Chiral-loop and vector-meson contributions to η → ππγγ decays

The process η → π⁰π⁰γγ is discussed in Chiral Perturbation Theory (ChPT). Special attention is deveted to one-loop corrections, η-η′ mixing effects and vector-meson dominance of ChPT counter-terms. The less interesting η → π⁺π⁻γγ transition is briefly discussed too.     

Observation of χb production in the exclusive reaction ′→γγχb→γγ→γγ(eeorμμ−)

We report on the observation of 1 ³P_J (χ_b) production in the reaction ′→γχ_b→γγ→γγ(e⁺e⁻ or μ⁺μ⁻). The data were recorded with the nonmagnetic CUSB detector at the Cornell Electron Storage Ring, CESR. We observe 124 γγ events with either an electron or muon pair in the final state. In the γγ correlation plot about 40% of the events cluster around (120, 430) MeV.     

Spectroscopic and structural investigations of α‐, β‐, and γ‐AlH3 phases

With its reputation as a high‐energy density fuel, aluminum hydride (AlH₃) has received renewed attention as a material that is particularly suitable, not only for hydrogen storage but also for rocket propulsion. While the various phases of AlH₃ have been investigated theoretically, there is a shortage of experimental studies corroborating the theoretical findings. In response to this, we present here an investigation of these compounds based primarily on two research areas in which there is the greatest scarcity of information in the literature, namely Raman and infrared (IR) absorption analysis. To the authors' knowledge, this is the first report of experimental far‐IR absorption results on these compounds. Two different samples prepared by broadly similar ethereal reactions of AlCl₃ with LiAlH₄ were analyzed. Both Raman and IR absorption measurements indicate that one sample is purely γ‐AlH₃ and that the other is a mixture of α‐, β‐, and γ‐AlH₃ phases. X‐ray diffraction confirms the spectroscopic findings, most notably for the β‐AlH₃ phase, for which optical spectroscopic data are reported here for the first time. Copyright © 2010 John Wiley & Sons, Ltd.     

Search for γγ→ηb in ee collisions at LEP 2

A search for the pseudoscalar meson η_b is performed in two-photon interactions at LEP 2 with an integrated luminosity of 699 pb⁻¹ collected at e⁺e⁻ centre-of-mass energies from 181 GeV to 209 GeV. One candidate event is found in the six-charged-particle final state and none in the four-charged-particle final state, in agreement with the total expected background of about one event. Upper limits of Γ_γγ(η_b)×BR(η_b→4 charged particles)<48 eV, Γ_γγ(η_b)×BR(η_b→6 charged particles)<132 eV are obtained at 95% confidence level, which correspond to upper limits of 9.0% and 25% on these branching ratios.     

Symmetry breaking and the decays ψ′ → J/ψπ(η) and J/ψ → η(η′) γ

The theoretical mechanisms for the decays ψ′ → ψπ⁰ and ψ′ → ψη, which violate SU₂ and SU₃, respectively discussed. It is argued that symmetry breaking in the decay amplitudes may be as important as π⁰ −η −η′ mixing. The π⁰ −η mechanism ψ′ → ψν → ψπ⁰ leads to Γ(ψ′ → ψπ⁰) = (3.3±1.0) × 10⁻³ Γ(ψ′ → ψν), but this number may be enhanced by a factor as large as 12 by π⁰−η′ mixing and isospin violation in the decay amplitude. The related decays ψ → ηγ and ψ → η′γ are also discussed.     

η,η′→ππγ with coupled channels

The decays η,η′→π⁺π⁻γ are investigated within an approach that combines one-loop chiral perturbation theory with a coupled channel Bethe–Salpeter equation which satisfies unitarity constraints and generates vector mesons dynamically from composite states of two pseudoscalar mesons. It is furthermore shown that the inclusion of the η′ as a dynamical degree of freedom does not renormalize the Wess–Zumino–Witten term.     

A measurement of the η radiative width Γη→γγ

The radiative width of the η meson has been measured at PETRA in photon-photon collisions. The resulting value is Γ_η→γγ = 0.53±0.04±0.04 keV.     

ηη′ threshold enhancement in p annihilations into πηη′ at rest

We report on the observation of an ηη′ threshold enhancement produced in p annihilations at rest into π⁰ηη′, which we identify with the recently discovered ƒ₀(1500).     

Electronic transitions in α, θ and γ polymorphs of ultraporous monolithic alumina

Spectroscopy of α, θ, and γ phases of high‐purity ultraporous alumina has been studied at cryogenic temperatures of 7 K in the near‐IR–VUV range of spectra with synchrotron radiation excitation. The UV photoluminescence (PL) spectra are dominated by optical transitions of self‐trapped excitons, while the PL excitation spectra are assigned to free excitons and interband transitions. The analysis of PL excitation spectra indicates a tendency to fundamental bandgap narrowing in order of 9.36 eV (α) to 7.60 eV (θ) and 6.85 eV (γ). Structural defects related to oxygen vacancies are responsible for the visible F⁺/F transitions decrease in order γ > θ > α. (© 2013 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Relative stabilities and molecular structures of the isomeric enol ethers and carboxylic esters derived from α‐acetyl‐γ‐butyrolactone and α‐acetyl‐δ‐valerolactone

Recently recorded ¹⁷O NMR spectra of compounds studied in a previous work (Taskinen E. Acta Chem. Scand. 1985; B39 : 489–494) dealing with the thermodynamics of isomerization of the enol ethers of α‐acetyl‐γ‐butyrolactone reveal an error in compound identification, caused by an unexpected isomerization reaction during the synthetic procedure. Thus, acid‐catalyzed treatment of the lactone with HC(OR)₃ in the respective alcohol ROH is shown to lead initially to the desired enol ethers which, however, are gradually isomerized to a mixture of the enol ethers and an ester of 2‐methyl‐4,5‐dihydrofuran‐3‐carboxylic acid. As a result, only one of the two isomeric compounds detected in the previous equilibration study was the expected enol ether (the thermodynamically more stable E isomer) of α‐acetyl‐γ‐butyrolactone, while the other, dominating species was the respective carboxylic ester. In the present work, the evidence provided by the ¹⁷O NMR spectra is presented, and the relative stabilities of the isomeric compounds are discussed on the basis of computational enthalpy data. The treatment is also extended to the respective isomeric compounds derived from α‐acetyl‐δ‐valerolactone. Copyright © 2007 John Wiley & Sons, Ltd.     

A new method for functionalizing α,γ‐dinitro compounds at the β‐position: application to the cyclization of β‐alkoxy‐α,γ‐dinitro compounds

Treatment of 2,4‐dinitropentane with bromine and sodium methoxide in methanol, affords formation of an ether product, 2,4‐dibromo‐3‐methoxy‐2,4‐dinitropentane, in 59% yield as a mixture of three diastereomers. This observation has led to a general synthesis of 3‐alkoxy‐2,4‐dibromo‐2,4‐dinitropentanes, obtained in 75‐86% yield from 2,4‐dibromo‐2,4‐dinitropentane as the preferred reactant. 4‐Bromo‐2,4‐dinitro‐2‐pentene has been identified as an intermediate in these reactions. The nitroalkene has been isolated and undergoes conjugate addition with alkoxides to afford the same ether products after brominative work‐up. The nitroalkene undergoes conjugate addition with sodium azide to give 3‐azido‐2,4‐dibromo‐2,4‐dinitropentane in 38% yield as a mixture of two isomers in which the (R*,R*) isomer predominates. Sequential treatment of 2,4‐dibromo‐2,4‐dinitropentane with sodium methoxide followed by sodium iodide and acetic acid gives 3‐methoxy‐2,4‐dinitropentane in 63% yield, the overall product of simple methoxylation of 2,4‐dinitropentane. However, attempted complete debromination of 2,4‐dibromo‐3‐methoxy‐2,4‐dinitropentane with excess sodium iodide and acetic acid results only in monodebromination to give 2‐bromo‐3‐methoxy‐2,4‐dinitropentane in 86% yield. Likewise, 2‐bromo‐3‐ethoxy‐2,4‐dinitropentane is formed in 93% yield from the ethoxy analog. A mechanistic rationale is offered for condition‐specific removal of the second Br atom in these reactions. Treatment of 3‐methoxy‐2,4‐dinitropentane with potassium acetate/iodine in dimethyl sulfoxide affords formation of 4,5‐dihydro‐3,4‐dimethyl‐3‐methoxy‐4‐nitroisoxazole 2‐oxide in 30% yield as a single diastereomer. Conversion of 2‐bromo‐3‐methoxy‐2,4‐dinitropentane in 15% yield to 4,5‐dihydro‐3,4‐dimethyl‐3‐methoxy‐4‐nitroisoxazole 2‐oxide is also possible by using potassium acetate in dimethyl sulfoxide. The mechanistic pathways for formation of 4,5‐dihydro‐3,4‐dimethyl‐3‐methoxy‐4‐nitroisoxazole 2‐oxide apparently involve unstable 3‐methoxy‐1,2‐dimethyl‐1,2‐dinitrocyclopropane as the common intermediate. Similarly, 2‐bromo‐3‐ethoxy‐2,4‐dinitropentane affords 4,5‐dihydro‐3‐ethoxy‐3,4‐dimethyl‐4‐nitroisoxazole 2‐oxide in 13% yield. Copyright © 2013 John Wiley & Sons, Ltd.     

Prediction of γ‐B28 ELNES with comparison to α‐B12

Using ab initio techniques we have calculated the electron energy loss near edge structure (ELNES) of a new high pressure phase of boron (γ‐B₂₈) and the structurally similar allotrope, α‐B₁₂. The total ELNES spectra are presented as weighted sums of the site specific spectra of the constituent non‐equivalent B atoms. The five different non‐equivalent B sites in γ‐B₂₈ all show rich ELNES spectra and their similarities and differences to the simpler α‐B₁₂ case are detailed. (© 2009 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Upper limit on the decay Σ(1385)→Σγ and cross section for γΣ→Λπ

Coherent Λπ⁻ production on Pb of 600 GeV Σ⁻ hyperons has been studied with the SELEX facility at Fermilab. Using the Primakoff formalism, we set a 90% CL upper limit on the radiative decay width Γ[Σ(1385)⁻→Σ⁻γ]<9.5 keV, and estimate the cross section for γΣ⁻→Λπ⁻ at  GeV to be 56±16 μb.     

Contribution to ε′/ε from anomalous gauge couplings

Recently the KTev Collaboration has measured Re (ε′/ε)=(28±4.1)×10⁻⁴ which is in agreement with early measurements from NA31. The Standard Model prediction for ε′/ε is on the lower end of the experimentally allowed range depending on models for hadronic matrix elements. In this paper we study the contributions from anomalous gauge couplings. We find that the contributions from anomalous couplings can be significant and can enhance ε′/ε to have a value closer to data.     

Density functional study of α–β phase transition of polyvinylidene difluoride

We perform density functional calculations to investigate structural and dynamical properties of crystalline polyvinylidene difluoride (PVDF) associated with the transition from α to β phase. We examine the change of the conformational energy and the corresponding structure of each phase depending on the lattice parameters of the orthorhombic crystalline structure. From this information, we construct the path that connects the point where the α phase is most stable to the point where the β phase is most stable, and identify the sub‐ region in the lattice parameter space where α and β phases have the same energy. In this sub‐region, we locate the point which gives the lowest conformation energy for both α and β phases, and examine the behaviour of the lowest energy profile and corresponding change of intermediate structures as the conformation of the PVDF chain transforms from α phase to β phase. Finally we perform ab‐initio molecular dynamics simulations and analyse the characteristic dynamics associated with transition from α to β phase. (© 2012 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

High‐pressure Raman spectroscopy study of α and γ polymorphs of AlH3

For the first time, Raman spectroscopy of α and γ polymorphs of AlH₃ has been performed in the pressure range from ambient up to 16.9 and 32.7 GPa, respectively using the diamond anvil cell (DAC) technique. An analysis of pressure response wavenumbers (ν) for α‐AlH₃ showed a change of dν_i/dP at a pressure of about 8 GPa and may indicate a monoclinic distortion from the initially hexagonal α‐AlH₃. The distortion is stable at least up to 16.9 GPa. The γ form exhibited more complex behavior transforming to the α form at a pressure of about 12 GPa. The structural phase transition was shown to be an irreversible and kinetically slow process that required at least 5 h to complete. Copyright © 2008 John Wiley & Sons, Ltd.     

M‐theory solutions invariant under D(2,1; γ) ⊕ D(2,1;γ)

We simplify and extend the construction of half‐BPS solutions to 11‐dimensional supergravity, with isometry superalgebra D(2,1;γ) ⊕ D(2,1;γ). Their space‐time has the form AdS₃× S³× S³ warped over a Riemann surface Σ. It describes near‐horizon geometries of M2 branes ending on, or intersecting with, M5 branes along a common string. The general solution to the BPS equations is specified by a reduced set of data (γ, h, G), where γ is the real parameter of the isometry superalgebra, and h and G are functions on Σ whose differential equations and regularity conditions depend only on the sign of γ. The magnitude of γ enters only through the map of h,G onto the supergravity fields, thereby promoting all solutions into families parametrized by |γ|. By analyzing the regularity conditions for the supergravity fields, we prove two general theorems: (i) that the only solution with a 2‐dimensional CFT dual is AdS₃× S³× S³× ℝ², modulo discrete identifications of the flat ℝ², and (ii) that solutions with γ < 0 cannot have more than one asymptotic higher‐dimensional AdS region. We classify the allowed singularities of h and G near the boundary of Σ, and identify four local solutions: asymptotic AdS₄/Z₂ or AdS₇^′ regions; highly‐curved M5‐branes; and a coordinate singularity called the “cap”. By putting these “Lego” pieces together we recover all known global regular solutions with the above symmetry, including the self‐dual strings on M5 for γ <0, and the Janus solution for γ > 0, but now promoted to families parametrized by |γ|. We also construct exactly new regular solutions which are asymptotic to AdS₄/Z₂ for γ < 0, and conjecture that they are a different superconformal limit of the self‐dual string. Finally, we construct exactly γ > 0 solutions with highly curved M5‐brane regions, which are the formal continuation of the self‐dual string solutions across the decompactification point at γ = 0.     

Resonance neutrino bremsstrahlung ν → νγ in a strong magnetic field

High energy neutrino bremsstrahlung ν → ν + γ in a strong magnetic field (B B_s) is studied in the framework of the Standard Model (SM). A resonance probability and a four-vector of the neutrino energy and momentum loss are presented. A possible manifestation of the neutrino bremsstrahlung in astrophysical cataclysm of type of a supernova explosion or a merger of neutron stars, as an origin of cosmological γ-burst is briefly discussed.     

Changes in electrical properties in α- and γ-exposed PADC track detector

The changes in the dielectric properties and temperature dependence of the d.c. conductivity of α-exposed poly allyl diglycol carbonate (PADC) have been studied. On α-irradiation the dielectric constant (′) as a function of frequency has been found to decrease significantly. The temperature dependence of resistivity in pristine and γ-irradiated samples is of the form ρ(T)=ρ_∝ exp(T₀/T) which can be attributed to conduction of thermally generated carriers. In case of (γ+α) irradiated samples the temperature dependence of resistivity is of the form ρ(T)=ρ_∝ exp(T₀/T)^1/2 which is due to one-dimensional hopping of carriers.     

TeV γ-ray astronomy

The TeV γ-ray sky displays at this time 9 sources comprising 6 supernova remnants (SNR) and 3 active galactic nuclei (AGN). They have been discovered with AIR ERENKOV TELESCOPES since 1989, and more sources are sure to be found. They are related to violent astrophysical events and promise to be used as unique tools for cosmological questions like the universal infrared photon field and the intergalactic magnetic field strength.