Crystal and Molecular Structure of Copper(Ⅰ) Complex 〔Cu(PPh_3)_2(NO_3)〕

1　 INTRODUCTIONCopper( ) displays a wide diversity in its structural chemistry,the copper co-ordination number ranging from two to four.Procedures to synthesize copper( )complexes are of greatinterestbecause of the diversity of products resulting from al-mostthe same methodology.Ithaslong been accepted thatcopper( ) complexesarediamagnetic and provide no optical absorption bands( no d- d transition isencountered) for a copper( ) ion with a d10 configuration and no electron spin reso-n…     

Synthesis and Crystal Structure of 〔EDA〕〔Ni(dmit)_2〕_3

１ＩＮＴＲＯＤＵＣＴＩＯＮＴｈｅＮｉ（ｄｍｉｔ）２ｍｏｌｅｃｕｌｅｓｇｉｖｅｒｉｓｅｔｏａｎｕｍｂｅｒｏｆｍｏｌｅｃｕｌａｒｃｏｎｄｕｃｔｏｒｓ〔１，２〕ｉｎａｄｄｉｔｉｏｎｔｏｓｕｐｅｒｃｏｎｄｕｃｔｏｒｓ〔３，４〕．Ｔｈｅｍｕｌｔｙｓｕｌｆｕｒｆ...     

Synthesis and Structure of the Copper(Ⅰ) Complex [Cu(PPh3)2(BH4)]

Mononuclear copper( Ⅰ ) complex [Cu(PPh3)2(BH4)] has been synthesized by ligand replacement reaction in methanol and characterized by elemental analyses, molecular weight determination, IR spectra and X-ray single crystal analysis,its conductivity has also been measured. The crystal is monoclinic, space group C2/c, a =24.776(4), b=9.173(7), c=15.564(2)A; β=116.10(1)°, V=3176.73 A3, Z =4, F(000)=1256, μ(MoKα)=8.11 cm-1, Dc=1. 26 g/cm3, M=602.79, R=0. 039, Rw= 0. 050. The results show that PPh3 coordinates as monodentate ligand to the Cu ( Ⅰ ) atoms, and BH4 behaves as a bidentate ligand in the prepared complex.The central copper atom belongs to tetrahedron coordination geometry.     

Synthesis and Structural Characterization of the Complex 〔Et_4N〕_2〔Ni_2(C_2S_4)(C_3S_5)_2〕

１ＩＮＴＲＯＤＵＣＴＩＯＮＴｈｅｃｈｅｍｉｓｔｒｙｏｆｃｏｍｐｏｕｎｄｓｗｉｔｈｄｍｉｔ（ｄｍｉｔ＝１,３ ｄｉｔｈｉｏｌｅ ２ ｔｈｉｏｎｅ ４,５ ｄｉｔｈｉｏｌａｔｅ）ｈａｓａｔｒａｃｔｅｄｃｏｎｓｉｄｅｒａｂｌｅａｔｅｎｔｉｏｎｒｅｃｅｎｔｌ...     

Synthesis and Structure of 〔Cu(Hcdta)〕(H_2O)

1mTRODUCTION.Theimportantprogressinmagnetostructuralchemistryinthepastfewyearsisthesystematicdevel0pmentofstructurallyorderedbimetalliccompound"'.Thefami-liesofcrystallineandam0rphouscomplexes[MM'(cdta)j.xH,O(M,M'maybethefirsttransitionmetalorthesecondmaingroupelements)haveprovidedniceex-amplesofstructuralversatilityinmagneticstudiest2-6i,wherequiteafewstructuresmentionedabove,includingbimetallicandhomometalliccompoundscomprisingcop-per0rothermetalatoms,havebeeninvestigated"-".Ontheother…     

Synthesis and Structure of a 〔Mo_3S_7〕~(3.5+) Complex〔Mo_3(μ_3-S)(μ_2-S_2)_3(Et_2dtc)_3〕_2Cl

1INTRoDUCTIoNPreparationofcompoundscontaining[Mo3(p,-S)(p2-S2),j' clustercorehasbeenextensivelyinvestigated"',andconvenientroutesforthesynthesisofthecom-plexeswithdifferentligandshavebeendeveloPedrecentlyt2~43.Hegetschweilerandcoworkerst4ihaveeverreportedacomplex[Mo,(p,-S)(p,-S,)3(Et,dtc),3.I(2)withclustercore[Mo,S,j' ,whichwaspreparedbyreactionof(Et,N)2[Mo,S(Se)zjwithEt,dtc-andNaI-Correspondingcomplexes{Mo3(p,-S)(p2-S2),[S,P(OEt,),j}Cl(3)and{Mo,(p,-S)(p,-S,),[S,P(oEt,),j}I(4)…     

Synthesis and Crystal Structure of First Trinuclear Copper(Ⅰ) Complex with Coplanar Cu3O3 Core

Very recently, five-coordination copper(Ⅰ) complex with distorted square-pyramidal geometry,[CuL¹(NCCH₃)]⁺(L¹=Dimethyl-2,4-bis(2-pyridinayl)-3,7-diazabicyc lo-[3.3.l]-nonane-9-on-l,5-dicarboxylate)^[1], has been synthesized. X-ray structure shows that the rigid ligand L^[1] is well suited for copper(Ⅱ) ion, and highly strained for copper(Ⅰ) ion. Those results indicate that the lack of Jahn-Teller effect of copper(Ⅰ) ion often decreases the stability of copper(Ⅰ) precursor complexes, and plays an important in the transportation or activation of dioxygen for copper-containing proteins^[1].     

Synthesis and Crystal Structure of Dinuclear Copper Cluster Compound ［Cu（dtp）PPh_3］_2

ＳｙｎｔｈｅｓｉｓａｎｄＣｒｙｓｔａｌＳｔｒｕｃｔｕｒｅｏｆＤｉｎｕｃｌｅａｒＣｏｐｐｅｒＣｌｕｓｔｅｒＣｏｍｐｏｕｎｄ［Ｃｕ（ｄｔｐ）ＰＰｈ_３］_２ＣｈｅｎＱｉｕ－Ｈｕａ；ＬｕＳｈａｏ－Ｆａｎｇ；ＨｕａｎｇＸｉａｏ－Ｙｉｎｇ（ＳｔａｔｅｋｅｙＬａｂ...     

Synthesis and Structure of 〔Cu(μ-C_6H_5COO)_2(C_4H_8O)〕_2

1mTRODUCT1ONBinuclearcoppercomplexesareimportantnotonlyincoordinationchemistryandmagnetostructuralstudiesbutalsoinpracticalapplication.tliInanattempttoseekthedisPersionandemulationreagentsofCWM(themixtureofcoalandwater),thetitlecomP0undwassynthesizedbyanoxidativepreparationmethodt2i,whosesynthesisandstructurearedifferentfromthosedescribedbyWangetoft3i.Here,0nlythesynthesisandstructureofthetitlecomP0undarereportedandthestudiesofitsappli-cationareinprogress.2EXPERIMENTAL2.1Preparati0n…     

Synthesis and Crystal Structure of a Two-dimensional Polymeric Holmium Complex〔Ho(H_2saln)_(1.5)(NO_3)_3〕

１ＩＮＴＲＯＤＵＣＴＩＯＮＭｅｔａｌｉｃｃｏｍｐｌｅｘｅｓｏｆｓｃｈｉｆｂａｓｅｓｈａｖｅａｔｒａｃｔｅｄｔｈｅａｔｅｎｔｉｏｎｏｆｒｅｓｅａｒｃｈｅｒｓｄｕｅｔｏｔｈｅｉｒａｎｔｉｖｉｒａｌ，ｆｕｎｇｉｓｔａｔｉｃ，ａｎｄｃａｔａｌｙｔｉｃａｃｔｉ...     

Synthesis and Crystal Structure of H_2Mo_8O_(26)〔(n-Bu)_4N_2〔(CH_3)_2 COHCH_2COCH_3〕_2

1　ＩＮＴＲＯＤＵＣＴＩＯＮＰｏｌｙｍｏｌｙｂｄａｔｅａｎｉｏｎｓｈａｖｅｂｅｅｎｓｔｕｄｉｅｄｆｏｒｍａｎｙｙｅａｒｓｂｅｃａｕｓｅｏｆｔｈｅｉｒａｐｐｌｉｃａ ｔｉｏｎｉｎｃａｔａｌｙｓｉｓｃｈｅｍｉｓｔｒｙ〔1〕.Ｉｎｔｈｅｓｙｎｔｈｅｓｉｓｏｆｏｒｇａｎｉｃｐｏｌｙｍｏｌｙｂｄａｔｅｄｅｒｉｖａｔｉｖｅｓｕｓｉｎｇａｃｅｔｏｎｅａｓｓｏｌｖｅｎｔ,ｗｅｆｏｕｎｄｔｈａｔｔｈｅｃｏｎｄｅｎｓａｔｉｏｎｒｅａｃｔｉｏｎｏｆａｃｅｔｏｎｅｏｃｃｕｒｒｅｄａｎｄｔｈｅｃｏｎｄｅｎｓａｔｉｏｎｐｒｏｄ…     

Synthesis and Structure of Dinuclear Molybdenum Carbonyl Thiolate Compound 〔Et_4N〕_2〔Mo_2(CO)_8(SC_6H_4-OCH_3-p)_2〕

１　ＩＮＴＲＯＤＵＣＴＩＯＮＩｎｏｕｒｅｆｆｏｒｔｓｔｏｄｅｖｅｌｏｐｔｈｅｌｏｗ－ｖａｌｅｎｃｅＭｏ－ＳＲｃｏｍｐｏｕｎｄｓ,ｗｅｈａｖｅｆｏｕｎｄａｎＭｏ（０）－ｃｏｍｐｏｕｎｄ,〔Ｍｏ２（ＳＲ）２（ＣＯ）８〕２－,ｗｈｉｃｈｉｓｏｂｔａｉｎｅｄｆｒｏｍｔｈｅｒｅａｃｔｉｏｎｏｆＭｏ（ＣＯ）６ｗｉｔｈＲＳ－ｉｎｈｉｇｈｙｉｅｌｄ,ｐｏｓｓｅｓｓｅｓａｎｉｎｔｅｒｅｓｔｉｎｇｔｗｏ－ｅｌｅｃｔｒｏｎｔｒａｎｓｆｅｒｐｒｏｐｅｒｔｙ．Ｎｕｍｅｒｏｕｓｋｉｎｄｓｏｆｄｉｎｕｃｌｅａｒｍｏｌｙｂｄｅ…     

Crystal Structure of 〔(Ph_3P)_2N〕〔FeCo_3(CO)_(12)〕

lINTRODUCTIONThefirstheteronucleartransitionmetalclusterHFeCo,(Co),,wassynthesizedbyChinit13in196Obyusingthepyrolysisofmeta1carbonyldimers.Analysisofcar-bonylIRspectraandX-raypowderpatternsindicatedthatthiscompoundisisostruc-tural.withCo'(CO),,andthushasC,.symmetry(".MaysE'-'ihascarriedoutIRspectraandmassspectraonthiscompoundandkineticisotopestudiesontheprotona-tionoftheanion[FeCo,(CO),,j-,andproposedonthebasisofthisevidencethatthehydrogenatommightbelocatedinthecenterofthecluster.…     

Crystal and Molecular Structure of Copper(Ⅰ) Complex [Cu(PPh3)2(NO3)]

Mononuclear copper( Ⅰ ) complex [Cu(PPh3)2(NO3)] has been synthesized by ligand reduction of cupric nitrate with PPh3 in methanol and characterized by elemental analyses, molecular weight determination, IR spectra and X-ray single crystal analysis; its molar conductivity has also been measured. The crystal is monoclinic, space group C2/c, a=24.52(5), b=9. 187(2), c=15. 489(3) A; β=116.69 (3)°, V=3118.7(11) A3, Z=4, F(000)=1520, Dc=1.584 g/cm3, R=0.0276,Rw= 0. 0321. The results show that PPh3 coordinates as a monodentate ligand to the Cu( Ⅰ ) atoms, and (NO3) behaves as a bidentate ligand in the prepared complex.     

Synthesis and Crystal Structure of 〔P(CH_2Ph)Ph_3〕〔PdWS_4(S_2CNC_4H_8)〕

1INTRoDUCTIoNThiomolybdate(thiotungstate)isafundamentalunitoPsomemolybdenumen-zymesandplaysanimportantroleincoordinationchemistryasaligandforothermet-alstoformanalogouscompoundsofmetalloproteinst'3.Recentlyinterestingnonlinearoptical(NLO)propertieshavebeendiscoveredforthetypeofMo(W)-Cu(Ag)-Sclusterst2.33.Bythevarioussyntheticmethodsseveralhundredmixedmetalclustersandcomplexes,Mo(W)-M-S(M=transitionmetal),havebeensynthesizedt'i.AmongthesecompoundsthecasesofMbeingCu,Ag,Feareusualwhile…     

Synthesis and Crystal Structure of 〔Co_3(CO)_9(μ_3-C)C(O)OCH_2〕_2

１ＩＮＴＲＯＤＵＣＴＩＯＮＩｎｒｅｃｅｎｔｙｅａｒｓ,ｈｉｇｈｅｒ ｎｕｃｌｅａｒｉｔｙｃｌｕｓｔｅｒｓｈａｖｅｒｅｃｅｉｖｅｄｃｏｎｓｉｄｅｒａｂｌｅａｔｅｎｔｉｏｎｂｅｃａｕｓｅｏｆｔｈｅｉｒｐｏｔｅｎｔｉａｌａｐｐｌｉｃａｔｉｏｎｓｉｎｍａｎｙ...     

Synthesis and Crystal Structure of FeCo_2(CO)_8(μ_3-S)〔P(OCH_2Ph)_3〕

1INTRODUCTIONBytreatingFeCo2(CO),(p,-S)withgroupVligands[L=PPh,,AsPh,,PBus",p(OEt),j,monosubstitutedderivativesFeCo2(CO),(p,-S)(L)havebeenobtained{1'2i.13C-NMRshowedthatthereplacementofCObyagroupVligandinFeCo,(CO),(p,-S)isatonecobaltatominthemonosubstitutedderivativet2).How-ever,thesubstitutedderivativeofFeCo,(CO),(p,-S)withP(OCH,Ph),hasnotbeenreportedanditscrystalstructurehasnotbeendetermined.WehavesynthesizedthetitlecompoundFeCo,(CO),(p,-S)[P(OCH,Ph),jandtestifiedth…     

Synthesis and Crystal Structure of Dinuclear Copper(Ⅱ)Complex Cu_2(μ-PhCOO)_4(amet)_2·2CH_3COCH_3

1INTRODUCT1ONFormode1ingcompoundsofcertaincopper-containingenzymes,theinvestigationofdinuclearcoppercomplexeshasattractedtheattentionofinorganicandbiologicchemistst1i.Actingasoxygentransportproteinsforinvertebrates,oxyhemocyanin(oxyHc)hasadinuclearcoppersitewithaCu-Cuseparationofca.3.6A[2'3i(Fig.1).In1984,Karlinetal-[4ireportedthesynthesisofadinuclearcopper(I)com-plexwithabidentateligand.Thecomplexreactswithdioxygenquasireversibly,whichproducesaperoxodinuclearcopper(I)complex(Nallo=8O3…     

Synthesis and Structure of Dinuclear Molybdenum Carbonyl Thiolate Compound〔Et_4N〕_2〔Mo_2(CO)_8(SC_6H_4-NH_2-p)_2〕

１ＩＮＴＲＯＤＵＣＴＩＯＮＴｈｅｅｘｉｓｔｅｎｃｅａｎｄｓｉｇｎｉｆｉｃａｎｃｅｏｆｔｈｅｍｏｌｙｂｄｅｎｕｍ ｓｕｌｆｕｒｂｏｎｄｉｎｇｉｎｍｏｌｙｂｄｅｎｕｍｅｎｚｙｍｅｓ〔１〕ｈａｖｅｓｔｉｍｕｌａｔｅｄｔｈｅｓｔｕｄｉｅｓｏｎｔｈｅｃｈｅｍｉ...