The influence of indium on the structural modification of the amorphous Ge–In–Se system

The effect of both the chemical composition and the nature of the chemical bonding of amorphous alloyed samples of Ge_xIn_ySe_100−x−y prepared under vacuum with x=20, 4y15 on the efficiency of the structural modification Δφ is analysed using a simple consideration based on the coordination number Z, and the number of topological constraints N_co. The previously obtained parameters have been used for the determination of the number of continuous deformation (i.e. zero-frequency modes f ), and for the estimation of the cohesive energies of these glasses, assuming simple additivity of bond energies. A trial has been made to correlate the results of this paper with the previously published data of glass transition temperature T_g, activation energy ₀ and the shift of the K-absorption edge (ΔE_K) of the composition of vacuum prepared Ge_xIn_ySe_100−x−y. It was found that there is a correlation between the lone-pair electrons and the stability of the vitreous state. According to the criterion of Liang, the above correlation has been interpreted in terms of Δφ.