ in the thermal-neutron beam interferometry experiment due to Colella et al. Setting $n=2$ and regarding $\varPsi $ as the quasi-particle wave function, or order parameter, we obtain the generalization of the fundamental macroscopic Ginzburg-Landau equation of superconductivity to curved space–time. Conservation of probability and electrical current requires both electromagnetic gauge and space–time  coordinate conditions to be imposed, which exemplifies the gravito-electromagnetic analogy, particularly in the stationary case, when div ${{\varvec{A}}}=\hbox {div}{{\varvec{A}}}^{(\mathrm g)}=0$ , where ${{\varvec{A}}}^{\alpha }=-A^{\alpha }$ and ${{\varvec{A}}}^{(\mathrm g)\alpha }=-\phi ^{(\mathrm g)}g^{0\alpha }$ . The quantum-cosmological Schrödinger  (Wheeler–DeWitt) equation is also discussed in the $\mathcal{D}$ -dimensional  mini-superspace idealization, with particular regard to the vacuum potential $\mathcal V$ and the characteristics of the ground state, assuming a gravitational  Lagrangian   $L_\mathcal{D}$ which contains higher-derivative  terms up to order $\mathcal{R}^4$ . For the heterotic superstring theory  , $L_\mathcal{D}$ consists of an infinite series in $\alpha '\mathcal{R}$ , where $\alpha '$ is the Regge slope parameter, and in the perturbative approximation $\alpha '|\mathcal{R}| \ll 1$ , $\mathcal V$ is positive semi-definite for $\mathcal{D} \ge 4$ . The maximally symmetric ground state satisfying the field equations is Minkowski  space for $3\le {\mathcal {D}}\le 7$ and anti-de Sitter  space for $8 \le \mathcal {D} \le 10$ .     

Structure of some FeII − III hydroxysalt green rusts (carbonate, oxalate, methanoate) from Mössbauer spectroscopy

The abundances of Fe^II and Fe^III environments within green rusts one, GR1s, that intercalate carbonate, oxalate and methanoate (formate) anions are found from Mössbauer spectra for compositions corresponding to [Fe $^{\rm II}_{6}$ Fe $^{\rm III}_{2}$ (OH)₁₆]^2?+??[CO $_{3}^{2-}$ ?5H₂O]^2???, [Fe $^{\rm II}_{4}$ Fe $^{\rm III}_{2}$ (OH)₁₂]^2?+??[CO $_{3}^{2-}$ ?3H₂O]^2???, [Fe $^{\rm II}_{6}$ Fe $^{\rm III}_{2}$ (OH)₁₆]^2?+??[C₂O $_{4}^{2-}$ ?4H₂O]^2??? and [Fe $^{\rm II}_{5}$ Fe $^{\rm III}_{2}$ (OH)₁₄]^2?+??[2HCOO^????3H₂O]^2???. These formulae correspond to orders α, β and γ where cation distances are (2 × a ₀), ( $\surd 3$ × a ₀) or a mixture of both leading to (7 × a ₀), where ratio x = {[Fe^III]/[Fe_total]} = 1/4, 1/3 and 2/7, respectively. Anion distributions within interlayers are also devised and long-range orders determined accordingly.     

Polarization degrees of freedom in near-threshold photoproduction of \omega -mesons in the \pi^{0}_{} \gamma decay channel

We study polarization variables in the photoproduction of $ \omega$ -mesons with subsequent $ \omega$ → $ \gamma$ $ \pi^{0}_{}$ decay. Single and double polarization observables are calculated as a function of different final-state angles. Reaction models include pomeron (natural parity) and $ \pi^{0}_{}$ (unnatural parity) exchange in the t -channel. In addition, the contribution of s -channel resonances is considered. The sensitivity of the polarization observables to the reaction dynamics is discussed.     

Analysis of the \frac{1} {2}^ - and \frac{3} {2}^ - heavy and doubly heavy baryon states with QCD sum rules

In this article, we study the $\frac{1} {2}^ -$ and $\frac{3} {2}^ -$ heavy and doubly heavy baryon states $\Sigma _Q \left( {\frac{1} {2}^ - } \right)$ , $\Xi '_Q \left( {\frac{1} {2}^ - } \right)$ , $\Omega _Q \left( {\frac{1} {2}^ - } \right)$ , $\Xi _{QQ} \left( {\frac{1} {2}^ - } \right)$ , $\Omega _{QQ} \left( {\frac{1} {2}^ - } \right)$ , $\Sigma _Q^* \left( {\frac{3} {2}^ - } \right)$ , $\Xi _Q^* \left( {\frac{3} {2}^ - } \right)$ , $\Omega _Q^* \left( {\frac{3} {2}^ - } \right)$ , $\Xi _{QQ}^* \left( {\frac{3} {2}^ - } \right)$ and $\Omega _{QQ}^* \left( {\frac{3} {2}^ - } \right)$ by subtracting the contributions from the corresponding $\frac{1} {2}^ +$ and $\frac{3} {2}^ +$ heavy and doubly heavy baryon states with the QCD sum rules in a systematic way, and make reasonable predictions for their masses.     

Reaction pp \rightarrow pp \pi \pi \pi as a background for hadronic decays of the \eta^{{\prime}}_{} meson

Isospin violating hadronic decays of the $ \eta$ and $ \eta{^\prime}$ mesons into 3 $ \pi$ mesons are driven by a term in the QCD Lagrangian proportional to the mass difference of the d and u quarks. The source giving large yield of the mesons for such decay studies are pp interactions close to the respective kinematical thresholds. The most important physics background for $ \eta$ , $ \eta{^\prime}$ $ \rightarrow$ $ \pi$ $ \pi$ $ \pi$ is coming from direct three-pion production reactions. In case of the $ \eta$ meson the background for the decays is relatively low ( $ \approx$ 10% . The purpose of this article is to provide an estimate of the direct pion production background for the $ \eta{^\prime}$ $ \rightarrow$ 3 $ \pi$ decays. Using the inclusive data from the COSY-11 experiment we have extracted the differential cross-section for the pp $ \rightarrow$ pp -multipion production reactions with the invariant mass of the pions equal to the $ \eta{^\prime}$ meson mass and estimated an upper limit for the signal to background ratio for studies of the $ \eta{^\prime}$ $ \rightarrow$ $ \pi^{+}_{}$ $ \pi^{-}_{}$ $ \pi^{0}_{}$ decay.     

Study of Alpha Decay Chains of Superheavy Nuclei and Magic Number Beyond Z = 82 and N = 126

We study various $\alpha $ -decay chains on the basis of the preformed cluster decay model. Our work targets the superheavy elements, which are expected to show extra stability at shell closure. Our computations identify the following combinations of proton and neutron numbers as the most stable nuclei: $Z=112$ , $N=161, 163$ ; $Z=114$ , $N=171, 178, 179$ ; and $Z=124$ , $N=194$ . We also investigate the alternative of heavy cluster emissions in the decay chain of ³⁰¹120, instead of $\alpha $ decay. Our study of cluster radioactivity shows that the half-life for ¹⁰Be decay in ²⁸⁹114 is larger, indicating enhanced stability at $Z=114$ , $N=175$ . Similar calculations concerning the emission of $\ ^{14}{\rm C}$ and $\ ^{34}{\rm Si}$ from ³⁰¹120 find the more stable combinations $Z=114$ , $N=173$ , and $Z=106$ , $N=161$ , respectively. From the same parent, ³⁰¹120, the emission of a $\ ^{49-51}{\rm Ca}$ cluster yielding a $Z=100$ , $N=152$ daughter is the most probable.