钡原子三重态的碰撞诱导受激辐射

在XeCl激光光泵的Ba蒸气中,首次观察到波长为551.9nm、606.3nm及611.1nm的受激辐射,它们分别对应于Ba原子的三重态跃迁:6s6d~3D_2—6s6p~3P_1、5d6p~3P_2-6s5d~3D_3及5d6p~3P_1—6s5d~3D_2.对于Ba原子的自旋禁戒跃迁6s7p~1P_1—6s6d~3D_2的可能性进行了探讨.     

SryBa1－yFCl0.5Br0.5:Sm2+在光谱

本文对无机光谱烧孔系列材料SryBa1－yFCl0.5Br0.5:Sm2+中不同组份的样品(y=0,0.25.0.5,0.75.1.00)4f5d能带的激发光谱、不同温度下5D2、5D1、5D0→7F0跃迁的荧光衰减进行了测量,研究了组份的变化对4f5d能带的位置,5D2、5D1、5D0→7F0跃迁的几率和烧孔效率的影响,并得出结论:在该系列材料中,随组份y的增加,4f5d带与5DJ能级更加接近,5D0→7F0的电子跃迁几率增大,烧孔效率提高。     

About Rotational Transitions and Muon Transfer in Muonic Hydrogen–Helium Systems

Hyperfine Interactions - Rotational J=1→J=0 transitions in muonic molecule, (3Heμd) J ++, in [(3Heμd)++,2e]–D and [(3Heμd)++,e]+–D collisions are considered. The...     

Stark effect in 6s 5d and 5d 6p states in barium measured with laser-atomic-beam spectroscopy

Zeitschrift für Physik A Hadrons and nuclei - The tensor polarizabilities of the 6s 5d 1 D,3 D levels and the 5d6p 1 P,1 F,3 P and3 D states in barium, as well as differential scalar...     

Universality class of fluctuating pulled fronts

It has recently been proposed that fluctuating "pulled" fronts propagating into an unstable state should not be in the standard Kardar-Parisi-Zhang (KPZ) universality class for rough interface growth. We introduce an effective field equation for this class of problems, and show on the basis of it that noisy pulled fronts in d+1 bulk dimensions should be in the universality class of the ((d+1)+1)D KPZ equation rather than of the (d+1)D KPZ equation. Our scenario ties together a number of heretofore unexplained observations in the literature, and is supported by previous numerical results.     

T1uhg杨-泰乐系统：D5d势阱中的各向异性现象

杨-泰乐(Jahn-Teller缩写为JT)系统在其最低的绝热势能面上常常典型地含有一系列相互等同的势阱.在C60分子中，若一个电子占据该分子的三重简并的能量最低电子态，这一具有T1u对称性的电子态将会与具有hg对称性的五重简并振动态发生相互作用，形成所谓的T1uhg JT系统.当考虑电声的非线性相互作用时，该系统的势能面上将出现D5d对称性的势阱并伴随D3d对称性的势垒；反之亦然.本文在幺正平移变换的基础上，引入了标度变换，研究了该JT系统中D5d势阱中的各向异性现象：在电子空间中，非线性项的引入使得 关键词： C60 杨-泰乐效应 各向异性 电声耦合 标度变换     

Study of a Selective Photoionization Scheme of 177Lu

Optics and Spectroscopy - The hyperfine structure of transitions in the three-step scheme 5d6s22D3/2–5d6s6p4F $$_{{5/2}}^{^\circ }$$ –5d6s7s4D3/2– (53 375 cm–1)...     

Ba原子6s5d~3 D与6p5d~3 F态的超精细结构及态间跃迁的同位素移动的直接确定

提出并演示了一种光泵预选态的原子光谱测量方法,并对Ba原子的6s5d3 D态与6p5d3 F态的超精细结构及该跃迁的同位素移动进行了直接测量。首先利用791nm的激光激发Ba原子特定同位素及特定超精细结构的6s6s 1 S0→6s6p3 P1跃迁,并利用6s6p3 P1→6s5d3 D2的自发辐射有选择地分别将这些同位素制备到6s5d3 D2态不同的超精细能级上,再用778nm的激光扫出对应的6s5d3 D2→6p5d3 F2跃迁的荧光光谱,通过这几组光谱之间的对比直接实现了对22条超精细谱线的认定和归属,从而得到了135 Ba和137 Ba的6s5d3 D2能级与6p5d3 F2能级的超精细结构常数及该跃迁的同位素移动。     

Jamming of Granular Flow in a Two-Dimensional Hopper

We study experimentally the jamming phenomenon of granular flow of monodisperse disks of D = 5 mm diameter in a two-dimensional hopper with opening R. The jamming probability J(d) is measured where d identical withR/D. We found that J(d) decreases from 1 to zero when d increases from 2 to 5. From observing the disk configurations of the arch in the jamming events, the jamming probability can be explained quantitatively by treating the arch as the trajectory of a restricted random walker.     

Observation of Single-slope Quasistatic Wings of Laser Induced Collision Energy Transfer

Three transitions of laser induced collision energy transfer from Eu (6s6p)8P5/2 to Sr (5s10s)1S0, Eu(6s6p)8P7/2 to Sr(5s9d)1D2 and Eu(6s6p)8Ps/2 to Sr(5s9d)1D2 have been observed in experiments. The relation between the breadth of spectral lines and the energy structures were analyzed experimentally and theoretically by two dipole-dipole interactions.     

Observation of Single-slope Quasistatic Wings of Laser Induced Collision Energy Transfer

1　Ｉｎｔｒｏｄｕｃｔｉｏｎ　　Ｌａｓｅｒ ｉｎｄｕｃｅｄｃｏｌｌｉｓｉｏｎｅｎｅｒｇｙｔｒａｎｓｆｅｒ(ＬＩＣＥＴ)ｉｓａｎｏｐｔｉｃａｌｐｈｅｎｏｍｅｎｏｎｉｎｖｏｌｖｉｎｇｔｈｅｓｉｍｕｌｔａｎｅｏｕｓｉｎｔｅｒａｃｔｉｏｎｓｏｆｂｏｔｈｔｈｅｌａｓｅｒｆｉｅｌｄａｎｄｃｏｌｌｉｓｉｏｎ[1～ 3 ] .ＴｈｉｓＬＩＣＥＴｒｅａｃｔｉｏｎｃａｎｂｅｗｒｉｔｔｅｎａｓ:Ａ Ｂ ｈΩ →Ａ Ｂ (1)Ｄｕｒｉｎｇｔｈｅｃｏｌｌｉｓｉｏｎｏｆａｔｏｍ Ａｗｉｔｈａｔｏｍ Ｂ ,ａｔｏｍＡｇｏｅｓｂａｃｋｔｏｇｒ…     

Reflection spectra of 1D photonic crystals based on aluminum oxide

Optical properties (transmission and reflection) of 1D photonic crystals (PCs) based on mesoporous anodic aluminum oxide with the lattice periods of 188 and 194nm are investigated. The experimentally measured reflection spectrum is compared in its first bandgap region with the theoretical dependence obtained from the dispersion relation for the 1D PC. Angular dependence is established for spectral positions of bandgaps in the 1D PC. A possibility of using mesoporous aluminum-oxide-based 1D PCs as narrow-band filters, narrow-band mirrors, and refractive sensors of molecular compounds is analyzed.     

One-dimensional instability in BaVS3

The 3d(1) system BaVS3 undergoes a series of remarkable electronic phase transitions. We show that the metal-insulator transition at T(MI)=70 K is associated with a structural transition announced by a huge regime of one-dimensional (1D) lattice fluctuations, detected up to 170 K. These 1D fluctuations correspond to a 2k(F)=c(*)/2 charge-density wave (CDW) instability of the d(z(2)) electron gas. We discuss the formation below T(MI) of an unconventional CDW state involving the condensation of the other V4+ 3d(1) electrons of the quasidegenerate e(t(2g)) orbitals. This study stresses the role of the orbital degrees of freedom in the physics of BaVS3 and reveals the inadequacy of current first principle band calculations to describe its electronic ground state.     

Ethane cation decomposition characterization by EBMI spectroscopy: gas-phase dissociative recombination as a source of secondary products

The decomposition products of the d(6) -ethane cation following charge-transfer ionization with Ar(+) , under conditions of varying ionization electron current, have been isolated in solid argon matrices at 18?K and examined using Fourier transform infrared spectroscopy. Gas samples containing 1?:?1600 d(6) -ethane?:?Ar were subjected to electron bombardment by using either a high (pin) or a low (plate) ionization density anode configuration with ionization currents between 20 and 150?μA. Under high ionization density conditions, the observed major products were d(4) -ethene (C(2) D(4) ) and d(2) -acetylene (C(2) D(2) ), with smaller yields of C(2) D(5) , C(2) D(3) , and C(2) D. The yield of each dehydrogenation product was enhanced with increased current. Analogous experiments employing the low ionization density plate anode resulted in reduced C(2) D(6) destruction and the formation of only C(2) D(4) and C(2) D(2) . The results suggest the onset of dissociative recombination processes under high ion density conditions. In this context, the results can be interpreted as a dissociative recombination of primary ion products, which gives rise to further dehydrogenation, and appearance of additional neutral radical products.     

Improved measurement of /V(cb)/ using B-->D*l nu decays

We determine the weak coupling /V(cb)/ between the b and c quarks using a sample of 3 x 10(6) BB; events in the CLEO detector at the Cornell Electron Storage Ring. We determine the yield of reconstructed B-->D*l nu; decays as a function of w, the boost of the D* in the B rest frame, and from this we obtain the differential decay rate d Gamma/dw. By extrapolating d Gamma/dw to w=1, the kinematic end point at which the D* is at rest relative to the B, we extract the product /V(cb)/F(1), where F(1) is the form factor at w=1. Combined with theoretical results for F(1) we determine /V(cb)/=0.0469+/-0.0014(stat)+/-0.0020(syst)+/-0.0018(theor).     

BaFClxBr1－x:Sm2+中5D2→7F0跃迁几率及其对烧孔效率的影响

本文以BaFClxBr1－x:Sm2+中5D2→7F0的跃迁几率随x变化为中心对BaFClxBr1－x:Sm2+体系4f5d带的激发光谱、5D2→7F0跃迁的荧光衰减随温度的变化特性、5D2→7F0的跃迁几率等进行了研究。从而得出结论:在BaFClxBr1－x:Sm2+中,随Br含量的增大,4f5d带与5D2能级更加接近,使7F0→5D2的吸收截面增大,从而可能提高在5D2:能级烧孔的效率。     

Phyllotactic description of hard sphere packing in cylindrical channels

We develop a simple analytical theory that relates dense sphere packings in a cylinder to corresponding disk packings on its surface. It applies for ratios R=D/d (where d and D are the diameters of the hard spheres and the bounding cylinder, respectively) up to R=1+1/sin(π/5). Within this range the densest packings are such that all spheres are in contact with the cylindrical boundary. The detailed results elucidate extensive numerical simulations by ourselves and others by identifying the nature of various competing phases.     

Open charm yields in d+Au collisions at squareroot[sNN]=200 GeV

Midrapidity open charm spectra from direct reconstruction of D0(D0)-->K-/+pi+/- in d+Au collisions and indirect electron-positron measurements via charm semileptonic decays in p+p and d+Au collisions at squareroot[sNN]=200 GeV are reported. The D0(D0) spectrum covers a transverse momentum (pT) range of 0.1相似文献   

一维NOE NMR 技术用于蒂巴因衍生物的立体结构研究

基于高效镇痛剂双氢埃托啡游离碱,对蒂巴因衍生物的立体化学结构的NMR 测定方法进行了研究．结果表明,采用多频率位移选择激发一维NOESY(1D NOESY)和二维NMR(2D NMR)相结合的方法,可有效解决该类化合物¹H 和¹³C NMR 谱复杂重叠的信号归属困难的问题．同时在阐明溶液构象的基础上,提出采用一维NOE(1D NOE)测定C-7和差向异构体的新方法．该方法简单、有效、不受样品浓度影响和杂质信号干扰,结果可靠,不需要标准品对照等优点．该结果有助于此类化合物的立体结构与生物活性关系的研究．     

Ab initio Study of the Potential Energy Surface and Product Branching Ratios for Reaction of O(1D) with C2H5Cl

用QCISD(T)/6-311++G(d,p)//MP2/6-31G(d,p)方法研究了O(1D)与CH3CH2Cl的反应．计算表明此反应存在一个插入-消去机理．此反应先形成IM1和IM2两个中间体,两个中间体再分解成各种产物．用RRKM理论计算了碰撞能分别为0、20.9、41.8、62.7、83.6、104.5和125.4 kJ/mol时通过IM1、IM2分解的各个通道的分支比率．IM1的主要分解产物是HCl,IM2的主要分解产物是CH2OH．因为IM1比IM2稳定,HCl很可能是反应的主要产物．计算结果能够提供反应机理而且可以对以后的实验提供可能的解释．