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A procedure is presented for the calculation of the double vibrational collision-induced absorption CO(2) (nu(3) = 1) + N(2) (nu(1) = 1) <-- CO(2) (nu(3) = 0) + N(2) (nu(1) = 0) on the basis of quantum lineshapes computed using an isotropic potential and dipole-induced dipole functions. The linestrengths and energies of the vibration-rotation transitions are treated explicitly for N(2), utilizing the HITRAN database for CO(2). The theoretical absorption profile is compared to recent experimental results. By narrowing the width of the individual lines contributing to the overall absorption profile relative to their values determined for N(2)-N(2) collision-induced absorption, excellent agreement between theory and experiment is obtained. Copyright 2000 Academic Press.  相似文献   

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The structure and orientational ordering of N2O molecules physisorbed on graphite (0001) is investigated applying x-ray, neutron, and low-energy electron diffraction techniques. Combining the results of the three techniques, we find that N2O forms a highly ordered, hexagonal, commensurate (sqrt[21]xsqrt[21])R10.89 degrees phase. The unit cell contains seven molecules which are arranged in a seven-sublattice pinwheel structure, unexpected for linear molecules on a hexagonal lattice. Potential energy calculations corroborate these results.  相似文献   

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We provide numerical evidence for composite fermion pairing in quantum Hall bilayer systems at filling nu=1/2+1/2 for intermediate spacing between the layers. We identify the phase as p_(x)+ip_(y) pairing, and construct high accuracy trial wave functions to describe the ground state on the sphere. For large distances between the layers, and for finite systems, a competing "Hund's rule" state, or composite fermion liquid, prevails for certain system sizes.  相似文献   

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用全实加关联方法计算了Ni25+离子1s2np(n≤9)态的能量和精细结构. 1s2np态的非相对论计算结果为-851.91237219 a.u, 与Yan.等人用Hylleraas型变分法和1/Z展开方法得到的-851.91246266(74)a.u.之间的相对偏差仅约 0.1 ppm. 在计算1s2np(n≤9)态的自旋-轨道相互作用以及自旋-其他轨道相互作用的期待值的基础上,通过引入价电子的有效核电荷,还估算了对精细结构劈裂的QED修正和高阶相对论修正.结果表明,这两种效应的贡献大约分别占总劈裂的0.2%和2%.  相似文献   

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The effective operator approach is applied to the calculation of both line positions and line intensities of the (13)C(16)O(2) molecule. About 11 000 observed line positions of (13)C(16)O(2) selected from the literature have been used to derive 84 parameters of a reduced effective Hamiltonian globally describing all known vibrational-rotational energy levels in the ground electronic state. The standard deviation of the fit is 0.0015 cm(-1). The eigenfunctions of this effective Hamiltonian have then been used in fittings of parameters of an effective dipole-moment operator to more than 600 observed line intensities of the cold and hot bands covering the nu(2) and 3nu(2) regions. The standard deviations of the fits are 3.2 and 12.0% for these regions, respectively. The quality of the fittings and the extrapolation properties of the fitted parameters are discussed. A comparison of calculated line parameters with those provided by the HITRAN database is given. Finally, the first observations of the 2nu(1) + 5nu(3) and nu(1) + 2nu(2) + 5nu(3) absorption bands by means of photoacoustic spectroscopy (PAS) is presented. The deviations of predicted line positions from observed ones is found to be less than 0.1 cm(-1), and most of them lie within the experimental accuracy (0.007 cm(-1)) once the observed line positions are included in the global fit. Copyright 2000 Academic Press.  相似文献   

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We consider mesoscopic fluctuations of Coulomb drag transresistivity between two layers at a Landau level filling factor nu = 1/2 each. We find that, at low temperatures, sample to sample fluctuations exceed both the ensemble average and the corresponding fluctuations at B = 0. At the experimentally relevant temperatures, the variance of the transresistivity is proportional to T(-1/2). We find the dependence of this variance on density and magnetic field to reflect the attachment of two flux quanta to each electron.  相似文献   

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New low-lying excitations are observed by inelastic light scattering at filling factors nu=p/(phip+/-1) of the fractional quantum Hall regime with phi=4. Coexisting with these modes throughout the range nu < or =1/3 are phi=2 excitations seen at 1/3. Both phi=2 and phi=4 excitations have distinct behaviors with temperature and filling factor. The abrupt first appearance of the new modes in the low-energy excitation spectrum at nu > or near 1/3 suggests a marked change in the quantum ground state on crossing the phi=2-->phi=4 boundary at nu=1/3.  相似文献   

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Using a "standard" NMR spin-echo technique we determined the spin polarization P of two-dimensional electrons, confined to GaAs quantum wells, from the hyperfine shift of Ga nuclei located in the wells. Concentrating on the temperature ( 0.05 less, similarT less, similar10 K) and magnetic field ( 7 less, similarB less, similar17 T) dependencies of P at Landau level filling factor nu = 1/2, we find that the results are described well by a simple model of noninteracting composite fermions, although some inconsistencies remain when the two-dimensional electron system is tilted in the magnetic field.  相似文献   

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We show that the complicated superpositionsV(r) of several important phenomenological forces may still lead to an elementary form of doublets of bound states under transparent algebraic constraints. Constructively, we show how (and when) the constrained couplings preserve compatibility with the physical regularity of wavefunctions.  相似文献   

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NMR measurements of the electron spin polarization (P) have been performed on a 2D electron system at and around half-filled lowest Landau level. Comparing the magnetic field and the temperature dependence of P to models of free and interacting composite fermions (CF), the imbalance of spin-up and spin-down CF Fermi seas is mapped as a function of Zeeman energy. Independent measurements of the CF effective mass, g factor, and Fermi energy are obtained from the thermal activation of P in tilted fields. The filling factor dependence of the P for 2 / 5相似文献   

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The average electron spin polarization Rho of a two-dimensional electron gas confined in GaAs/GaAlAs multiple quantum wells was measured by NMR near the fractional quantum Hall state with filling factor nu = 2/3. Above this filling factor (2/3< or = nu < 0.85), a strong depolarization is observed corresponding to two spin flips per additional flux quantum. The most remarkable behavior of the polarization is observed at nu = 2/3, where a quantum phase transition from a partially polarized (Rho approximately 3/4) to a fully polarized (Rho = 1) state can be driven by increasing the ratio between the Zeeman and the Coulomb energy above a critical value eta(c) = Delta(Z)/Delta(C) = 0.0185.  相似文献   

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Fluorescence decay of the 2s2p(6)np (1)P(o) excited states of neon has been observed directly for the first time. This process has also been observed indirectly by threshold photoelectron spectroscopy and in electron/photon coincidences. The measurements have allowed this weak decay channel to be characterized and branching ratios derived. The fluorescence excitation spectrum is well described by a simple Rydberg model that highlights the interplay and competition between the decay channels of autoionization and fluorescence.  相似文献   

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根据塞曼效应理论和浙江磁共振(LMR)光谱原理,本文建立一了套用于标识激光磁共振光谱的模型方法,并成功地对CF X^2П(ν=1)远红外及NO X^2П(ν←0)中红外激光磁共振光谱进行了标识。为新自由基分子的激光磁共振光谱提供了快速而准确的方法。  相似文献   

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In bilayer quantum Hall systems at filling fractions near nu=1/2+1/2, as the spacing d between the layers is continuously decreased, intralayer correlations must be replaced by interlayer correlations, and the composite fermion (CF) Fermi seas at large d must eventually be replaced by a composite boson (CB) condensate or "111 state" at small d. We propose a scenario where CBs and CFs coexist in two interpenetrating fluids in the transition. Trial wave functions describing these mixed CB-CF states compare very favorably with exact diagonalization results. A Chern-Simons transport theory is constructed that is compatible with experiment.  相似文献   

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