煤颗粒热膨胀量与破碎特性的研究

煤颗粒的热膨胀破碎特性直接影响流化床锅炉的运行效率.本文利用热机械分析仪(TMA)测定了不同种类不同密度的型煤和原煤的热膨胀特性,并对部分破碎微观形貌进行了FSEM观察;通过旋转炉内的燃烧试验研究了热膨胀特性和破碎的关系.研究表明,煤颗粒在燃烧过程中其热膨胀破碎主要发生在挥发分析出阶段;内部挥发分的析出会使颗粒内压增大而产生膨胀,进而产生细小裂纹并破碎;挥发分越高,颗粒密度越大,其热膨胀形变率越大,越容易发生破碎现象;主要挥发分析出后热膨胀引起的破碎可以忽略.     

光学系统实现热补偿的通用条件

运用光学系统的近轴成像公式，推导出微分形式的物面位于任意位置时热补偿的通用条件，包括薄单透镜、密接薄透镜组和分离薄透镜组等不同情况。推导过程中假设物面位置不随温度发生变化，并且忽略分离薄透镜组中各组分上光线入射高度随温度的变化。利用推导的条件建立了像距的归一化温度变化率与各透镜光热膨胀系数之间的关系，指出所得到的条件具有更加普遍的意义，能够指导机械和伺服控制系统的工程设计，并且在物面位于无穷远时与目前普遍采用的热补偿条件相吻合，即光学系统的光热膨胀系数等于壳体的热膨胀系数。     

Thermal expansion of nanostructured PbS films and anharmonicity of atomic vibrations

The dependences of the coherent scattering region size and thermal expansion coefficient α of a PbS nanofilm on the annealing temperature in the range of 293–473 K and on the duration of annealing at a constant temperature of 423 K have been measured. It has been found that the thermal expansion coefficient α of the PbS nanofilm is almost twice as much as the coefficient α of coarse-grained lead sulfide. It has been shown that the large difference in the coefficients α is associated with the small size of particles in the film, which leads to an increase in the anharmonicity of atomic vibrations. The contribution from the small size of particles to the thermal expansion coefficient of the PbS nanofilm has been evaluated theoretically.     

3GPa压力处理对Cu-Zn合金热膨胀系数的影响

利用膨胀仪测试了Cu-Zn合金在3 GPa压力处理前后、25~700℃温度范围内的热膨胀系数;借助金相显微镜、X射线衍射(XRD)及差示扫描量热分析(DSC)技术,对高压处理前后合金的金相组织及相变进行了分析。在此基础上,探讨了高压处理对Cu-Zn合金热膨胀性能的影响。结果表明:高压处理能增大Cu-Zn合金的热膨胀系数,改变热膨胀系数随温度的变化规律,当温度为535.14℃时,热膨胀系数呈现高峰值,较同等温度未经高压处理的Cu-Zn合金的热膨胀系数增大了49.48%。     

Design of an optical fiber sensor for linear thermal expansion measurement

Design and operation of an optical fiber device for temperature sensing and thermal expansion measurement are reported. The modulated intensity has been measured by using a pair of 450 μm core fiber, one acting as the source and the other one as receiving fiber. In this design, the light intensity modulation is based on the relative motion of the optical fibers and a reflective coated lens. By using displacement calibration data for this sensor, the linear thermal expansion of the aluminum rod is determined. This sensor shows an average sensitivity of about 11.3 mV/°C for temperature detection and 7 μm/°C for thermal expansion detection. Device resolution for a linear expansion measurement is about 3 μm for a dynamic range of 600 μm corresponding to a temperature change of 100°C. The measured linear expansion results are checked against the expected theoretical ones and an agreement within ±2 μm is noticed. The operation of this sensor was also compared with other types and some advantages are observed, which verify the capability of this design for such precise measurements.     

Thermal expansion of cadmium fluoride crystals at high temperatures

The thermal expansion coefficient of cadmium fluoride crystals has been measured over the temperature range of 300 to 1070 K. The data fit well to measurements done by other authors in the range 80–300 K. At temperatures above 1070 K the thermal expansion coefficient shows an anomalous behaviour which has been attributed to the formation of cadmium oxide on the surface of the sample.     

Anomalous thermal expansion of InSe layered semiconductors in the low-temperature region

The temperature dependence of the linear thermal expansion coefficient (TEC) of an InSe single crystal in the (001) plane is measured in the temperature range 7–50 K. A peak in the thermal expansion is detected near T = 10 K, after which the sample shrinks upon heating. The effect of an external magnetic field of up to 6 T, which is parallel to the (001) plane, on the TEC is investigated. The observed partial suppression of the peak and crystal compression by the field indicates the relation of these anomalies to possible electron ordering in InSe layers.     

Negative longitudinal expansion and the amplitude of longitudinal vibrations in poly(ethylene) crystals

The experimental temperature dependences of the thermal expansion coefficient and the mean-square amplitude of atomic vibrations in the longitudinal direction (along the axes of chain molecules) in poly(ethylene) crystals of different sizes are measured using x-ray diffraction in the temperature range 5–350 K. Theoretical calculations of the temperature dependences of the thermal expansion coefficient and the mean-square amplitude of atomic vibrations in poly(ethylene) crystals are carried out. It is shown that the results of calculations are in good agreement with experimental data. The temperature ranges in which the quantum character of lattice dynamics affects the thermal expansion coefficient and the mean-square amplitude of vibrations are determined. It is revealed that the shear longitudinal modes play an important role in the lattice dynamics of crystals with a chain structure.     

Thermal expansion of the skeleton of chain molecules in polymer crystals

The expansion of the carbon skeleton of molecules in crystallites and the longitudinal contraction of the crystallite lattice in poly(ethylene) (PE) and poly(caproamide) (PCA) with an increase in the temperature are measured using IR and Raman spectroscopy and x-ray diffraction. The thermal expansion of the carbon skeleton due to transverse vibrations is theoretically calculated within the atomic chain model. The theoretical and experimental data on the thermal expansion of the carbon skeleton are in good agreement.     

Thermal expansion of polymers subjected to low-amplitude temperature cycling

The temperature dependence of the thermal expansion of polymers subjected to small harmonic temperature oscillations about certain base temperatures near the glass transition range is considered. The conformational component of the expansion as a function of temperature is calculated in terms of the conformational transition kinetics. The temperature dependences of the expansion and the expansion vs. oscillation phase shift are analyzed with allowance for the vibrationally anharmonic component. The thermal expansion of polyvinylacetate at base temperatures of 295–320 K, oscillation frequencies of 0.3 and 0.1 Hz, and an oscillation amplitude of 0.8 K are studied experimentally. The measured and calculated data for the expansion and expansion vs. temperature phase shift are shown to be in good agreement.     

Thermal expansion of nanocrystalline and coarse-crystalline silver sulfide Ag<Subscript>2</Subscript>S

In situ studies of the thermal expansion of polymorphic phases of coarse-crystalline and nanocrystalline silver sulfide, namely, monoclinic acanthite α-Ag₂S and cubic argentite β-Ag₂S, have been performed for the first time by high-temperature X-ray diffraction. The temperature dependences of the unit cell parameters of acanthite and argentite have been measured from temperatures in the range of 300–623 K, and the thermal expansion coefficients of acanthite and argentite have been determined. The observed difference between the thermal expansion coefficients of nano- and coarse-crystalline acanthite is shown to be due to a small size of nanocrystalline silver sulfide particles, which leads to an increase in the anharmonicity of atomic vibrations.     

Magnetic order in the heavy fermion compound CeCu6 at mK temperatures

We have measured the ac magnetic susceptibility in various fields and thermal expansion of single crystals of the heavy fermion compound CeCu6 at temperatures down to 250 &mgr;K. The susceptibility of CeCu6 shows a peak at about 2 mK and has a large anisotropy. We also detected an anomaly of thermal expansion at the same temperature. The observed behaviors of the susceptibility and the thermal expansion in CeCu6 indicate the occurrence of an antiferromagnetic order.     

Calculation of anisotropic properties of dental enamel from synchrotron data

Obtaining information about the intrinsic structure of polycrystalline materials is of prime importance owing to the anisotropic behaviour of individual crystallites. Grain orientation and its statistical distribution, i.e. the texture, have an important influence on the material properties. Crystallographic orientations play an important role in all kinds of polycrystalline materials such as metallic, geological and biological. Using synchrotron diffraction techniques the texture can be measured with high local and angular resolving power. Here methods are presented which allow the spatial orientation of the crystallites to be determined and information about the anisotropy of mechanical properties, such as elastic modulus or thermal expansion, to obtained. The methods are adapted to all crystal and several sample symmetries as well as to different phases, for example with overlapping diffraction peaks. To demonstrate the abilities of the methods, human dental enamel has been chosen, showing even overlapping diffraction peaks. Likewise it is of special interest to learn more about the orientation and anisotropic properties of dental enamel, since only basic information is available up to now. The texture of enamel has been found to be a tilted fibre texture of high strength (up to 12.5×). The calculated elastic modulus is up to 155 GPa and the thermal expansion up to 22.3 × 10^?6 °C^?1.     

钨/石墨烯/钨面向等离子体复合材料力学与热学及耐辐照性能衰减的第一性原理计算

通过第一性原理计算研究了钨/石墨烯/钨复合材料相比于纯钨金属在力学与热学性质方面的变化,并用氦原子-空位缔合缺陷模拟核聚变辐照损伤评估等离子体辐照条件下的性能。计算结果表明：钨/石墨烯/钨复合材料的体积弹性模量、杨氏模量与剪切模量呈现一定程度的下降,但是提升了钨基材料的延展性;钨/石墨烯/钨复合材料的热膨胀系数有所增加,但是具有较高的最小热导率。本文阐述了石墨烯界面层可以对基体杂质与缺陷进行吸附的独特机制,通过这种机制,钨/石墨烯/钨复合材料在力学、热膨胀系数以及最小热导率有更低程度的衰减,这显示了钨/石墨烯/钨复合材料在抗辐照性能方面具有较大的应用潜力。     

Measurement of thermal expansion coefficient of nonuniform temperature specimen

A new technique is developed to measure the longitudinal thermal expansion coefficient of C/C composite material at high temperature. The measuring principle and components of the apparatus are described in detail. The calculation method is derived from the temperature dependence of the thermal expansion coefficient. The apparatus mainly consists of a high temperature environmental chamber, a power circuit of heating, two high-speed pyrometers, and a laser scanning system. A long solid specimen is resistively heated to a steady high-temperature state by a steady electrical current. The temperature profile of the specimen surface is not uniform because of the thermal conduction and radiation. The temperature profile and the total expansion are measured with a high-speed scanning pyrometer and a laser slit scanning measuring system, respectively. The thermal expansion coefficient in a wide temperature range (1000 - 3800 K) of the specimen can therefore be obtained. The perfect consistency between the present and previous results justifies the validity of this technique.     

X-ray studies on the thermal expansion of copper indium disulphide

The lattice parameters of the compound copper indium disulphide (CuInS₂) have been measured by x-ray diffraction. The data have been used to evaluate the coefficients of thermal expansion, perpendicular and parallel to the principal axis. The thermal expansion studies revealed the anisotropy between the axial expansion coefficients having a larger coefficient of expansion alonga axis than that alongc axis. The anisotropic thermal expansion of this compound is interpreted in terms of the thermal expansion of the Cu-S and In-S bonds.     

Changes of thermal, mechanical and magnetic properties of an amorphous Fe80Cr5B15 alloy during magnetic and structural phase transitions

Thermal, mechanical and thermomagnetic properties associated with the magnetic and structural transition of an amorphous Fe₈₀Cr₅B₁₅ alloy are described. The investigation was carried out in a simultaneous dilatometric and thermomagnetic experiment. An anomaly of the thermal expansion coefficient at the Curie point and a change in mechanical properties just before the onset of crystallization are observed. The results are compared with the thermal behavior obtained by differential scanning calorimetry.     

金属线胀系数的测定

线胀系数是表征物质膨胀特性的重要参数,采用YJ-RZ-4数字智能化热学综合仪,利用千分表方法测定了金属样品的线胀系数。应用最小二乘法和隔项逐差法对测量数据进行分析处理,得到了预期的结果。     

Thermal expansion of the C15 Laves-phase materials TaV2 and TaV2H x

The thermal expansion of the C15 Laves-phase material TaV₂H _x was measured over the temperature range of 130–350?K for x?=?0, 0.34 and 0.53. A primary objective of the study was to see if the anomalous temperature dependence of elastic constants found in an earlier study is due to, or associated with, unusual thermal expansion. The expansion was typical of transition metals, and quite close to theoretical results for related Laves-phase materials. Grüneisen parameters were determined from the measurements, and these were also typical of transition metals, and close to calculated values for related materials. Both the thermal expansion and the Grüneisen parameters of TaV₂ decreased somewhat with the addition of hydrogen. No anomalous behavior of the expansion was found that might account for the highly anomalous temperature dependence of elastic moduli reported earlier. This absence is consistent with the attribution of the elastic constant behavior to an electronic structure effect.     

类克尔介质中原子布居数的演化和偶极压缩效应

研究了一个两能级原子处于充满类克尔介质的高Ｑ腔里与单模辐射场多光子相互作用的系统中，原子能级布居数的时间演化特性以及原子的偶极压缩效应，着重讨论了类克尔介质与单模辐射场作用的耦合强度ｘ和失谐量Δ对原子系统行为的影响。