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1.
1 INTRODUCTIONRareEarth (RE)elementsareappliedinagricultureandmedicine .Therfore,betterunderstandingofthebondingofREionsinthecomplexeswithaminoacidsisnecessary .ThecrystalstructureofREcomplexeswiththesimplestaminoacidglycinewerestudiedbefore[1- 4].Toresearch…  相似文献   

2.
1 INTRODUCTIONAmethodofspacegrouprevisionbywhichthestructurefactorsofthelower symmetrystructurearegeneratedandthestructureisthensolvedfromthesimulatedintensitydatahasbeenrecentlyreported[1].Thismethodisnowappliedtotherevi sionofthespacegroupofthemetal cl…  相似文献   

3.
1 INTRODUCTIONOneofourcurrentinterestsfocusesonthedesignandsynthesesofpolyazamacrocyclicligands,andthestabilitiesofcorrespondingmetalcomplexes.Twopolyazadiphenolmacrocycles,R(babp) 2 (dfc) 2 andR (bac) 2 (dfp) 2 ;[1 ]oneoctaaza macrocycle,BPBD ;[2 ,3]andseveralhexaazama…  相似文献   

4.
1 INTRODUCTIONAsatypeofimportanceprecursor,alotoforganolanthanidechloridecomplexeshavebeensynthesizedandstructurallycharacterized[1].Thebimetalliccomplexescontainingalkalimetal,Cp2Ln(μCl)2M(L)(Cp=η5C5H5orC5Me5;M=Li,Na;L=THF,TMEDA),isamainstructuretype.Inthecourseo…  相似文献   

5.
尹汉东  王传华  马春林  王勇 《中国化学》2002,20(12):1608-1611
IntroductionOrganotin(IV)derivativesofcarboxylicacidwereextensivelystudiedduetotheirbiologicalactivities .1 5Inrecentyearsmoreandmorereportsonthesynthesis ,anti tumouractivities ,biocidalactivities ,antibioticactivitiesandstructuralelucidationofvariousorgan…  相似文献   

6.
1 INTRODUCTIONTransitionmetalclustercomplexeshavebeenreceivingconsiderableattentioninrecent yearslargelybecauseoftheir potentialapplicationsincatalysisaswellasthenoveltyandversatilityoftheirreactionsandstructures.[1~ 4] Ourinterestinmetalclustercatalysisp…  相似文献   

7.
1 INTRODUCTIONCertaincoppercomplexeshavebeenshowntohaveunusualchemicalpropertiessuchasoxygentransfer,oxidativeadditionandhomogenouscatalytichydrogenation[1].Oxidativeadditionreactionsarekeystepsintheactivationofσbondsinagreatnumberofcatalyticprocess.Cop…  相似文献   

8.
Horseradishperoxidase(HRP)canstronglycatalyzethereactionofH2O2oxidizingophenylenediamine(OPD),thechromaticproductofwhichcanbedetectedinenzymelinkedimmunosorbentassay(ELISA)withspectrophotometry[1].Involtammetricenzymelinkedimmunoassay[2—4],OPDH2O2HRPsystemhasf…  相似文献   

9.
1 INTRODUCTIONThefirstpolyhedralruthenaboraneisstructurallytypifiedbythecompound〔(PPh3)2RuB10H8(OEt)2〕in1984〔1〕,whichisobtainedin40%yieldbythereactionoftheclosodecaboraneanionB10H102-with〔RuCl2(PPh3)3〕inethanol/chloroformsolution.Researchershavesy…  相似文献   

10.
1 INTRODUCTIONRecentyearshavewitnessedamarkedincreaseintheliteratureintheuseofsele niumandtelluriumasbridgingandstabilizingligandssincetheyexhibitunusualstruc turalandreactivitypatterns.〔1〕Ourongoingresearchprogramaimedatexploringnewconvenientsynthetic…  相似文献   

11.
Recently ,therehasbeenagrowinginterestincoor dinationpolymers1withaone (1 D) ,two (2 D)orthree dimensional (3 D)structure .Theuniquephysico chemicalpropertiesofthesepolymers ,highthermalsta bility,2 gasadsorptionanddesorption ,3 smallmoleculesocclusion ,4 ionexchange5…  相似文献   

12.
1 INTRODUCTIONMostoftheureacompoundshavetheherbicidalability[1].Inordertoinvestigatetherelationshipsbetweenthestructuresandactivities,wesynthesizedaseriesofN,N’(substitutedphenyl)ureacompoundsanddeterminedthebiologicalactivitiesinhibitingALS(AcetolactateS…  相似文献   

13.
StructureofPalisadinB,C_(15)H_(24)Br_2O¥HuangYou-Qing;HuSheng-Zhi(DepartmentofChemistry,XiamenUniversity,Xiamen,361005)ZhongYo?..  相似文献   

14.
1 INTRODUCTIONSincethiolateligandwasintroducedintomolybdenumcarbonylcompoundin1 984 [1],theinvestigationonlow valenceMo -SRcompoundshasreceivedattentionforthiskindoflow valencecompoundspossesscertainadvantageoncompoundsyn thesis,moleculestructureandphysicala…  相似文献   

15.
Synthesis,CrystalStructureandStudiesontheNoncovalentInteractionof[Zn(BpheO)2(phen)]2·2CH3OH·3H2OSHENLiang*andSHENGGuo-ding(De...  相似文献   

16.
InlightofKohnvariationtheory,Millerconstructedanewquantumreactivescatteringmethod:theSmatrixvariationmethod[1,2],whichisatypicaloneinwhichalgebraicmethodisusedtosolvedirectlytheSchrdingerequation.Becausethemethodincludesnaturallytheboundaryconditions,thew…  相似文献   

17.
路嫔  单永奎 《结构化学》1996,15(4):301-306
SynthesisandCrystalStructureofK_8H_5[La(SiW_2Mo_9O_(39))_2(H_2O)_(17)]4H_2OLuBin(DepartmentofChemistry,HarbinNormalUniversity,Har?..  相似文献   

18.
CrystalStructureof[Cu(C_(21)H_(25)N_2O_4)(H_2O)_2]·NO_3·2H_2OWuJie-Ying;XieFu-Xin;TianYu-Peng;ChenYao;NiShi-Sheng;DuShao-Wu;WuXin...  相似文献   

19.
Polyoxometalates (POMs)containingKegginmoi etieshavebeenreceivingextensiveattentioninrecentyearsowingtotheirgreatfundamentalandpracticalinter est .1Especiallytheunusualelectronicproperty (highnegativecharges) ,oneofthemostimportantpropertiesofPOMs ,haspoten…  相似文献   

20.
1 INTRODUCTION3methyl4hydroxybenzofuranisanintermediateusedforthesynthesisofnatureproducts[1].Ithasbeensynthesizedfrom1,3dihydroxybenzene[2-3].Tosynthesizeabietanequinonediterpenoidswithit[4,5],weintendedtoprotectthehydroxyattachedtoitwithMe2SO4.Finally,twocompou…  相似文献   

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