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本文在对O1(^1△g)最佳气相传输温度计算的分析基础上,从防止O1(^1△g)在经过渡段的淬来,气流温度对氧碘混合程度和对氧碘化学反应效率的影响三个方面进行了讨论,指出了获得最佳O1(^1△g)气相传输温度的途径。同时还讨论了实现激光器低温运行提高出光功率的可行性。 相似文献
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Deng Liezheng Shi Wenbo Wang Xiangdan Yang Heping Qu Lishen Sha Guohe 《化学物理学报(中文版)》2004,17(4):378-384
The absolute O2 (1Δ)concentration measurement performed for a singlet oxygen generator(SOG)by using the infrared radiation-calorimetry method is reported with a detailed discussion of its principle and related technique. The influence of O2 (1Δ)gas temperature variation is considered and the corresponding correction has been made,which is neglected by the previous researchers and may cause a significant error in the case of measurement for the large O2 (1Δ)flowrate. Furthermore,an automatically balanced Wheatstone bridge circuit,which is necessary for O2 (1Δ)detection on the SOG of short operation period,is designed and tested by measuring the heat capacity of oxygen. The final error analyses give out a total relative error of ±16% for the O2 (1Δ)concentration,which mainly arises from the measurements of infrared radiation,pressure and temperature at the optical cell. 相似文献
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Fullerene[60]在光的作用下可以诱导产生单线态氧(^1O2),C60H36是一个富电子化合物,在室温下,单线态氧可以氧化C60H36,使透明的C60H36溶液(甲苯和已烷作溶剂)在短时间内变混浊,结果产生氧化产物C60H36-x(x=1-18)。 相似文献
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以AlCl3 为络合物配体, 研究Sm2O3Eu2O3Gd2O3 的分离特性。结果表明, 其传输能力为:Sm ≈Gd> Eu, 氯化物主要在980 ~1100 K 沉积。不同温区的最大分离系数分别为: βEu/Sm;1200 K= 1-70 ,βEu/Gd;1300 K= 1-88 , βSm/Gd;1300 K = 1-24 , β′Sm/Eu;850 ~880 K= 2-76 , β′Gd/Eu;880~900 K = 2-83 , β′Gd/Sm;800 K=1-12 , 高于传统的湿法分离系数。 相似文献
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Lin HX Chen GH Liu HL Li D Huang XC Liu WG Jiao YQ 《The journal of physical chemistry. A》2011,115(46):13581-13588
A detailed theoretical study of the potential energy surface of poorly understood ion-molecule reaction of NH(2)(-) and O(2) (a(1)Δ(g)) is explored at the density functional theory B3LYP/6-311++G(d,p), ab initio of QCISD/6-311++G(d,p) and CCSD(T)/6-311++G(3df, 2pd) (single-point) theoretical levels for the first time. It is shown that there are six total possible products from P(1) to P(6) on the singlet potential energy surface. Among these, the charge-transfer product P(1) (NH(2) + O(2)(-)) is the most favorable product with predominant abundances, whereas P(4) (NO(-) + H(2)O) and P(2) (HNO + OH(-)) may be the second and third feasible products followed by the almost neglectable P(3) (NO(2)(-) + H(2)), while P(5) (c-NO(2)(-) + H(2)) and P(6) (ONO(-) + H(2)) will not be observed due to their either high barriers or being secondary products. The present theoretical study points out that besides P(1) (NH(2) + O(2)(-)) and P(2) (HNO + OH(-)), P(4) (NO(-) + H(2)O) should be also observed, which is different from the previous experiment study by Anthony Midey et al. in 2008. In addition, almost all of the reaction pathways to products are exothermic and the reaction rate should be very fast since the reaction barriers are very low except for P(5) (c-NO(2)(-) + H(2)) which is in agreement with the measured total reaction rate constant k = 9.0 × 10(-10) cm(3)s(-1) at 300 K in the experiment study. It is expected that the present theoretical study may be helpful for the understanding of the reaction mechanism related to NHX(-), NX(2)(-), PHX(-), and PX(2)(-) (X = H, F, and Cl). 相似文献
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Collisional relaxation of O2(X3Σg(-), υ = 1) and O2(a1Δg, υ = 1) by atmospherically relevant species
Pejaković DA Campbell Z Kalogerakis KS Copeland RA Slanger TG 《The Journal of chemical physics》2011,135(9):094309
Laboratory measurements are reported of the rate coefficient for collisional removal of O(2)(X(3)Σ(g)(-), υ = 1) by O((3)P), and the rate coefficients for removal of O(2)(a(1)Δ(g), υ = 1) by O(2), CO(2), and O((3)P). A two-laser method is employed, in which the pulsed output of the first laser at 285 nm photolyzes ozone to produce oxygen atoms and O(2)(a(1)Δ(g), υ = 1), and the output of the second laser detects O(2)(a(1)Δ(g), υ = 1) via resonance-enhanced multiphoton ionization. The kinetics of O(2)(X(3)Σ(g)(-), υ = 1) + O((3)P) relaxation is inferred from the temporal evolution of O(2)(a(1)Δ(g), υ = 1), an approach enabled by the rapid collision-induced equilibration of the O(2)(X(3)Σ(g)(-), υ = 1) and O(2)(a(1)Δ(g), υ = 1) populations in the system. The measured O(2)(X(3)Σ(g)(-), υ = 1) + O((3)P) rate coefficient is (2.9 ± 0.6) × 10(-12) cm(3) s(-1) at 295 K and (3.4 ± 0.6) × 10(-12) cm(3) s(-1) at 240 K. These values are consistent with the previously reported result of (3.2 ± 1.0) × 10(-12) cm(3) s(-1), which was obtained at 315 K using a different experimental approach [K. S. Kalogerakis, R. A. Copeland, and T. G. Slanger, J. Chem. Phys. 123, 194303 (2005)]. For removal of O(2)(a(1)Δ(g), υ = 1) by O((3)P), the upper limits for the rate coefficient are 4 × 10(-13) cm(3) s(-1) at 295 K and 6 × 10(-13) cm(3) s(-1) at 240 K. The rate coefficient for removal of O(2)(a(1)Δ(g), υ = 1) by O(2) is (5.6 ± 0.6) × 10(-11) cm(3) s(-1) at 295 K and (5.9 ± 0.5) × 10(-11) cm(3) s(-1) at 240 K. The O(2)(a(1)Δ(g), υ = 1) + CO(2) rate coefficient is (1.5 ± 0.2) × 10(-14) cm(3) s(-1) at 295 K and (1.2 ± 0.1) × 10(-14) cm(3) s(-1) at 240 K. The implications of the measured rate coefficients for modeling of atmospheric emissions are discussed. 相似文献
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The emission spectra of BiO has been first obtained by studying the reaction: Bi+O_2(~1△_g)in the atomic-beam apparatus. 22 new bands has been obtained from the emission spectra of BiO (A ~2Π_g) which are attributed to the collisional energy transfer process of BiO(X,v)+O_2(b ~1Σ_g~+). The O_2(b ~1Σ_g~+) is produced by the following process: O_2(~1△_g)+O_2(~1△_g)→O_2(b ~1Σ_g~+)+O_2(X ~3Σ_g~-). 相似文献
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建立了钙钛矿材料中金属离子的碘滴定分析方法,并通过该方法对BaCe0.1CoxFe0.9-xO3-δ和BaZr0.1CoxFe0.9-xO3-δ钙钛矿透氧膜材料中钴铁离子价态进行了测定.研究表明,随着钴含量的增加,钴铁离子的平均价态呈下降趋势,这意味着氧空位浓度也在随之增加.对比发现在相同掺杂比例时(x),BaCe0.1CoxFe0.9-xO3-δ体系中钴铁离子的平均价态要低于BaZr0.1CoxFe0.9-xO3-δ系列中钴铁离子的平均价态,因此BaCe0.1CoxFe0.9-xO3-δ系列比BaZr0.1CoxFe0.9-xO3-δ系列拥有更多氧空位数. 相似文献
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采用较新的半经验分子轨道方法Austin Model 1(简称AM1方法), 辅以Berny梯度优化方法, 对单线态氧(~1O_2)与咪唑的1,2-环加成反应,进行了理论研究。计算获得实验尚未检测到的4,5-二氧环丁烷(4,5-dioxetane)的结构, 并在反应势能面上找到单重态双自由基中间体及通过该中间体的两步反应的过渡态。通过对过渡态的结构特征、虚振动方向以及对反应过程的电荷分布情况、轨道相互作用等的分析, 说明该反应是经由单重态双自由基中间体的分步反应。两步反应的活化势垒分别为39.2 kJ·mol~(-1)和150.5 kJ·mol~(-1)。 相似文献
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用 XPS 法和碘量法分析了 YBCO 超导体及有关化合物。结果表明 YBCO 超导体碘量滴定反应中的“两电子氧化剂”不是 Cu~(3+)离子,而可能是O_2~(2-)(或 O~(1-))种类的氧离子。 相似文献
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本文系统地研究了SnO2系和γ-Fe2O3元件在变温过程中与H2O(g)、O2(g)和还原性气体相互作用的规律。结果表明:Al2O3、MgO、Pd、Pt和Sb2O3均对元件的体电阻均有调制作用。Al2O3是以微粒状存在于元件内,它为元件提供了活化中心,提高了元件的灵敏度。而γ-Fe2O3具有超微细结构。 相似文献
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调节硫酸氧钒与盐酸羟胺溶液至pH~4制得的题目晶体属空间群P2_1/n,晶胞参数a=8.201,b=8.597,c=9.947A,β=93.00°,Z=4.结构解出精修后R因子为0.069.结果表明,不对称单位中二个羟胺根以侧接态与VO~(3+)配位,另一羟胺取端接态以O占据V的第五赤道配位位置,配位水处于氧钒基强键反位,Cl~-则在配阳离子界外以平衡电荷,晶体对的化学式确证为[(VO~(3+))(NH_2O~_)_2(NH_3O)(H_2O)][Cl~-] 相似文献