共查询到20条相似文献,搜索用时 15 毫秒
1.
Jussara Lopes de Miranda Judith Felcman James L. Wardell Janet M. S. Skakle 《Acta Crystallographica. Section C, Structural Chemistry》2002,58(9):m471-m474
The title compound, [Cu2(NO3)2(C3H7N3O2)4], forms a centrosymmetric dimer, with the two Cu2+ ions separated by 2.6525 (6) Å. The asymmetric unit contains a Cu atom coordinated to two guanidinoacetic acid ligands (via one carboxylate O atom from each ligand) and to a nitrate group. The inversion centre in P generates the entire molecule, in which each Cu atom is coordinated to four carboxylate and to one nitrate O atom; ignoring the Cu—Cu separation, the geometry about each Cu atom is square pyramidal. The amino acid ligand is in the zwitterionic form. Strong N—H?O hydrogen bonds lead to a three‐dimensional supramolecular structure, in which the N?O distances are in the range 2.931 (4)–3.278 (3) Å, with N—H?O angles ranging from 128 to 170°. 相似文献
2.
Jan Moncol Jaroslava Maroszova Milan Melník Marian Koman 《Acta Crystallographica. Section C, Structural Chemistry》2007,63(3):m114-m116
The title compound, [Cu3(C3H5O2)6(C6H7NO)4]n, is composed of polymeric chains formed by alternating centrosymmetric Cu2(μ‐CH3CH2CO2)4 and Cu(C3H5O2)2(C6H7NO)2 units. These elemental units are linked by two bridging 3‐pyridylmethanol (3PM) ligands. The Cu2(μ‐CH3CH2CO2)4 group presents a centrosymmetric tetrabridged structure with four syn–syn bridging propionate ligands to which two 3PM molecules are bonded (through N), occupying the apical positions of each square‐pyramidal polyhedron around the CuII ions. The remaining mononuclear group is centred around a third CuII ion, which lies on a symmetry centre and is bound to two monodentate propionate groups (through O), two monodentate 3PM molecules (through N) and two bridging 3PM molecules (through O), thus completing a square‐bipyramidal CuO2N2O2 coordination. 相似文献
3.
Eleonora Freire Ricardo Baggio 《Acta Crystallographica. Section C, Structural Chemistry》2008,64(4):m164-m166
The present form of barium acetate, formulated as [Ba(C2H3O2)2(H2O)3]n, is the largest reported hydrate of the salt and this leads to a distinct structural behaviour setting it apart from the rest of the family. The compound is a linear polymer with a nine‐coordinate Ba(Oaqua)3(Oacetate)6 monomer unit. The non‐H part of the structure is ordered according to C2/m symmetry, while the disordered water H atoms only abide by this symmetry in a statistical sense. Each molecule is halved by a mirror plane bisecting the Ba centre, one water molecule and one acetate ligand, while containing the other acetate ligand. The chains are interconnected by a disordered water–water/acetate O—H...O hydrogen‐bonding network involving all water H atoms. The structure and stability of this phase are compared with the other known acetates of barium which differ in the degree of hydration. 相似文献
4.
Mrcia R. Siqueira Liange de Oliveira Diehl Robert A. Burrow 《Acta Crystallographica. Section C, Structural Chemistry》2006,62(2):m67-m69
In the centrosymmetric title compound, [Co2(C12H10O2P)4(C5H5N)4(H2O)2], each approximately octahedral Co atom features two trans‐coordinated pyridine molecules, one water molecule, a terminally coordinated monodentate diphenylphosphinate ligand, and two bidentate diphenylphosphinate ligands that bridge the two Co atoms across a centre of inversion to form a dimeric binuclear complex. The discrete molecules are linked by double hydrogen bonds between the terminally coordinated diphenylphosphinate ligand and the water molecule to form a continuous chain along the crystallographic b axis. 相似文献
5.
Jian‐Hai Luo Chang‐Cang Huang Xi‐He Huang Jin‐Gen Wang 《Acta Crystallographica. Section C, Structural Chemistry》2008,64(3):m121-m122
The title compound, [Cu2Fe3(C5H5)3(C2H3O2)(C6H4O2)3(C3H7NO)2], belongs to the classic dimeric paddle‐wheel structure type. It is an unusual example in that it contains two different carboxylate groups, viz. ferrocenecarboxylate and acetate. With three ferrocenecarboxylate groups and only one acetate group bridging the two Cu centres, a noncentrosymmetric molecular arrangement results. 相似文献
6.
Xin‐Yi Cao Jian Zhang Yao Kang Jian‐Kai Cheng Yuan‐Gen Yao 《Acta Crystallographica. Section C, Structural Chemistry》2004,60(12):m654-m656
In the title compound, [Cu(C8H4O5)(C5H5N)2]n or [Cu(OH‐BDC)(py)2]n (where OH‐H2BDC is 5‐hydroxyisophthalic acid and py is pyridine), the Cu atoms are coordinated by two N atoms from the pyridine ligands and by three O atoms from hydroxyisophthalate ligands in a highly distorted triangular bipyramidal environment, with Cu—O distances in the range 1.941 (4)–2.225 (5) Å and Cu—N distances of 2.014 (6) and 2.046 (6) Å. The [Cu(OH‐BDC)]n two‐dimensional network is built up from interlocking 22‐, 15‐ and eight‐membered rings via sharing of Cu atoms and O—H⋯O hydrogen bonds. Consolidation of the packing structure is achieved by edge‐ or point‐to‐face C—H⋯π interactions and offset or slipped π–π stacking interactions. 相似文献
7.
Ricardo Baggio Juan Carlos Muoz Mireille Perec 《Acta Crystallographica. Section C, Structural Chemistry》2002,58(10):m498-m500
The title compound, [Dy2(C2H3O2)6(H2O)4]·4H2O, crystallizes in the form of dimeric units related by an inversion centre. Each cation is nine‐coordinate, binding to two water molecules and three acetate groups, two of which are bidentate and the third tridentate. This last acetate group acts as a bridge between neighbouring metal atoms, leading to an intradimer Dy?Dy separation of 4.170 (1) Å. 相似文献
8.
Peter D.W. Boyd Paul M. Johns Clifton E.F. Rickard 《Acta Crystallographica. Section C, Structural Chemistry》2006,62(12):m590-m593
The title compounds, [CuFe2(C5H5)2(C9H8O2)2], (I), and [CuFe4(C5H5)4(C13H9O2)2], (II), are four‐coordinate square‐planar copper(II) complexes with two bidentate 1‐ferrocenylbutane‐1,3‐dionate or 1,3‐diferrocenylpropane‐1,3‐dionate ligands, respectively. The copper ion in (I) lies on an inversion centre, with one‐half of the molecule in the asymmetric unit, while in (II), there are two independent half molecules in the asymmetric unit, with the copper ions also situated on inversion centres. The ferrocene substituents in (I) are in an anti arrangement. The molecules assemble in the crystal structure in layers with ferrocene groups at the surface. The pairs of ferrocene substituents on each ligand in complex (II) are syn and these adopt an anti arrangement with respect to the pair on the other diketonate ligand. As found in (I), complexes assemble in a layered structure with ferrocene‐coated surfaces. 相似文献
9.
Shan Gao Ji‐Wei Liu Li‐Hua Huo Zhi‐Zhong Sun Jin‐Sheng Gao Seik Weng Ng 《Acta Crystallographica. Section C, Structural Chemistry》2004,60(8):m363-m365
In the title neutral coordination polymer, [Cd(C6H3ClNO2)2(H2O)2]n, each CdII ion is coordinated by one N and four O atoms from three 2‐chloronicotinate ligands and by two aqua ligands, defining a distorted monocapped octahedral coordination geometry. Adjacent Cd atoms are linked by the pyridyl N atom and the bidentate carboxylate functional group of a 2‐chloronicotinate ligand, forming a one‐dimensional infinite chain along the b axis. The Cd⋯Cd distance is 8.112 (3) Å. These chains are linked by O—H⋯O and O—H⋯N hydrogen bonds into a three‐dimensional network structure. 相似文献
10.
Andrew W. G. Platt Anthony M. J. Lees 《Acta Crystallographica. Section C, Structural Chemistry》2007,63(10):m433-m435
The structure of the title complex, [Cu(NO3)2(C27H26O2P2)]n, consists of polymeric chains formed by propane‐1,3‐diylbis(diphenylphosphine oxide) ligands bridging between metal centres. The Cu atom lies on a twofold rotation axis and a further symmetry centre bisects the bridging bisphosphine dioxide ligand. The CuO6 coordination geometry is a distorted octahedron, with the bidentate chelating nitrate groups adopting a cis configuration. 相似文献
11.
Hong‐Ping Xiao Xin‐Hua Li Ji‐Xin Yuan Mao‐Lin Hu 《Acta Crystallographica. Section C, Structural Chemistry》2004,60(2):m63-m64
In the title complex, [Cu2(C10H2O8)(C10H8N2)2]n, the CuII cation has a four‐coordinated environment, completed by two carboxyl O atoms belonging to two 1,2,4,5‐benzenetetracarboxylate anions (TCB4−) and two N atoms from one 2,2′‐bipyridine (2,2′‐bipy) ligand, forming a distorted square‐planar geometry. The [Cu(2,2′‐bipy)]2+ moieties are bridged by TCB4− anions, which lie about inversion centres, forming an infinite one‐dimensional coordination polymer with a double‐chain structure along the a axis. A two‐dimensional network structure is formed via a face‐to‐face π–π interaction between the 2,2′‐bipy rings belonging to two adjacent double chains, at a distance of approximately 3.56 Å. 相似文献
12.
Fang‐Fang Jian Yu‐Ping Tong Hai‐Lian Xiao Ping‐Ping Sun Pu‐Su Zhao 《Acta Crystallographica. Section C, Structural Chemistry》2004,60(7):m348-m349
The title compound, [Co2(H2PO4)4(C10H8N2)2], is dinuclear, centred on a symmetry centre of the P space group. Each Co atom has a distorted square‐pyramidal coordination involving two N atoms from a bipyridine molecule and three O atoms from two bridging and one terminal dihydrogen orthophosphate anion. The molecular structure and packing are stabilized by intermolecular hydrogen‐bond interactions. 相似文献
13.
Yoshiyuki Kani Masanobu Tsuchimoto Shigeru Ohba 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(5):e193-e193
The title complex, [Cu2(C2H3O2)4(C7H6N2)2], shows a binuclear cage structure having an inversion centre. There are intramolecular N—H?O hydrogen bonds between the 7‐azaindole ligands and the bridging acetate O atoms. 相似文献
14.
Yanko Moreno Yimmy Salgado María Teresa Garland Ricardo Baggio 《Acta Crystallographica. Section C, Structural Chemistry》2007,63(11):m487-m489
In the title monomer, [Cu(NO3)2(C18H12N2)], the six‐coordinated CuII atom lies on a twofold axis which bisects one of the ligands (a chelating biquinoline) and duplicates the remaining ligand, a chelating nitrate. The latter binds in a very asymmetric way, consistent with a Jahn–Teller distortion in the coordination polyhedron which, due to the triple chelation, is extremely distorted and difficult to describe in terms of any regular model. 相似文献
15.
Lesaw Siero Maria Bukowska‐Strzyewska 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(1):19-21
In the title dimeric complex, [Cu2(C4H4O4)2(C7H6N2S)4], which possesses a centre of symmetry, the Cu atoms are enclosed in a 14‐membered ring. They adopt a distorted square‐bipyramidal (4+2) coordination. The four closest donor atoms are two N atoms of 2‐aminobenzothiazole ligands and two O atoms of the succinate carboxylate groups. They form a square‐planar cis arrangement, with an average Cu—N distance of 2.003 (3) Å and Cu—O distances of 1.949 (3) and 1.965 (3) Å. Two longer Cu—O bonds of 2.709 (3) and 2.613 (3) Å involving the remaining O atoms of the carboxylate groups complete the sixfold coordination of the Cu atoms. The H atoms of each amino group of the 2‐aminobenzothiazole molecules form intra‐ and intermolecular N—H?O hydrogen bonds. A nearly perpendicular intermolecular C—H?Cg interaction (Cg is the centroid of the imidazole ring) is observed. The intramolecular Cu?Cu distance is 6.384 (2) Å. 相似文献
16.
Fen Sun Yan‐Tuan Li Zhi‐Yong Wu Yu‐Lan Song Man Jiang 《Acta Crystallographica. Section C, Structural Chemistry》2006,62(12):m584-m586
The structure of the title compound, [Cu2(C12H24N4O2)(C3H4N2)2(CH4O)2](ClO4)2 or [Cu2(dmoxpn)(HIm)2(CH3OH)2](ClO4)2, where dmoxpn is the dianion of N,N′‐bis[3‐(dimethylamino)propyl]oxamide and HIm is imidazole, consists of a centrosymmetric trans‐oxamidate‐bridged copper(II) binuclear cation, having an inversion centre at the mid‐point of the central C—C bond, and two perchlorate anions. The CuII atom has square‐pyramidal coordination geometry involving two N atoms and an O atom from the dmoxpn ligand, an N atom from an imidazole ring, and an O atom from a methanol molecule. The crystal structure is stabilized by O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds and imidazole π–π stacking interactions to form a three‐dimensional supramolecular array. 相似文献
17.
Oga vajlenov Jn Van
o Jaromír Marek 《Acta Crystallographica. Section C, Structural Chemistry》2004,60(6):m275-m277
Crystals of the title compound, [Cu2(C10H9NO3)2(H2O)2]·2CH4N2O, consist of two (N‐salicylidene‐β‐alaninato‐κ3O,N,O′)copper(II) coordination units bridged by two water moieties to form a dimer residing on a crystallographic inversion center, along with two uncoordinated urea molecules. The CuII atom has square‐pyramidal coordination, with three donor atoms of the tridentate Schiff base and an O atom of the bridging aqua ligand in the basal plane. The axial position is occupied by the second bridging water ligand at a distance of 2.5941 (18) Å. Hydrogen bonds between molecules of urea and the neighboring dimer units lead to the formation of a two‐dimensional grid of molecules parallel to [101]. The superposition of the normals of the pyramidal base planes in the direction [100] indicates possible π–π interactions between the neighboring units. 相似文献
18.
G. Prochniak V. Videnova‐Adrabinska 《Acta Crystallographica. Section C, Structural Chemistry》2009,65(2):m103-m106
This study presents the coordination modes and two‐dimensional network of a novel strontium(II) coordination polymer, [Sr(C7H5O5S)2(H2O)3]n. The eight‐coordinate Sr2+ ion is in a distorted bis‐disphenoidal coordination environment, surrounded by four sulfonate and one carboxyl O atom from five benzenesulfonate ligands, two of which are symmetry unique, and by three O atoms from three independent aqua ligands. The compound exhibits a monolayer structure with coordination bonds within and hydrogen bonds between the layers. The μ4 acid ligand bridges the metal ions in two dimensions to form a thick undulating monolayer with a hydrophobic interior and hydrophilic surfaces. A second independent monoanion is arranged outward from both sides of the monolayer and serves to link adjacent monolayers via carboxyl–water and water–carboxyl hydrogen bonds. 相似文献
19.
Miroslav Bo
a Ingrid Svoboda Franz Renz Hartmut Fuess 《Acta Crystallographica. Section C, Structural Chemistry》2004,60(12):m631-m633
The structure of the title compound, {(CH6N)[Co(CHO2)3]}n, consists of a three‐dimensional net of central CoII ions connected via formate (methanediolate) bridges. The negative charge is compensated by protonated methylamine cations. The CoO6 chromophores form slightly distorted octahedra, which are bridged by C atoms of formate groups. The central Co atom lies on an inversion center and most of the other atoms lie on an m plane. 相似文献
20.
Jian Zhang Zhao‐Ji Li Yi‐Hang Wen Yao Kang Ye‐Yan Qin Yuan‐Gen Yao 《Acta Crystallographica. Section C, Structural Chemistry》2004,60(8):m389-m391
The title compound, [Cd(C6H4NO2)2(H2O)2]n, forms a one‐dimensional chain structure based on a Cd atom with approximate pentagonal bipyramidal coordination geometry and two nicotinate ligands in different coordination modes. One acts as a tridentate ligand, chelating one Cd atom through the carboxylate group while simultaneously binding to a second symmetry‐related Cd atom through the pyridine N atom; the other acts only as a bidentate ligand through its carboxylate group. Hydrogen bonds utilizing the coordinated water molecules, uncoordinated nitrogen and carboxylate O atoms as acceptors link the chains. 相似文献