Surface mass diffusion and step stiffness on an anisotropic surface; Mo(0 1 1)

Results of step fluctuation experiments for Mo(0 1 1), using low-energy electron microscopy, are re-examined using recently developed procedures that offer accurate coefficients of surface mass diffusion. By these means, surface diffusion D_s is documented at T/T_m ∼ 0.5, while the crossover to relaxation driven by bulk vacancy diffusion is inferred for T/T_m ∼ 0.6. Here, T_m is the melting temperature T_m = 2896 K. We obtain D_s = 4 × 10⁻⁴ exp(−1.13 eV/k_BT) cm²/s for the temperature interval 1080-1680 K. Possible indications of diffusion along step edges appear for T/T_m ∼ 0.4. The same measurements of step fluctuation amplitudes determine also the step stiffness, which by symmetry is anisotropic on Mo(0 1 1). It is shown that three independent procedures yield mutually consistent step stiffness anisotropies. These are (1) step fluctuation amplitudes; (2) step relaxation rate anisotropies; and (3) the observed anisotropies of islands in equilibrium on the Mo(0 1 1) surface. The magnitude of the step stiffness obtained from step edge relaxation is consistent with earlier measurements that determine diffusion from grain boundary grooving.     

Effect of pressure anisotropy on magnetorotational instability

It is shown that two new instabilities of hybrid type can occur in a rotating magnetized plasma with anisotropic pressure, i.e., the rotational firehose instability and the rotational mirror instability. In the case of β_∥ > β_⊥, where β_∥ and β_⊥ are the ratios of the parallel and perpendicular plasma pressure to the magnetic field pressure, the pressure anisotropy tends to suppress both new instabilities; in the case β_⊥ > β_∥, it leads to their strengthening. In the latter case, the perturbations considered can be unstable even if the Velikhov instability criterion is not satisfied. The text was submitted by the authors in English.     

Electrically stimulated motion of dislocations in a constant magnetic field

This paper reports on the results of investigations into the dislocation mobility in n-Si single crystals (N _d =5×10²⁴ m^?3) upon simultaneous exposure to electric (j=3×10⁵ A/m²) and magnetic (B≤1 T) fields. It is found that the introduction of dislocations (≈10⁹ m^?2) into dislocation-free silicon doped with phosphorus leads to the appearance of the paramagnetic component of the magnetic susceptibility. The paramagnetic component increases with an increase in the dopant concentration. Similar transformations in silicon account for the formation of magnetically sensitive impurity stoppers that respond to external magnetic perturbations. An analysis of the behavior of dislocations in electric and magnetic fields has revealed a parabolic dependence of the dislocation path length on the magnetic induction B. The effective charges and mobilities of dislocations are numerically calculated from the results obtained. A model is proposed according to which the observed increase in the dislocation mobility is associated with the decrease in the retarding power of magnetically sensitive stoppers due to a local change in the magnetic characteristics of the material and the spin-dependent reactions stimulated by a magnetic field.     

High-Resolution Study of the Atilde;A′→X?A″ Transition of DO2: Analysis of the 000-000 Band

The near-infrared emission spectrum of the Atilde;²A′→X?²A″ transition of DO₂ has been studied by Fourier-transform spectrometry. The 000→000 band has been recorded at high spectral resolution. ΔK_a=±1 subbands up to K_a′=12→K_a″=11 and K_a′=9→K_a″=10, comprising lines from rotational levels up to N′=34, have been observed. With about a factor of 5-10 lower intensity, ΔK_a=0 subbands 0-0 to 6-6 were found, which are due to magnetic dipole transitions. Several local perturbations extending over 3-10 N″ values were observed. Two prominent perturbations in the F₁ levels of the òA′, 000, K_a″=11 and 12 states are attributed to ΔK_a=0, ΔJ=0, ΔN=±1 interactions with the 211 level of the X?²A″ ground state. The rotational constants for HO₂ and DO₂ have been used to deduce the molecular geometry of HO₂ at the zero point levels of the X?²A″ and òA′ states.     

Use of ferromagnetic resonance to determine the size distribution of γ-Fe2O3 nanoparticles

Ferromagnetic resonance (FMR) experiments were performed as a function of temperature (10-300 K) on γ-Fe₂O₃ nanoparticles prepared by a sol-gel method. By measuring at several temperatures the relative intensity of the spectrum due to superparamagnetic particles and the anisotropy field of the spectrum due to ferrimagnetic particles, we determined the size distribution of γ-Fe₂O₃ nanoparticles. It was found to be a log-normal distribution with a most probable diameter D_m=8.1 nm and a standard deviation σ=0.25. Transmission electron microscopy measurements performed on the same samples yielded a log-normal distribution with D_m=11.2 nm and σ=0.23. The difference is attributed to the existence of a disordered surface layer in the particles.     

Microwave power absorbed by and scattered from a multilayered zero-index anisotropic metamaterial-semiconductor cylinder

We present here dependencies of scattered and absorbed powers of incident perpendicularly and parallel polarized microwaves by a multilayered cylinder. We consider here the normal (angle ??=90^°) and oblique (angles ??=60^°,30^°,5^°) incidence of microwave on the cylinder. The one consists of a glass core that is coated by the six anisotropic metamaterial and lossy n-Si semiconductor alternative layers. Characteristics of a cylinder with the semiconductor external layer are presented. The dispersion dependency of n-Si losses was taken into account. The metamaterial is a uniaxial anisotropic medium with the electric and magnetic plasma resonances in the frequency range from 1 until 4?GHz. The anisotropic metamaterial can include the constitutive parameters equal to zero. The multilayered cylinder has the external radius equal to 2?mm. The glass core has a radius equal to 0.5?mm. The thickness of all layers is the same. We have compared the scattered and absorbed power dependencies on the microwave polarization, the angle of microwave incidence (the normal and oblique directions of the incidence to the z-axis), and the n-Si specific resistivity. We discovered specific dependencies of scattered and absorbed powers on the parameters.     

Ferroelastic phase transition and anomalous elastic and thermal properties of betaine borate (CH3)3NCH2COO·H3BO3

The temperature and pressure derivatives of the elastic constants of orthorhombic betaine borate, (CH₃)₃NCH₂COO·H₃BO₃, have been determined by measuring temperature and stress induced shifts of resonance frequencies of thick plates at ca. 15 MHz in the range between 140 and 300 K and 0 and 3 kbar. The elastic ‘shear’ resistance c₄₄ exhibits a value as low as 0.0492×10¹⁰Nm^-2at 293 K. With decreasing temperature c₄₄ approaches zero at ca. 142.5 K, indicating an acoustic soft mode behaviour connected with a ferroelastic phase transition. The softening of c₄₄ is described in a good approximation by c₄₄(T)_p=0 =alogT/T₀ with a=0.0663×10¹⁰Nm^-2 and T₀ = 139.5 K. Further, c₄₄ decreases with increasing pressure according to the linear relation c₄₄(p)_{T=293 K} = 0.0492?0.184×10^-4p (p in bar, c₄₄ in 10¹⁰ Nm^-2). All other elastic constants show a quite normal temperature and pressure dependence. At 293 K the transition is induced by a pressure of 2.65 kbar. The transition temperature T_c depends linearly on pressure according to T_c = 142.5+0.0568 p (pinbar, T_cinK). Passing through the transition no discontinuous change of the lattice constants is observed. The three principal coefficients of thermal expansion and the pressure derivatives of the dielectric constants exhibit discontinuities at the transition. The transition is of strongly second order.     

Acoustic waves emitted by a vortex ring passing near a circular cylinder

Acoustic waves emitted by a vortex ring moving near a circular cylinder have been studied experimentally and theoretically. The vortex rings used in the experiments had a translational speed ν₀ in the range 26 ⪅ ν₀ ⪅ 58 m/s and a radius of about 4·7 mm comparable in size with the cylinder radius. The acoustic pressure signals were detected by four microphones in the far field, and analyzed by digital methods. The observed pressure p obeys the scaling law p ∞ ν₀³L⁻⁴, where L is the impact distance of the vortex path to the cylinder. The observed sound wave is of dipole radiation type, and the direction of the dipole axis rotates as the vortex position changes relative to the cylinder. The direction of the dipole axis is related to that of the normal to the plane of the vortex ring. The instantaneous resultant force exerted on the cylinder by the vortex motion has also been examined, and the magnitude and the direction determined experimentally as a function of time. The theory of vortex sound predicts that the wave profile is proportional to the second time derivative of the volume flux (of a hypothetical potential flow around the cylinder) through the vortex ring. The observed scaling law and dipole directivity of the pressure are in good agreement with the theoretical predictions. The pressure profiles are calculated by using the observed vortex motion. These profiles also agree well with the observed ones, confirming the validity of the theory.     

Synthesis and characterization of silicon carbonitride films by plasma enhanced chemical vapor deposition (PECVD) using bis(dimethylamino)dimethylsilane (BDMADMS), as membrane for a small molecule gas separation

Silicon carbonitride thin films have been deposited by plasma enhanced chemical vapor deposition (PECVD) from bis(dimethylamino)dimethylsilane (BDMADMS) as a function of X = (BDMADMS/(BDMADMS + NH₃)) between 0.1 and 1, and plasma power P (W) between 100 and 400 W. The microstructure of obtained materials has been studied by SEM, FTIR, EDS, ellipsometrie, and contact angle of water measurements. The structure of the materials is strongly depended on plasma parameters; we can pass from a material rich in carbon to a material rich in nitrogen. Single gas permeation tests have been carried out and we have obtained a helium permeance of about 10⁻⁷ mol m⁻² s⁻¹ Pa⁻¹ and ideal selectivity of helium over nitrogen of about 20.     

Measurement of the quadratic Zeeman shift of Rb hyperfine sublevels using stimulated Raman transitions

We demonstrate a technique for directly measuring the quadratic Zeeman shift using stimulated Raman transitions. The quadratic Zeeman shift has been measured yielding Δν=1296.8±3.3 Hz/G² for magnetically insensitive sublevels (5S_1/2,F=2,m_F=0→5S_1/2,F=3,m_F=0) of ⁸⁵Rb by compensating the magnetic field and cancelling the ac Stark shift. We also measured the cancellation ratio of the differential ac Stark shift due to the imbalanced Raman beams by using two pairs of Raman beams (σ⁺, σ⁺) and it is 1:3.67 when the one-photon detuning is 1.5 GHz in the experiment.     

Instabilities of electron-hole plasma under impact ionization and microwave emission

The nonlinear stage of the evolution of electron—hole plasma instabilities in semiconductors under impact ionization (static differential conductivity σ_d > 0) is considered for the case of spatially uniform pertubations of density and electric field. If the differential mobility of carriers μ _d > 0, the instability arises only with allowance for the retardation of the process of impact ionization (linear theory of this effect was developed by M. Toda [4]). When μ _d < 0, the instability may appear in the absence of the retardation. Both these instabilities exhibit oscillating form and are due to h.f. negative dynamic differential conductivity. We determine time sweeps of the electric field under condition of fixed current for the case n-InSb at T = 77 K. The amplitude and the frequency (f>10¹⁰Hz) of the oscillations are evaluated and the conditions, when the shape of E(t)-oscillations is essentially non-harmonic, are determined. Microwave emission observed in semiconductors under impact ionization may have resulted from the instabilities at hand.     

Steady state and transient self-interaction of a laser beam in a strongly ionized moving plasma

The steady state and transient self-interaction of a laser beam with a strongly ionized plasma flowing transverse to the direction of propagation have been investigated by a phenomenological approach using perturbation theory, WKB and paraxial ray approximations. The effect of the transverse motion of the plasma has been included by a convection term in the energy balance equation and is found to result in the non-symmetrical heating of electrons. As a result the beam is shifted towards the direction of transverse flow of the plasma by an amount that increases with the flow velocity. The extent of asymmetry in self-focusing along the transverse directions is, however very small. In a typical case of 7.6×10⁵ watt laser of ω=10⁴ GHz and initial beam widthr ₀=0.05 cm the transverse shiftx _p=0.1r ₀ is predicted in a distance of propagationz=0.34 cm in a strongly ionized plasma of electron densityN _e=10¹⁶ cm^?3 and transverse flow velocityW ₀=10⁷ cm/sec.     

Die Energieaufnahme der Ionen in einem sehr schnellen Theta-Pinch

In a theta pinch with an extremely fast rising magnetic field (dB/dt 10¹¹ G/sec), a strong compression wave is produced in an initially fieldless low-density deuterium plasma. Assuming simple plasma models, a high-energy gain of the ions is expected already during the implosion of the plasma. In agreement with these calculations for a filling pressure of 20 μ D₂, a mean ion energy of 1–2 keV is determined from the first neutron emission at the end of the implosion, only 150 nsec after ignition. Decreasing the initial pressure to 10 μ D₂ does not cause any further increase of the achieved ion energy. This limitation of the ion heating is explained by a strong broadening of the current carrying layer at low densities which is observed by magnetic probe measurements. In the adiabatic compression, the mean ion energy attains values of several keV. During the first part of this phase, the energy distribution function of the ions is found to be essentially anisotropic, and monoenergetic rather than Maxwellian.     

Structure and high pressure behaviour of organic crystals based on aromatically substituted 1,3,4-oxadiazoles

The crystalline structure of a new compound containing the 1,3,4-oxadiazole moiety, 4-(5-methyl-1,3,4-oxadiazole-2yl-)-N,N′-dimethyl-phenylamine (MODPA) was determined. It shows a monoclinic structure with space group P2₁/c and lattice parameters: a=1.02997(6), b=0.64840(4), c=1.58117(10) nm and β=99.4820(10)°. To study the intermolecular interactions in oxadiazole containing organic crystals, X-ray studies on MODPA and 2,5-diphenyl-1,3,4-oxadiazole (DPO) were performed up to 5 GPa at room temperature. The Murnaghan equation of state is used to describe the compression behaviour of both substances. From these results, the bulk modulus and its pressure derivative were determined. The values obtained are: K₀=6.3 GPa and K′₀=6.8 for MODPA and K₀=7.3 GPa and K′₀=6.7 for DPO. Additionally, measurements under increasing temperature at ambient pressure were carried out to evaluate the thermal expansion coefficient: α=1.8×10⁻⁴ K⁻¹ for MODPA and α=1.9×10⁻⁴ K⁻¹ for DPO.     

Cooperative phenomena of random electric dipoles in an amorphous matrix

A ferroelectric phase transition has been observed for the first time in a series of glasses containing WO₆-octahedra. The techniques of thermally stimulated depolarization currents were used to observe the transition from independent dipole behavior to cooperative behavior in this amorphous system as a function of concentration. These measurements yielded the activation energy ΔE=1.2eV, the pre-exponential τ₀=2 × 10^-22sec, and the dipole moment p?=1.3 × 10^?15 esu cm for WO₃ in Li₂B₄O₇. A dipole moment bearing species due to Li₂B₄O₇ was observed with ΔE=0.44eV and pre-exponential τ₀=5 × 10^?8 sec. The depolarization peaks of WO₃ occur in the temperature range 265–275 K depending upon WO₃ concentration and are pressure dependent with an initial slope of 2 × 10^?5K dyne^?1 cm². A model was developed for a possible phase transition associated with a random “pseudo-spin” system in an amorphous matrix.     

Air-broadening coefficients of the HO2 radical in the 2ν1 band measured using cw-CRDS

In this paper we present measurements of the air-broadening coefficients of HO₂ at room temperature in the 2ν₁ band around 1.5 microns. The HO₂ radicals were created by flash photolysis of SOCl₂ in a flow of O₂/CH₃OH mixtures. To observe air-broadening, N₂ (79%) and O₂ (21%) were added using calibrated flow controllers and a total pressure controller. The total pressure was monitored in parallel using a capacitive pressure gauge. Air-broadening coefficients at 296 K were determined for 34 absorption lines between 6631 and 6671 cm⁻¹. The air-broadening coefficients of HO₂ show a rotational dependence (decreasing from about 0.14 cm⁻¹/atm for N″ = 3 to about 0.09 cm⁻¹/atm for N″ = 10). No evidence for collisional narrowing was observed.     

Effects of thermal light source properties in two-photon subwavelength coincidence interference experiments

We perform two-photon coincidence subwavelength interference experiments from double slit using independent photons obtained from a pseudo-thermal light source produced by (i) slowly rotating ground glass (RGG) with turbid solution of a different density and (ii) RGG. The turbid solution is water solution containing 3 μm diameter polystyrene microspheres. It is found that the visibility of the obtained interference pattern decreases in first experiment with increasing the density of the turbid solution from N = 10¹⁰ spheres m⁻³ to N = 10¹⁴ spheres m⁻³. However, the results are reported here for the density of N = 10¹⁴ spheres m⁻³. The visibility obtained with RGG with turbid solution having N = 10¹⁴ spheres m⁻³is 23% which increases to 27% with RGG but the resolution decreases. The effect of coherence width of source in two-photon interference pattern is also studied with pseudo-thermal light obtained by RGG. It was observed that on increasing the coherence width the visibility of interference fringes increased and quality of the fringe reduced and when the coherence width was more then slit separation, in coincidence measurements, no interference pattern appeared. The results are used to explore the classical subwavelength interference nature with thermal light.     

Microwave cyclotron resonance of hot electrons in p-type GaSb

A microwave photocreated cyclotron resonance signal is observed in p-type GaSb in the temperature range 1–30 K. Circular polarization and other measurements identify the carriers as electrons in the (000) conduction band. The problem of a surface effect on the measured peak position, reported for the first time is avoided by bulk carrier creation. An exponential loss of signal intensity at 27 K is explained by the theory of background plasma effects. The measured ωτ of 1·5–4 yields an electron collision time of τ ～ 10^?11 sec. The scattering mechanism at liquid helium temperatures is identified as being partly due to neutral defect acceptor scattering of hot electrons, with an unidentified residual scattering process. The electron polaron effective mass is measured to be (m *(polaron)/m₀) = 0·0412 ± 0·0012 for hot electrons with an average energy of ～ 14 MeV and is isotropic within 1 per cent. When corrections for conduction-band non-parabolicity and hot polaron effects are applied, the band-edge free electron mass is calculated to be (m₀*(free)/m₀) = 0·0396 ± 0·0021 (±5·2 per cent).     

Dynamic stabilization of the helicalm=1 instability in a linear screw pinch

Dynamic stabilization of the helicalm=1 instability was studied in the linear high-β screw pinch ISAR III (T _i ≈50 to 500eV;n _e ≈5·10¹⁶ cm^?3; β≧0.5). The experimentally determined growth rates ω _i (0.5 to 3·10⁶ s^?1) and wavelengths (100 to 200 cm) of these modes are about the same as in a toroidal screw pinch and both agree well with theory. Two methods of dynamic stabilization were investigated. In both cases the stabilizing effects were better than expected from existing theory. In the first method an axially uniform oscillating field \(\tilde B_{zo} \) ·sin (ω _s t) was superposed on the quasi-steadyB _zo field (ω _s >ω _i ). Them=1 mode is stabilized and a stabilization condition \(\tilde B_{zo} /B_{zo} \gtrsim 2\omega _i /\omega _s \) holds. This stabilizing effect is very likely caused by inertial forces produced by enforcedm=0,k=0 oscillations of the plasma column. When working in resonance with the natural plasma oscillations, it is easier to satisfy the above condition. In the second method oscillating currents \(\tilde I_{zo} \) · sin (ω _s t) were added to the axial plasma currentI _zo to study the stabilization by dynamic shear (ω _s >ω _i ). Magnetic probe measurements showed that the \(\tilde I_z \) flows in the dilute plasma outside the dense plasma column. The measured skin depths and resistivities are larger than those expected from classical theory. Nevertheless, a reduction of the growth of them=1 mode occurred which was larger the more closely \(\tilde I_z \) flowed alongside the plasma column, giving a stabilization condition \(\tilde I_{zo} /I_{zo} > \omega _s /(5\omega _i )\) .     

Dynamics of CO2 molecules confined in the micropores of solids as studied by C NMR

The pressure and temperature dependence of ¹³C NMR of CO₂ adsorbed in several porous materials was measured. For CO₂ in activated carbon fiber (ACF), the spectrum observed in the pressure range from 0 to 10 MPa consisted of two lines. A very sharp peak at δ = 126 ppm was attributed to free CO₂ gas and a broad peak at δ = 123 ppm was attributed to confined CO₂ molecules in the micropores of ACF, although CO₂ in microporous materials such as zeolites and mesoporous silica, gave only a single peak attributed to free CO₂ gas. In the low-pressure region, the peak at δ = 123 ppm shifted to 118 ppm and a very broad peak with a line width of about 200 ppm appeared. This indicates that there are two kinds of CO₂ molecules confined in ACF with different rates of molecular motion: one is undergoing isotropic rotation and the other is undergoing anisotropic motion, which rotates around an axis tilted by 30° from the molecular axis. This implies that small pockets with a characteristic diameter exist on the surface of the ACF micropore.