关于医院制剂软件建设的几点思考

为适应新的制剂要求,使制剂工作更严格、规范,提出了加大制剂软件建设包括指导性软件、规范行为软件和记录软件等的建议。     

1stOpt软件在蔗糖水解实验教学中的应用

将1stOpt软件用于物理化学实验蔗糖水解反应速率常数的测定中，在无需严格记录反应开始时间和测定反应终了旋光度的情况下，通过非线性拟合无需编程及公式变换就可以简单方便准确地得到反应速率常数，避免了传统数据处理方法所带来的人为误差，可以补充和改进物理化学实验的教学。     

1stΟpt软件在蔗糖水解实验教学中的应用

将1stΟpt软件用于物理化学实验蔗糖水解反应速率常数的测定中,在无需严格记录反应开始时间和测定反应终了旋光度的情况下,通过非线性拟合无需编程及公式变换就可以简单方便准确地得到反应速率常数,避免了传统数据处理方法所带来的人为误差,可以补充和改进物理化学实验的教学。     

20年来三代可记录光盘记录材料的研究概况

本文综述了近20年来应用于红外光CD-R、红光DVD±R和蓝光BD-R/HD DVD-R三代可记录光盘中的记录材料的研究和应用进展,介绍了菁类、大环氮杂、偶氮、金属螯合物、苯并杂环等类染料作为光记录材料进行的研究,评述了可记录光盘记录材料的薄膜光学、记录灵敏度、光热稳定性、旋涂成膜性等特性,概括了每一代可记录光盘记录材料的特性与光盘系统的关系,讨论了大环氮杂金属配合物具有的良好材料特性,尤其是高光热稳定性和适中的记录灵敏度,并结合大环氮杂金属配合物在早期两代可记录光盘中已得到的重要应用及本课题组对此类材料的研究结果,认为其将是高密度蓝光盘记录材料的重要发展方向之一.     

化学计量检定管理系统设计

提出化学计量检定管理系统软件的总体设计思路。介绍了软件中旧数据维护、网络传输、登陆安全维护、新建记录、总揽记录、分类统计记录、任意条件查询记录、打印记录、应用帮助及软件退出10个子系统的功能。     

用于光盘记录介质的“偶氮染料-聚合物”复合材料

由噻唑类偶氮染料和硝化纤维组成的复合材料涂布于玻璃载体上可用作光盘记录介质,测定这一记录介质的光学性质和物理性质,表明其具有良好的记录灵敏性和读写特性。     

化学软件专卖店

北京宏剑科讯化学系统软件中心 ,全部面向 PC机平台 ,使您的家庭电脑也能完成工作站上的化学计算。我们为您提供了三十余个版本的化学软件 ,包括全世界最优秀的化学桌面系统软件 Chem Office2 0 0 0 ,Sci Vision和 Gaussian98W等系列软件包 ,适合业内教授、高级工程师及学生使用 ,使您的化学研究乘上互联网的世界快车。 Chem Office Ultra2 0 0 0 Enhanced集成化学软件桌面系统给化学家带来一个意想不到的惊奇 ,优秀的价格性能比 ,三位一体 (Chem Draw Ultra6 .0、Chem3D Ultra5 .0和 Chem Finder Ultra5 .1 )的功效以及强大的高端…     

化学软件专卖店

北京宏剑科讯化学系统软件中心,为您提供三十余个版本的化学软件,包括全世界最优秀的化学桌面系统软件ChemOffice2000,SciVision和Gaussian98W等系列软件包,适合业内教授、高级工程师及学生使用,使您的化学研究乘上互联网的世纪快车。ChemOffice2000Ultra集成化学软件桌面...     

SPT-Ⅱ型光导热塑全息片的研制

全息照相术被称为反映和了解我们周围世界的一种万能工具,全息记录材料就是这种万能工具不可缺少的记录介质。     

最近130ka中国的古季风——Ⅰ.古季风记录

现今中国季风气候的特点可以作为辨认古季风气候记录的线索。文中着重阐述最近130ka东南季风区的各种古季风记录,它们主要是:历史记录,包括黄土-古土壤序列、沙漠、湖泊、雪线和林线、大陆架沙漠化现象等的地质记录,由植被和哺乳动物代表的生物记录。其中,黄土高原的黄土-古土壤序列反映了过去亚洲冬季风和夏季风的环境效应突出气候期相互交替的历史。亚洲古季风变迁是中国古气候和古环境变迁的一个重要控制因素。     

Mapping of the distribution of 137Cs in Irish Sea sediments

The Sellafield nuclear fuel reprocessing plant released a total of 41 PBq of ¹³⁷Cs into the Irish Sea in the period 1952–1998. The present work integrates a series of surveys of the ¹³⁷Cs distribution in sediment offshore Sellafield which was aimed at obtaining a detailed picture of the patterns of sediment contamination and their time evolution, and an estimate of the ¹³⁷Cs inventory in sediment. The authors applied NaI(Tl)-based underwater -ray spectrometry to record a series of 1800 one-minute spectra along 14 transects totaling 160 Nm. The dominant feature of the contamination pattern obtained from this survey remains a stripe extending northwestwards along the coast from the discharge point, as reported for previous surveys. Steep gradients are observed perpendicular to the coast, with ¹³⁷Cs countrates decreasing to half the recorded maximum over a distance of less than 2000 m.     

两点电位滴定法及其应用

提出了只需两组数据即可计算电位滴定计量点的电位滴定数据处理新方法－两点法，并在此理论基础上，提出了两点电位测定法。该法只需记录两次电极电位值和相应滴定剂体积，利用公式即可计算滴定化学计量点。详细讨论了各因素对方法准确度的影响，给出了衡量滴定进行程度的客观指标，为两点位置的选择提供了充分的理论依据。实验结果表明：该法操作方便，数据处理简单，精密度与准确度均较高，分析速度较经典电位滴定法有较大提高。     

Routine FT-Raman spectroscopy with modified standard FT-IR instrument

A commercial FT-IR spectrometer (BRUKER IFS 66) was combined with a Raman module, having an NdYAG laser as source, a sample compartment, a filter for elimination of the exciting line from the spectrum and a detector. The interferometer and computer of the IFS 66 was used to record Raman spectra of small amounts of liquids and solids using a spherical sapphire sample cell.     

人教版高中化学必修模块教科书实验活动的分析与比较*——以2019年版教科书“实验”和“实验活动”栏目为例

以人教版高中化学必修模块教科书(2019年版)“实验”和“实验活动”栏目的实验活动为研究对象,采用Herron修正的“实验活动探究层次分类法”(LOLA)和笔者提出的“学生实验行为要求分类法”(RSBLA)对其进行分析,并与2007年版教科书进行对比。研究发现,2019年版教科书的实验活动探究层次处于层次1和层次2,学生行为要求为“观察”“记录实验现象”“回答与实验有关的问题”和“设计实验”。卡方检验表明,2019年版教科书和2007年版教科书“实验”栏目的实验活动探究层次分布比例和学生实验行为要求均存在显著性差异。     

半导体凝固点测定仪的研制及其应用

为了配合物理化学实验“凝固点降级法测定萘的摩尔质量”,研制出半导体制冷凝固点测定仪,实现了凝固点测定和摩尔质量计算的自动化,解决了老式实验装置存在的问题。通过对环己烷凝固点和萘摩尔质量的测定,验证了该仪器的可靠性,同时还探讨了搅拌速率和冷阱的温度变化对凝固点测定值的影响。     

Mechanical selfsimilarity of polymers during chemical gelation

Network polymers near their gel point exhibit selfsimilar mechanical behavior, as expressed by power law relaxations. The range of selfsimilarity is defined by two limiting length scales. The upper limit is the correlation length, defined by the linear size of the typical cluster, and a lower limit, roughly given by the size of one preformed linear chain, i. e., the mean distance between crosslinks. The correlation length increases with the approach to the gel point, and diverges at the critical extent of reaction, i. e., the gel point where the infinite cluster is formed. Above the gel point, it decreases again with further crosslinking. Dynamic mechanical measurements of the complex modulus at the gel point show a power law in the frequency dependence over the entire frequency range, monitoring selfsimilarity. Swelling effects reduce the fractal dimension of the percolation cluster form 2.5 to 2. It is shown how the power law G() ^1/2, found by experiment, is connected to the structure of the polymeric cluster.Presented at the Physikertagung 1987 in Berlin.     

NMR properties of sedimented solutes

This perspective paper is intended to give some insights into the recently proposed technique of NMR of solutes sedimented by ultracentrifugation in a rotor used for solid state NMR experiments. Sedimented "states" correspond to molecules with very little reorientational capability in extremely concentrated solutions. They provide solid state NMR spectra comparable in quality with those of the best microcrystalline samples. Here we report some experiments to look for chemicals which affect the properties of the sediment, and we show that it is possible to fill the rotor in a true ultracentrifuge and then record the spectra. The latter possibility opens new horizons for NMR of sedimented systems.     

Variations of radon in soils induced by external factors

Experiments were designed to evaluate, in a controlled way, some of the variations that can be expected in radon concentration in soil due mainly to meteorological factors and to close spacing monitoring in the field. Electronic continuous radon monitoring and the track-etch method were used to record the radon -decay. The radon emanation in daily measurements and in long term surveys showed a general effect modulated by temperature and pressure variations. Radon monitoring in soil for nearby stations showed that a 10% range of variation can be expected with the track-etch method and as a result of non-homogeneous emanation pattern of the soil.     

Electromechanical effect in cholesteric mixtures with a compensation temperature

Abstract

An electromechanical effect arises in cholesteric (N*) liquid crystals due to a cross-coupling between fluxes and forces specific to chiral systems. We recently described an experiment to study this effect on samples with fixed boundary conditions. Here, we have derived the basic theoretical expressions relevant to this experiment. We have now used this technique to record the electromechanical signal across the compensation temperature of cholesteric mixtures consisting of cholesteryl chloride, 4′-heptyl-4-cyanobiphenyl and 2-cyano-4-heptylphenyl 4′-pentylbiphenyl-4-carboxylate. The sign of the electromechanical signal changes at the compensation point, clearly demonstrating the macroscopic origin of this effect.     

HCN→HNC异构化反应过渡态附近的拓扑特性

电荷密度拓扑分析方法(topological analysis of charge distribution)已经被广泛应用于研究化合物的各种静态性质及反应特性.对IRC反应途径上过渡态附近构型的拓扑性质研究报导较少.本工作是用电荷密度分布的拓扑分析方法对HCN→HNC异构化反应IRC过渡态附近的性质进行了研究.对电荷密度分布拓扑分析和IRC途径确定选用相同的基组,得到了一些新的结论。