Updated Analysis of Gallium Chelate and Vanadium Chelate Solutions with 4‐(2‐Pyridylazo)Resorcinol and Xylenol Orange

The characteristic factors of the gallium and vanadium chelates with the ligands 4(2pyridylazo)resorcinol (PAR) and xylenol orange (XO) have been determined with the aid of the principle of correction, which makes it possible to eliminate the influence of the surplus ligand in the solution of its chelate with methane (which makes calculation easier) and thereby provides a more acceptable method in comparison with others. The real molar coefficients of extinction of the chelates Ga and V with PAR and XO have been determined and a detailed calculation of the stoichiometric ratios of chelates has been made. The results have shown that the chelates formed have the following structure: Ga(PAR), Ga(XO), V(PAR)₂, and V(XO).     

Analytic Properties of the Structure Function for the One-Dimensional One-Component Log–Gas

The structure function S(k; ) for the one-dimensional one-component log–gas is the Fourier transform of the charge–charge, or equivalently the density–density, correlation function. We show that for |k|j in the power series expansion of f(k; ) about k=0 is of the form of a polynomial in /2 of degree j divided by (/2)^j. The bulk of the paper is concerned with calculating these polynomials explicitly up to and including those of degree 9. It is remarked that the small k expansion of S(k; ) for the two-dimensional one-component plasma shares some properties in common with those of the one-dimensional one-component log–gas, but these break down at order k⁸.     

Investigation of Rust Formed on Steel Surfaces and Related Oxyhydroxides

In order to indentity the corrosion products formed on steel surfaces from ⁵⁷Fe Mössbauer spectroscopy, detailed Mössbauer parameters have been determined for various kinds of iron-oxyhydroxides: -FeOOH, -FeOOH, -FeOOH and -FeOOH. ⁵⁷Fe Mössbauer measurements of the iron oxyhydroxides indicate the following results. Fe occupies a single site in -FeOOH, but below the Néel temperature as at e.g., 300 K the Mössbauer spectrum is always broad, showing a distribution of the strength of the magnetic exchange interactions. Its shape depends on the grain-size and synthetic methods of the specimen. Fe occupies 3 sites in -FeOOH. High-purity reagents of -FeOOH always contain small amounts of -FeOOH and their Néel temperatures depend on the synthetic methods of the specimen. Mössbauer spectroscopy of the synthetic -FeOOH shows very broad distribution of the hyperfine magnetic fields.     

Calculation of characteristics of benzene derivatives

The C₆H₅X compounds are considered as regards the energy and wave function _x as functions of within limits of –3 and +3, and also as functions of _cx within limits of 0. 5 and 1. 5. Convenient numerical tables are compiled.We are indebted to N.A. Prilezhaev and V.I. Danilov for extensive collaboration in this work.     

The phase transition in a general class of Ising-type models is sharp

For a family of translation-invariant, ferromagnetic, one-component spin systems—which includes Ising and ⁴ models—we prove that (i) the phase transition is sharp in the sense that at zero magnetic field the high- and low-temperature phases extend up to a common critical point, and (ii) the critical exponent obeys the mean field bound 1/2. The present derivation of these nonperturbative statements is not restricted to regular systems, and is based on a new differential inequality whose Ising model version isMh+M ³+ M ²M/. The significance of the inequality was recognized in a recent work on related problems for percolation models, while the inequality itself is related to previous results, by a number of authors, on ferromagnetic and percolation models.     

Millimeter wave propagation through a chiral medium model of human trunk

That millimeter wave propagation through a chiral medium of human trunk has been discussed by obtaining the electromagnetic filed, absorbent power, specific absorption rate, temperature field and their distribution in a human trunk model with plane strati calate homogeneous tissues under a normal incidence plane wave. The chiral medium is described electromagnetically by the constitutive relationsD=E+B andB=H+E. The constants, and ate real and have values that are fixed by the size, the shape, and the spatial distribution of the elements that collectively compose the medium. Also, the principle of thermal therapeutics for millimeter wave is discussed preliminaryly.     

Relativistic scattering theory for long-range potentials of the nonelectrostatic type

We define a modified free-time evolution for the Dirac equation with long-range potentials (1/|x|), where is the Dirac matrix, and prove a strong asymptotic completeness of the corresponding wave operators. Our methods also work for the magnetic fields ·A(x).     

Analysis of the Structure of the Bands in the IR Spectrum of β-D Glucose by the Regularized Method of Deconvolution

Deconvolution of the IR absorption spectrum of -D glucose in the spectral range 1500–450 cm^–1 has been carried out. The results of the deconvolution were compared with the IR and Raman spectra recorded at room and low temperatures and with the data obtained by theoretical calculations for the frequencies of the normal vibrations of the -D glucose molecule in the crystalline state. It is shown that deconvolution of the IR spectra recorded at room temperature makes it possible to separate the bands observed experimentally only at a very low temperature of the sample and a number of components that were not resolved earlier. The number of bands separated on deconvolution of the IR spectra of -D glucose in the spectral range 1500–450 cm^–1 is more than twice the number of visible absorption maxima in the usual spectrum. The results of deconvolution of the IR spectrum of -D glucose are in good agreement with the data of theoretical calculations for the frequencies of the normal vibrations of the -D glucose molecule in the crystalline state. The existence of the factor-group (Davydov) splitting of a number of frequencies of the nondegenerate fundamental vibrations of molecules in a crystal cell has been revealed in the IR spectrum of -D glucose. It was concluded that the model of an isolated molecule is insufficient for detailed theoretical interpretation of the vibrational spectra of carbohydrates.     

Total absorption spectroscopy of the β-delayed proton emitter 117Ba

The very neutron-deficient ¹¹⁷Ba nuclei were produced in ⁵⁸Ni-induced reactions on a ⁶³Cu target and selected for spectroscopic studies by using BaF⁺ molecules formed in the ion source of the GSI on-line mass separator. The -decay of ¹¹⁷Ba was investigated by means of the total absorption -ray spectrometer and a telescope for -delayed particle detection. In the analysis combining the -delayed -ray and proton data the energy window available for -delayed proton emission, the branching ratios for proton transitions to the ¹¹⁶Xe levels and the -feeding of the -ray and proton-emitting ¹¹⁷Cs states were determined. The -strength function for ¹¹⁷Ba derived from the measured -feeding distribution revealed the existence of a broad resonance structure at ¹¹⁷Cs excitation energy of about 4-5 MeV. The results of the -delayed proton studies and -strength measurements are confronted with theoretical predictions.     

A generalized fluctuation-dissipation theorem for the one-dimensional diffusion process

The [, , ]-Langevin equation describes the time evolution of a real stationary process withT-positivity (reflection positivity) originating in the axiomatic quantum field theory. For this [, , ]-Langevin equation a generalized fluctuation-dissipation theorem is proved. We shall obtain, as its application, a generalized fluctuation-dissipation theorem for the one-dimensional non-linear diffusion process, which presents one solution of Ryogo Kubo's problem in physics.     

Exponential decay near resonance,without analyticity

We consider a quantum mechanical model which displays the behaviour associated with having a resonance or metastable state. The Hamiltonian depends on a parameter . When =0, there is an eigenstate ₀; when 0, ₀ dissolves into the continuous spectrum, showing approximate exponential decay. We prove this result without using dilatation analyticity. The model describes a two-state atom coupled to the quantized radiation field. The state space of the field is truncated, so that only the vacuum and one-photon states are included.This work was partially supported by NSF Grant DMS-8922941     

The choice of test functions in gauge quantum field theories

We discuss the problem of the choice of test functions in gauge quantum field theories. Analysis of explicitly soluble models suggests that the test function spaces which are suitable for local and covariant formulation of gauge theories are the Gelfand and Shilov spaces , +>1. We also discuss a possible generalization of the spectral condition.     

Trace states and KMS states for approximately inner dynamical one-parameter groups of *-automorphisms

The usual definition of approximately inner one-parameter groups of *-automorphisms ofC*-algebras (approximately inner dynamical one-parameter groups) contains a slight asymmetry. When this asymmetry is corrected, we show that if an approximately inner dynamical one-parameter group hasKMS states forone value of inverse temperature =1/kT, then it hasKMS states for all values of . By the Powers-Sakai Theorem it is enough to show that there is a trace state. We obtain a trace state as a limit of a sequence of vector states with respect to a givenKMS state and thus solve a problem raised in [6].Supported by Odense University, Denmark     

Space Videophotometric System for Recording Optical Radiations in the Earth Atmosphere

This paper describes the VFS-3M videophotometric system designed for automatic remote recording of images and parameters of optical radiations following lightning discharges from aboard the Russian segment of the International space station. The characteristics of the system and the possibilities of recording such types of radiation as Red Sprites and Blue Jets are given.     

Levels in <Superscript>127</Superscript>La fed by the <Superscript>127</Superscript>Ce beta-decay

The low-lying levels in ¹²⁷La have been studied through the -decay of ¹²⁷Ce ( T_1/2 = 29s) produced by bombarding a ^natMo target with a 185-MeV ³⁵Cl beam. Reaction products were on-line mass-separated, and -ray singles and - coincidence measurements were performed. Conversion electrons were also measured and multipolarities of transitions have been derived. The half-life of the 210.9-keV level was determined to be (1.9±0.3)ns by the - delayed coincidence technique. The level scheme obtained has been compared with calculations based on the Nilsson model.     

A new rigorous upper bound for the inverse critical temperature of the two-dimensional Coulomb gas

In this paper we show how to improve the recent result _c 17.2 on the inverse critical temperature for the two-dimensional Coulomb gas at low density to get the following upper bound: _c 16.     

Allowed β-γ angular correlations induced by magnetic interactions

Allowed - angular correlations from nuclei of paramagnetic ions is considered. It is shown that a magnetic hyperfine interaction creates an anisotropy of the -ray if a static magnetic field is simultaneously present.     

An ARC Facility for Studying Carbon Plasma and Obtaining Low‐Dimensional Carbon Structures

An experimental DUF2000 facility for spectroscopic investigations of a reducedpressure carbon arc and also for production of lowdimensional carbon structures (fullerenes, nanotubes, etc.) is described.     

Phases of the number-theoretic spin chain

We present numerical and analytical evidence for a first-order phase transition of the ferromagnetic spin chain with partition functionZ()=(–1)/() at the inverse temperature _cr=2.     

Mixing properties,differentiability of the free energy and the central limit theorem for a pure phase in the Ising model at low temperature

For the Ising model with nearest neighbour interaction it is shown that the spin correlations _{A B} - _{A B} decrease exponentially asd(A, B) in a pure phase when the temperature is well belowT _c. This is used to prove that the free energyF(,h) is infinitely differentiable in and has one sided derivatives inh of all orders forh=0. The bounds are also used to prove that the central limit theorem holds for several variables such as e.g. the total energy and the total magnetization of the system, the limit distribution being gaussian with variances determined by the second derivatives ofF(,h).