应变多量子阱激光器的阱数与腔长

本文从理论上分析计算并给出了应变多量子阱激光器阱数与腔长的优化设计结果.考虑到多生子阱阱区的注入不均匀性,提出了一种新的分析和计算方法.以1.55μmInGaAs(P)1.5%压缩应变多量子阱激光器为例,最佳的阱数为4个,最佳腔长为500μm左右.     

量子阱半导体激光器阈值的理论分析

分析了单量子阱(SQW)、多量子阱(MQW)和分别限制异质结构量子阱(SCH-SQW)半导体激光器的阈值.求出了表示光增益随注入载流子密度变化的方程.利用这个结果,得到了上述三种量子阱半导体激光器的阈值电流密度的表达式.     

双重势垒一维光子晶体量子阱内部局域电场分布

利用传输矩阵法理论,研究了双重势垒一维光子晶体量子阱(AB)k(CD)m(DCD)n(DC)m(BA)k的内部局域电场.结果表明:双重势垒光量子阱内部分布着很强的局域电场,且越靠近阱中心,局域电场越强;双重势垒光量子阱垒层特别是内垒层和外垒层厚度同时增大时,内部局域电场快速增强,而且阱中心增强最明显;双重势垒光量子阱阱层宽度增大时,越靠近阱中心,局域电场越强,但阱宽按偶数倍增大时阱中心的局域电场不变并保持恒定极大值,而阱宽按奇数倍增大到一定数值后,光量子阱内部局域电场则趋于阱宽按偶数倍增大时的局域电场恒定极大值.该研究可为分析光量子势阱的量子化效应机理和分立透射谱的形成内因,以及量子光学产品的实际设计等提供指导.     

NPB/Alq3有机量子阱光电特性研究

利用热蒸发的方法制备了有机量子阱发光器件和Alq3单层发光器件,其中NPB(N,N′-Di-[(lnaphthalenyl)-N,N′-diphenyl]-(1,1′-biphenyl)-4,4′-diamine)作垒层,Alq3(Tris-(8-quinolinolato) aluminum)作阱层,量子阱结构类似于无机半导体的Ⅱ型量子阱结构.实验发现有机量子阱发光器件结构中存在垒层向阱层的F(o)rster无辐射共振能量转移,具有良好的电流-电压特性,光谱的窄化及蓝移,并且光谱的蓝移程度随电压的增大而逐渐增强.     

量子阱、超晶格结构的线性电光效应研究进展

本文综合比较了各种用以解释量子阱、超晶格结构线性电光效应(LEO)的理论和模型,如:EFT理论,GBC理论,HBF模型等;并按三种量子阱结构:阱区和势垒层具有一种相同原子的I型量子阱(CA QWs)、阱区和势垒层不具有相同原子的I型量子阱(NCA QWs)以及II型量子阱,给出了具体的量子阱超晶格结构线性电光效应的研究现状;最后总结了目前硅基量子阱、超晶格LEO的一些研究结果,并分析指出了对其作进一步研究的发展方向。     

有机量子阱电致发光器件

制备了普通的有机量子阱结构,并对结构进行了表征.在此基础上,制备了量子阱结构的白光电致发光器件.在分析了制作工艺对有机量子阱结构特性可能产生的影响之后,为了减少垒、阱界面互扩散效应的影响,提出了有机掺杂量子阱的概念,即垒与阱的母体是相同材料,只是在生长垒层的过程中同时掺入少量发光剂.由于掺杂剂的浓度梯度只有百分之零点几,因此,界面互扩散的影响很小,实际上我们用这种办法制备的有机量子阱器件的亮度、效率均有明显提高.在研究了阱数对器件特性的影响之后,我们发现一般情况下,两个阱是最好的.进一步研究了阱母体材料对有机量子阱器件特性的影响,结果发现,用NPB作母体比Alq作母体更好,这时器件的效率(cd/A)在45～13V工作电压范围内变化不大.     

有机多层阱结构中光谱蓝移的研究

为了研究有机多层阱结构中光谱蓝移的原因,制备了以N,N′-Di-[(1-naphthalenyl)-N,N′-diphenyl]-(1,1′-biphenyl)-4,4′-diamine (NPB) 为垒层和以Tris-(8-quinolinolato)aluminum(Alq3) 为阱层的有机多层阱结构器件.利用光致发光的方法,对具有不同周期及不同阱层厚度的有机多层阱结构器件进行研究.分析认为有机多层阱结构中的光谱蓝移是由于光谱重叠造成的,而并非量子尺寸效应或激子限制效应.     

双波泵浦非对称量子阱的光学整流效应

为了实现基于光整流方式的室温下宽调谐高效率太赫兹源,设计了一种适于双波长CO2激光器共振子带跃迁泵浦的双阱嵌套形非对称量子阱结构,结构组分为Al0.5Ga0.5As/Ga As/Al0.2Ga0.8As,采用密度矩阵及迭代方法计算了其二阶非线性光整流系数χo(2)表达式,在导带为抛物线形和非抛物线形两种条件下对χo(2)进行对比研究。计算结果表明,其偶极跃迁矩阵元随量子阱总阱宽的增大而逐渐减小。当固定量子阱总阱宽及其中一束泵浦光波长不变时,χo(2)随着另一束泵浦光波长的增加,呈现出先增大后减小的变化趋势。当深阱为7 nm、总阱宽为23 nm、两束泵浦光相等为10.64μm时,χo(2)达到最大值5.925×10-6m/V;随着总阱宽的增大,χo(2)曲线呈现"红移"现象,其原因为量子限制效应导致了不同阱宽条件下的量子阱能级值差不同,从而造成满足泵浦光光子能量与能级差共振条件的变化。导带为抛物线形和非抛物线形两种条件下的χo(2)的最大值对应泵浦光波长基本相同,χo(2)数值上的差异主要由跃迁矩阵元的不同导致。     

量子阱、超晶格结构的线性电光效应研究进展

本文综合比较了各种用以解释量子阱、超晶格结构线性电光效应(LEO)的理论和模型,如:EFT理论,GBC理论,HBF模型等;并按三种量子阱结构:阱区和势垒层具有一种相同原子的I型量子阱(CA QWs)、阱区和势垒层不具有相同原子的I型量子阱(NCA QWs)以及II型量子阱,给出了具体的量子阱超晶格结构线性电光效应的研究现状;最后总结了目前硅基量子阱、超晶格LEO的一些研究结果,并分析指出了对其作进一步研究的发展方向。     

有机多层阱结构中光谱蓝移的研究

为了研究有机多层阱结构中光谱蓝移的原因,制备了以N,N′-Di-[(1-naphthalenyl)-N,N′-diphenyl]-(1,1′-biphenyl)-4,4′-diamine (NPB) 为垒层和以Tris-(8-quinolinolato)aluminum(Alq3) 为阱层的有机多层阱结构器件.利用光致发光的方法,对具有不同周期及不同阱层厚度的有机多层阱结构器件进行研究.分析认为有机多层阱结构中的光谱蓝移是由于光谱重叠造成的,而并非量子尺寸效应或激子限制效应.     

Magneto-optical study of nonmagnetic quantum dots coupled to a magnetic semiconductor quantum well

We have investigated a series of double-layer structures consisting of a layer of self-assembled non-magnetic CdSe quantum dots (QDs) separated by a thin ZnSe barrier from a ZnCdMnSe diluted magnetic semiconductor (DMSs) quantum well (QW). In the series, the thickness of the ZnSe barrier ranged between 12 and 40 nm. We observe two clearly defined photoluminescence (PL) peaks in all samples, corresponding to the CdSe QDs and the ZnCdMnSe QW, respectively. The PL intensity of the QW peak is observed to decrease systematically relative to the QD peak as the thickness of the ZnSe barrier decreases, indicating a corresponding increase in carrier tunneling from the QW to the QDs. Furthermore, polarization-selective PL measurements reveal that the degree of polarization of the PL emitted by the CdSe QDs increases with decreasing thickness of the ZnSe barriers. The observed behavior is discussed in terms of anti-parallel spin interaction between carriers localized in the non-magnetic QDs and in the magnetic QWs.     

ZnSe-ZnS应变超晶格的光致发光

本文讨论了使用常压金属氧化物化学汽相沉积(MOCVD)技术生长的ZnSe-ZnS应变超晶格的发光特性。ZnSe-ZnS应变超晶格的发射光谱,在高密度激发下通常仅存在一个发射峰;在低密度激发下除带边发射之外,还存在深中心的发射;与低密度激发相比,高激发下发光峰值红移且其半高宽展宽,高质量的ZnSe-ZnS应变超晶格在低激发下,带边发光很强,而深中心发射能被大大抑制,我们观测到一个新的激子发射峰,考虑应变效应与量子限制效应,本文将这一新的发射峰归结为与n=1的轻空穴激子有关的复合发光。 关键词：     

ZnSe-ZnS超晶格的通光蚀孔及列阵研究

用MOCVD方法在GaAs衬底上生长ZnSe-ZnS超晶格.用化学腐蚀方法在GaAs衬底上开一个通光窗口,使该窗口上仅剩有1～1.8μm厚的生长层.室温下测量了蚀孔后由于化学腐蚀造成生长层表面差异的ZnSe-ZnS超晶格的吸收光谱.研究了带有生长过渡层和无过渡层的超晶格质量对其吸收光谱性能的影响.发现过渡层的存在保护了超晶格激子吸收性能.在此基础上首次采用新工艺在3×3mm2面积上把GaAs衬底金部腐蚀掉,剩下均匀、光滑的ZnSe-ZnS超晶格层,在其上做出了300×300μm2的列阵,为在ZnSe-ZnS超晶格上实现光学双稳的集成化提供了必要条件.     

Optical excitation and emission processes of Si-QD/SiO2 multilayer films with different SiO2 layer thicknesses

Si-rich oxide/SiO₂ multilayer films with different SiO₂ layer thicknesses have been deposited by the plasma enhanced chemical vapor deposition technique, and crystallized Si quantum dot (Si-QD)/SiO₂ multilayer films are obtained after annealing at 1100 ^°C. The photoluminescence (PL) intensity of the multilayer films increases significantly with increasing SiO₂ layer thickness, and the PL peak shifts from 1.25 eV to 1.34 eV. The PL excitation spectra indicate that the maximal PL excitation intensity is located at 4.1 eV, and an excitation–transfer mechanism exists in the excitation processes. The PL decay time for a certain wavelength is a constant when the SiO₂ thickness is larger than 2 nm, and a slow PL decay process is obtained when the SiO₂ layer is 1 nm. In addition, the PL peak shifts toward high energy with decreasing temperature only when the SiO₂ layer is thick enough. Detailed analyses show that the mechanism of PL changes from the quantum confinement effect to interface defects with decreasing SiO₂ layer thickness.     

掺杂ZnSe/BeTe Ⅱ型量子阱结构中带电激子的磁场效应

报道了n型掺杂ZnSe/BeTe/ZnSe Ⅱ型量子阱(type-Ⅱ QW)在极低温 (5—10 K)条件下的各种光学性质. 磁场中(Farada配置)ZnSe层的反射光谱展示了一个典型的负的带电激子(X^-)的跃迁特征. 对于空间间接光致发光(spacially indirect PL)光谱,它的主发光峰显示了一个反玻尔兹曼分布的非对称性,并且在磁场中(Voigt配置)它的峰值能量随磁场的增加而降低. 这些实验结果显示了该掺杂样品的空间间接PL是来自Ⅱ型QW结构所特有的带电激子的跃迁. 关键词： 光致发光 二维电子气 带电激子 Ⅱ型量子阱     

Temperature dependent photoluminescence from ZnO/MgZnO multiple quantum wells grown by pulsed laser deposition

We have studied temperature dependent photoluminescence (PL) from ZnO Multiple Quantum Wells (MQWs) of different well layer thicknesses in the range 1–4 nm grown on (0001) sapphire by a novel in-house developed buffer assisted pulsed laser deposition. At 10 K the PL peak shifted toward blue with decreasing well layer thickness and at constant well layer thickness the PL peak shifted towards red with increasing temperature. To the best of our knowledge we have observed for the first time an efficient room temperature (RT) PL emanating from such MQWs. The red shift of the PL peak with increasing temperature has been found to be due to the band gap shrinkage in accordance with the Varshni’s empirical relation. The spectral linewidth was found to increase with increasing temperature due to the scattering of excitons with acoustic and optical phonons in different temperature regimes. Both at RT and at 10 K the PL peak shifted with respect to the well layer thickness in the range of 3.35–3.68 eV with decreasing thickness in agreement with the calculated values.     

Optical investigation of A-plane ZnO/ZnMgO multiple quantum wells grown by pulsed laser deposition

In this study, we present the optical characteristics of A-plane ZnO/ZnMgO multiple quantum wells (MQWs) with different well widths grown on R-plane sapphire substrates by pulsed laser deposition (PLD). The energy gaps of ZnO and ZnMgO have been observed by photoluminescence (PL) and absorption spectra. The electrons confined in the ZnO wells transit from the electron ground sub-band to the heavy-hole ground sub-band (noted as 11H) located at 3.40 and 3.57 eV for the ZnO/ZnMgO MQWs samples with well widths of 5.6 and 1.2 nm, respectively. The strong anisotropic polarization characteristic has been studied by polarization-dependent PL measurements. For comparison, we also calculated the transition energies of different well thicknesses varying from 1 to 6 nm. The theoretical results match quite well with the experimental values and revealing the suitable conduction band offset Q_c=0.6. The temperature dependence of PL spectra is being investigated, in the temperature range between 10 and 300 K.     

低压-MOCVD方法制备CdS-ZnS应变多量子阱

本文报道了用低压(LP)-MOCVD方法制备CdS-ZnS应变多量子阱结构.通过X-射线衍射谱证实了所制备的样品具有比较好的多层结构,并通过77K下的光致发光(PL)光谱,观测到了大的垒层对电子的限制效应及由大的应变引起的阱层带边变化所导致的发光峰蓝移.     

Temperature induced size selective synthesis of hybrid Cds/pepsin nanocrystals and their photoluminescence investigation

There is growing interest in materials chemistry for taking advantage of the physical and chemical properties of biomolecules in the development of next generation nanoscale materials for opto-electronic applications. A biomimetic approach to materials synthesis offers the possibility of controlling size, shape, crystal structure, orientation, and organization. The great progress has been made in the control that can be exerted over optical materials synthesis using biomolecules (protein, nucleic acid)/mineral interfaces as templates for directed synthesis. We have synthesized the CdS nanocrystals using pepsin by biomimetic technique at four different set temperatures. X-ray diffraction (XRD) and small angle X-ray scattering (SAXS) results showed that we are able to tune the size and distribution profile just by tuning the reaction (Rx) temperature and goes towards excitonic Bhor radius (2.5 nm) at low temperature (4 °C). The narrow absorption peak at 260 nm from Cd²⁺-pepsin complex dominates and indicates the size dispersion of the modified CdS nanoparticles are fairly monodisperse. Effective mass approximation (EMA) shows large blue-shift (~1 eV) in the band gap for the cubic phase from bulk hexagonal CdS. The photoluminescence (PL) and photoluminescence excitation (PLE) spectra are dominated by a strong and narrow band-edge emission tunable in the blue region indicating a narrow size distribution. The reduction in PL efficiency is observed when the Rx temperature increases however no change in PLE spectra and temporal profiles of the band-edge PL is observed. At 4 °C, high emission efficiency with shift of PL spectrum in the violet region is observed for 1.7 nm size CdS quantum dots (QDs). Presence of pepsin has slowed the PL decay which is of the order of 100 μs.     

ZnSe0.93Te0.07-ZnSe多量子阱的光泵受激发射

宽带Ⅱ-Ⅵ族化合物半导体在短波长可见光范围内优越的发光特性使其在器件的研制方面有着广阔的前景.ZnSe基量子阱和超晶格结构,尤其是ZnCdSe-ZnSe量子阱已经在器件的制备方面取得了可喜的进展,因而人们研究的比较多.