Interferometric determination of refraction and dispersion of a birefringent material: non-numerical procedure

Fringes of equal chromatic order are produced in air, immersion liquid and mica sample interferometric gaps. The three gaps are of the same thickness and simultaneously enclosed in a wedge interferometer. A single-shot interferogram contains fringes in the three gaps is sufficient to deduce the needed experimental data. A non-numerical procedure is used for determining the refractive indices of the immersion liquid and mica sample across the visible spectrum. There is no need for any numerical fitting stage nor for the application of any theoretical model concerning the dispersion behavior of the sample under test. A modified two-term Sellmeier dispersion formula has been used for fitting the experimental data and deducing the needed dispersion parameters.     

Interferometric determination of refraction and dispersion of a birefringent material: numerical procedure

Air, liquid and solid sample interferometric gaps of the same thickness and simultaneously enclosed in a wedge interferometer are used to produce fringes of equal chromatic order. A mica sample of dimensions 2×5 mm² and an immersion liquid of the same refractive index are used. A single shot interferogram containing fringes in the three gaps is sufficient to deduce the needed experimental data. Locations of fringe maxima are introduced in a numerical procedure to retrieve the sample and liquid refractive indices across the visible spectrum. The numerical procedure is based on a simple dispersion function of wavelength and wavenumber. A modified two-term Sellmeier dispersion formula has been used for fitting the experimental data and deducing the needed dispersion parameters.     

Interferometric determination of the refractive indices and birefringence of some highly oriented fibres

Variable wavelength interferometric technique (VAWI) is a direct method for determining the refractive indices and birefringence of highly oriented fibres. This method uses the polarizing interference Pluta microscope with a monochromatic light from wedge interference filter that provides a continuously variable wavelength. The standard calibration process of the Pluta polarizing interference microscope is carried out and a calibration graph is obtained. The refractive indices and birefringence of PEN, CONEX and TECHNORA were measured over the visible range of the spectrum and the constants for the Cauchy's dispersion formula were determined. The oscillation and dispersion energies were calculated from the measurements of the refractive index.     

Interferometric studies on the influence of temperature on the optical and dispersion parameters of GRIN optical fibre

Opto-thermal device attached to automate Fizeau interferometer is used to investigate the influence of temperature on opto-thermal properties of multimode graded-index (GRIN) optical fibre in the range from 27 to 54 °C. The effect of temperature on the refractive index profile of fibre is studied. The optical parameters and the opto-thermal coefficient of this fibre are determined. Also the variation of oscillation and dispersion energies, zero dispersion wavelengths, coupling efficiency, normalised frequency, number of propagation modes with the temperature and the material dispersion with the wavelength at different temperatures are calculated. Microinterferograms are given for illustration.     

Group refractive index measurement by fringes of equal chromatic order

Fringes of equal chromatic order in transmission across a thin liquid or a thin solid sample inside a wedge interferometer, followed with a grating spectrograph, are produced. A single-shot interferogram of the air and sample regions is recorded. Locations of fringes maxima in the air region are fitted in a numerical procedure based on Cauchy's dispersion function. Then it is used for measuring the interferometric gap thickness. The order of interference in the sample region is represented by a third-order polynomial in the wavenumber for deducing the sample group refractive index. An error analysis of the measured group refractive index is given. The method is applied for measuring the group refractive index of water and mica samples across the visible spectrum. The method measures both the sample thickness and its group refractive index. It is static with no moving parts and suitable for thin liquid or solid samples without immersion liquids.     

Interference of white light in tandem configuration of birefringent crystal and sensing birefringent fiber

Spectral interference of white-light beams propagating through a tandem configuration of birefringent crystal and sensing birefringent fiber is analyzed theoretically and experimentally. The spectral interference law is expressed analytically under the condition of a Gaussian response function of a spectrometer taking into account the dispersion of birefringence in the crystal and in the fiber. Two types of spectral interferograms are modeled knowing dispersion characteristics of the sensing fiber and using a quartz crystal of the positive or a calcite crystal of the negative birefringence. The theoretical analysis is accompanied by two experiments employing a highly birefringent fiber and a birefringent quartz crystal of two suitable thicknesses. Within both experiments the spectral interference fringes are resolved in accordance with the theory with phases dependent on the fiber length.     

Automatic determination of refractive index profile of fibers having regular and/or irregular transverse sections considering the refraction of light rays by the fiber

A new model, using non-destructive two- and/or multiple-beam interferometric techniques, is suggested for measuring the refractive index profile of fibers having regular and/or irregular cross-sectional shape taking into consideration the refraction of the light rays by the fiber. The proposed model is applied for three different fibers having different cross-sectional shapes and different refractive index profiles. These fibers are PPT, homogeneous fiber, with circular cross-section, graded index optical fiber of circular cross-sectional shape and Dralon fiber of irregular cross-section. To validate the proposed model it is used, firstly, to calculate the index profile for a standard PPT fiber. Secondly, the calculated results for the irregular Dralon fiber and GR-IN optical fiber are compared with that calculated using other conventional method. From this comparison, we recommend that the refraction must be taken into account to obtain accurate results especially for birefringent fibers and graded index optical fibers.     

Automatic determination of refractive index profile, sectional area, and shape of fibers having regular and/or irregular transverse sections

A new method based on a mathematical model and a computer program is suggested to determine the refractive index profile of fibers having regular and/or irregular transverse sectional shape. Microinterferogram of both multiple-beam Fizeau fringes and the duplicated image from two-beam interference microscope are used for the determination of refractive index profile, cross-sectional area and shape of three different types of fibers. To confirm the suggested model, the calculated area and the shape of the transverse section of these fibers are compared with those results obtained using conventional methods.     

Ultrasound assisted combined molecularly imprinted polymer for selective extraction of nicotinamide in human urine and milk samples: Spectrophotometric determination and optimization study

Ultrasound-assisted dispersive solid phase microextraction followed by UV–vis spectrophotometer (UA-DSPME-UV–vis) was designed for extraction and preconcentration of nicotinamide (vitamin B₃) by HKUST-1 metal organic framework (MOF) based molecularly imprinted polymer (MIP). This new material was characterized by FTIR and FE-SEM techniques. The preliminary Plackett–Burman design was used for screening and subsequently the central composite design justifies significant terms and possible construction of mathematical equation which give the individual and cooperative contribution of variables like HKUST-1-MOF-NA-MIP mass, sonication time, temperature, eluent volume, pH and vortex time. Accordingly the optimum condition was set as: 2.0 mg HKUST-1-MOF-NA-MIP, 200 μL eluent and 5.0 min sonication time in center points other variables were determined as the best conditions to reach the maximum recovery of the analyte. The UA-DSPME-UV–vis method performances like excellent linearity (LR), limits of detection (LOD), limits of quantification of 10–5000 μg L⁻¹ with R² of 0.99, LOD (1.96 ng mL⁻¹), LOQ (6.53 μg L⁻¹), respectively show successful and accurate applicability of the present method for monitoring analytes with within- and between-day precision of 0.96–3.38%. The average absolute recoveries of the nicotinamide extracted from the urine, milk and water samples were 95.85–101.27%.     

Structural, morphological and optical properties of CuAlS2 films deposited by spray pyrolysis method

The structural, morphological and optical properties of CuAlS₂ films deposited by spray pyrolysis method have been investigated. CuAlS₂ in the form of films is prepared at different deposition conditions by a simple and economical spray pyrolysis method. The structural, surface morphology and optical properties of the films were analyzed by X-ray diffraction (XRD), scanning electron microscope (SEM), atomic force microscope (AFM) and absorbance spectra, respectively. The films were polycrystalline, crystallized in a tetragonal structure, and are preferentially orientated along the (1 1 2) direction. Grain size values, dislocation density, and d% error of CuAlS₂ films were calculated. The optical band gap of the CuAlS₂ film was found to be 3.45 eV. The optical constants such as refractive index, extinction coefficient and dielectric constants of the CuAlS₂ film were determined. The refractive index dispersion curve of the film obeys the single oscillator model. Optical dispersion parameters E_o and E_d developed by Wemple-DiDomenico were calculated and found to be 3.562 and 12.590 eV.     

Linear and nonlinear optical properties of strained GaN/AlN quantum dots: Effects of impurities,radii of QDs,and the incident optical intensity

The linear and nonlinear optical properties of cylinder GaN/AlN quantum dots with strain effects and impurity are investigated by taking into account the effects of the deformation potential and piezoelectric potential on the conduction band edge. The results are presented as a function of photon energies and QD radii. The optical absorption spectrum and refractive index changes have a blueshift in the presence of the impurity. With increasing distance of the impurity’s position along the growth direction, the peak values of the refractive index changes decrease and shift to higher photon energy. When the sizes of the QDs increase, redshift effects are observed and the relative amplitudes diminish. It can be found that the nonlinear effect becomes obvious with increase of the incident optical intensity. Then there is a “hole-burning” in the absorption coefficient spectra and two new peaks will appear in the total refractive index change spectrum when the optical intensity becomes larger enough. Finally it can be concluded that the intensity of the incident light and the position of the impurity play an important role in the linear and nonlinear optical properties.