近红外吸收菁染料光氧化反应机理的研究

本文选择了三种分子结构相同而母核杂原子不同的近红外吸收菁染料,对它们的光谱性能特征及光氧化稳定性能进行了研究。结果表明,具有三种不同母核杂原子的菁染料,其光氧化稳定性顺序为:苯并 唑>苯并噻唑>苯并硒唑。通过猝灭实验给出,在三种菁染料的光氧化反应机制中,具有反应活性的单线态氧和超氧负离子同时存在,其中单线态氧是导致菁染料褪色的主要因素。     

高亮度近红外荧光染料研究进展

近红外光(650～1700nm)在生物成像中具有组织穿透深度大、受生物体自身荧光干扰小和对生物体光损伤小等优点.因此,近红外染料已成为生物成像新的研究热点.近红外荧光染料较窄的能量带隙使激发态非辐射跃迁几率增大,导致荧光强度大幅降低.同时较长的共轭疏水骨架及强大的分子电荷转移能力,使他们容易与外部分子交互,从而加剧非辐射能量损耗增加,致使荧光强度降低.为了获取高亮度近红外荧光染料,研究人员针对近红外染料做了很多改进和修饰.从荧光染料的结构-性质关系角度,综述了目前主流的高亮度近红外染料的发展情况,希望能为发展高亮度近红外荧光染料提供帮助和指导.     

四甲川苯乙烯菁染料的合成及其激光性能

合成了一系列四甲川苯乙烯菁染料。以Nd:YAG锁模激光倍频(532nm)作泵浦源,测定了染料的激光性能,包括激光调谐范围、中心激光波长、激光转换效率及稳定性。探讨了该类分子结构与其激光性能之间的关系。     

近红外菁染料敏化的准固态太阳电池的光电化学研究

一个新型的近红外五甲川菁染料敏化剂(Cy)通过3,3-二甲基-1-乙基-2-[4-(N-苯乙酰氨基]-1,3-丁二烯-1-基]-3H-苯并[e]吲哚碘盐和5-羧基-1-丁基-2,3,3-三甲基-3H-吲哚碘盐的Knoevenagel缩合反应合成, 其结构用核磁、质谱和紫外等方法进行了确定; 使用疏水性气相法纳米SiO2 R974固化1-丁基-3-丙基咪唑碘离子液体制备了一种新的准固态电解质, 将其应用于菁染料(Cy)敏化的太阳电池, 对该染料敏化的准固态太阳电池的光电化学性能进行了研究. 在AM1.5G标准光源下, 得到1.49%的光电转换效率. 此方法对拓展准固态染料敏化太阳电池的研究具有一定的意义.     

氧钒酞菁在激光光盘系统中的应用研究

氧钒酞菁在激光光盘系统中的应用研究董长征，沈永嘉，任绳武（华东理工大学精细化工研究所上海２００２３７）袁海俊（中国科学院上海光学精密机械研究所上海２０１８００）关键词：信息储存，激光光盘，功能染料，氧钒酞菁自１９７２年Ｐｈｉｌｉｐｓ公司推出激光光盘（...     

BODIPY类近红外荧光染料的研究进展

近红外BODIPY分子是一类新兴的荧光染料,因其具有优异的光物理和光化学性能而得到广泛的研究,已成为一个新兴的研究热点。本文综述了近年来BODIPY类近红外荧光分子的设计、合成及应用的最新研究进展,并展望了其未来的发展方向和应用前景。     

BODIPY类近红外荧光染料的研究进展

近红外BODIPY分子是一类新兴的荧光染料, 因其具有优异的光物理和光化学性能而得到广泛的研究, 已成为一个新兴的研究热点。本文综述了近年来BODIPY类近红外荧光分子的设计、合成及应用的最新研究进展, 并展望了其未来的发展方向和应用前景。     

生物分析中近红外荧光探针进展

本文评述了10余年来方酸菁类、花菁类、噻嗪类、E嗪类、罗丹明类、BODIPY及酞菁等近红外荧光探针的发展。按其种类分别讨论了试剂结构与性能之间的关系,并介绍了它们在生物分析中的某些应用。引用文献42篇。     

~(60)Co-γ射线原位辐射聚合法制备近红外吸收滤光片

设计并合成了2个可溶性的金属酞菁类化合物(A和B)作为近红外吸收染料。其中,染料A是铜酞菁衍生物,在N,N-二甲基甲酰胺(DMF)中的最大吸收波长为710nm,染料B是钒氧萘酞菁衍生物,在DMF中的最大吸收波长为800nm。将它们加入到丙烯酸酯单体中,采用60 Co-γ射线原位辐射聚合的方法制得了交联型聚丙烯酸酯近红外滤光片。采用紫外-可见-近红外吸收光谱仪测定聚丙烯酸酯滤光片的吸收光谱曲线,结果表明:染料A和B均能均匀地分布在丙烯酸酯聚合物中,且聚丙烯酸酯近红外滤光片在DMF、丙酮、甲苯等溶剂中几乎不溶。在聚丙烯酸酯滤光片中,染料A与B的吸收峰范围分别为620~780nm和700~870nm。制备的交联型滤光片对上述波长范围的近红外光有较好的屏蔽作用,耐溶剂性能良好。     

菁染料和份菁染料溶液的光降解机理的研究

利用UV-Vis吸收光谱仪和光化学反应器,研究了菁染料和份菁染料溶液的光降解动力学,认为染料在乙腈溶液中的光褪色反应服从假一级或零级动力学.利用GC/MS光谱仪检测了染料的光降解产物.与相应的份菁染料相比,携带正电荷的菁染料具有相对较好的光稳定性.研究结果表明,菁染料光降解反应的中间体可能是染料的半氧化态Dye⁺,并利用纳秒级闪光光解技术研究了Dye⁺的瞬态吸收光谱.     

Visible and near-infrared light activated azo dyes

The photoisomerization properties of azo derivatives have been widely used in the fields of materials and biology.One serious restriction to the development of functional azo-based materials is the necessity to trigger switching by UV light,which damage the corresponding surfaces and penetrate only partially through the matter.Therefore,developing the visible and near-infrared light activated azo switches can solve this problem.This review provides a summary of molecular design strategies for driving the isomerization of azo derivatives with visible light and near-infrared light:(1) smart design directly excited by visible light,(2) the addition of upconversion nanoparticles,(3) the employment of twophoton absorption,(4) indirect excitation in combination with metal sensitizer.     

A general approach to the design of high-performance near-infrared (NIR) D-π-A type fluorescent dyes

A four-step method is presented as a general guideline for design of high performance NIR absorbing/emitting dyes.     

Fluorescence lifetime properties of near-infrared cyanine dyes in relation to their structures

Structurally diverse near-infrared (NIR) absorbing polymethine dyes were prepared and their fluorescence lifetimes (FLT) were evaluated in relation to their structural features. Comparative FLT analysis based on the modification of methine chain length and heterocyclic system showed that indolium or benzo[e]indolium heptamethine dyes exhibited longer FLT than the benzo[c,d]indolium trimethine dye. Modification of heterocyclic system alone with an intact chain length showed that indolium-based heptamethine dyes showed approximately 30% longer FLT than the benzo[e]indolium-based dyes. In general, the FLT of polymethine dyes increased from polar to non-polar solvents. In addition, correlation study between the theoretical and the experimental FLT for indocyanine green (ICG) suggests that the lack of structural rigidity for these cyanine dyes is primarily responsible for the loss of the excited state energy via non-radiative pathway.     

Rhodamine-inspired far-red to near-infrared dyes and their application as fluorescence probes

Probes to dye for: Rhodamine-inspired Si-pyronine, Si-rhodamine, Te-rhodamine, and Changsha NIR dyes have been developed recently. These dyes show fluorescence in the far-red to near-infrared region, while retaining the advantages of the original rhodamines, such as high fluorescence quantum yield, tolerance to photobleaching, good water solubility, and exhibit great potential for biological application.     

Conformationally restricted aza-BODIPY: highly fluorescent, stable near-infrared absorbing dyes

Novel NIR fluorescent, conformational restricted aza-dipyrromethene boron difluoride (aza-BODIPY) dyes were prepared by an efficient process. Such conformational restricted aza-BODIPY dyes possess intense absorption, strong fluorescence, high chemical and photostability. Additionally, the sharp fluorescence of non-amine containing aza-BODIPY dyes is insensitive to solvent polarity.     

Synthesis and characterization of near-infrared absorbing benzannulated aza-BODIPY dyes

A series of novel aza‐diisoindolmethine dyes 9 with six different aryl and heteroaryl groups at the indole moiety have been synthesized by the addition of aryl Grignard compounds to phthalodinitrile and subsequent reaction with formamide. A plausible reaction mechanism, through a Leuckart–Wallach‐type reduction has been confirmed by means of DFT calculations of the related transition and intermediate states. The corresponding boron difluoride complexes ( 10) of 9 were prepared in a subsequent reaction step and the spectroscopic and electrochemical properties of 9 and 10 have been investigated both experimentally and theoretically. The aza‐diisoindolmethines 9 exhibit an absorption maximum in the range from 615 to 720 nm, whereas the complexes 10 show a bathochromically shifted absorption maximum between 681 and 793 nm. Measurements of 9 and 10 by cyclic voltammetry display fully reversible redox waves for the reduction and oxidation with higher potentials for 10 . From the measured redox potentials, the HOMO and LUMO energy levels were calculated for 9 and 10 . The frontier orbital energies, the energies of the absorption bands, as well as the orbitals involved in the absorption process were calculated with DFT and compared to the measured results of 9 and 10 . The absorption maximum can be related to an intense HOMO–LUMO transition and the more‐pronounced stabilization of the LUMO upon complexation is the origin of the bathochromic shift of the absorption. Additionally, single‐crystal structures for two species, 10 d and 10 f , are reported.     

Tuning the photoinduced electron transfer in near-infrared heptamethine cyanine dyes

An efficient photoinduced electron transfer (PET) system in near-infrared region was described. The PET in heptamethine cyanine dyes was tuned by changing the electron-donating ability of the substituent at the central position of the polymehine chain. 4-Aminophenylthio-substitution led to an efficient PET and the lowest fluorescence quantum yield. The acetylation, protonation or transition metal cation coordination of the amino group could recover fluorescence greatly via suppressing the PET.     

A review of chromatographic methods for determination of synthetic food dyes

The purpose of this work was to present a chromatographic methods to analyse synthetic food dyes. The following techniques has been described: thin-layer liquid chromatography (TLC), high performance thin-layer chromatography (HPTLC), traditional column chromatography, high performance liquid chromatography (HPLC), include: ion-pair chromatography (HPLC IP), reversed phase chromatography (RP HPLC) and high performance ion chromatography.