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采用尿素溶胶法合成(Y0.95Eu0.05)2O3纳米粉,用超临界干燥技术制备了n-(Y0.95Eu0.05)2O3/SiO2气凝胶介孔组装体。结果表明,当Y^3+:Eu^3+=20:1,均相反应时间为4h,且经680℃、4h灼烧热处理后得到的n-(Y0.95Eu0.05)2O3中,光致发光强度最大(发光峰位于612nm),以Si与2Y摩尔比为1:7的n-(Y0.95Eu0.05)2O3/SiO2气凝胶介孔组装体,经同样条件热616nm)。对产生上述发光强度减弱和峰位红移现象进行讨论。 相似文献
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GexSi1—x/Si应变超晶格雪崩光电探测器的分析与优化设计 总被引:1,自引:1,他引:0
对GexSi1-x/Si应变超晶格雪崩光电探测器进行了分析与优化设计,优化结构为:i-Si雪崩区厚是1.8~2μm;p-Si区的掺杂浓度是10^18cm^-3厚为17nm超晶格总厚为340nm,它可探测1.3~1.6μm的红外光。 相似文献
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从名义组份Bi2.4Sr2PrCu2Oy生长出一种新的Bi2222相单晶,其实际组份测定为Bi2Sr1.5Pr2.5Cu2Oy.用X射线衍射对单晶的结构进行了表征,并且研究了该单晶生长中Bi2201和Bi2212相的交生等相关问题.另外,如果从名义组份为Bi2.4Sr1.5Pr2.5Cu2Oy出发,得到的却是Pr2CuO4单晶. 相似文献
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1.55μmSi1—xGex光波导在Si1—xGex/Si多量子阱探测器集成的优… 总被引:2,自引:1,他引:1
对1。55μm波长的Si1-xGex光波导和Si1-xGex/Si多量子阱红外探测器的集成器件结构进行了系统的分析和优化设计。优化结果为:1)对Si1-xGex光波导,Ge含量x=0.05,脊宽,高和腐蚀深度分别为8,3和2.6μm,2)对SI1-xGex/Si多量子阱红外探测器,Ge含量x=0.5,探测器由厚度为550nm,23个周期的6nmSi0.5GE0.5+18nmSi组成,长度约2mm。 相似文献
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对1.55μm波长的Si1-xGex光波导和Si1-xGex/Si多量子阱(MQW)红外探测器的集成器件结构进行了系统的分析和优化设计。优化结果为:1)对Si1-xGex光波导,Ge含量x=0.05,脊宽、高和腐蚀深度分别为8、3和2.6μm;2)对Si1-xGex/Si多量子阱红外探测器,Ge含量x=0.5,探测器由厚度为550nm、23个周期的6nmSi0.5Ge0.5+17nmSi组成,长度约2mm。结果表明,这种结构器件的内量子效率可达88%。 相似文献
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应用溶胶凝胶法合成了平均尺寸为40nm的La0.7Sr0.3MnO3纳米粉末,在0.2GPa到4.5GPa的压力范围内加压成型,制成=6mm,厚为1mm的纳米固体样品。测量了不同成型压力下样品的正电子寿命谱,研究了纳米固体内部存在的三类空位缺陷随压力的变化规律。在低于1.0GPa的情况下,三类缺陷随压力的增加变化敏感,成型压力高于1.0GPa时,纳米固体内部的压致碎化导致十几个单空位尺寸大小的微孔洞缺陷数量的剧增,使纳米固体内部的缺陷密度增加,呈现反常的压力依赖关系。 相似文献
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热导率的动态热线法测量系统 总被引:8,自引:0,他引:8
介绍了我们研制的动态热线法测热导率系统的特点,原理和装置,通过对某些标准样品的测量结果表明,该系统的测量精度在2%以内,利用这一装置我们还测量了新型纳米多孔性材料SiO2气凝胶的热导率与气压和温度的关系。 相似文献
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本工作研究了Sm3+离子在立方和六角两种结构硫化锌中的光谱。实验上,采用不同激发条件下的高分辨光谱、时间分辨光谱和激发光谱,同时配合低温退火处理实验,鉴别出硫化锌中Sm3+具有两种不同的发光中心。采用发光方法,第一次对稀土离子在硫化锌中的C3v对称发光中心进行分析。在中间耦合自由离子能级基础上利用不可约张量方法和Wigner-Eckart定理进行晶体场计算,得到的晶体场参数实验值和点电荷模型计算的晶体场参数值相符合。 相似文献
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研究了紫外光照射乙醇-水混合溶液的稳态和时间分辨荧光光谱.通过检测其荧光光谱和激发光谱,得到了稳态发射光谱的三个荧光峰,峰值分别位于290 nm、305 nm、330 nm,相应的最佳激励光分别为265 nm, 280 nm 和236 nm.在荧光光谱峰值波长处分别监测其荧光强度随时间的衰变过程,将获得的荧光衰减动力学曲线采用指数拟合并进行解卷积处理获得不同荧光光子的寿命值.乙醇-水溶液稳态光谱的特点和三个不同的荧光寿命都表明了溶液中含有三个不同的生色团,分析认为乙醇和水分子间通过氢键作用形成了不同结构的团簇分子. 相似文献
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M. Sabooni M. Esmaeili H. Haratizadeh B. Monemar P. Paskov S. Kamiyama M. Iwaya H. Amano I. Akasaki 《Opto-Electronics Review》2007,15(3):163-167
We report results from optical spectroscopy such as photoluminescence (PL) and time resolved photo-luminescence (TRPL) techniques
from different well width MOCVD grown GaN/Al0.07Ga0.93N MQW samples. There is evidence of localization at low temperature in all samples. The decay time of all samples becomes
non-exponential when the detection energy is increased with respect to the peak of the emission. Localization of carriers
(excitons) is demonstrated by the “S-shape” dependences of the PL peak energies on the temperature. The time-resolved PL spectra
of the 3-nm well multi quantum wells reveal that the spectral peak position shifts toward lower energies as the decay time
increases and becomes red-shifted at longer decay times. There is a gradient in the PL decay time across the emission peak
profile, so that the PL process at low temperatures is a free electron-localized hole transition. 相似文献
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The absorption and fluorescence spectra of labetalol and pseudoephedrine have been studied in different polarities of solvents and β-cyclodextrin (β-CD). The inclusion complexation with β-CD is investigated by UV-visible, steady state and time resolved fluorescence spectra and PM3 method. In protic solvents, the normal emission originates from a locally excited state and the longer wavelength emission is due to intramolecular charge transfer (TICT). Labetalol forms a 1:2 complex and pseudoephedrine forms 1:1 complex with β-CD. Nanosecond time-resolved studies indicated that both molecules show triexponential decay. Thermodynamic parameters (ΔG, ΔH, ΔS) and HOMO, LUMO orbital investigations confirm the stability of the inclusion complex. The geometry of the most stable complex shows that the aromatic ring is deeply self included inside the β-CD cavity and intermolecular hydrogen bonds were established between host and guest molecules. This suggests that hydrophobic effect and hydrogen bond play an important role in the inclusion process. 相似文献
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Eu3+摩尔浓度对Y2O2S:Eu3+,Mg2+,Ti4+红色长余辉材料光谱的影响 总被引:12,自引:2,他引:12
用高温固相法制备了Y2O2S:Eu^3 ,Mg^2 ,Ti^4 红色长余辉材料。测量了该材料的余辉曲线,余辉时间为1h以上;由X射线衍射得到晶体结构为Y2O2S.测量了不同Eu^3 摩尔浓度下的激发光谱和发射光谱,得到从^5DJ(J=0,1,2,3)^-7FJ(J=0,1,2,3,4,5)的发射谱线,并得到位于260,345,468和540nm激发峰。由于激活剂饱和效应,Y2O2S:Eu^3 ,Mg^2 ,Ti^4 发射光谱中513.6,540.1,556.4,587.3和589.3nm属于从^5D2,^5D1到^7FJ(J=0,1,2,3,4)跃迁的发射峰随Eu^3 摩尔浓度的增加相对削弱;激发谱包括位于350nm左右属于电荷转移态吸收(Eu^3 -O^2-,Eu^3 -S^2 )的激发主峰和在可见光区位于468,520和540nm属于Eu^3 离子4f-4厂吸收的激发峰。随着Eu^3 摩尔浓度的增加,位于468,520和540nm的激发峰相对增强。 相似文献
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The emission spectra and its time decay in PbCl2 at low temperature are reported. Three emission bands lying at 3.81 (uv), 2.93 (blue) and 2.60 eV are found for the photo-excitation in the intrinsic absorption region, at 4.2 K. An exponential decay with decay time of 11.4 μs is observed for the uv emission. For the blue emission two kinds of time decay spectra are observed: a second order process below 10 K and an exponential decay above 14 K. The mechanisms of these emission are discussed by taking into account the above results. 相似文献
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掺杂在晶体Y2 SiO5(YSO)中的Pr3 ,运用脉冲激光激发 3H4 → 1 D2 跃迁 ,粒子通过非辐射能量转移从能级 1 D2 转移到能级 3P0 ,测得了对应于 3P0 → 3H4 跃迁的反斯托克斯荧光光谱 ,由此可确定 3H4 的Stark分裂能级以及 3P0 能级的能量高度。与运用激光激发 3H4 → 1 D2 跃迁 ,通过观察 1 D2 → 3H4 斯托克斯荧光光谱确定3H4 的Stark分裂能级方法相比 ,该过程避免了不同晶点位置中 (Crystallographicsite)Pr3 的 1 D2 能级间的能量转移影响 ,从而具有较高的确定性。同时 ,我们观察了反斯托克斯荧光的时间特性 相似文献
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Time‐resolved luminescence properties of Ce3+ doped Y3Al5O12 (YAG) nanocrystals have been studied by means of vacuum‐ultraviolet excitation spectroscopy. It was discovered that additionally to the regular Ce3+ yellow‐green emission which is well‐known luminescence in YAG, new emission covering a broad spectral range from 2.7 eV to 3.5 eV was revealed in the luminescence spectra for all YAG:Ce nanocrystals studied. This blue‐UV emission has fast decay time about 7 ns as well as intensive well‐resolved excitation band peaking at 5.9 eV and, in contrast to green Ce3+ emission, practically is not excited at higher energies. The origin of the blue‐UV emission is tentatively suggested and discussed. (© 2016 WILEY‐VCH Verlag GmbH &Co. KGaA, Weinheim) 相似文献