共查询到20条相似文献,搜索用时 15 毫秒
1.
《Analytical letters》2012,45(17-18):1787-1792
Abstract A simple two factor simplex is used to optimize the separation of several ionic naphthylamines by varying the pH and percent methanol in the eluting solvent. 相似文献
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一种新改进单纯形优化方法 总被引:5,自引:0,他引:5
本文采用模糊数学方法计算了多指标综合评价值,并以它作为单纯形优化的目标函数,建立了一种新改进单纯形优化方法,改进了反射基点、形心点和反射系数的计算方法。 相似文献
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Using different reduction conditions Pd powders have been prepared and characterized by chemisorption and TPO (Temperature Programmed Oxidation) measurements. The amount of carbon deposits introduced during preparation seems to be peculiar to the preparation procedure. The O2 consumption curves attributed to PdO formation have shown two peak minima suggesting strong differences in the accessibility of Pd particles. 相似文献
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This study presents a Chromatographic Optimization Function (COF) to optimize chromatographic separation conditions. The COF proposed herein provides several advantages over conventional COFs, including the ability to eliminate the ambiguous selection of the weighting factors and easily obtain the acceptable or maximum resolution in the shortest separation time. The parameters used to construct this COF are in the form of sigmoidal functions to reduce the weight of the response for less acceptable conditions and to filter out undesired situations. In addition, resolution between peaks, length of separation time, and number of peaks separated are used as parameters for constructing the proposed COF. Closely examining the performance of the COF for both simulated and experimental chromatographic separations reveals an adequate correlation with human judgment and, also, creates no problems in selecting weighting factors. 相似文献
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本文研究了气相色谱柱温智能优化软件在卤代烃毒物分析中的应用。智能优化使得包含多个卤代烃与烃的混合样品达到了满意的分离效果,保留值预测误差在1.1%以内,吻合程度很好。 相似文献
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Suwannee Junyapoon Keith Bartle Andrew Ross Michael Cooke 《International journal of environmental analytical chemistry》2013,93(2):47-59
Volatile compounds containing Group V and Group VI elements in landfill gases are of concern as a source of toxic pollutants and unpleasant odors. Conventional analytical techniques for these compounds e.g. ICP-MS, ICP-AES are complicated, expensive and time consuming. The use of a simple programmed temperature vaporization injection (PTV) technique coupled to gas chromatography with atomic emission detection (GC-AED) has been successfully demonstrated to identify compounds containing arsenic, antimony, and sulfur in landfill gas. With an adapted PTV injection system (using a combination of a ten-port and a six-port Valco valves), problems associated with AED discharge tube damage due to high carrier gas flow rate during sample loading can be overcome. The gas samples generated from both a laboratory biowaste digester and a domestic landfill site were characterized using these techniques. Large sample gas volumes were adsorbed onto a cooled sorbent trap containing Porapak Q, followed by rapid liberation onto a porous layer open tubular column (PLOT) using programmed thermal desorption. Arsenic and antimony were also detected in the landfill leachate collected from the same landfill site using hydride generation-atomic absorption spectrometry (Hy-AAS). The efficiency of different traps has also been compared. 相似文献
9.
Javier Tabera Guillermo Reglero Marta Herraiz Gracia P. Blanch 《Journal of separation science》1991,14(6):392-396
The use of a programmed temperature vaporizing (PTV) injector has been evaluated for the on-line concentration and injection of trace organic compounds either sampled from the head-space above grape juices or purged from solution. The Simplex method was used to improve the sensitivity of the method by optimization of the experimental conditions. 相似文献
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《Analytical letters》2012,45(11):1259-1267
Abstract The nuclear magnetic resonance chemical shifts of the lower polyphosphate compounds are strongly dependent on the hydrogen ion concentration of the solution, both absolutely and relative to each other. At an optimum pH, the chemical shifts of pyrophosphate and tripolyphosphate will be most widely separated, and these two compounds can be determined in the presence of each other and in the presence of higher polyphosphates. The univariate simplex procedure found the optimum pH in ten trials, but required two more measurements to define the minimum width of the maximum response region, pH 8.4 to 8.7 相似文献
11.
This article discusses the optimization of a newly developed method for measuring the activity of plasminogen activators using
a thickness-shear-mode acoustic sensor. A variable-size simplex algorithm was used for optimization. Preliminary tests were
performed to design the first simplex. A desirability function was defined to translate each performance value to a membership
value of 0 to 1. If there was more than one performance variable, their membership values were translated to an aggregated
membership value using another function that considers their individual influence on sensor performance. Two rounds of optimization
were carried out for streptokinase followed by a single optimization for tissue-type plasminogen activator. In the last optimization,
ratios of control variables were used in order to reduce the number of parameters and to formulate easily adjustable assay
conditions. The results showed the usefulness of the simplex method for optimizing this type of assay, and the importance
of preliminary tests and prior knowledge in providing rapid convergence using fewer experiments. The optimized plasminogen
activator assay can be considered a reference method for measurement of all members of this drug class. 相似文献
12.
本文运用单纯形最优化法,测定了V(V)-PAR-H2O2以及W(Ⅵ)PV-CTMAB三元配合物的组成比。提出了对应于三元配合物的λmax处二元配合物也有部分吸收时的二种处理办法及体系最初酸度调节的新看法,并经上述三元配合物体系,验证了方法的可行性,进一步完善了单纯形最优化法测配合物组成比这一手段。 相似文献
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Fernando M. Lanas Roseli A. Francelin Ailton J. de Souza 《Journal of separation science》1991,14(6):407-411
The modified simplex algorithm proposed by Nelder and Mead has been used to optimize the separation by temperature programmed capillary GC, of volatile compounds present in alcoholic beverages. An adequate objective function, CRF, based on the separation factor of Kaiser has been used for the optimization process. A factorial design was initially performed to verify the relationship between the several parameters of interest. Following this, the optimization was executed and a surface adjusted within the set of experimental data. 相似文献
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Suwannee Junyapoon Andrew B. Ross Keith D. Bartle Bernard Frere Alastair C. Lewis Michael Cooke 《Journal of separation science》1999,22(1):47-51
Programmed temperature vaporization injection (PTV) coupled to gas chromatography and atomic emission detector (AED) has been studied for large volume injection of gaseous samples. As examples of the effectiveness of the technique, the results of the analysis of a series of headspace samples of foods such as garlic and onion, and of landfill gases are presented. The volumes of gaseous samples reconcentrated varied from a few milliliters up to liters depending on analyte dilution, through focusing onto a sorbent trap, then rapid liberation into the GC-AED system by programmed thermal desorption. Despite the high carrier gas flow rates associated with direct PTV-GC, AED performance and sensitivity were unaffected. The detailed elemental information obtained from the PTV-GC-AED analyses was confirmed using a PTV coupled to a gas chromatograph with ion trap detector mass spectrometer as detector (PTV-GC-ITD/MS). 相似文献
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单纯形优化高效液相色谱法分离测定维生素E的各种异构体 总被引:2,自引:0,他引:2
本文用计算机辅助单纯形优化高效液相色谱法分离、测定了精炼植物油副产物中维生索E的各种异构体。探讨了单纯形优化法指导高效液相色谱选择分离的实验条件,并编写了实用的计算机程序。实验结果表明,本法可使比较困难的条件选择工作有章可循,从而提高工作效率。 相似文献
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Suwannee Junyapoon Keith D. Bartle Andrew B. Ross Michael Cooke Brian F. Smethurst 《International journal of environmental analytical chemistry》2013,93(4):337-348
Abstract Trace volatile compounds emitted from both domestic and industrial landfills have been identified by programmed temperature vaporization injection (PTV) coupled to gas chromatography with detection by ion-trap mass spectrometry (GC-ITD/MS). The PTV injection system has been developed using a combination of two six-port valves to achieve problems of interference in GC-MS while loading sample. A large volume of landfill gas was re-concentrated onto a sorbent trap, then rapidly liberated into the GC-ITD/MS system by programmed thermal desorption. Using this method, trace volatile compounds in gases from both domestic and industrial landfills such as aromatic hydrocarbons, terpenes, chlorinated hydrocarbons, and sulfur compounds can be identified and quantified. 相似文献
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《Analytical letters》2012,45(4):261-269
Abstract This paper describes the separation and identification of phenolics derived from lignin, a major component of wood, by gas chromatography (G.C.) using a Tenax GC column. 相似文献
19.
本文根据误差理论提出了单纯形法收敛准则的一种改进,导出了收敛精度计算式,并用实验进行了验证。 相似文献