共查询到20条相似文献,搜索用时 46 毫秒
1.
M. Bryushinin V. Golubev Y. Kumzerov D. Kurdyukov I. Sokolov 《Applied physics. B, Lasers and optics》2009,95(3):489-495
We report an experimental investigation of the non-steady-state photoelectromotive force in nanostructured GaN within porous
glass and polypyrrole within chrysotile asbestos. The samples are illuminated by an oscillating interference pattern created
by two coherent light beams and the alternating current is detected as a response of the material. Dependences of the signal
amplitude versus temporal and spatial frequencies, light intensity, and temperature are studied for two wavelengths λ=442 and 532 nm. The conductivity of the GaN composite is measured: σ=(1.1–1.6)×10−10 Ω−1 cm−1 (λ=442 nm, I
0=0.045–0.19 W/cm2, T=293 K) and σ=(3.5–4.6)×10−10 Ω−1 cm−1 (λ=532 nm, I
0=2.3 W/cm2, T=249–388 K). The diffusion length of photocarriers in polypyrrole nanowires is also estimated: L
D=0.18 μm. 相似文献
2.
A. V. Besnosov S. Yu. Savinov O. O. Novozhilova M. A. Antonenkov 《Physics of Atomic Nuclei》2011,74(14):1930-1936
Presented are the results of experimental research of temperature and velocity fields for lead and lead-bismuth coolant flows
in channels having circular and annular cross sections under varying oxygen content in the coolant and varying characteristics
of insulating coatings. Tests are performed under the following operating conditions: (1) lead-bismuth eutectic—temperature
T = 400−520°C, thermodynamic oxygen activity a = 10−5–100, average flow velocity of the coolant w = 0.12−1.84 m/s, value of magnetic induction B = 0−0.85 T, Reynolds number Re = (0.24–3.5) × 105, Hartmann number Ha = 0−500, and Peclet number Pe = 320−4600; (2) lead coolant-T = 400−550°C, a = 10−5−100, w = 0.1−1.5 m/s, Re = (2.36−2.99) × 105, and Pe = 500−7000. 相似文献
3.
Conductivity studies of plasticized anhydrous PEO-KOH alkaline solid polymer electrolyte 总被引:1,自引:0,他引:1
Polyethylene oxide (PEO)–potassium hydroxide (KOH)-based alkaline solid polymer electrolyte films have been prepared by using
methanol as solvent. The highest room temperature ionic conductivity of (2.1 ± 0.5) × 10−8 S cm−1 was achieved for the composition of 70 wt% PEO:30 wt% KOH. The addition of plasticizer, ethylene carbonate, propylene carbonate,
or polyethylene glycol to the highest conductivity of PEO–KOH system helps to increase the ambient ionic conductivity to the
order of 10−6–10−4 S cm−1. The log σ vs 1/T plot of PEO–KOH showed a small conductivity decrease at 50–60 °C range. The small decrease and the hysteresis that occur
during the heating–cooling cycle was overcome by the presence of the plasticizer. X-ray diffraction observation supports the
conductivity results. 相似文献
4.
A. N. Vystavkin D. V. Shuvaev L. S. Kuz’min M. A. Tarasov E. Aderstedt M. Willander T. Claeson 《Journal of Experimental and Theoretical Physics》1999,88(3):598-602
This paper describes the design and experimental testing of a high-sensitivity hot-electron bolometer based a film of normal
metal, exploiting the Andreev reflection from superconductor boundaries, and cooled with the help of a superconductor-insulator-normal
metal junction. At the measured thermal conductivity, G≈6×10−12 W/K, and a time constant of τ=0.2 μs, and a temperature of 300 mK, the estimated noise-equivalent power NEP=5×10−18 W/Hz1/2, assuming that temperature fluctuations are the major source of noise. At a temperature of 100 mK, the thermal conductivity
drops to G≈7×10−14 W/K, which yields NEP=2×10−19 W/Hz1/2 at a time constant of τ=5 μs. The microbolometer has been designed to serve as a detector of millimeter and FIR waves in space-based radio telescopes.
Zh. éksp. Teor. Fiz. 115, 1085–1092 (March 1999) 相似文献
5.
V. I. Tsebro O. E. Omel’yanovskii E. F. Kukovitskii N. A. Sainov N. A. Kiselev D. N. Zakharov 《Journal of Experimental and Theoretical Physics》1998,86(6):1216-1219
Bulk samples of carbon multilayer nanotubes with the structure of nested cones (fishbone structure) suitable for transport
measurements, were prepared by compressing under high pressure (∼25 kbar) a nanotube precursor synthesized through thermal
decomposition of polyethylene catalyzed by nickel. The structure of the initial nanotube material was studied using high-resolution
transmission electron microscopy. In the low-temperature range (4.2–100 K) the electric resistance of the samples changes
according to the law ln R ∝ (T
0/T)1/3, where T
0∼7 K. The measured magnetoresistance is quadratic in the magnetic field and linear in the reciprocal temperature. The measurements
have been interpreted in terms of two-dimensional variable-range hopping conductivity. It is suggested that the space between
the inside and outside walls of nanotubes acts as a two-dimensional conducting medium. Estimates suggest a high value of the
density of electron states at the Fermi level of about 5×1021 eV−1 cm−3.
Zh. éksp. Teor. Fiz. 113, 2221–2228 (June 1998) 相似文献
6.
The ionic conductivity of PVC–ENR–LiClO4 (PVC, polyvinyl chloride; ENR, epoxidized natural rubber) as a function of LiClO4 concentration, ENR concentration, temperature, and radiation dose of electron beam cross-linking has been studied. The electrolyte
samples were prepared by solution casting technique. Their ionic conductivities were measured using the impedance spectroscopy
technique. It was observed that the relationship between the concentration of salt, as well as temperature, and conductivity
were linear. The electrolyte conductivity increases with ENR concentration. This relationship was discussed using the number
of charge carrier theory. The conductivity–temperature behaviour of the electrolyte is Arrhenian. The conductivity also varies
with the radiation dose of the electron beam cross-linking. The highest room temperature conductivity of the electrolyte of
8.5 × 10−7 S/cm was obtained at 30% by weight of LiClO4. The activation energy, E
a and pre-exponential factor, σ
o, are 1.4 × 10−2 eV and 1.5 × 10−11 S/cm, respectively. 相似文献
7.
The temperature dependence of the electrical conductivity, thermoelectric power and dielectric constant of the antiferromagnetic
CuWO4 have been studied in the temperature range 300–1000 K. The conductivity results can be summarised by the equations σI=6.31 × 10−3 exp (−0.29 eV/kT) ohm−1 cm−1 in the temperature range 300–600 K and σII=3.16 × 105 exp (−1.48 eV/kT) ohm−1 cm−1 between 600 K and 1000 K. The thermoelectric power can be expressed byθ=[− 1.25 (103/T) + 3.9] mV/K. Initially dielectric constant increases slowly but for high temperatures its increase is fast. 相似文献
8.
M. Prabu S. Selvasekarapandian A. R. Kulkarni G. Hirankumar A. Sakunthala 《Ionics》2010,16(4):317-321
Lithium samarium oxide has been prepared by solid-state reaction method and characterized by X-ray diffraction (XRD) and impedance
spectroscopy. XRD pattern of the sample reveals the formation of the sample. The conductivity studies, dielectric studies,
and modulus analysis of the samples have been carried out for different temperatures. The bulk conductivity of the sample
has been found to be 1.21 × 10−5 Scm−1 at 420 °C. The temperature variation of the direct current conductivity obeys the Arrhenius relation. The modulus analysis
of the sample indicates the non-Debye nature of the sample which corresponds to long-time slow polarization and relaxation of hopping charges. 相似文献
9.
M.?Cristina?Gon?alves Verónica?de?Zea Bermudez M.?M.?Silva M.?J.?Smith Enrique?Morales Rute?A.?Sá Ferreira Luís?D.?Carlos 《Ionics》2010,16(3):193-201
Variable chain length di-urethane cross-linked poly(oxyethylene) (POE)/siloxane hybrid networks were prepared by application
of a sol-gel strategy. These materials, designated as di-urethanesils (represented as d-Ut(Y′), where Y′ indicates the average
molecular weight of the polymer segment), were doped with lithium triflate (LiCF3SO3). The two host hybrid matrices used, d-Ut(300) and d-Ut(600), incorporate POE chains with approximately 6 and 13 (OCH2CH2) repeat units, respectively. All the samples studied, with compositions ∞ > n ≥ 1 (where n is the molar ratio of (OCH2CH2) repeat units per Li+), are entirely amorphous. The di-urethanesils are thermally stable up to at least 200 °C. At room temperature the conductivity
maxima of the d-Ut(300)- and d-Ut(600)-based di-urethanesil families are located at n = 1 (approximately 2.0 × 10−6 and 7.4 × 10−5 Scm−1, respectively). At about 100 °C, both these samples also exhibit the highest conductivity of the two electrolyte systems
(approximately 1.6 × 10−4 and 1.0 × 10−3 Scm−1, respectively). The d-Ut(600)-based xerogel with n = 1 displays excellent redox stability. 相似文献
10.
N. I. Sorokin M. V. Fominykh E. A. Krivandina Z. I. Zhmurova B. P. Sobolev O. I. Lyamina 《Physics of the Solid State》1998,40(4):604-607
The fluoride-ion conductivity of the nonstoichiometric tysonite phases La0.95(Ba1−x
Srx)0.05Fe2.95 (0⩽x⩽1) is investigated by impedance spectroscopy. Electrophysical measurements are performed in the frequency range 5–5×105 Hz and temperature range 300–700 K. A discontinuity is observed in the temperature dependence of the conductivity at T
c=410–430 K. The behavior of the temperature dependence of the electrical conductivity is explained within a transport model
taking into account the migration of fluoride ions between different inequivalent structural sites. The maximum value of the
conductivity at room temperature (293 K) is 2×10−4 Ω−1 cm−1 for the solid solution La0.95Sr0.05F2.95. The fluorine-ion conductivity in La0.95(Ba1−x
Srx)0.05F2.95 single crystals is almost an order of magnitude larger than the value for the commercial solid electrolyte La0.992Eu0.008F2.992 (a fluorine-selective membrane) having a tysonite structure.
Fiz. Tverd. Tela (St. Petersburg) 40, 658–661 (April 1998) 相似文献
11.
A. V. Anan’ev Yu. I. Zhdanov A. P. Gerashchenko K. N. Mikhalev S. V. Verkhovskii E. Yu. Medvedev K. A. Okulova N. I. Chebotaev V. N. Goshchitskii 《JETP Letters》1998,67(3):182-188
The spin-spin relaxation rate 63
T
2
−1
of 63Cu nuclei in CuO2 layers is measured in the normal and superconducting states of the compound YBa2Cu3O6.9 (T
c
onset
=94 K) subjected to radiation-induced disordering by a fast-neutron flux Φ to T
c
onset
=68 K (Φ=7×1018 cm−2) and T
c
onset
<4 K (Φ=12×1018 cm−2). It is found that as the structural disorder increases, the contribution of the indirect spin-spin interaction 63
T
2G
−1
, which is related to the value of the spin susceptibility at the boundary of the Brillouin zone of the copper planes χs(q={π/a; π/a}), decreases slightly at the transition to the superconducting state for the initial sample and remains unchanged for the
weakly disordered sample. This behavior of the short-wavelength contribution to the spin susceptibility attests to the stability
of the x
2−y
2 symmetry of the energy gap against structural disorder, in accordance with proposed theoretical models of Cooper pairing
for high-T
c cuprates.
Pis’ma Zh. éksp. Teor. Fiz. 67, No. 3, 172–177 (10 February 1998) 相似文献
12.
A. A. Samokhvalov T. I. Arbuzova N. A. Viglin V. V. Osipov N. I. Solin S. V. Naumov V. G. Bamburov N. I. Lobachevskaya O. G. Reznitskikh 《Physics of the Solid State》1999,41(2):262-264
Mg1−x
CuxO solid solutions having an NaCl structure with 0⩽x⩽0.20 are synthesized and Cu-Mg1−x
CuxO structures are prepared for superconductivity studies. The magnetic susceptibility χ, electron paramagnetic resonance (EPR), and electrical conductivity of the solid solutions are studied at temperatures of
5–550 K. It is shown that χ
−1(T) obeys the Curie-Weiss law with a paramagnetic Curie temperature Θ close to zero and an effective magnetic moment μ
eff=1.9 μ
B, close to the 1.73 μ
B of a Cu2+ ion with spin S=1/2. The width ΔH of the EPR line depends weakly on temperature and increases as x is raised. The volume narrowing of the EPR linewidth ΔH is used to estimate the exchange interaction parameter, 3×10−4 eV. The g-factor is close to 2 and is temperature independent. The electrical conductivity of Mg1−x
CuxO at T=300 K is ≈10−11–10−12 Ω−1 cm−1 for x=0 and increases to 10−5–10−6 Ω−1 cm−1 for x=0.15–0.20. The conductivity is p-type. Magnetic shielding is observed in Cu-Mg1−x
CuxO structures with x=0.15 and 0.20. The possible connection of this phenomenon with interference superconductivity in the contact layer of the
structure is discussed.
Fiz. Tverd. Tela (St. Petersburg) 41, 293–296 (February 1999) 相似文献
13.
The temperature variation of the lattice parameter of CsPbCl3 in the cubic phase has been studied by x-ray method, from a determination of the precision lattice parameter at various temperatures,
ranging from 50°C to 400°C. The coefficient of thermal expansion of CsPbCl3 can be expressed by the quadratic equation,α
T
= 21.6 × 10−6 + 2.44 × 10−9
T + 5.90 × 10−11
T
2. 相似文献
14.
V. K. Voronkova Yu. V. Yablokov J. Legendziewicz M. Bozechowska 《Physics of the Solid State》1999,41(12):1976-1979
The new heteronuclear crystal CuPr2(CCl3COO)8·6H2O, constructed of chains containing copper and praseodymium atoms, has been synthesized and investigated by EPR at 9.3 GHz
at temperatures ranging from room temperature down to 10 K. At temperatures T∼300–130 K, EPR spectra are observed which are characteristic of isolated polyhedra of copper ions with g
z=2.330±0.005, g
x,y
=2.053±0.005, A
z=139×10−4 cm−1, and A
x,y
<26×10−4 cm−1. At temperatures T<130 K a complex spectrum is observed, associated with the appearance of weak exchange interactions between the copper ions
in the chain (J
Cu-CuΣS
i·S
i+1), comparable in magnitude with the hyperfine interactions J
Cu-Cu=0.015 cm−1 at T=10 K. The magnitude of the exchange interaction decreases smoothly as the temperature is raised. It is conjectured that orbitals
of the praseodymium ions participate in the process of indirect exchange between the copper ions.
Fiz. Tverd. Tela (St. Petersburg) 41, 2154–2157 (December 1999) 相似文献
15.
Pt electrodes with defined contact geometries were studied by using impedance spectroscopy. The specific polarisation conductivity
per unit length of the three-phase boundary was determined. It is found to be 1 × 10−4 S·cm−1 at 977 °C in an atmosphere of “pure” hydrogen with an oxygen partial pressure of 10−20 atm at 1000 °C. Investigations carried out in an atmosphere of pure oxygen revealed a pronounced dependence of the polarisation
conductivity on the electrode history. The polarisation conductivity was found to be in a range of 2 × 10−4 to 6.5 × 10−4 S·cm−1 at a temperature of 977 °C. It was possible to estimate the area of the electrolyte surface which takes part in the electrode
reaction. The real exchange current density was determined. 相似文献
16.
S. Vatnik M. C. Pujol J. J. Carvajal X. Mateos M. Aguiló F. Díaz V. Petrov 《Applied physics. B, Lasers and optics》2009,95(4):653-656
The three thermo-optic coefficients of the biaxial laser host KLu(WO4)2 are measured at 633 nm by a deflection method. Their values at 300 K amount to ∂
n
g
/∂
T=−7.4×10−6 K−1; ∂
n
m
/∂
T=−1.6×10−6 K−1 and ∂
n
p
/∂
T=−10.8×10−6 K−1. Nearly athermal propagation directions are found for polarizations along the N
m
and N
p
dielectric axes. 相似文献
17.
A. A. Petukhov B. E. Zhurtanov S. S. Molchanov N. D. Stoyanov Yu. P. Yakovlev 《Technical Physics》2011,56(4):520-525
The electroluminescent characteristics of an InGaAsSb/GaAlAsSb heterostructure LED emitting at 1.85 μm are studied in the
temperature range 20–200°C. It is shown that the emission power exponentially drops as P ≅ 0.4exp(2.05 × 103/T) with a rise in temperature primarily because of an increase in the Auger recombination rate. It is found that band-to-band
radiative recombination goes in parallel with recombination through acceptor levels, the latter causing the emission spectrum
to broaden. With a rise in temperature, the activation energy of the acceptor levels decreases by the law ΔE≅ 32.9 − 0.075T and the maximum of the LED’s emission spectrum shifts toward the long-wavelength range (hν
max = 0.693 − 4.497 × 10−4
T). Based on the dependence E
g
= hν
max − 0.5kT and experimental data, an expression is derived for the temperature variation of the bandgap in the In0.055Ga0.945AsSb active area, E
g
≅ 0.817 − 4.951 × 10−4
T, in the range 290 K < T < 495 K. The resistance of the heterostructure decreases exponentially with rising temperature as R
0 ≅ 5.52 × 10−2exp(0.672/2kT), while cutoff voltage U
cut characterizing the barrier height of a p−n junction decreases linearly with increasing temperature (U
cut = −1.59T + 534). It is found that the current through the heterostructure is due to the generation-recombination mechanism throughout
the temperature interval. 相似文献
18.
Tin oxide (SnO2) thin films have been grown on glass substrates using atmospheric pressure chemical vapour deposition (APCVD) method. During
the deposition, the substrate temperature was kept at 400°C–500°C. The structural properties, surface morphology and chemical
composition of the deposited film were studied by X-ray diffraction (XRD), scanning electron microscope (SEM) and Rutherford
back scattering (RBS) spectrum. XRD pattern showed that the preferred orientation was (110) having tetragonal structure. The
optical properties of the films were studied by measuring the transmittance, absorbance and reflectance spectra between λ = 254 nm to 1400 nm and the optical constants were calculated. Typical SnO2 film transmits ∼ 94% of visible light. The electrical properties of the films were studied using four-probe method and Hall-voltage
measurement experiment. The films showed room temperature conductivity in the range 1.08 × 102 to 1.69 × 102 Ω−1cm−1. 相似文献
19.
Here we report the synthesis, chemical stability, and electrical conductivity of Ti-doped perovskite-type BaCe0.8-x
Ti
x
Y0.2O3-δ
(x = 0.05, 0.1, 0.2, and 0.3; BCTY). Samples were synthesized by conventional solid state (ceramic) reaction from corresponding
metal salts and oxides at elevated temperature of 1,300–1,500 °C in air. The powder X-ray diffraction confirmed the formation
of a simple cubic perovskite-type structure with a lattice constant of a = 4.374(1), 4.377(1), and 4.332(1) ? for x = 0.05, 0.1, and 0.2 members of BCTY, respectively. Like BaCe0.8Y0.2O3-δ
(BCY), Ti substituted BCTY was found to be chemically not stable in 100% CO2 and form BaCO3 at elevated temperature. The bulk electrical conductivity of BCTY decreased with increasing Ti content and the x = 0.05 member exhibited the highest conductivity of 2.3 × 10−3 S cm−1 at 650 °C in air, while a slight increase in the conductivity, especially at low temperatures (below 600 °C), was observed
in humidified atmospheres. 相似文献
20.
E. A. Kataeva A. D. Bozhko S. V. Demishev 《Bulletin of the Lebedev Physics Institute》2010,37(11):347-351
The conductivity of carbon films grown by polymethylphenylsiloxane vapor decomposition in stimulated dc discharge plasma was
studied. It is found that the Mott hopping conductivity $
\sigma \left( T \right) = \sigma _0 \left( T \right)\exp \left\{ { - \frac{{T_0 }}
{T}^{{1 \mathord{\left/
{\vphantom {1 4}} \right.
\kern-\nulldelimiterspace} 4}} } \right\}
$
\sigma \left( T \right) = \sigma _0 \left( T \right)\exp \left\{ { - \frac{{T_0 }}
{T}^{{1 \mathord{\left/
{\vphantom {1 4}} \right.
\kern-\nulldelimiterspace} 4}} } \right\}
is characteristic of the samples under study in the temperature range of 80–400 K in the electric field E to 5 · 104 V/cm. An analysis of the pre-exponential factor σ
0(T) = σ
00(T
0)T
α allowed the conclusion that the hopping transport is most adequately described in the model with the exponential energy dependence
of the density of localized states for which α = −1/2 and the universal relation ln σ
00 −T
01/4 0 is valid, which is satisfied in the range where the parameter σ
00 varies by eight orders of magnitude. 相似文献