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Cedric Dielemann Dominique Matt Peter G. Jones Holger Thnnessen 《Acta Crystallographica. Section C, Structural Chemistry》2003,59(5):o247-o249
The title compound, 25,26:27,28‐bis(methylenedioxy)pentacyclo[19.3.1.13,7.19,13.115,19]octacosa‐1(25)3,5,7(28),9,11,13(27),15,17,19(26),21,23‐dodecaene dichloromethane solvate, C30H24O4·CH2Cl2, possesses crystallographic twofold symmetry in both components. The calixarene shows a pinched cone conformation with an elliptical cavity, in which the guest dichloromethane solvent molecule is accommodated. The contact distance between guest and host (H⋯ring centroid = 2.44 Å) is extremely short. 相似文献
3.
Stefanus Otto 《Acta Crystallographica. Section C, Structural Chemistry》2001,57(7):793-795
The crystal structure of the title compound, [PtCl(CH3)(C18H33P)2], is isostructural with various platinum(II) and palladium(II) complexes containing two bulky tricyclohexylphosphine ligands in a trans orientation. The Pt atom resides on an inversion centre, resulting in a 50% statistical disorder in the chloro and methyl positions. The most significant geometrical parameters are Pt—P 2.3431 (8), Pt—Cl 2.440 (4) and Pt—C1 2.179 (13) Å, and P—Pt—P 180, P—Pt—Cl 89.15 (12) and 90.85 (12), and C—Pt—Cl 172.7 (5)°. The effective and Tolman cone angles for the tricyclohexylphosphine ligands were calculated as 160 and 162°, respectively. 相似文献
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Michael Bolte Alexander Degen Ernst Egert 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(11):1338-1342
We have determined the crystal structures of bicyclo[2.2.1]hept‐2‐ene‐endo‐cis‐5,6‐dicarboxylic anhydride, C9H8O3, (I), 1,2,3,4,7,7‐hexachlorobicyclo[2.2.1]hept‐2‐ene‐endo‐cis‐5,6‐dicarboxylic anhydride diethyl ether solvate, C9H2Cl6O3·0.16C4H10O, (II), bicyclo[2.2.1]hept‐2‐ene‐endo‐cis‐5,6‐dicarboxylic acid, C9H10O4, (III), 1,2,3,4,7,7‐hexachlorobicyclo[2.2.1]hept‐2‐ene‐endo‐cis‐5,6‐dicarboxylic acid, C9H4Cl6O4, (IVa) and (IVb), and ethyl 1,2,3,4,7,7‐hexachloro‐6‐carboxybicyclo[2.2.1]hept‐2‐ene‐endo‐cis‐5‐carboxylate monohydrate, C11H8Cl6O4·H2O, (V). Compounds (I) and (II) were prepared by a standard Diels–Alder reaction from maleic anhydride and cyclopentadiene or hexachlorocyclopentadiene, respectively. The crystal‐growing processes of these compounds led to surprising results: rapid recrystallization of (I) from diethyl ether and (II) from petroleum ether gave crystals of these compounds, however, crystallization by slow evaporation techniques using common solvents yielded new compounds in which the five‐membered heterocycle has been cleaved. 相似文献
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B. de Castro C. Freire M. Teresa Duarte M. F. Minas da Piedade I. C. Santos 《Acta Crystallographica. Section C, Structural Chemistry》2001,57(4):370-372
In the title complex, trans‐{2,2′‐[cyclohexane‐1,2‐diylbis(nitrilomethylidyne)]diphenolato‐κ4O,N,N′,O′}nickel(II)–chloroform (1/1), [Ni(C20H20N2O2)]·CHCl3, the Ni atom has a square‐planar geometry, slightly tetrahedrally distorted. The Ni—N and Ni—O bonding distances are within the expected ranges for Ni–Schiff base derivatives. The diimine bridge has a gauche conformation with the cyclohexyl ring almost coplanar with the NiN2O2 plane. The complex molecules pack in dimers with an Ni?Ni distance of 3.59 (1) Å and form a three‐dimensional structure displaying a herring‐bone configuration. Channels are occupied by solvent molecules, which are involved in C—H?O hydrogen bonds with the ligand O atoms. 相似文献
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Il Yoon Byeong Soon Yoo Shim Sung Lee Bong Gon Kim 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(7):758-759
The preparation and crystal structure of the title compound, cis‐dichloro[6,9‐dioxa‐3,12‐dithiabicyclo[12.4.0]octadeca‐14,‐16,18(1)‐triene‐S,S′]palladium(II), [PdCl2(C14H20O2S2)], are described. The Pd atom has a square‐planar environment, coordinated to two S atoms of the dithiadioxa macrocycle and to two Cl? ions. The non‐coordinating O atoms are oriented away from the metal coordination plane. Upon complexation, a bicyclic chelate structure, which consists of a seven‐ and an eleven‐membered ring, is formed. 相似文献
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Thierry Le Borgne Pierre Thury Michel Ephritikhine 《Acta Crystallographica. Section C, Structural Chemistry》2002,58(1):m8-m9
The ligand 1,2,3,4‐tetramethyl‐5‐(2‐pyridyl)cyclopentadiene (cp*py) forms a dinuclear complex with UIV, i.e. di‐μ‐oxo‐bis{chloro(diethyl ether‐κO)[(η5,κN)‐1,2,3,4‐tetramethyl‐5‐(2‐pyridyl)cyclopentadienyl]uranium(IV)}, [U2Cl2O2(C14H16N)2(C4H10O)2], in which cp*py acts as a chelating ligand, being bound to the metal atom by the cyclopentadienyl unit and also by the N atom of the pyridyl ring. 相似文献
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Atilio Anzellotti Alexander Briceo Gerzon Delgado Graciela Díaz de Delgado Bernardo Fontal 《Acta Crystallographica. Section C, Structural Chemistry》2002,58(6):m355-m357
In the title compound, [RuCl2(C42H42NP3)]·2.5CHCl3·H2O, the Ru atom is six‐coordinated, to one tetradentate tris(diphenylphosphinoethyl)amine ligand and two Cl atoms, in a distorted octahedral arrangement. Molecules of chloroform and water stabilize the framework through intermolecular hydrogen bonds. 相似文献
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Ramis Rao Subramanian Shanmuga S. Anandan Kuan Hiang Kwek Kum Sang Low S. Shanmuga Sundara Raj Hoong‐Kun Fun Ibrahim Abdul Razak John V. Hanna Seik Weng Ng 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(7):e292-e294
The monoclinic cell of dicyclohexylammonium 2,4‐dichlorophenoxyacetate contains four C12H24N+·C5H8Cl2O3? ion pairs. The ammonium N atom is hydrogen bonded to the oxygen ends of two carboxyl groups to form a 12‐membered O—C—O?HNH?O—C—O?HNH ring. In (2,4‐dichlorophenoxylacetato)bis(triphenylphosphine)silver(I), [Ag(C8H5Cl2O3)(C18H15P)2], the carboxyl CO2 unit chelates to the Ag atom in an anisobidentate manner [Ag—O = 2.436 (2) and 2.517 (2) Å]; the Ag atom shows distorted tetrahedral geometry. 相似文献
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Tamami Koshiyama Masako Kato 《Acta Crystallographica. Section C, Structural Chemistry》2003,59(11):m446-m449
The title PtII complexes, viz. (2,2′‐bipyridine‐κ2N,N′)[(1R,2R)‐1,2‐diaminocyclohexane‐κ2N,N′]platinum(II) bis(hexafluorophosphate), [Pt(C6H14N2)(C10H8N2)](PF6)2, and [(1R,2R)‐1,2‐diaminocyclohexane‐κ2N,N′](1,10‐phenanthroline‐κ2N,N′)platinum(II) bis(hexafluorophosphate), [Pt(C6H14N2)(C12H8N2)](PF6)2, containing an aromatic α‐diimine and a non‐planar diaminocyclohexane, both form a ladder‐type structure, which is constructed via loose π–π stacking on the α‐diimine ligands and hydrogen bonding between the cyclic amines and the counter‐anions. In the former compound, there are two independent complex cations, both of which have a twofold axis through the Pt atom. 相似文献
11.
Maria H. Johansson ke Oskarsson Karin Lvqvist Fotini Kiriakidou Pramesh Kapoor 《Acta Crystallographica. Section C, Structural Chemistry》2001,57(9):1053-1055
Both cis‐ and trans‐dichlorobis(diphenyl sulfide)platinum(II), [PtCl2(C12H10S)2], crystallize as mononuclear pseudo‐square‐planar complexes. In the cis compound, the Pt—Cl distances are 2.295 (2) and 2.319 (2) Å, and the Pt—S distances are 2.280 (2) and 2.283 (2) Å. In the trans compound, Pt is located on a centre of inversion and the Pt—Cl and Pt—S distances are 2.2786 (15) and 2.3002 (12) Å, respectively. 相似文献
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Robert W. Clark Ilia A. Guzei Wiechang C. Jin Clark R. Landis 《Acta Crystallographica. Section C, Structural Chemistry》2003,59(4):m144-m145
The crystal structure of a prospective olefin catalyst, namely {2‐[1‐acetyl‐5‐(2‐hydroxyphenyl)‐4‐phenyl‐1,2,4‐diazaphospholan‐3‐yl]phenyl acetate‐κP}chloro(η4‐cycloocta‐1,5‐diene)rhodium(I) dichloromethane solvate, [RhCl(C8H12)(C24H23N2O4P)]·CH2Cl2, has been determined at 173 K. The five‐membered heterocycle of the phosphine ligand is in a slightly distorted twist conformation. An intramolecular N1—H1⃛Cl1 hydrogen bond contributes to the adopted conformation and may additionally participate in secondary interactions with substrates during catalysis. 相似文献
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Davide Barreca Franco Benetollo Simona Garon Eugenio Tondello Pierino Zanella 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(7):e290-e291
The title compound, di‐μ‐diethylamido‐N:N‐bis[chlorodimethyltin(IV)], consists of discrete [Sn2Cl2(CH3)4(C4H10N)2] dimer molecules, with Sn atoms linked by bridging diethylamido groups. The coordination geometry about the metal atom is distorted trigonal bipyramidal, with the two methyl C atoms and one N atom in the equatorial plane, and the Cl and second N atom in axial positions. 相似文献
14.
Kenneth W. Muir David G. Morris Cindy Ong Woei Chii 《Acta Crystallographica. Section C, Structural Chemistry》2004,60(2):m60-m62
In the title compound, hexa‐μ‐chloro‐dichlorotetrakis(N‐trimethylammonio‐p‐toluenesulfonamidate‐κ2N,O)tetramercury(II), [Hg{Me3N(+)N(−)SO2C6H4CH3‐p}Cl2]4 or [Hg4Cl8(C10H16N2O2S)4], four nearly linear and parallel Cl—Hg—Cl units associate through pairwise Hg⋯Cl interactions of 3.1–3.2 Å. Each Hg atom is also coordinated through N and O atoms to a ylide molecule. The available structural data indicate that coordination of a sulfonyl‐stabilized nitrogen ylide to a metal atom (Hg or Ag) has no detectable effect on its geometry. 相似文献
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F. Bentefrit P. Lemoine D. Nguyen‐Huy G. Morgant B. Viossat 《Acta Crystallographica. Section C, Structural Chemistry》2003,59(8):m331-m333
The asymmetric unit of the title compound, [Ni(C11H16ClN5)2]Cl2·C3H7NO, contains one monomeric nickel(II) complex cation, two Cl− anions and one dimethylformamide solvent molecule. The Ni atom is coordinated to each of two 1‐(p‐chlorophenyl)‐5‐isopropylbiguanide (proguanil) ligands via two N atoms. The complex exhibits a square‐planar coordination, with the Ni atom lying 0.021 (2) Å out of the basal plane. The crystal packing is characterized by several hydrogen bonds. 相似文献
16.
Yong Nie Chun‐Hua Hu Xue Li Wei Yong Jian‐Min Dou Jie Sun Ruo‐Shui Jin Pei‐Ju Zheng 《Acta Crystallographica. Section C, Structural Chemistry》2001,57(8):897-899
Each of the title compounds, 8‐methoxy‐7,7‐bis(triphenylphosphine‐P)‐8,9:10,11‐di‐μH‐7‐platina‐nido‐undecaborane dichloromethane hemisolvate, [Pt(CH14B10O)(C18H15P)2]·0.5CH2Cl2, (I), 8‐isopropoxy‐7,7‐bis(triphenylphosphine‐P)‐8,9:10,11‐di‐μH‐7‐platina‐nido‐undecaborane dichloromethane solvate, [Pt(C3H18B10O)(C18H15P)2]·CH2Cl2, (II), and 9‐isopropoxy‐7,7‐bis(triphenylphosphine‐P)‐8,9:10,11‐di‐μH‐7‐platina‐nido‐undecaborane dichloromethane solvate, [Pt(C3H18B10O)(C18H15P)2]·CH2Cl2, (III), has an 11‐vertex nido polyhedral skeleton, with the 7‐platinum centre ligating to two exo‐polyhedral PPh3 groups and an alkoxy‐substituted polyhedral borane ligand. Compounds (II) and (III) are isomers. The Pt—B distances are in the range 2.214 (7)–2.303 (7) Å for (I), 2.178 (16)–2.326 (16) Å for (II) and 2.205 (6)–2.327 (6) Å for (III). 相似文献
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Manfred Zabel Josef Breu Franz Rau Klaus‐Jürgen Range Volker Krey Anka Uffrecht Armin Buschauer 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(2):250-251
The structural information gained from the study of the chiral building block (R)‐(?)‐4‐(3,4‐dichlorophenyl)‐4‐(2‐pyridyl)butanoic acid–l ‐(?)‐ephedrine [methyl(1‐hydroxy‐1‐phenylprop‐2‐yl)ammonium 4‐(3,4‐dichlorophenyl)‐4‐(2‐pyridyl)butanoate], C10H16NO+·C15H12Cl2NO2?, can be used to deduce the absolute configuration of highly potent arpromidine‐type histamine H2 receptor agonists, as the chiral butanoic acid can be converted to (R)‐(?)‐3‐(3,4‐dichlorophenyl)‐3‐(2‐pyridyl)propylamine and to the corresponding R‐configured arpromidine analogue. 相似文献
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John Kouvetakis Cole Ritter Thomas L. Groy 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(12):e564-e564
The title molecule is dimeric, i.e. di‐μ‐trimethylsiloxy‐bis(dichloroaluminium), [Al2Cl4(C3H9Si)2], and possesses exact crystallographic inversion symmetry. The O atoms of the trimethylsiloxy groups bridge the two Al atoms to form a four‐membered ring. The Si—O bond distance [1.711 (3) Å], the Al—O mean bond distance [1.806 (4) Å] and the mean Si—C bond distance [1.875 (6) Å] appear to agree well with standard data. Mean values for C—Si—C, O—Si—C, and Si—O—Al angles are 112.9 (3), 105.8 (2), and 131.8 (2)° repectively. The two ring angles O—Al—O and Al—O—Al are 84.43 (16) and 95.57 (16)°, respectively. 相似文献
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Won Seok Han Soon W. Lee 《Acta Crystallographica. Section C, Structural Chemistry》2004,60(4):m189-m190
In the title compound, azido‐2κN‐bis[μ‐(1η5:2κP)‐diphenylphosphinocyclopentadienyl][2(η5)‐pentamethylcyclopentadienyl]iron(III)rhodium(III) hexafluorophosphate, [{Rh(C10H15)(N3)}{Fe(μ‐C17H14P)2}]PF6 or [FeRh(C10H15)(μ‐C17H14P)2(N3)]PF6, the coordination sphere of RhIII can be described as pseudo‐tetrahedral, composed of two P atoms from a 1,1′‐bis(diphenylphosphino)ferrocene (dppf) ligand, an azido N atom and the centroid of the ring of a C5Me5 (Cp*) ligand. The two cyclopentadienyl rings in the dppf moiety adopt an eclipsed conformation. The Rh⋯Fe distance is 4.340 (2) Å. 相似文献
20.
Veysel T. Yilmaz Ahmet Karadag Carsten Thne Regine Herbst‐Irmer 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(8):948-949
In the neutral title complex, trans‐bis(2,2′‐iminodiethanol‐N,O)bis(isothiocyanato)nickel(II), [Ni(NCS)2(C4H11NO2)2], the isothiocyanate ions and the diethanolamine molecules act as monodentate and bidentate ligands, respectively. The NiII ion exhibits a distorted octahedral configuration with crystallographically imposed inversion symmetry and NNCS—Ni—Namine and NNCS—Ni—Oamine bond angles of 88.78 (10) and 89.44 (10)°, respectively. The Ni—N bond distances are in the range 2.069 (3)–2.096 (2) Å. The molecules are linked by hydrogen bonds to form a three‐dimensional infinite lattice. 相似文献