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运用量子理论推导和数值计算相结合的方法,本文首先得到了一维势箱函数的示意图及其模型.接着,全面、系统地研究了量子理论中N维势箱函数的波函数、能级和概率密度.最后,运用MATLAB软件对势箱函数的所有特性进行了仿真模拟.我们发现:N维势箱中粒子的能量是量子化的、不连续;量子数n不能为零,且n越大对应的能级越高,而质量m越大,对应的能级越低.一般条件下,一维势箱长度a越大(粒子运动范围越大),对应的能级越低;节点数为n-1,节点越多,波长越短,频率越高,能级越高.二维势箱函数波函数的峰值个数为n x 0x0E?SymboltB@0x0Fn y,且与Ψ=0平面的交线数也为n x 0x0E?SymboltB@0x0Fn y;概率密度分布的极大值个数也为n x 0x0E?SymboltB@0x0Fn y.对于简并度,一般情况下,二维势箱模型下的粒子的简并度是不确定的;但对于二维正方势箱函数模型,其箱内微观粒子的能级简并度分为特殊和一般两种情况.三维势箱函数的简并度为n x+n y+n z.最后,首次借助MATLAB软件的色彩实现了四维表现,得到了三维势箱函数的四维空间切片图.这种可视化的结果与理论结果完全一致,这对于抽象性概念的理解具有重要意义. 相似文献
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采用满足连续性条件的多项式独立基函数,应用线性变分法通过求解广义本征值方程研究了一维无限深势阱中粒子的能级和波函数.计算表明,随着试验基函数个数的增大,线性变分法的结果趋近于精确的解析结果. 相似文献
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利用相对论小核赝势研究了重金属钋化物分子MPo(X2∏),(M=Cu,Ag,Au).用群论方法结合原子分子反应静力学原理导出了分子的基电子状态和相应的离解极限,并在各种电子相关理论水平上计算了它们的平衡几何和振动频率.在此基础上用Murrell-Sorbie函数形式拟和势能曲线,得到了总的解析势能函数,并计算出了光谱数据和力常数. 相似文献
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对500个Sn原子分别用两种模型(紧束缚势和修正的嵌入原子势)计算了400℃~1700℃温度范围内纯Sn的双体相关函数g(r).将计算结果与实验数据进行了对比分析,发现两种计算结果都能基本上反映液态Sn的结构及其随温度的变化情况:原子最近邻距离与实验结果相近;随着温度降低,双体相关函数第一峰变得尖锐,第二峰变得明朗.修正的嵌入原子势模型得到的双体相关函数的第一峰右侧有个突起的肩膀,这在实验结果中也被发现,而紧束缚势模型得到的双体分布函数肩膀不明显. 相似文献
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耦合径向基函数与多项式基函数的无网格方法 总被引:3,自引:1,他引:2
耦合径向基函数和多项式基函数,形成一种新的近似函数.该近似函数对散乱分布的离散数据点进行逼近时,只需节点信息,不需要划分网格.详细描述了耦合近似函数的建立、属性、插值行为及其形函数和形函数导数的性质.最后引入修正变分原理和单位分解积分技术求解边值问题,并给出了计算实例,表明耦合径向基函数和多项式基函数是一种非常有效的方法. 相似文献
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Inner‐shell electronic structures, properties and ionization spectra of DNA/RNA bases are studied with respect to their parent pyrimidine and purine species. Density functional theory B3LYP/aug‐cc‐pVTZ has been employed to produce the geometries of the bases, whereas LB94/et‐pVQZ//B3LYP/aug‐cc‐pVTZ is used to calculate site‐related Hirshfeld charges and core (vertical) ionization energies, as well as inner‐shell spectra of C1s, N1s and O1s for DNA/RNA bases and their parent pyrimidine and purine species. The site‐dependent variations of properties indicate the changes and inheritance of chemical environment when pyrimidine and purine become substituted. In general, although the changes are site‐dependent, they are also ring‐dependent. Pyrimidine bases change less significantly with respect to their parent pyrimidine than the purine bases with respect to their parent purine. Pyrimidine bases such as uracil, thymine and cytosine inherit certain properties from their parent pyrimidine, such as the Hirshfeld charge distributions and the order of core ionization energy level etc. No particular sites in the pyrimidine derivatives are engaged with a dramatic chemical shift nor with energy crossings to other sites. For the core shell spectra, the purine bases inherit very little from their parent purine, and guanine exhibits the least similarities to the parent among all the DNA/RNA bases. 相似文献
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在短程球形势阱的模型下 ,运用线性变分法并采用B 样条作为展开基函数计算了内陷于C60 几何中心的氢原子能谱和波函数 ,并计算了势阱深度对能谱的影响 ,详细讨论了内陷氢原子表现出的一系列特殊性质 ,从而对低维半导体材料性能的研究提供了有效的数据 ;同时这一工作也表明 ,用线性变分法结合B 样条函数在处理这类问题时是非常有效的。 相似文献
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《Physics letters. A》2020,384(1):126033
Electron localization and delocalization of endohedrally confined hydrogen atom has been investigated employing Fisher information theory. Confinement has been modeled using a spherical Gaussian-type potential. B-spline bases expansion method was used to solve the Schrödinger equation to obtain the required energy eigenvalues and the corresponding wave functions. Changes in energies with depths of potential are explained using Hellmann-Feynman theorem. The behavior of Fisher information against the confining potential depths and positions are demonstrated. Moreover, our results show that Fisher information is an effective way to measure the localization of valence electrons. 相似文献
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讨论了三种新型非对称Schiff碱3,4-二羟基苯甲叉单草酰胺肟,2-羟基苯甲叉单草酰胺肟和苯甲叉单草酰胺肟的1H NMR谱,并给出这三种化合物的活泼氢的归属. 相似文献
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本文研究了三种反对称Schiff碱的Raman振动特性,分析了三种Schiff碱的拉曼振动模式,给出了所观察到的Raman振动的归属。 相似文献
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Jelena Đorović Zoran Marković Zorica D. Petrović Dušica Simijonović Vladimir P. Petrović 《Molecular physics》2017,115(19):2460-2468
The time-dependent density functional theory (TDDFT) was applied in conjunction with the natural bond orbital analysis to examine the UV-Vis properties of 10 phenolic Schiff bases. The calculations were performed with different functionals, but main discussion refers to results obtained at the B3LYP/6-311+G(d,p) level of theory. The approach based on the natural localised molecular orbital clusters indicates similar behaviour for majority of examined compounds. The HOMO (“highest occupied molecular orbital”) cluster is delocalised over the ring which is electron richer, the HOMO-1 cluster is spread over the other ring, whereas the LUMO (“lowest unoccupied molecular orbital”) cluster is situated on the imino group. The two bands at long wavelengths correspond to the HOMO → LUMO and HOMO-1 → LUMO transitions, i.e. from both A and B rings to the imino group. The next band originates from a transition from the imino group to the imino group. The band at the smallest wavelengths originates from a transition from the A ring to the A ring, or from the B ring to the B ring. Our findings are in very good agreement with the existing literature data. 相似文献
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Schilf W Kamieñski B Szady-Chelmieniecka A Grech E 《Solid state nuclear magnetic resonance》2000,18(1-4):97-105
Two Schiff bases; N, N′-bis(5-bromosalicylidene)-1,2-diaminoethane, BS, and 7-[(1-{5-bromo-2-hydroxyphenyl} methylidene)amino]-4-methylcoumarin, Sc, and two appropriate Schiff–Mannich bases, N, N′-bis{5-bromo-3-[(diethylamino)methyl]salicylidene}-1,2-diaminoethane, BSM, and 7-[(1-{5-bromo-3-[(diethylamino)methyl]-2-hydroxyphenyl} methylidene)amino]-4-methylcoumarin, SMc, capable of intramolecular hydrogen bonding have been investigated by multinuclear magnetic resonance methods in both solid and liquid phases. In all of the compounds under investigation tautomeric equilibrium involving an intramolecular hydrogen bond has been found. The Schiff–Mannich bases, which can form two different kinds of H bonds at room temperature, form relatively weak H bonds with the imino nitrogen atoms. At low temperatures the tautomeric proton exchange becomes slow on the NMR time scale and both hydrogen-bonded forms can be observed by 1H, 13C, and 15N NMR methods. In the solid state the tautomeric process is frozen and only one H-bonded form is present. On the basis of 13C and 15N CPMAS NMR spectra this is identified as the form with hydrogen bonds involving the imino groups. This conclusion is in good agreement with previous results obtained by X-ray diffraction methods.
The investigated Schiff bases (BS and Sc) form relatively weak H bonds. The proton position in the hydrogen bridge, estimated from 15N and 13C chemical shifts, is very similar in both the solution and solid phases. In chloroform solution the observed tautomeric equilibria are almost insensitive to a temperature change within the range 223 to 303 K. 相似文献
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本文回答了文献《光子学报》1999,28(2):118~119对我们的论文(《光子学报》1998,27(8):734~738)所作的评论,强调指出,量子力学的整体性概念具有深刻的物理基础,Lan-dau和Lifshitz所讨论的一维无限深势阱中粒子的动量概率分布的出发点和结论是完全正确的。 相似文献
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We study the quantum standard teleportation based on the generic measurement bases. It is shown that the quantum standard teleportation does not depend on the explicit expression of the measurement bases. We have giventhe correspondence relation between the measurement performed by Alice and the unitary transformation performed byBob. We also prove that the single particle unknown states and the two-particle unknown cat-like states can be exactlytransmitted by means of the generic measurement bases and the correspondence unitary transformations. 相似文献