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对甲基苯磺酰化蛋氨酸镧配合物的合成 总被引:1,自引:0,他引:1
合成了一种新型对甲基苯磺酰化蛋氨酸镧配合物, 并利用红外光谱、 紫外光谱及热重分析对配合物及配体的结构进行了表征和确认. 以对甲基苯磺酰化蛋氨酸镧配合物作为修饰剂, 研制了修饰碳糊电极, 该电极对镧离子具有能斯特响应, 为此建立了溶液中镧离子的直接电位分析法. 修饰电极对镧离子的能斯特响应工作曲线方程为E(mV)=-19.50pCLa(III)-363.50, 相关系数R=0.9996,线性范围为4.0×10-2~4.0×10- 6 mol · L-1, 检测下线为1.6 ×10- 6 mol · L-1, pH响应范围是3.2~6.0. 试验了14种外加离子对测定的影响, 结果表明Ca2+, Mg2+, Zn2+, Ba2+, Cu2+, Co2+等金属离子对测定有微弱干扰. 利用该修饰电极对人工合成样品中镧离子含量进行测定. 相似文献
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4-(4-(4-(Didodecylamino)phenylazo)phenyl)butyric acid is synthesized, and its Langmuir-Blodgett (LB) monolayer is successfully fabricated. The drastic changes in electronic spectra of this compound are found in acidic solution and in LB monolayer upon exposure to HCl vapor (mainly the decrease in absorption at 416 nm and great increase at 540 nm). The UV-visible and infrared spectra reveal a mechanism of protonation to either azo group or amino group. This phenomenon has been suggested to have its prospective application in fundamental interfacial materials for pH sensors. Copyright 2000 Academic Press. 相似文献
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Lizai-guo Huang Run-qiu Li Hui-ying 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1)
Abstract Recently, we found that some derivatives of heterocyclic substituted α aminophosphonic acid showed very good inhibitory effects against tobacco mosaic virus. In this paper, we report the synthesis of the title compounds, which may serve as plant virucides. 相似文献
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LI Xun XU Wen-Fang ② 《结构化学》2005,24(6):706-710
1 INTRODUCTION Aminopeptidase N (APN), a member of mem- brane-bound zinc-dependent exopeptidase, is known to be high expression on the brush border membran- es of the small intestine and renal proximal tubules[1]. The over-expression of APN has been involved in several pathological conditions including cancer[2], leukemia, diabetic nephropathy[3], rheumatoid arth- ritis[4], angiogenesis[5] and central nervous system di- seases, such as Alzheimer’s disease[6]. This has led to the sear… 相似文献
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Chamathka Dehiwala Liyanage José J. Ortiz-Garcia Annalena Struckmeier Dr. Michael Kienzler Dr. Rebecca C. Quardokus 《Chemphyschem》2023,24(17):e202300160
Photochromic molecules can undergo a reversible conversion between two isomeric forms upon exposure to external stimuli such as electromagnetic radiation. A significant physical transformation accompanying the photoisomerization process defines them as photoswitches, with potential applications in various molecular electronic devices. As such, a detailed understanding of the photoisomerization process on surfaces and the influence of the local chemical environment on switching efficiency is essential. Herein, we use scanning tunneling microscopy to observe the photoisomerization of 4-(phenylazo)benzoic acid (PABA) assembled on Au(111) in kinetically constrained metastable states guided by pulse deposition. Photoswitching is observed at low molecular density and is absent in tight-packed islands. Furthermore, switching events were noted in PABA molecules coadsorbed in a host octanethiol monolayer, suggesting an influence of the surrounding chemical environment on photoswitching efficiency. 相似文献
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The synthesis of 2-(4-hydroxyphenoxy) propionic acid, useful as an important intermediate for herbicides, had been reported[1-3]. In this paper, The synthesis of 2-(4-hydroxyphenoxy)propionic acid had been studied by the reacting hydroquinone with cheap 2-chloropropionic acid in the presence of base. 相似文献