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Radiative rates for the b→a, b→X, and a→X transitions in NCl have been determined in solid argon. The rates - corrected for the refractive index - are 520, 260, and 0.27 s−1. The b→X and a→X rates are in good agreement with calculated rates, whereas the b→a rate is enhanced by five orders of magnitude in the matrix. 相似文献
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