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Marc Van Hooste Albert T. H. Lenstra Michał Kwiecinski Stanisław Tyrlik 《Transition Metal Chemistry》1982,7(1):50-53
Summary The title compound crystallizes in the monoclinic space group P21/n, with cell dimensions:a = 8.535(4) Å,b = 13.009(4) Å,c = 20.615(5) Å, = 100.57(3) and Z = 4. The central cobalt atom coordination is a slightly distorted octahedron, formed by five N-atoms (two glyoximes and morpholine) and one C-atom.The interaction between the complex Co-units is weak: the strongest nearest neighbour interaction is formed by a hydrogen bridge in which the water molecule of crystallization acts as the donor part. 相似文献
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M. M. El-Dessouky M. W. Abdel-Raouf 《Journal of Radioanalytical and Nuclear Chemistry》1998,229(1-2):195-197
Chelation studies of cobalt(III) with 1,2 bis(beta-aminoethoxy)ethane N,N,N',N' sodium sulfonate triacetic acid (ASTA) were
performed. The results showed the effectiveness of ASTA as a chelating agent by using: molar ratio, continuous variation and
slope ratio methods. Stable complex 1∶1 was formed at pH from 6.0 to 10.5. Solutions of Co-ASTA chelate of different molar
ratios at pH 6.5 and 8.0 were irradiated by different gamma-radiation doses. The results showed a linear decrease of absorbance
with gamma-radiation dose which can be utilized as a dosimeter for low dose rate measurement in the range studied. A proposed
radiolytic mechanism is discussed. The degradation of the ASTA ligand has been related to hydroxyl radical attack. 相似文献
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The first O-bonded sulfenate species [Co(en)2(py-SO-O)]2+ has been synthesized by isomerization of its S-bonded linkage isomer, [Co(en)2(pyridine-2-sulfenate-S]2+. The sulfenate ion in both forms is stabilized by coordination to the electropositive cobalt(III) ion. The driving force for the formation of the O-bonded sulfenate linkage isomer comes from the four to five membered ring expansion which accompanies the rearrangement. Crystal structures of the green O-sulfenate confirm the formulation and reveal varying amounts of a cocrystallized O-bonded sulfinate diastereomer. The cations have essentially identical structures except for the extra oxygen in the O-sulfinate. Differences in packing of cations and perchlorates give rise to two different structural types for the salts, corresponding to sulfenate-rich and sulfinate-rich phases. 相似文献
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