Strongly enhanced flux pining of GdBCO coated conductors with BaSnO3 nanorods by pulsed laser deposition

We report the effects of BSO addition on the crystallinity, texture, and the field dependency of critical current density (J_c) of GdBCO coated conductors (CCs) prepared by pulsed laser deposition (PLD). Undoped and BSO-doped GdBCO films showed only c-axis oriented growth, and the incorporated BSO nanorods exhibited epitaxial relationship with the GdBCO matrix. In comparison with undoped film, BSO-doped GdBCO film exhibited greatly enhanced J_c and higher pinning force densities in the entire field region of 0–5 T (H//c) at 77 and 65 K. The BSO-doped GdBCO film showed the maximum pinning force densities (F_p) of 6.5 GN/m³ (77 K, H//c) and 32.5 GN/m³ (65 K, H//c), ～2.8 times higher than those of the undoped sample. Cross-sectional TEM analyses exhibited nano-structured BSO nanorods roughly aligned along the c-axis of the GdBCO film, which are believed effective flux pinning centers responsible for strongly improved critical current densities in magnetic fields.     

Long RE123 coated conductors with high critical current over 500 A/cm by IBAD/PLD technique

We have developed long RE₁Ba₂Cu₃O_7?X (RE123) coated conductors with large current capacity by the ion beam assisted deposition (IBAD) and the pulsed laser deposition using hot wall heating (HW-PLD) technique. As a result, we could fabricate an 8 m-long Gd₁Ba₂Cu₃O_7?X (Gd123) coated wire with the minimum and maximum critical current (I_c) of 951 A/cm-w and 1003 A/cm-w at 77 K, 0 T, respectively, measured in 0.7 m-long sections by the standard 4-probe technique. Furthermore, we succeeded in preparation of over 600 m-long Gd123 coated wire with the uniform I_c distribution over 600 A/cm-w. It had average, maximum and minimum I_c of 665, 698, 609 A/cm-w, respectively. The n-values of the sample showed the maximum I_c and minimum I_c were 40 and 36, respectively. As a result, we set the new world record of I_c × L value as 374535 A m (= 609 A × 615 m). The in-field performance of this long wire was quite high as well; the minimum I_c exceeded 50 A/cm-w at 77 K, 3 T.     

Flux pinning by discontinuous columnar defects in 74 MeV Ag-irradiated YBa2Cu3O7 coated conductors

Linear damage tracks are created in production-quality YBCO coated conductors by irradiation with 61–74 MeV Ag ions. The ion tracks are observed by transmission electron microscopy to be elongated but discontinuous. The in-field transport critical current (I_c) is enhanced significantly for fields applied parallel to the irradiation direction with a broad peak appearing in the magnetic field-angle dependence of the critical current, coinciding with the irradiation direction. The zero-field I_c is typically reduced somewhat, however annealing at 200 °C partially restores this and enhances the in-field I_c even for field parallel to the irradiation direction. Lower energies tend to produce a weaker peak, but also retain the zero-field I_c to a greater extent, consistent with a trend of greater discontinuity in the ion tracks.     

Effects on Jc of pinning center morphology for multiple-in-line-damage in coated conductor and bulk,melt-textured HTS

The properties of discontinuous aligned pinning centers (PCs) created by high-energy heavy-ions are compared for bulk melt-textured and coated conductor HTS. Properties of PCs, which increase J_c (pinning potential and entanglement), and negative properties which decrease J_c (e.g., decreased T_c and percolation paths) are evaluated. Mechanisms are proposed to explain the very large increases in J_c resulting from multiple-in-line-damage (MILD) compared to continuous columnar pinning centers (CCPC). In particular, a mechanism which results in fluxoid entanglement, even for parallel (unsplayed) PCs, is discussed. The same mechanism is found to also account for restoration of much of the pinning potential expected to be lost due to the gaps in MILD PCs. It also accounts for the fact that at high fluence, J_c increases as fluence is increased, instead of decreasing as expected. The very low self-field in coated conductor permits separation of the negative and positive effects of PCs. It is found that parameters developed to quantify the negative effects in bulk melt-textured YBCO, by 63 GeV U²³⁸ ions, successfully describe damage to 2.1 μm thick coated conductor by 1 GeV Ru⁴⁴ ions. Coated conductor at 77 K and self-field is generally known to have J_c about 100 times that of melt-textured YBCO. However, at 77 K and applied field of 1 T, when both forms of HTS are processed with comparable numbers of near-optimum MILD PCs, the difference in J_c is reduced to a factor of 1.3–2. Whereas J_c for melt-textured YBCO increased sharply, by a factor of up to 16.8 for high-fluence MILD PCs, J_c in coated conductor increased by a smaller factor of 2.5–3.0. Nevertheless, 2.1 μm thick coated conductor, with near-optimum MILD PCs, exhibits J_c = 543 kA/cm² at 77 K and applied field of 1.0 T, and I_c = 114 A/cm-width of conductor. This is the highest value we find in the literature. The phenomenology developed indicates that for optimum MILD PCs in coated conductor, J_c ～ 700 ± 70 kA/cm² should be achievable at 77 K, 1.0 T.     

High performance GdBa2Cu3O7−z film preparation by non-fluorine chemical solution deposition approach

Biaxially textured GdBa₂Cu₃O_7?z (GdBCO) films with T_c above 93 K have been prepared on (0 0 l) LaAlO₃ substrate by self-developed non-fluorine polymer-assisted chemical solution deposition (PA-CSD) approach. The GdBCO films show smooth and crack-free morphology. Many nanoscale particles with homogeneous distribution are observed in the GdBCO films, which have not been observed yet in the YBa₂Cu₃O_7?z (YBCO) films prepared by the same processing technique. Besides a high J_c (77 K, 0 T) of 2.28 MA/cm², the optimized GdBCO films show a better J_c–B behavior and an improved high-field J_c, compared to the YBCO films.     

Current carrying capability of HTS Roebel cable

We have developed a numerical technique to estimate the current carrying capability of HTS Roebel cable composed from coated conductor strands. The influence of self-field on the critical current density is studied computationally for a Roebel cable using a realistic field and angle dependence behaviour of critical current. The computations are carried out for N/2 (number of strands/strand width in mm), and N/5 Roebel cable for N = 2–15. The local current distribution in each strand satisfies the self-consistent criteria J = J_c(B(J)) except for a small region where the current density is set to zero to maintain the condition of equal currents in all strands. The variation of critical current with vertical and horizontal separation between the strands is also investigated. Results are compared with the measured values of critical current for some of our cables. The comparison shows an error of up to 10% which we attribute mostly to the model not accounting for the spread in I_c values of the constituent strands.     

Thickness dependence of Ic and Jc of LTG-SmBCO coated-conductor on IBAD-MgO tapes

We have reported SmBa₂Cu₃O_y (SmBCO) films on single crystalline substrates prepared by low-temperature growth (LTG) technique. The LTG-SmBCO films showed high critical current densities in magnetic fields compared with conventional SmBCO films prepared by pulsed laser deposition (PLD) method. In this study, to enhance critical current (I_c) in magnetic field, we fabricated thick LTG-SmBCO films on metal substrates with ion-beam assisted deposition (IBAD)-MgO buffer and estimated the I_c and J_c in magnetic fields.All the SmBCO films showed c-axis orientation and cube-on-cube in-plane texture. T_c of the LTG-SmBCO films were 93.1–93.4 K. J_c and I_c of a 0.5 μm-thick SmBCO film were 3.0 MA/cm² and 150 A/cm-width at 77 K in self-field, respectively. Those of a 2.0 μm-thick film were 1.6 MA/cm² and 284 A/cm-width respectively. Although I_c increased with the film thickness increasing up to 2 μm, the I_c tended to be saturated in 300 A/cm-width. From a cross sectional TEM image of the SmBCO film, we recognized a-axis oriented grains and 45° grains and Cu–O precipitates. Because these undesired grains form dead layers, I_c saturated above a certain thickness. We achieved that I_c in magnetic fields of the LTG-SmBCO films with a thickness of 2.0 μm were 88 A/cm-width at 1 T and 28 A/cm-width at 3 T.     

I–V characteristics and magnetic field profile studies in high Tc BSCCO based Helmholtz coil

A double pancake wound high T_c Helmholtz coil has been fabricated using commercial grade BSCCO tape. The current voltage (I–V) characteristics of this HTS coil has been carried out using standard four probe technique. From the I–V characteristics, the critical current based on self field dependent of HTS coil and quality index “n” value have been calculated. Magnetic field profiles have been studied along the axis of this coil for various amplitudes of applied current ranging from 10 A to 50 A at 77 K. The measured field profiles have a very good agreement with that of theoretical values predicted in the literature.     

Reel-to-reel fabrication of meter-long YBCO coated conductor

YBa₂Cu₃O_7?δ (YBCO) superconductors were coated on the CeO₂/YSZ/Y₂O₃ buffered Ni-5at%W tapes by a reel-to-reel pulsed laser deposition (PLD). The process of a multi-layer deposition of YBCO film was explored. X-ray diffraction texture measurements showed good both in-plane and out of plane crystalline orientations in YBCO films. The average values calculated at a full width at half maximum (FWHM) of the peaks from phi-scans (φ) and omega (ω) scans for one meter-long YBCO tape were 7.49° and 4.71°, respectively. The critical current (I_c) was over 200 A/cm-width at 77 K and under self-field for meter-long YBCO tape. The critical transition temperature of the YBCO tape was typically as 90.1 K with 0.5 K transition widths.     

Deposition of Gd2Zr2O7 single buffer layers with different thickness for YBa2Cu3O7−δ coated conductors on metallic substrates

A series of Gd₂Zr₂O₇ (GZO) single buffer layers with different thicknesses were epitaxially grown on highly textured Ni–5 at.% W tapes using pulsed laser deposition. These allow the subsequent growth of high-quality superconducting YBa₂Cu₃O_7?δ layers. The superconducting transition temperature T_c reaches a maximum value of 92.4 K as well as a narrow transition width of 0.8 K for the optimized GZO layer thickness. The inductive measurements show the critical current density as high as 1.2 MA/cm² at 77 K in self-field, indicating that a GZO single buffer layer is a suitable alternative for simplifying the second generation high T_c superconducting coated conductors architecture.     

Modified Lanthanum Zirconium Oxide buffer layers for low-cost,high performance YBCO coated conductors

The pyrochlore Lanthanum Zirconium Oxide, La₂Zr₂O₇ (LZO), has been developed as a potential replacement barrier layer in the standard RABiTS three-layer architecture of physical vapor deposited CeO₂ cap/YSZ barrier/Y₂O₃ seed on Ni–5%W metal tape. The main focus of this research is to ascertain whether: (i) we can further improve the barrier properties of LZO; (ii) we can modify the LZO cation ratio and still achieve a high level of performance; and (iii) it is possible to reduce the number of buffer layers. We report a systematic investigation of the LZO film growth with varying compositions of La:Zr ratio in the La₂O₃–ZrO₂ system. Using a metal–organic deposition (MOD) process, we have grown smooth, crack-free, epitaxial thin films of La_xZr_1?xO_y (x = 0.2–0.6) on standard Y₂O₃ buffered Ni–5W substrates in short lengths. Detailed XRD studies indicate that a single epitaxial LZO phase with only (0 0 1) texture can be achieved in a broad compositional range of x = 0.2–0.6 in La_xZr_1?xO_y. Both CeO₂ cap layers and MOD–YBCO films were grown epitaxially on these modified LZO barriers. High critical currents per unit width, I_c of 274–292 A/cm at 77 K and self-field were achieved for MOD–YBCO films grown on La_xZr_1?xO_y (x = 0.4–0.6) films. These results indicate that LZO films can be grown with a broad compositional range and still support high performance YBCO coated conductors. In addition, epitaxial MOD La_xZr_1?xO_y (x = 0.25) films were grown directly on biaxially textured Ni–3W substrates. About 3 μm thick YBCO films grown on a single MOD–LZO buffered Ni–3W substrates using pulsed laser deposition show a critical current density, J_c, of 0.55 MA/cm² (I_c of 169 A/cm) at 77 K and 0.01 T. This work holds promise for a route for producing simplified buffer architecture for RABiTS based YBCO coated conductors.     

Homoepitaxial growth of MOD-YBCO thick films on evaporated and MOD templates

We have prepared metal organic deposition (MOD)-YBCO thick films by repeating the coating-pyrolysis-crystallization procedure onto ～100-nm-thick evaporated and MOD templates. Surface morphology of the template was found to strongly affect the homoepitaxial growth of MOD-YBCO layers on the template; namely, the epitaxial growth of MOD-YBCO on the evaporated template was much easier than that on the MOD template. A 220-nm-thick epitaxial MOD-YBCO film was successfully prepared on the 100-nm-thick evaporated-YBCO template to obtain a 320-nm-thick YBCO film, which exhibited J_c = 2.44 MA/cm² and I_c = 78 A/cm. The I_c value has significantly increased from 37 A/cm for the evaporated-template.     

Fabrication of single domain GdBCO bulks with different new kind of liquid sources by TSIG technique

Single domain GdBCO bulk superconductors have been fabricated with different new kinds of liquid sources by Top Seeded Infiltration and Growth process. A conventional liquid source is a mixture of REBa₂Cu₃O_7?x and Ba₃Cu₅O₈ in a ratio of 1:1; new liquid sources are made of a mixture of RE₂BaCuO₅ + 9BaCuO₂ + 6CuO or RE₂O₃ + 10BaCuO₂ + 6CuO. The microstructures and levitation forces of the GdBCO bulks have also been investigated. The properties of the samples fabricated are nearly the same as those of samples fabricated with conventional liquid sources, which indicates that the new liquid sources are very important to reduce the cost and improve the working efficient on the fabrication of single-domain GdBCO bulk superconductors.     

Effect of the composition on the superconducting properties of IBAD-MgO SmBCO coated conductors with superconducting film directly deposited on epi-MgO layer

Sm_1+xBa_2?xCu_3+yO_7?δ (SmBCO) films were directly deposited on the epi-MgO/IBAD-MgO/Y₂O₃/Al₂O₃/Hastelloy template by co-evaporation using the evaporation using drum in dual chambers (EDDC) system without the buffer layer in order to investigate the effect of the composition ratios on superconducting property, microstructure and texture of SmBCO film. The films with gradient composition ratios of Sm:Ba:Cu were deposited using a shield with an opening which was placed between the substrate and the boats. The highest I_c of 52 A (corresponding to J_c = 1.6 MA/cm² and a thickness of 800 nm) was observed at 77 K in self field at a composition x = 0.01–0.05 and y = ?0.23 to ?0.46. When the composition ratio is outside this range, the I_c value rapidly decreased. The superconducting critical current was highly dependent on the composition ratio. As the composition ratio is farther away from that of the highest I_c, the SmBCO (1 0 3) peak intensity increased and the amount of a-axis oriented parts increased. A dense microstructure with round-shape grains was observed in the region showing the highest I_c. The optimum composition ratio can be found by analyzing films deposited with variable deposition rates of each depositing element.     

R&D of coated conductors for applications in Japan

On the research and development of coated conductors in Japan, the I_c characteristics and the length have been remarkably improved in the national project. Five hundred meter-long tapes with higher I_c values than 300 A/cm-width were realized by the pulsed laser deposition (PLD) and the metal organic deposition using trifluoroacetates (TFA-MOD) processings for the superconducting layer on the IBAD-GZO buffered substrates. In order to realize the low cost by the increasing the production rate of the ion beam assisted deposition (IBAD) layer, the process of IBAD-MgO was developed and a 1000 m-long IBAD buffer tape was fabricated at an extremely high production rate of 1 km/h. On the other hand, the artificial pinning center has been introduced in both PLD and MOD processing. The BaZrO₃ nano-rods were aligned along the c-axis of GdBCO superconducting films by the PLD process. The J_c value in the magnetic field parallel to the c-axis was remarkably improved. Additionally, the BaZrO₃ nano-particles were uniformly dispersed in YGdBCO films by the TFA-MOD process and the J_c–B–θ property was confirmed to be isotropic.     

The effect of pinning centers in Zn-doped CuBa2Ca3Cu4O12−y high-temperature superconductors

CuBa₂Ca₃Cu₄O_12−y (Cu:1234) high-temperature superconductors (HTS) doped with up to 2% Zn were grown using the high-pressure synthesis technique. Magnetization loops of the samples were measured at various temperatures between 5 and 77.3 K and magnetic fields up to 14 T. Critical current densities J_c of the samples were estimated using the critical state model. The results show that Zn-induced pinning centers increase J_c of Cu:1234 several times, depending on field and temperature. From the experimentally determined field-temperature region in which a higher Zn concentration lead to a higher J_c, we suggest the existence of a cross-over from quite efficient, extended (in the c-axes direction) pinning centers to point-like (inefficient) pinning centers at a certain temperature, depending on field. This effect can be attributed to the fact that, unlike other HTS, in Cu:1234 there is a second critical temperature T_c2 of about 70–80 K (in zero field, and 50–60 K in 15 T), related to the over-doping of pyramidal basal plane (outer CuO₂ plane).     

Tunable supercurrent in superconductor/normal metal/superconductor Josephson junctions

When two superconductors are connected by a weak link a supercurrent flows determined by the difference in the macroscopic quantum phases of the superconductors. Originally, this phenomenon was discovered by Josephson for the case of a weak link formed by a thin tunnel barrier. The supercurrent I is related to the phase difference ϕ through the Josephson current–phase relation, I = I_csin ϕ, with I_c, the critical current, depending on the properties of the weak link. A similar relation holds for weak links consisting of a normal metal, a semiconductor or a constriction . In all cases, the phase differenceϕ =  0 when no supercurrent flows through the junction, and ϕ increases monotonically with increasing supercurrent until the critical current is reached. Using nanolithography techniques we have succeeded in making and studying a Josephson junction with a normal metal weak link, in which we have direct access to the microscopic current-carrying states inside the link. We find that the fundamental Josephson relation can be changed fromI = I_csin ϕ toI = I_csin(ϕ + π), i.e. to a π -junction, by suitably controlling the energy distribution of the current-carrying states in the normal metal. This fundamental change in the way these Josephson junctions behave has potential implications for their use in superconducting electronics as well as (quantum) logic circuits based on superconductors.     

Solderability study of RABiTS-based YBCO coated conductors

The solderability of commercially available YBa₂Cu₃O_7?x (YBCO) coated conductors that were made from Rolling Assisted Biaxially Textured Substrates (RABiTS)-based templates was studied. The coated conductors, also known as second-generation (2G) high temperature superconductor (HTS) wires (in the geometry of flat tapes about 4 mm wide), were laminated with copper, brass, or stainless steel strips as stabilizers. To understand the factors that influence their solderability, surface profilometry and scanning electron microscopy were used to characterize the wire surfaces. The solderability of three solders, 52In48Sn, 67Bi33In, and 100In (wt.%), was evaluated using a standard test (IPC/ECA J-STD-002) and with two different commercial fluxes. It was found that the solderability varied with the solder and flux but the three different wires showed similar solderability for a fixed combination of solder and flux. Solder joints of the 2G wires were fabricated using the tools and the procedures recommended by the HTS wire manufacturer. The solder joints were made in a lap-joint geometry and with the superconducting sides of the two wires face-to-face. The electrical resistances of the solder joints were measured at 77 K, and the results were analyzed to qualify the soldering materials and evaluate the soldering process. It was concluded that although the selection of soldering materials affected the resistance of a solder joint, the resistivity of the stabilizer was the dominant factor.     

YBCO films buffered by pyrochlore Nd2Mo2O7 layer on YSZ substrates by chemical solution deposition

A chemical solution deposition process was used to grow epitaxial Nd₂Mo₂O₇ (NMO) buffer layers on YSZ substrates to produce YBa₂Cu₃O_7?δ (YBCO) coated conductors. The NMO precursor solution prepared using metal acetylacetonates was spin-coated onto single crystal YSZ substrate of 10 mm × 10 mm in size at 3000 rpm for 30 s and heat-treated at 1000 °C for 2 h in Ar after calcinated at 550 °C for 1 h. The YBCO film was deposited by TFA-MOD route on top of the NMO/YSZ architecture. The phase purity and the crystalline orientation of NMO and YBCO films were evaluated by X-ray diffraction (XRD). Scanning electron microscopy (SEM) and atomic force microscopy (AFM) were used to observe their microstructure and their surface roughness. The critical current density (J_c) of YBCO film on NMO/YSZ is 1.8 MA/cm² at 77 K in self-field, which indicates that the Nd₂Mo₂O₇ is a potential buffer for YBCO coated conductor.     

1.34 μm fluorescence and laser properties of Nd:La0.11Y0.89VO4 crystal

For Nd:La_xY_1−xVO₄ (x = 0.11) crystal, the ⁴F_3/2 → ⁴I_13/2 transition property was investigated for the first time. The fluorescence peak of Nd:La_0.11Y_0.89VO₄ crystal exhibited obvious inhomogeneous broadening comparing with that of Nd:YVO₄ crystal. With laser diode array as pump source, 1.34 μm continuous-wave (CW) and active Q-switched laser operations based on ⁴F_3/2 → ⁴I_13/2 transition were realized. For CW laser operation, the maximum output power of 2.47, 2.13 W is obtained with slope efficiencies of 29.4%, 27.6%, and optical to optical conversion efficiency of 26.2%, 24.7%, respectively for a, c cut crystal samples. For acousto-optic (AO) Q-switched laser operation, the shortest pulse width, highest peak power and maximum pulse energy came from the a-cut sample, which were 13 ns, 2.69 kW and 35 μJ, respectively.