Extremal properties of distribution function and statistical operator in equilibrium and nonequilibrium thermodynamics

It is shown that the distribution function and the statistical operator, in the case that the considered system is close to the equilibrium state, can be received by the method relying upon minimizing the information gain, which is connected with the transition of the system from a nonequilibrium state to the equilibrium state. For the systems far from equilibrium the nonequilibrium distribution function or the nonequilibrium statistical operator can be derived using a variational principle based on Jaynes' maximum entropy formalism including memory effects.     

On a Liouville-master equation formulation of open quantum systems

The dynamics of open quantum systems is formulated in terms of a probability distribution on the underlying Hilbert space. Defining the time-evolution of this probability distribution by means of a Liouvillemaster equation the time-dependent wave function of the system becomes a stochastic Markov process in the sense of classical probability theory. It is shown that the equation of motion for the two-point correlation function of the random wave function yields the quantum master equation for the statistical operator. Stochastic simulations of the Liouville-master equation are performed for a simple example from quantum optics and are shown to be in perfect agreement with the analytical solution of the corresponding equation for the statistical operator.     

The quantumstatistical aspects of the independent-particle model for the nucleus

We present a new justification of the independent particle model for the nucleus. It is based on a statistical theory of the short-range correlations in large Fermion systems. The statistical operator of many-body Fermion systems — if averaged over a suitable ensemble — can be written as a product of statistical operators for a one-body system. The statistical operator for the one-body system obeys a Hartree-Fock equation. Physical interpretation and conclusions are discussed.     

用动力学方法研究原子分子碰撞过程中的统计平均问题

动力学李代数方法在研究原子分子碰撞问题中是一种很重要的方法.在计算过程中我们用密度算子导出了物理量的统计平均值.同时我们用时间演化算子计算了振转能量的跃迁几率.作为例子我们用此方法计算了H2和He的碰撞问题.     

Generating Functionals in Nonequilibrium Statistical Mechanics

The main ideas and methods of calculations within the framework of the generating functional technique are considered in a systematical way. The nonequilibrium generating functionals are defined as functional mappings of the nonequilibrium statistical operator and so appear to be dependent on a certain set of macroscopic variables describing the nonequilibrium state of the system. The boundary conditions and the differential equation of motion for the generating functionals are considered which result in an explicit expression for the nonequilibrium generating functionals in terms of the so-called coarse-grained generating functional being the functional mapping of the quasiequilibrium statistical operator. Various types of integral equations are derived for the generating functionals which are convenient to develop the perturbation theories with respect to either small interaction or small density of particles. The master equation for the coarse-grained generating functionals is obtained and its connection with the generalized kinetic equations for a set of macrovariables is shown. The derivation of the generalized kinetic equations for some physical systems (classical and quantum systems of interacting particles, the Kondo system) is treated in detail, with due regard for the polarization effects as well as the energy and momentum exchange between the colliding particles and the surrounding media.     

Theory of irreversible processes in nonequilibrium quantum systems. I. General formalism

The theory of Van Hove for nonequilibrium quantum statistical mechanics is extensively reformulated in terms of a superspace (a kind of operator space). This reformulation enables us to introduce a diagrammatic method which makes it convenient to deal with practical problems in physical systems. In our formalism, quantum statistical effects are considered on the basis of a systematic rule for the contraction technique. A complicated statistical effect in boson or fermion systems can be treated by starting with a simple unsymmetrized formalism in the Boltzmann statistics.