共查询到20条相似文献,搜索用时 31 毫秒
1.
N. Shemeena Basheer B. Rajesh Kumar Achamma Kurian Sajan D. George 《Applied physics. B, Lasers and optics》2013,113(4):581-587
The plasmonic absorption band of silver nanoparticles in the visible range of electromagnetic spectrum has been successfully exploited to alter the emission characteristics of the Rhodamine 6G dye molecule. The influence of the nanoparticle size on the fluorescence quantum yield of Rhodamine 6G is interrogated via steady state fluorescence as well as dual beam thermal lens technique. The potential of the thermal lens technique that probe nonradiative path in contrast to radiative path exhibited in the fluorescence spectra as a complementary method to measure the quantum yield of a dye molecule is exploited. Analysis of the results clearly indicates that the particle size and the spectral overlap between the emission spectra of Rhodamine 6G, and absorption spectra of the silver nanoparticles determine the quantum yield value of dye–nanoparticle mixture. 相似文献
2.
R. Yasukuni T. Asahi T. Sugiyama H. Masuhara M. Sliwa J. Hofkens F. C. De Schryver M. Van der Auweraer A. Herrmann K. Müllen 《Applied Physics A: Materials Science & Processing》2008,93(1):5-9
Highly fluorescent organic nanoparticles with size of about 300 nm were prepared by nanosecond laser ablation of micrometer-sized
powder of dendronized perylenediimide dispersed in water. The nanoparticle colloidal solution provided a fluorescence quantum
yield of 0.58. The absorption and emission spectral studies demonstrated that the bulky dendron groups at the side bays of
perylenediimide chromophore efficiently suppress the interchromophoric interactions in the nanoparticles. Fluorescence measurement
on several single nanoparticles underlines that the prepared nanoparticles are bright and photo-stable enough to be a useful
probe for single particle fluorescence investigation. 相似文献
3.
Silver nanoparticles were synthesized by chemical reduction of silver ions by sodium borohydride in the presence of poly-(N)-vinyl-2-pyrrolidone in solution of short chain alcohols. The nanoparticles are stable in 2-propanol, and the average diameter
of the Ag colloid obtained in this solvent is about 6 nm. The photophysical properties of acridinium and coumarin dyes in
2-propanol are affected by the presence of silver nanoparticles. The interaction of silver nanoparticles with acridinium derivative
leads to a spectral change of its intramolecular charge transfer (ICT) absorption band. The dye emission increases suddenly
with the initial addition of the Ag metal nanoparticles, but at a high concentration of the colloid, static fluorescence quenching
occurs with a progressive decrease of the fluorescence efficiency. Amino coumarin fluorescence is only quenched by the silver
nanoparticles in solution. 相似文献
4.
S. Zolghadri A. A. Saboury A. Golestani A. Divsalar S. Rezaei-Zarchi A. A. Moosavi-Movahedi 《Journal of nanoparticle research》2009,11(7):1751-1758
The binding of silver nanoparticles to bovine hemoglobin (BHb) was studied by fluorescence, UV–Visible, and circular dichroism
(CD) spectroscopic techniques at different temperatures of 20, 37, and 42 °C. The absorption spectrum of soret band, in the
presence of silver nanoparticle, showed a significant spectral change, which indicated the heme groups of BHb were directly
attacked and degraded by silver nanoparticle. The fluorescence data explained that the nanoparticle binding to BHb occurred
at a single binding site, which demonstrated a dynamic quenching procedure. Nanoparticles could reduce the fluorescence of
tryptophanyl residues of BHb to a lesser extent. Circular dichroism studies demonstrated a conformational change of BHb in
the presence of silver nanoparticles. The helicity of BHb was reduced by increasing silver nanoparticle concentration at different
temperatures. Thermodynamic analysis of the protein interaction by silver nanoparticles suggested that the binding process
is only entropy driven. 相似文献
5.
The spectral and temporal emission properties of a Rhodamine (Rh) dye solution embedded with nanoparticle fractal aggregates are studied. An experiment on the pump-power density dependence of Rh emission spectra shows that the lasing threshold of a Rh6G solution embedded with TiO(2) nanoparticle fractal aggregates is significantly reduced compared with that of a neat dye solution. The mechanism of this reduction in lasing threshold is discussed, together with the lasing properties of narrow bandwidth and short duration. 相似文献
6.
Hamdan A.S. Al-Shamiri Maram T.H. Abou Kana I.M. Azzouz Y.A. Badr 《Optics & Laser Technology》2009,41(4):415-418
The field of laser dyes-active solid polymer materials is a promising field and quite competitive with liquid dye lasers. This paper investigates some photo-physical parameters of pyromethene (PM-567, PM-597) and Rhodamine B dyes incorporated into glycidyl methacrylate (GMA) promising polymeric host matrix. These parameters are: absorption and emission cross-sections, fluorescence lifetime and quantum yield, in addition to FT-Raman spectra as an indication for binding the dye molecules with the backbones of GMA polymeric chain. 相似文献
7.
Abbas J. Al-Wattar Baha T. Chiad Wesam A. A. Twej Sarmed S. Al-Awadi 《Central European Journal of Physics》2006,4(3):341-348
The solid host of a laser dye modifies its spectroscopic properties with respect to its liquid host. During the Sol-Gel process
the dye molecules suffer from changing their environment. Two parameters affect this matter, the change in the concentration
due to the evaporation of the solvent (drying) and the caging of dye molecules inside the pores or attachment to the silica
network. Rhodamine 6G absorption and fluorescence spectra with different concentrations, during Sol-Gel time processing, have
been studied. Both, absorption and fluorescence spectra of the dye in the solid host, for different concentrations, show a
blue-shift relative to its liquid phase. 相似文献
8.
The molecular aggregation and spectroscopic properties of Pyronin Y (PyY) in the suspension containing natural bentonite clay were studied using molecular absorption, steady-state and time-resolved fluorescence spectroscopy techniques. Interaction between the clay particles and the cationic dye compounds in aqueous solution resulted in significant changes in spectral properties of PyY compared to its molecular behavior in deionized water at the same concentration. These changes were due to the formation of dimer and aggregate of PyY in the clay suspension as well as the presence of the dye monomer. The H-type aggregates of PyY in the clay suspension were identified by the observation of a blue-shifted absorption band of the dye compared to that of its monomer. In spite of diluted dye concentrations, the H-aggregate of PyY in the clay suspension was formed. The intensive aggregation in the clay suspension attributed to the localized high dye concentration on the negatively charged clay surfaces. Adsorption sites of PyY on the clay particles were discussed by deconvulated absorption and excitation spectra. Fluorescence spectroscopy studies revealed that the fluorescence intensity of PyY in the clay suspension is decreased by H-aggregates drastically. Moreover, the presence of H-aggregates in the clay suspension resulted in the decrease of fluorescence lifetime and quantum yield of PyY compared to those in deionized water. 相似文献
9.
I. V. Marchenko G. S. Plotnikov A. N. Baranov A. M. Saletskii T. V. Bukreeva 《Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques》2010,4(1):95-98
Polyelectrolyte capsules with Rhodamine 6G molecules included into the shell are obtained in this work. The inclusion of dye
molecules into the shell can provide the destruction of capsules by photosensitization. Measurements of the dye fluorescence
intensity in the shell show that the energy of photoexcited molecules is effectively dissipated by the surrounding organic
matrix. The capsule suspension is laser irradiated in the absorption band of Rhodamine 6G molecules. Measurements of the size
distribution of capsules before and after laser irradiation reveal that the capsules are destroyed by laser illumination. 相似文献
10.
We have studied the absorption and fluorescence spectra of Malachite Green and Crystal Violet in aqueous and alcoholic-aqueous solutions in which nanoparticles from Ln(III) and Sc(III) diketonates are formed at concentrations of complexes in a solution of 5–30 μM. We have shown that, if the concentrations of the dyes in the solution are lower than 0.5 μM, dye molecules are incorporated completely into nanoparticles or are precipitated onto their surface. The fluorescence intensity of these incorporated and adsorbed Malachite Green and Crystal Violet molecules increases by several orders of magnitude compared to the solution, which takes place because of a sharp increase in the fluorescence quantum yields of these dyes and at the expense of the sensitization of their fluorescence upon energy transfer from β-diketonate complexes entering into the composition of nanoparticles. We have shown that, if there is no concentration quenching, the values of the fluorescence quantum yield of the Crystal Violet dye incorporated into nanoparticles and adsorbed on their surface vary from 0.06 to 0.13, i.e., are close to the fluorescence quantum yield of this dye in solid solutions of sucrose acetate at room temperature. The independence of the fluorescence quantum yield of Crystal Violet on the morphology of nanoparticles testifies to a high binding constant of complexes and the dye. The considerable fluorescence quantum yields of triphenylmethane dyes in nanoparticles and sensitization of their fluorescence by nanoparticle-forming complexes make it possible to determine the concentration of these dyes in aqueous solutions by the luminescent method in the range of up to 1 nM. 相似文献
11.
In this work, we study the effect of concentration, host medium, PH and phase states on the fluorescence emission from the
laser dye Rhodamine B pumped by UV laser as exited source. The polymethylmethacrylate PMMA is used as a host medium in case
of solid phase samples while, ethanol and Tetrahydrofuran (THF) are used in case of a liquid one. Laser Induced Fluorescence
(LIF) technique was used to study the fluorescence properties of both cases of liquid and thin film solid-state samples. In
addition, the Dual Thermal Lens (DTL) technique was used to study the quantum yield of these samples. The concentrations of
Rhodamine B in ethanol as solvent between 2 × 10−2 M and 5 × 10−6 M were studied. The maximum fluorescence emission is observed at concentration of Rhodamine B C = 3 × 10−4 M. Comparison studies were investigated for different host medium such as ethanol, THF, PMMA in liquid phase state and PMMA
in solid phase state. The measurements revealed that, the behavior of both phases state was analogous. Rhodamine B/PMMA thin
film sample by ratio of 4:1 and thickness 0.12 mm was found to have the best photostability sample with a quantum yield about
≈0.82. 相似文献
12.
13.
罗丹明101染料的光谱特性研究 总被引:1,自引:0,他引:1
观测了罗丹明101染料在甲醇和酸性甲醇溶液巾的稳态吸收、稳态荧光和时间分辨荧光光谱,得到了吸收与荧光光谱的特征信息以及荧光寿命;通过拉曼光谱、红外光谱和密度泛函理论计算,对罗丹明101染料分子的振动模式进行了指认.研究结果全面系统地表征了罗丹明101染料的光谱特征以及分子结构和振动信息,为罗丹明101染料在染料敏化太阳能电池和生物荧光标记等方面的应用研究提供了依据. 相似文献
14.
15.
The dye 1,4-bis(9-ethyl-3-carbazovinylene)-2-methoxy-5-(2′-ethyl-hexyloxy)-benzene (abbreviated 2CzV-MEH-B) dissolved in tetrahydrofuran (THF) and as neat film is characterised by optical absorption and emission spectroscopy. The absorption and stimulated emission cross-section spectra, the fluorescence quantum distributions, fluorescence quantum yields, degrees of fluorescence polarisation, and fluorescence lifetimes are determined. A lasing characterisation is carried out by pumping with single second harmonic pulses of a mode-locked ruby laser (wavelength 347.15 nm, pulse duration 35 ps). The excited-state absorption at the pump laser wavelength is determined by saturable absorption measurements. Laser oscillation of the dye in THF in a rectangular cell is achieved by transverse pumping using the uncoated cell windows for light feedback. From the emission behaviour around threshold the excited-state absorption cross-section spectrum in the laser active spectral region is extracted. The wave-guided travelling-wave lasing behaviour of the dye as neat film is studied by analysis of the amplification of the transverse pumped spontaneous emission. Surface emitting distributed-feedback lasing was achieved with a neat film on corrugated second-order periodic gratings. 相似文献
16.
Shajesh Palantavida Nataliia V. Guz Igor Sokolov 《Particle & Particle Systems Characterization》2013,30(9):804-811
The problem of functionalization of recently reported ultrabright fluorescent mesoporous silica nanoparticles while preserving their fluorescent brightness is solved. This is a serious issue because of the open geometry of mesoporous channels and physical encapsulation of fluorescent dye inside those channels. Amine modification of mesoporous nanoparticles is described to preserve the brightness comparable to that of earlier reported ultrabright silica nanoparticles. Scaling to 40 nm sized particles, amine‐functionalized nanoparticle have fluorescent brightness equivalent to the one of 630 free rhodamine 6G (R6G) dye molecules in water. To demonstrate further most challenging functionalization, which relies on using organic‐solvent‐based chemistry, folic acid conjugation is developed. Two different methods are used to conjugate folites to the amine functionalities. Both methods result in a decrease of fluorescence intensity, which can nonetheless still be called ultrabright. The brightness can drop to either 310 or 80 R6G dye molecules per particle of nominal diameter of 40 nm. 相似文献
17.
Surface-enhanced resonance Raman scattering (SERRS) of
Rhodamine 6G (R6G) adsorbed on colloidal silver clusters has been studied.
Based on the great enhancement of the Raman signal and the quench of the
fluorescence, the SERRS spectra of R6G were recorded for the samples of dye
colloidal solution with different concentrations. Spectral inhomogeneity
behaviours from single molecules in the dried sample films were observed with
complementary evidences, such as spectral polarization, spectral diffusion,
intensity fluctuation of vibrational lines and even ``breathing' of the
molecules. Sequential spectra observed from a liquid sample with an average of
0.3 dye molecules in the probed volume exhibited the expected Poisson
distribution for actually measuring 0, 1 or 2 molecules. Difference between
the SERRS spectra of R6G excited by linearly and circularly polarized light
were experimentally measured. 相似文献
18.
Bini Pathrose V. P. N. Nampoori P. Radhakrishnan A. Mujeeb 《Journal of fluorescence》2014,24(3):895-898
The dual beam thermal lens technique is an effective method for the measurement of fluorescence quantum yield of dye solutions. The concentration-dependent quantum yield of a novel dye of triaminotriphenylmethane family in ethanol is studied using this technique. The absolute fluorescence quantum yield is measured and is observed that the reduction in the quantum yield is due to the non-radiative relaxation of the absorbed energy. 相似文献
19.
The transmission spectra of Rhodamine B and Rhodamine 6G dyes coated on silver island films for various thickness were recorded.
A strong coupling between the silver particle plasma resonance and the dye molecules is observed. The absorption of dye molecules
increases when the absorption band of individual dyes and silver particles overlaps. In higher silver film thicknesses, transmission
increases. The theoretical calculation using Maxwell-Garnett theory and Wang and Kerker’s results qualitatively supports the
observed phenomenon. A red shift in the absorption peak of dyes on silver surfaces in comparison to solution phase absorption
peak indicates photobleaching. 相似文献
20.
胶束中的若丹明6G荧光增强和激光行为 总被引:8,自引:2,他引:6
使用阴离子表面活性剂十二烷基硫酸钠 (SDS)有效的增强了若丹明 6G染料水溶液的荧光 ,在若丹明 6G浓度分别为 5 47× 10 -7和 5 47× 10 -4 mol·L-1时 ,最大增强比率分别为 1 95和 9 7。在后一浓度下SDS的加入使若丹明 6G染料激光阈值降低 ,能量转化效率提高。不加SDS时的激光阈值功率密度约为 6 5MW·cm-2 ,加入 4 1× 10 -2 mol·L-1的SDS后 ,激光阈值功率密度降为 0 8MW·cm-2 。泵浦光功率密度为 6 5MW·cm-2 时 ,能量转化效率达到 2 5 %。同时还观察到SDS的加入使溶液吸收谱、荧光谱和染料激光发生了红移。对以上现象的物理机制进行了讨论。 相似文献