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1.
(Microwave digestion of plant material for trace element determination.) A digestion method utilizing a mixture of nitric acid, hydrofluoric acid and hydrogen peroxide in closed vessels with a microwave system was developed for the determination of trace elements in plant materials and was tested on NIST standard reference materials [Citrus Leaves (SRM 1572) and Pine Needles (SRM 1575)] for Al, As, Ba, Cr, Cu, Fe, K, Mg, Mn, Ni, P, Pb, Rb, Sr and Zn. Analyses were done by d.c. plasma atomic emission spectrometry. The results showed high reproducibility and good agreement with the certified values. Rapid ashing and dissolution of plant material, reduced sources of contamination and the simplicity of the system make the microwave digestion system suitable for routine laboratory application. 相似文献
2.
Roseli M. de Souza Andr L. Saraceno Christiane Duyck Carmem Lúcia P. da Silveira Ricardo Q. Auclio 《Microchemical Journal》2007,87(2):99-103
A simple procedure for the extraction of Fe, Ni and V from asphaltene into acid solutions prior to the ICP OES determination is proposed. Either sonication or vortex agitation was used to disperse the organic sample into concentrated nitric acid, achieving efficient analyte extraction into the aqueous acid solution. Both procedures were compared and the advantage of the ultrasound-assisted procedure was evaluated. In both cases, pre-heating of sample–acid mixtures was necessary to enable quantitative extractions. Optimized conditions for the ultrasonic bath were established: 1 L of water at room-temperature, 20 min of sonication and tubes (maximum of eight) in vertical position. By using the vortex, 50 min of vigorous mechanical agitation was needed for each one of the tubes containing samples. The acid solution obtained after extraction was directly aspirated into the ICP in order to perform quantification by optical emission. Calibration was made with aqueous analyte standards containing Sc as internal standard. The procedures were tested using certified fuel oil (SRM NIST 1634c) and the method was applied for the determination of Fe, V and Ni in one asphaltene sample obtained by the fractionation of the SRM NIST 1634c. Recoveries above 90% were achieved and limits of quantification in the asphaltene sample were 1.5, 15 and 1.0 μg g− 1 estimated for Fe, Ni and V, respectively. 相似文献
3.
Lachas H Richaud R Herod AA Dugwell DR Kandiyoti R 《Rapid communications in mass spectrometry : RCM》2000,14(5):335-343
Most of the analytical techniques used to quantify elements associated with solid samples suffer from high detection limits and cannot be used for trace elements in biomass samples, particularly when only 20 mg are available for analysis. Inductively coupled plasma mass spectrometry (ICP-MS) can achieve detection limits of parts-per-trillion with liquid sample introduction by solution nebulisation. This technique was therefore tested with two standard biomass reference materials: oriental tobacco leaves and cabbage leaves. Two preparations successfully used on coal standards were used to digest the solid samples: a total digestion method (wet ashing digestion) and a partial leaching (microwave extraction). The concentrations of up to seventeen elements (As, Ba, Be, Cd, Co, Cr, Cu, Ga, Mn, Mo, Ni, Pb, Sb, Se, Sn, V and Zn) were measured after the two preparations. The accuracy and sensitivity of the measurements improved when the dilution factor decreased from 5000 to 1000 and to 500. Since the proportion of mineral matter in biomass samples is small (5%), the microwave digestion extracted elements that are generally not completely extracted from coal samples (e.g. Sb). However, some trace element concentrations were below the limit of quantification after microwave extraction, even with a reduced dilution factor (As, Se and Mo) and could not be quantified. A fuel oil was also digested. The trace element concentrations were very low (between 28 and 0.1 microgram g(-1)) but acceptable results were obtained by applying a dilution factor of 100. Only six elements in the fuel oil (As, Ba, Co, Ni, Se and V) had certified or indicated values. Factors affecting the accuracy and sensitivity of the analyses are discussed. The reproducibility of analysis of the tobacco leaf standard was checked over a period of nine months by both digestion methods. The wet ashing method gave acceptable reproducibility for Ba, Cd, Co, Cu, Ga, Mn, Mo, Ni, Pb, V and Zn but poor precision for Cr, Se and Sn and showed evidence of residual chloride interference for As. The microwave extraction gave good reproducibility for As, Ba, Cd, Co, Cr, Cu, Mo, Ni and Zn but poor precision for Se and low recoveries for Ga, Mn, Sn and V. In spite of the small quantities of material analysed, it proved possible to determine the trace elements at levels down to 0.1 microgram g(-1) in the reference materials. 相似文献
4.
I. E. Bechmann S. Stürup L. V. Kristensen 《Analytical and bioanalytical chemistry》2000,368(7):708-714
The contents of V, Cr, Co, Ni, Cu, Ga, Rb, Cd, Ba, and Pb in the soft tissue of blue mussel (Mytilus edulis) were determined by a high resolution inductively coupled plasma mass spectrometry (HR-ICPMS) method. Sample digestions were performed in closed microwave vessels using nitric acid and hydrogen peroxide. Using HR-ICPMS it is possible to resolve the analytical peaks from otherwise interfering polyatomic ions with a mass resolution setting of 4000 (Cr, Ni, Cu). The proposed method was validated using a mussel tissue reference material (NIST SRM 2974). The proposed method was applied to real samples of blue mussel from seven sites in the inlet “Limfjorden”, Denmark, and the levels of trace elements found were compared with the levels found in an earlier study. For the mussel samples large inter-regional differences in trace element concentrations in the tissues were recorded. The mussels from the different sites could be separated using principal component analysis (PCA). Comparison with the levels of trace elements in mussels found in 1982 showed that the trace elemental contamination has increased during the last 15 years. From the data obtained, mussel tissue appears to be good bio-indicator for identification of coastal areas exposed to metallic contaminants. 相似文献
5.
Sulphoxine cellulose microcolumn was used in an FI-GFAAS system for the preconcentration of trace metals, Cd, Co, Ni, Pb and V from water and from highly mineralised water and also in the presence of complexing agent, e.g. citrate. The recovery was quantitative at pH 5 for all of the elements from NIST 1643c trace elements in water SRM and from highly mineralised water samples. No significant difference was found in the sorption of V(IV) and V(V) during preconcentration. The preparation of the 8-hydroxyquinoline-5-sulphonic acid cellulose (sulphoxine-cellulose) by Mannich reaction from aminoethyl cellulose or via chlorodeoxy and ethylenediamine cellulose is also described. 相似文献
6.
Non-destructive neutron activation has been used to analyze 6 different samples of crude oil and heating oil, from Western
Canada and Venezuela. These samples were irradiated with thermal neutrons for 2, 30 and 240 min in the SLOWPOKE reactor and
the concentrations of 18 trace and minor elements (Al, As, Br, Cl, Co, Dy, Eu, Fe, I, La, Mn, Mo, Ni, Na, S, Se, Sm and V)
ranging from 0.6 ppb to 2.24% have been measured. Eleven elements (As, Br, Co, Cl, Fe, Mo, Mn, Na, Ni, S and V) were determined
in the fuel oil (SRM-1634) obtained from the National Bureau of Standards and were found to be in good agreement with the
values certified by NBS 相似文献
7.
The contents of V, Cr, Co, Ni, Cu, Ga, Rb, Cd, Ba, and Pb in the soft tissue of blue mussel (Mytilus edulis) were determined by a high resolution inductively coupled plasma mass spectrometry (HR-ICPMS) method. Sample digestions were performed in closed microwave vessels using nitric acid and hydrogen peroxide. Using HR-ICPMS it is possible to resolve the analytical peaks from otherwise interfering polyatomic ions with a mass resolution setting of 4,000 (Cr, Ni, Cu). The proposed method was validated using a mussel tissue reference material (NIST SRM 2974). The proposed method was applied to real samples of blue mussel from seven sites in the inlet "Limfjorden", Denmark, and the levels of trace elements found were compared with the levels found in an earlier study. For the mussel samples large inter-regional differences in trace element concentrations in the tissues were recorded. The mussels from the different sites could be separated using principal component analysis (PCA). Comparison with the levels of trace elements in mussels found in 1982 showed that the trace elemental contamination has increased during the last 15 years. From the data obtained, mussel tissue appears to be good bio-indicator for identification of coastal areas exposed to metallic contaminants. 相似文献
8.
Swami K Judd CD Orsini J Yang KX Husain L 《Fresenius' Journal of Analytical Chemistry》2001,369(1):63-70
A microwave digestion method in a closed vessel was developed for the determination of trace metals in atmospheric aerosols using inductively coupled plasma mass spectrometry (ICP-MS). A recovery study for the elements V, Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Se, Cd, Sb, and Pb was conducted using multi-elemental standard solutions, NIST 1633b Trace Elements in Coal Fly Ash, and NIST 1648 Urban Particulate Matter. A simple digestion method using only HNO3/H2O2 gave good recoveries (90%-108%) for all elements except Cr in SRM 1648, but yielded low recoveries for SRM 1633b. A more robust method using HNO3/H2O2/HF/H3BO3 yielded higher recoveries (82%-103%) for the lighter elements (V-Zn) in SRM 1633b, and improved the Cr recovery in SRM 1648, but decreased the Se recovery in both SRMs. A comparative analysis of aerosol samples obtained at a remote mountain location Nathiagali, Pakistan (2.5 km above mean sea level), and Mayville, New York, downwind from the highly industrialized Midwestern United States, was carried out using Instrumental Neutron Activation Analysis (INAA) for the elements Cr, Mn, Fe, Co, Zn, As, Se, and Sb. The simple digestion method yielded excellent agreement for Cr, Fe, Zn, As, Se, and Sb, with slopes of the ICP-MS vs. INAA regressions of 0.90-1.00 and R2 values of 0.96-1.00. The regressions for Mn and Co had slopes of 0.82 and 0.84 with R2 values of 0.83 and 0.82, respectively. Addition of HF/H3BO3 did not improve the correlation for any of the elements and degraded the precision somewhat. The technique provides sensitivity and accuracy for trace elements in relatively small aerosol samples used in atmospheric chemistry studies related to SO2 oxidation in cloud droplets. The ability to determine concentrations of a very large number of elements from a single analysis will permit source apportionment of various trace pollutants and hence strategies to control the sources of air pollution. This is particularly important as the health effects of particulate matter are increasingly recognized. 相似文献
9.
A matrix removal procedure has been developed for the determination of trace elements, including As, Cd, Co, Cr, Cu, Hg, Ni,
Pb, Sb, Se, Sn, Tl, Zn and V, in siliceous materials by inductively coupled plasma mass spectrometry (ICP-MS). Soil and sediment
samples were dissolved in a mixture of HNO3 and HF in sealed vessels by using a microwave oven. Silicon matrix in the solutions was precipitated as sparingly soluble
sodium fluorosilicate (Na2SiF6) by adding 0.5 mL of 300 mg mL−1 NaCl solution. Simultaneous precipitation of sodium and silicon was achieved in highly acidic solutions containing 30–40%
(v/v) HNO3. A mixture of methanol and nitric acid afforded back-extraction of the trace elements without significant dissolution of
the Na2SiF6. Samples were analyzed by ICP-MS for trace elements and residual silicon. Calibration was made by aqueous multi-element standard
solutions. Up to 95% of the silicon was successfully removed yielding solutions suitable for introduction to ICP-MS. The method
was validated by analysis of two NIST certified reference materials; SRM 2711 (Montana Soil) and SRM 2704 (Buffalo River Sediment).
Accurate results were obtained for all elements, including those for As, Hg and Se that suffer from losses due to the presence
of their volatile species when silicon was converted to volatile SiF4 via heat-assisted evaporation to dryness. The recoveries from the SRM samples varied between 80% (Cr) and 109% (Hg). No significant
interferences were observed from molecular ions of chloride and residual sodium on 75As, 63Cu, 60Ni, 77Se and 51V.
Correspondence: Zikri Arslan, Department of Chemistry, Jackson State University, Jackson, MS 39217, USA 相似文献
10.
M. C. Wende J. A. C. Broekaert 《Spectrochimica Acta Part B: Atomic Spectroscopy》2002,57(12):1897-1904
A procedure based on electrothermal evaporation (ETV) and inductively coupled plasma atomic emission spectrometry (ICP-OES) for the determination of trace impurities in Al2O3 powders without any sample pretreatment is presented. With the aid of matrix modifier the transport and the evaporation efficiency for refractory compounds could be increased by forming halides with a lower boiling point. As calibration is still a problem in direct solid sample analysis, different calibration approaches including the use of certified reference materials from NIST and standard addition of aqueous solutions of analytes were discussed. The accuracy obtained with calibration and with the standard addition method was shown up for the elements Ca, Fe, Ga, Mg, Mn, Na, Ni and V for the case of Al2O3 NIST standard reference material (SRM 699). The ETV–ICP-OES method was used for the analysis of Al2O3 powders with impurities in the low μg/g range and the results for the elements Ca, Fe, Ga, Mg, Mn, Na, Ni and V obtained with evaporation of discrete powder amounts with ETV–ICP-OES and slurry evaporation under the use of ultrasonic homogenization during the sampling and ETV–ICP-MS were shown to be in a good agreement. 相似文献
11.
A method for the direct determination of volatile and non-volatile nickel and vanadium compounds in crude oil without previous treatment using direct solid sampling graphite furnace atomic absorption spectrometry is proposed. The crude oil samples were weighed directly onto solid sampling platforms using a microbalance and introduced into a transversely heated solid sampling graphite tube. In previous work of our group losses of volatile nickel and vanadium compounds have been detected, whereas other nickel and vanadium compounds were thermally stable up to 1300 and 1600 °C, respectively. In order to avoid this problem different chemical modifiers (conventional and permanent) have been investigated. With 400 μg of iridium as permanent modifier, the signal started to drop already after two atomization cycles, possibly because of an interaction of nickel (which is a catalyst poison) with iridium. Twenty micrograms of palladium applied in each determination was found to be optimum for both elements. The palladium was deposited on the platform and submitted to a drying step at 150 °C for 75 s. After that the sample was added onto the platform and submitted to the furnace program. The influence of sample mass on the linearity of the response and on potential measurement errors was also investigated using four samples with different nickel content. For the sample with the lowest nickel concentration the relationship between mass and integrated absorbance was found to be non-linear when a high sample mass was introduced. It was suspected that the modifier had not covered the entire platform surface, which resulted in analyte losses. This problem could be avoided by using 40 μL of 0.5 g L−1 Pd with 0.05% Triton X-100. Calibration curves were established with and without modifier, with aqueous standards, oil-in-water emulsions and the certified reference material NIST SRM 1634c (trace metals in residual fuel oil). The sensitivity for aqueous standards and emulsions was close to that for SRM 1634c, making possible the use of aqueous standards for calibration. The limits of detection and quantification obtained for nickel and vanadium under this condition were found to be 0.02 and 0.06 μg g−1, respectively, for both elements, based on 10 mg of sample. Nickel and vanadium were determined in the samples with (total Ni and V) and without the use of Pd (thermally stable compounds), and the concentration of volatile compounds was calculated by difference. The results were compared with those obtained by high-resolution continuum source graphite furnace atomic absorption spectrometry by emulsion technique; no significant differences were found for total Ni and V at the 95% confidence level according to a Student's t-test. 相似文献
12.
Single-step microwave digestion with HNO(3) alone for determination of trace elements in coal by ICP spectrometry 总被引:1,自引:0,他引:1
A microwave digestion method with HNO3 alone was conducted at a temperature as high as 250 °C for determination of 19 trace elements (Li, Be, V, Cr, Mn, Co, Ni, Cu, Zn, Ga, As, Se, Rb, Sr, Cd, Cs, Ba, Hg, and Pb) in coal jointly by inductively coupled plasma optical emission spectrometry (ICP-OES), inductively coupled plasma mass spectrometry (ICP-MS), and flow injection ICP-MS (FI-ICP-MS). The validity of determination was assessed by using three standard coals, SRM 1632c, BCR 180, and SARM 19. It was found that the high-temperature digestion led to an extensive decomposition of the organic matrix and clay in coal, and no dissolved and solid carbon remained in the final solution after evaporation. Good recoveries were observed for all trace elements in three coals, with the exception of V, Rb, and Cs in high-ash SARM 19. Additionally, FI-ICP-MS combined with the present digestion without evaporation pretreatment was proved to be a rapid and efficient approach for determination of ultra-trace elements such as Se, Cd, and Hg in coal. 相似文献
13.
NIST standard reference material SRM 2783 was employed to validate a high temperature, high pressure, two-stage microwave assisted acid digestion procedure using HNO3, HF and H3BO3 developed for the analysis of trace elements (including rare earths) in atmospheric fine particulate matter (PM2.5) prior to inductively coupled plasma mass spectrometry (ICP-MS). This method quantitatively solubilized Na, Mg, Al, K, Ti, V, Mn, Fe, Co, Ni, Cu, Zn, As, Se, Rb, Sb, Cd, Cs, Ba, Pb, Th, U and several rare earth elements (REEs) (La, Ce, Pr, Nd, Gd, Dy, Er, Sm and Eu) from SRM 1648 and SRM 2783. A small amount of HF in the first stage was required to dissolve silicates necessitating the corresponding addition of H3BO3 in second stage to dissolve fluoride precipitates of Mg, La, Ce and Th. The optimized microwave dissolution—ICP-MS method detected Na, Mg, Al, K, Ti, V, Mn, Fe, Co, Ni, Cu, Zn, As, Se, Rb, Sr, Cd, Mo, Sb, Cs, Ba, La, Ce, Pr, Nd, Sm, Gd, Pb, Th and U at trace to ultra-trace levels in ambient airborne fine particles from three sites in North Carolina. La to light lanthanide signature ratios suggested that soil and motor vehicles are the dominant REE sources in SRM 2783 and PM2.5 samples collected during this study. 相似文献
14.
The main difficulties of trace metals analysis in estuarine and seawater stem from their very low concentration (mug/l to sub-mug/l), and, by contrast, the high salt content (up to 38 g/l in the Mediterranean Sea). ICP-MS allows multi-elemental analysis and offers great sensitivity, but may be strongly affected by matrix effects induced by high salt contents (> 1 g/l). To perform trace metals analysis both in riverine, estuarine and seawater, we have developed a hyphenated method: ion chelation chromatography coupled on-line with ICP-MS. Iminodiacetate resin, Metpac CC-1 (Dionex), was used to concentrate most of the trace metals, and to separate them from alkaline and alkaline-earth metals. Behaviour of 17 elements (Pb, Cu, Cd, Ni, U, Cr, Mn, Al, Co, Ga, In, Zn, V, Tl, Bi, Ag and Sn) towards the resin was qualitatively investigated. A method validation, partly derived from AFNOR standard XPT 90-210, was carried out on 12 elements (Pb, Cu, Cd, Ni, U, Cr, Mn, Al, Co, Ga, Bi and In). Replicate measurements of multi-elemental standard solutions were used to check linearity, and to determine repeatability and detection limits. Method accuracy was then assessed by analysing two certified materials: a synthetic freshwater (SRM 1643d), and a natural filtered coastal seawater (NRCC CASS-3). An application assay of natural samples from the Rh?ne river (France) was eventually carried out, and the analytical results were found to be consistent with previous works. 相似文献
15.
K. Swami C. D. Judd J. Orsini K. X. Yang L. Husain 《Analytical and bioanalytical chemistry》2001,369(1):63-70
A microwave digestion method in a closed vessel was developed for the determination of trace metals in atmospheric aerosols using inductively coupled plasma mass spectrometry (ICP-MS). A recovery study for the elements V, Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Se, Cd, Sb, and Pb was conducted using multi-elemental standard solutions, NIST 1633b Trace Elements in Coal Fly Ash, and NIST 1648 Urban Particulate Matter. A simple digestion method using only HNO3/H2O2 gave good recoveries (90%–108%) for all elements except Cr in SRM 1648, but yielded low recoveries for SRM 1633b. A more robust method using HNO3/H2O2/HF/H3BO3 yielded higher recoveries (82%–¶103%) for the lighter elements (V – Zn) in SRM 1633b, and improved the Cr recovery in SRM 1648, but decreased the Se recovery in both SRMs. A comparative analysis of aerosol samples obtained at a remote mountain location Nathiagali, Pakistan (2.5 km above mean sea level), and Mayville, New York, downwind from the highly industrialized Midwestern United States, was carried out using Instrumental Neutron Activation Analysis (INAA) for the elements Cr, Mn, Fe, Co, Zn, As, Se, and Sb. The simple digestion method yielded excellent agreement for Cr, Fe, Zn, As, Se, and Sb, with slopes of the ICP-MS vs. INAA regressions of 0.90–1.00 and R2 values of 0.96–1.00. The regressions for Mn and Co had slopes of 0.82 and 0.84 with R2 values of 0.83 and 0.82, respectively. Addition of HF/H3BO3 did not improve the correlation for any of the elements and degraded the precision somewhat. The technique provides sensitivity and accuracy for trace elements in relatively small aerosol samples used in atmospheric chemistry studies related to SO2 oxidation in cloud droplets. The ability to determine concentrations of a very large number of elements from a single analysis will permit source apportionment of various trace pollutants and hence strategies to control the sources of air pollution. This is particularly important as the health effects of particulate matter are increasingly recognized. 相似文献
16.
R. H. Filby S. Nguyen S. Campbell A. Bragg C. A. Grimm 《Journal of Radioanalytical and Nuclear Chemistry》1987,110(1):147-158
Three proposed National Bureau of Standards clay standard reference materials, flint clay SRM 97b, plastic clay, SRM 98b, and brick, SRM 679 were investigated for homogeneity with respect to their contents of Sm, La, Sc, Th, Hf, As, Ga, Fe and Cr. Sub-samples were analyzed by instrumental neutron activation analysis (INAA) and replicate determinations were made on nominal sample weights of 100, 400, 750, and 1000 g. For Sm, La, Sc and Th, no increase in the relative standard deviation with decreasing sample weight was observed in all SRMs indicating that subsampling error for these elements was not a large component of the overall error. For Ga in all SRMs and Cr, As and Fe in SRM 98b, an increase in the relative standard deviation with decreasing sample weight suggests that these elements are concentrated in a minor component of the sample. The three clays should be good reference materials for trace element microanalysis for the elements investigated. 相似文献
17.
高分辨电感耦合等离子体质谱可以区分干扰元素和目标元素微弱的质量数差别,能解决大多数多原子、氧化物干扰问题,在煤炭痕量元素分析领域受到关注,但煤炭样品中痕量金属元素尤其是稀土元素受到的质谱干扰挑战未被系统地报道.采用HNO3-HF混酸微波消解煤炭样品,优化了消解时间、赶酸、复溶等前处理条件,研究了煤炭中V、Cr、Mn、C... 相似文献
18.
Al-Swaidan HM 《Talanta》1996,43(8):1313-1319
The coupling of sequential injection with inductively-coupled plasma mass spectrometry as an analytical tool for trace element detection is described. The technique is applied for determining the concentrations of lead, nickel and vanadium at part per billion levels in sample solutions of Saudi arabian crude oils. A microemulsion crude oil sampling procedure and a standard addition method using oil-soluble organo metallic salts of trace elements were used. A reference oil sample (NBS 1634b) was analyzed to obtain the accuracy and precision of the method. Results showed percentage recovery values of 98.2%, 95.7% and 101.4% and standard deviations of 2.9%, 1.5% and 2.0% for lead, nickel and vanadium respectively. The method is sensitive, requires only small sample volumes and is quick. 相似文献
19.
Nickel is not coprecipitated with lanthanum hydroxide in ammonium hydroxide solution because it forms rapidly soluble nickel ammine complexes. This behaviour is used for the separation of Ni matrix from trace elements. These are simultaneously and quantitatively coprecipitated with lanthanum hydroxide at pH 10.0 and separated from the Ni matrix. Seven trace elements (Al, As, Cr, Fe, Ti, V and Zr) in Ni metal and 3 certified elements (Cr, Fe and Ti) in a standard reference material of nickel oxide have been simultaneously determined by inductively coupled plasma-atomic emission spectrometry (ICP-AES). 相似文献
20.
煤中痕量元素在循环流化床锅炉中的迁移行为与富集特性 总被引:2,自引:0,他引:2
对天津市某电厂循环流化床(CFB)锅炉燃用的原煤及燃烧产物底灰、飞灰、细飞灰(≤50 μm)进行痕量元素含量的测定,分析了Be、Zn、Hg、V、Cr、Mn、Co、Ni、Cu、As、Se、Cd、Pb 13种痕量元素在燃烧过程中的迁移行为,揭示了痕量元素在CFB锅炉中的分配、富集特性。结果表明,CFB锅炉中,较低的炉温对于痕量元素的迁移富集产生了较大的影响。由相对富集系数得知,Be、V、Co、Se在底灰中耗散,在飞灰中富集,Zn、Mn倾向于在底灰中富集,元素Cd、Pb、Ni、Cu挥发性较强,在底灰和飞灰中均是耗散。As受钙氧化物影响,挥发性表现并不明显。Hg在底灰和飞灰中相对富集系数均很低,表明Hg在整个燃烧过程中以气态形式排放;Hg、As、Se、V、Cr、Mn、Co、Ni、Cu、Zn、Pb均有向小颗粒物中富集的趋势。根据相对富集系数以及研究的13种元素在低温CFB锅炉中的迁移行为,将这些元素分为三类:A类(ER<0.1),主要是以气态形式排放元素Hg;B类(0.1R≤0.85),较易挥发元素As、Be、Ni、Cu、Se、Cd、Pb、Co、V;C类(ER>0.85),主要残留在固体产物中元素Zn、Mn、Cr。 相似文献