The virtual origin of riblets in an open channel flow

In this paper, a method using the mean velocity profiles for the buffer layer was developed for the estimation of the virtual origin over a riblets surface in an open channel flow. First, the standardized profiles of the mixing length were estimated from the velocity measurement in the inner layer, and the location of the edge of the viscous layer was obtained. Then, the virtual origins were estimated by the best match between the measured velocity profile and the equations of the velocity profile derived from the mixing length profiles. It was made clear that the virtual origin and the thickness of the viscous layer are the function of the roughness Reynolds number. The drag variation coincided well with other results.Nomenclature f _r skin friction coefficient - f _ro skin friction coefficient in smooth channel at the same flow quantity and the same energy slope - g gravity acceleration - H water depth from virtual origin to water surface - H ⁺ u*H/ - H false water depth from top of riblets to water surface - H ⁺ u*H/ - I _e streamwise energy slope - I _b bed slope - k riblet height - k ⁺ u*k/ - l mixing length - l _s standardized mixing length - Q flow quantity - Re Reynolds number volume flow/unit width/v - s riblet spacing - u mean velocity - u* friction velocity = - u* false friction velocity = - y distance from virtual origin - y distance from top of riblet - y ₀ distance from top of riblet to virtual origin - y _v distance from top of riblet to edge of viscous layer - y ⁺ u*y/ - y ⁺ u*y/ - y ₀ ⁺ u*y ₀/ - u ⁺ u*y/ - shifting coefficient for standardization - thickness of viscous layer=y ₀+y - ⁺ u*/ - ⁺ u*/ - eddy viscosity - ridge angle - v kinematic viscosity - density - shear stress     

Bursting and structure of the turbulence in an internal flow manipulated by riblets

The buffer layer of an internal flow manipulated by riblets is investigated. The distributions of the ejection and bursting frequency from the beginning to the middle part of the buffer layer, together with high moments of the fluctuating streamwise velocity,u, and its time derivative are reported. The profiles of the ejection and bursting frequency are determined and compared using three single point detection schemes. The effect of the riblets on the bursting mechanism is found confined in a localized region in the buffer layer. The multiple ejection bursts are more affected than the single ejection bursts. The skewness and flatness factors of theu signal are larger in the manipulated layer than in the standard boundary layer. That, also holds true for the flatness factor of the time derivative, but the Taylor and Liepman scales are not affected. The spectrum of theu signal is altered at the beginning part of the viscous sublayer.Nomenclature u Friction velocity - Viscosity - l _v ;f _v wall scalesv/u ;u ² /v - y Vertical distance to the wall - z Spanwise extent - (⁺) Variable normalized with wall scales - u Velocity;u=Turbulence intensity - h, s Height and width of the riblets - f _e Ejection frequency - f _b Bursting frequency - f _BME Frequency of the Bursts with Multiple Ejection - f _BSE Frequency of Single Ejection Bursts - S andS _du/dt Skewness factor ofu and its time derivative - F _u andF _du/dt Flatness factor ofu and its time derivative Abbreviations SBL Standard (non-manipulated) Boundary Layer - MBL Manipulated Boundary Layer - BME Bursts with Multiple Ejections - BSE Bursts with Single Ejections - VITA Variable Interval Time Averaging technique - u–l u-level technique - mu Modifiedu-level technique     

On physical criteria for the selection of wood for soundboards of musical instruments

In order to develop criteria for the physical evaluation of wood for soundboards of musical instruments, measurements were made of dynamic Young's modulusE, static Young's modulusE, internal frictionQ ^–1 in longitudinal direction, and specific gravity for numerous species of broad-leaved wood. From the results obtained, including those of our previous paper on coniferous wood [1], it was found that the suitability of wood for soundboards could be evaluated by the quantity ofQ ^–1/(E/), and that there were very high correlations betweenQ ^–1/(E/) andE/, and betweenE andE, regardless of wood species. Consequently, it becomes possible to select practically any wood suitable for soundboards by using the value ofE/, which can be measured easily, and it was derived that the relation betweenE/ andQ ^–1 of wood could be expressed by an exponential equation regardless of wood species.     

A class of nonlinear,completely integrable abstract wave equations

IfL is a positive self-adjoint operator on a Hubert spaceH, with compact inverse, the second-order evolution equation int,u+Lu+u _H ² u=0 has an infinite number of first integrals, pairwise in involution. It follows from this that no nontrivial solution tends weakly to 0 inH ast. Under an additional separation assumption on the eigenvalues ofL, all trajectories (u,u) are relatively compact inD(L ^1/2)×H. Finally, if all the eigenvalues are simple, the set of initial values of quasi-periodic solutions is dense in the ball B=(u ₀,u ₀ )D(L ^1/2)×H; L^1/2 u _{0 H} ² +u ² < for sufficiently small.     

Effects of MHD free convection and mass transfer on the flow past an oscillating infinite coaxial vertical circular cylinder

The effects of MHD free convection and mass transfer are taken into account on the flow past oscillating infinite coaxial vertical circular cylinder. The analytical expressions for velocity, temperature and concentration of the fluid are obtained by using perturbation technique.

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Einwirkungen von freier MHD-Konvektion und Stoffübertragung auf eine Strömung nach einem schwingenden unendlichen koaxialen vertikalen Zylinder

Zusammenfassung Die Einwirkungen der freien MHD-Konvektion und Stoffübertragung auf eine Strömung nach einem schwingenden, unendlichen, koaxialen, vertikalen Zylinder wurden untersucht. Die analytischen Ausdrücke der Geschwindigkeit, Temperatur und Fluidkonzentration sind durch die Perturbationstechnik erhalten worden.

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Nomenclature C _p Specific heat at constant temperature - C the species concentration near the circular cylinder - C _w the species concentration of the circular cylinder - C the species concentration of the fluid at infinite - * dimensionless species concentration - D chemical molecular diffusivity - g acceleration due to gravity - Gr Grashof number - Gm modified Grashof number - K thermal conductivity - Pr Prandtl number - r _a ,r _b radius of inner and outer cylinder - a, b dimensionless inner and outer radius - r,r coordinate and dimensionless coordinate normal to the circular cylinder - Sc Schmidt number - t time - t dimensionless time - T temperature of the fluid near the circular cylinder - T _w temperature of the circular cylinder - T temperature of the fluid at infinite - u velocity of the fluid - u dimensionless velocity of the fluid - U ₀ reference velocity - z,z coordinate and dimensionless coordinate along the circular cylinder - coefficient of volume expansion - * coefficient of thermal expansion with concentration - dimensionless temperature - H ₀ magnetic field intensity - coefficient of viscosity - _e permeability (magnetic) - kinematic viscosity - electric conductivity - density - M Hartmann number - dimensionless skin-friction - frequency - dimensionless frequency     

Flow through a helically coiled annulus

In this paper the flow is studied of an incompressible viscous fluid through a helically coiled annulus, the torsion of its centre line taken into account. It has been shown that the torsion affects the secondary flow and contributes to the azimuthal component of velocity around the centre line. The symmetry of the secondary flow streamlines in the absence of torsion, is destroyed in its presence. Some stream lines penetrate from the upper half to the lower half, and if is further increased, a complete circulation around the centre line is obtained at low values of for all Reynolds numbers for which the analysis of this paper is valid, being the ratio of the torsion of the centre line to its curvature.Nomenclature A =constant - a outer radius of the annulus - b unit binormal vector to C - C helical centre line of the pipe - D rL - g 1000 - K Dean number=Re² - L 1+r sin - M (L ²+ ² r ²)^1/2 - n unit normal vector to C - P, P pressure and nondimensional pressure - p ₀, p pressures of O(1) and O() - Re Reynolds number=aW ₀/ - (r, , s), (r, , s) coordinates and nondimensional coordinates - nonorthogonal unit vectors along the coordinate directions - r ₀ radius of the projection of C - t unit tangent vector to C - V _r, V , V _s velocity components along the nonorthogonal directions - V_r, V, V _s nondimensional velocity components along - W ₀ average velocity in a straight annulus Greek symbols , curvature and nondimensional curvature of C - U, V, W lowest order terms for small in the velocity components along the orthogonal directions t - _r, , _s first approximations to V _r , V, V _s for small - =/=/ - kinematic viscosity - density of the fluid - , torsion and nondimensional torsion of C - , stream function and nondimensional stream function - nondimensional streamfunction for U, V - a inner radius of the annulus After this paper was accepted for publication, a paper entitled On the low-Reynolds number flow in a helical pipe, by C.Y. Wang, has appeared in J. Fluid. Mech., Vol 108, 1981, pp. 185–194. The results in Wangs paper are particular cases of this paper for =0, and are also contained in [9].     

Concentration dependence of the critical viscoelastic properties of gelatin at the gel point

Gelatin gel properties have been studied through the evolution of the storage [G()] and the loss [G()] moduli during gelation or melting near the gel point at several concentrations. The linear viscoelastic properties at the percolation threshold follow a power-law G()G() and correspond to the behavior described by a rheological constitutive equation known as the Gel Equation. The critical point is characterized by the relation: tan = G/G = cst = tan ( · /2) and it may be precisely located using the variations of tan versus the gelation or melting parameter (time or temperature) at several frequencies. The effect of concentration and of time-temperature gel history on its variations has been studied. On gelation, critical temperatures at each concentration were extrapolated to infinite gel times. On melting, critical temperatures were determined by heating step by step after a controlled period of aging. Phase diagrams [T = f(C)] were obtained for gelation and melting and the corresponding enthalpies were calculated using the Ferry-Eldridge relation. A detailed study of the variations of A with concentration and with gel history was carried out. The values of which were generally in the 0.60–0.72 range but could be as low as 0.20–0.30 in some experimental conditions, were compared with published and theoretical values.     

Optical co-ordinates in general relativity 2 — the problem of distance

Summary Let denote the congruence of null geodesics associated with a given optical observer inV ₄. We prove that determines a unique collection of vector fieldsM₍₎ ( =1, 2, 3) and ₍₀₎ overV ₄, satisfying a weak version of Killing's conditions.This allows a natural interpretation of these fields as the infinitesimal generators of spatial rotations and temporal translation relative to the given observer. We prove also that the definition of the fieldsM₍₎ and ₍₀₎ is mathematically equivalent to the choice of a distinguished affine parameter f along the curves of, playing the role of a retarded distance from the observer.The relation between f and other possible definitions of distance is discussed.

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Sommario Sia la congruenza di geodetiche nulle associata ad un osservatore ottico assegnato nello spazio-tempoV ₄. Dimostriamo che determina un'unica collezione di campi vettorialiM₍₎ ( =1, 2, 3) e ₍₀₎ inV ₄ che soddisfano una versione in forma debole delle equazioni di Killing. Ciò suggerisce una naturale interpretazione di questi campi come generatori infinitesimi di rotazioni spaziali e traslazioni temporali relative all'osservatore assegnato. Dimostriamo anche che la definizione dei campiM₍₎, ₍₀₎ è matematicamente equivalente alla scelta di un parametro affine privilegiato f lungo le curve di, che gioca il ruolo di distanza ritardata dall'osservatore. Successivamente si esaminano i legami tra f ed altre possibili definizioni di distanza in grande.

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Work performed in the sphere of activity of: Gruppo Nazionale per la Fisica Matematica del CNR.     

Effects of temperature and pressure on the rheological behavior of montmorillonite sols

Summary The effects of high temperatures up to 180 C and high pressures up to 560 kg/cm² on the rheological properties of pure montmorillonite suspensions with well-defined base-exchange cations have been investigated. The suspensions behave very much asBingham plastics according to the equation=+, in which is the shear stress,D the shear rate, the plastic viscosity, and the yield stress which is largely a measure of residual flocculation.The observed effects depend strongly on the interparticle forces that govern the colloidal stability and the rheological behavior of the suspensions. One can distinguish between two categories of suspensions:P-type sols in which the clay particles are associated through Coulombic attraction between positive edges and negative faces and are located in a primary potential energy minimum, andS-type sols in which the particles are associated edge-to-edge and are located in a weaker secondary potential minimum obtained by the summation ofvan der Waals attraction and double layer repulsion.Both theBingham yield stress and the plastic viscosity of theP-type sols decrease with increasing temperature. The temperature dependence of follows theArrhenius equation. TheP-type suspensions are either weakly or not at all thixotropic at room temperature and are definitely non-thixotropic at higher temperatures. Pressure slightly increases both the plastic viscosity and the yield stress.TheS-type sols, on the other hand, display an increase in yield stress and degree of thixotropy with increasing temperature and generally a decrease in the plastic viscosity. This behavior is modified in the case of Ca-montmorillonite suspensions, in which both and pass through a maximum at 150C, followed by a decline. The maximum can be explained by disaggregation of face-to-face aggregated clay packets.Pressure causes a decrease both in and the degree of thixotropy in theS-type suspensions, while it causes a slight increase in the plastic viscosity. This behavior is a consequence of the destruction of the hydration shell caused by high pressure.

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Zusammenfassung Der Einfluß von hohen Temperaturen (bis 180 C) und hohen Drucken (bis zu 560 kp/cm²) auf die rheologischen Eigenschaften reiner Suspensionen von Montmorillonit mit definierten Austauschionen wurde untersucht. Die Suspensionen folgen dem Binghamschen Flie\gesetz gemÄ\ der Gleichung=+, worin die Schubspannung,D das GeschwindigkeitsgefÄlle, dieBingham- ViskositÄt und die Flie\spannung darstellen. Letztere zeigt in erster Linie das Ausma\ der Koagulation an.Die beobachteten Effekte hÄngen stark von den KrÄften zwischen den Teilchen ab, welche die StabilitÄt der Kolloide und das rheologische Verhalten der Suspensionen bestimmen. Man kann zwei Kategorien von Suspensionen unterscheiden: Sole vom sog.P-Typ, in denen die Tonteilchen durch Coulombsche AnziehungskrÄfte zwischen positiven Kanten und negativen FlÄchen assoziiert sind und sich in einem primÄren Potentialminimum befinden, und Sole vomS-Typ, in denen die Teilchen Kante-zu-Kante assoziiert sind und sich in einem flacheren sekundÄren Potentialminimum befinden, welches durch das Zusammenwirken vonvan der Waalsschen AnziehungskrÄften und von Absto\ungskrÄften infolge der Wechselwirkung der elektrischen Doppelschichten entsteht.Sowohl die Flie\grenze als auch dieBingham-ViskositÄt der Sole vomP-Typ nehmen mit wachsender Temperatur ab. Die TemperaturabhÄngigkeit von folgt derArrhenius-Gleichung. Die Suspensionen vomP-Typ sind bei Zimmertemperatur entweder gar nicht oder nur schwach thixotrop, wÄhrend sie bei hoher Temperatur in keinem Fall thixotrop sind. Mit wachsendem Druck erhöht sich sowohl dieBingham-ViskositÄt als auch die Flie\grenze ein wenig.Bei den Solen vomS-Typ andererseits steigt die Flie\spannung und der Grad der Thixotropie mit steigender Temperatur, wÄhrend dieBingham-ViskositÄt im allgemeinen abnimmt. Bei Ca-Montmorillonit-Suspensionen ist das Verhalten etwas anders: Sowohl als auch erreichen bei 150 C ein Maximum und fallen dann wieder ab. Das Maximum kann durch Desaggregation flÄchenhaft aggregierter Tonpartikel erklÄrt werden. Bei steigendem Druck fÄllt sowohl als auch der Grad der Thixotropie in den Suspensionen vomS-Typ ab, wÄhrend dieBingham-YiskositÄt leicht ansteigt. Dieses Verhalten ist eine Folge der dann eintretenden Zerstörung der Solvathüllen.

     

A third order scheme in the vlasov theory and some consequences in the evolution of few body systems

Summary A set of implemented evolution equations, describing the coherent nonlinear interaction of plasma waves, based on the perturbation method, has been derived, taking into account initial value effects and third order nonlinearities in the modal amplitudes.The equations reduce, in the appropriate limit, to well known stochastic triplets of hydrodynamic type.It is argued that, the stochastization mechanism of the decay instability in strongly damped regime, may be interpreted as a Duffing-type behavior.

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Sommario Si presenta un sistema di equazioni di evoluzione descrivente l'interazione coerente nonlineare di onde di plasma, tenendo conto di effetti di condizioni iniziali e nonlinearità del terzo ordine nelle ampiezze modali. Le equazioni si riducono, nel limite appropriato, a ben noti tripletti stocastici di tipo idrodinamico.Si ipotizza che il processo di stocastizzazione della instabilità di decadimento, in regime di forte dissipazione, possa essere interpretato da un modello dinamico del tipo Duffing.

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Lyst of greek symbols omega (lower case)=frequency - delta (1.c.)=partial derivative - pi (1.c.)=greek pi (=3,14r. units) in (26) - Sigma (Capital case)=Summation symbol - Delta (C.c)=def. as in (14) - epsilon (1.c.) def. as in (10) - sigma (1.c.)=def. as in (36) - gamma (1.c.)=def. as in (37) - beta (1.c.)=def. as in (37) - ro, (1.c.)=def. as in (37) - alfa (1.c.)=def. in connection with _k in (60) - Gamma (C.c.)=def. as in (63) and (66), (67) - delta (1.c.)=def. as in (66) - psi (1.c.)=def. as in (75) - fi (1.c.)=def. in (71) in connection with ₀ - Fi (C.c.)=def. as in (75) - Omega (C.c.)=def. in (78)     

On the localness of the spectral energy transfer in turbulence

By utilizing available experimental data for net energy transfer spectra for homogeneous turbulence, contributions P(, ) to the energy transfer at a wavenumber from various other wavenumbers are calculated. This is done by fitting a truncated power-exponential series in and to the experimental data for the net energy transfer T(), and using known properties of P(, ). Although the contributions P(, ) obtained by using this procedure are not unique, the results obtained by using various assumptions do not differ significantly. It seems clear from the results that for a region where the energy entering a wavenumber band dominates that leaving, much of the energy entering the band comes from wavenumbers which are about an order of magnitude smaller. That is, the energy transfer is rather nonlocal. This result is not significantly dependent on Reynolds number (for turbulence Reynolds numbers based on microscale from 3 to 800). For lower wavenumbers, where more energy leaves than enters a wavenumber band, the energy transfer into the band is more local, but much of the energy then leaves at distant wavenumbers.     

The behaviour of a mass-spring system provided with a discontinuous dynamic vibration absorber

Summary The influence of a specific discontinuous dynamic vibration absorber on the motion of a vibrating system is investigated. Attention is paid to the effectiveness in the case of free vibrations and of vibrations due to sinusoidal excitations, where structural damping is also taken into account. For certain configurations numerical results are given.Notation M mass of the vibrating system - m mass of the ball - c spring constant - k structural damping coefficient - g acceleration of gravity - F ₀ amplitude of external force - frequency of external force - 2 distance over which the ball may move - x displacement of centre of tube - y displacement of the ball x and y are measured positive downward from the equilibrium position of the system when no gravitational force would act     

A note on the tan δ(T) peak as a glass transition indicator in biosolids

The plasticization of many biosolids can take place over a fairly broad temperature range. The resulting loss of stiffness is primarily expressed by a drastic drop of G(T) whose magnitude is usually higher than G(T) by one or two orders of magnitude. Both G(T) and G(T) have characteristic properties that can vary widely among biomaterials. Consequently, the tan (T) peak need not be a mark of the transition center and it can be observed at temperatures where different materials have undergone a very different degree of plasticization as judged by the magnitude of G(T). This is demonstrated by computer simulations using typical functions that describe G(T) and G(T) at the glass transition region and with published data on the dynamic mechanical behavior of a variety of biosolids.     

Stefan — like problems with space — dependent latent heat

Summary A wide class of one-dimensional heat conduction problems with phase change is considered on the assumption that the latent heat is a given function of the position of the separation plane between the two phases: L=[s(t)].Some sufficient conditions for the existence and uniqueness of the solution in a given time-interval are given. This work permits the generalization of some previous results and the investigation of some cases of particular interest.

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Sommario Si studia una vasta classe di problemi di conduzione unidimensionale del calore in presenza di cambiamento di fase, nel caso in cui il calore latente sia funzione della posizione del fronte di separazione tra le due fasi: L=[s(t)].Si trovano delle condizioni sufficienti per l'esistenza e la unicità della soluzione del problema in un certo intervallo di tempo; si mostra infine che la trattazione permette di generalizzare risultati già noti e di estendere lo studio a casi di particolare interesse.

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Work performed within the Research Group (Grant. no. 115.2210) of the C.N.R.     

On the dynamic response of viscoelastic fluids

Summary To define the dynamic shear behaviour of a viscoelastic fluid we require two functions — one elastic and one viscous. There are two simple alternatives based on the Voigt and Maxwell concepts which are mathematically interrelated. Current practice interprets the dynamic response of fluids as a function of angular frequency () in terms of the storage (G) and loss (G) moduli: the loss function is commonly converted to a viscosity = G/. As is well known the parameters andG are the elements of a Voigt model whereas it is near universal practice to interpret steady flow in terms of the Maxwell model. This paper shows how the interpretation of dynamic experiments on fluids in terms of the apparent Maxwell parameters is more simple, more sensitive, more consistent with steady flow behaviour, and physically more realistic.

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Zusammenfassung Zur Festlegung des dynamischen Scherverhaltens einer viskoelastischen Flüssigkeit benötigt man zwei Funktionen, eine für das elastische und eine für das viskose Verhalten. Dafür gibt es zwei einfache, mathematisch miteinander verknüpfte Alternativen, die entweder auf dem Voigtschen oder dem Maxwellschen Konzept gründen. Die übliche Praxis beschreibt das dynamische Verhalten der Flüssigkeiten als Funktion der Winkelgeschwindigkeit durch den SpeichermodulG und den VerlustmodulG bzw. die zugeordnete Viskosität = G/. Die Parameter undG sind bekanntlich die Elemente eines Voigt-Modells, wohingegen es nahezu allgemein üblich ist, das stationäre Fließen durch ein Maxwell-Modell zu beschreiben. Diese Arbeit zeigt nun, daß die Beschreibung dynamischer Versuche mit Hilfe von apparenten Maxwell-Parametern einfacher, empfindlicher, mit dem stationären Verhalten konsistenter und in physikalischer Hinsicht realistischer ist.

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Paper presented at British Society of Rheology conference. Rheometry: Methods of measurement and analysis of results, Shrivenham, April 8–11, 1975.

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With 13 figures and 2 tables     

Effect of alkali metal ions on the viscoelasticity of concentrated kappa-carrageenan and agarose gels

The effect of the addition of the monovalent cations Li⁺, Na⁺, K⁺, and Cs⁺ on the gelation of agarose and kappa-carrageenan aqueous gels has been studied by the measurement of longitudinal vibration. The dynamic Youngs's modulusE of 2% w/w agarose and 0.4–6% w/w kappa-carrageenan gels containing the alkali metal salt LiCl, NaCl, KCl or CsCl of various concentrations from 0 to 4.5 mol/l has been measured at various temperatures. By the addition of the alkali metal salt, the value ofE for agarose gels is influenced only slightly, while for kappa-carrageenanE is increased substantially. Kappa-carrageenan has many sulphate groups. The addition of the alkali metal ions screens the electrostatic repulsion between these groups. As a result of this, the helical structure of kappa-carrageenan is stabilised and the helices may form densely packed aggregates, so increasingE. In contrast, agarose has a naturally stable molecular structure and therefore, the structure and henceE is not sensitive to added ions. The K⁺ and Cs⁺ ions increaseE more than Li⁺ and Na⁺ for kappa-carrageenan gels. This is interpreted on the basis that these ions are either structure ordering or structure disordering ions for water.     

Beschreibung des visko-elastischen Verhaltens des polymeren Mischsystems Phenolnovolakharz-Nitrilkautschuk (PF/NBR) mit Hilfe der Van-der-Poel-Gleichung

Zusammenfassung Morphologische Untersuchungen an dem polymeren Mischsystem Phenolnovolakharz-Nitrilkautschuk haben gezeigt, daß diese Mischungen eine Struktur aufweisen, in der harte kugelige PF-Teilchen in einer Kautschukmatrix bzw. weiche Kautschukteilchen in einer Harzmatrix eingebettet sind. Mit Hilfe der morphologischen und mechanisch-dynamischen Untersuchungen wird versucht, das viskoelastische Verhalten von Polyblends mit der Van-der-Poel-Gleichung zu beschreiben. Es konnte gezeigt werden, daß bis zu ModulwertenGhart/Gweich ~ 100 eine gute Übereinstimmung mit der Van-der-Poel-Gleichung gefunden wird. Hohe Modulverhältnisse der harten Einlagerungskomponente zur weichen KomponentenGhart/Gweich ~ 1000, wie sie im kautschukelastischen Bereich auftreten, zeigen eine Übereinstimmung mit der Van-der-Poel-Gleichung nur bei einer Volumenkonzentration der harten EinlagerungskomponenteV _f < 0,3. Diese Ergebnisse werden mit anderen bekannten theoretischen Überlegungen über den Zusammenhang zwischen Elastizitätsmodul und Zusammensetzung von Verbundwerkstoffen verglichen.Schlüsselwörter Phenolnovolakharz-Nitrilkautschuk-System, viskoelastisches Verhalten, Torsionspendel, Van-der-Poel-Gleichung

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Summary Morphological investigations of the polymer compound-system novolak resin-nitril rubber (PF/NBR) have shown, that these mixtures exhibit structures, in which hard spherical particles are embedded in a rubber matrix, respectively soft rubber particles in a resin matrix.An attempt was made to describe the viscoelastic behaviour of these polyblends by means of morphological and dynamic-mechanical investigations with the relation given by Van der Poel.Up to ratios of the moduliGhard/Gsoft ~ 100 a good agreement with the Van-der-Poel equation was found. In the rubber elastic region at ratiosG hard/G soft ~ 1000 this agreement was found for volume concentrations of the phenolic componentV _f ~ 0.3 only.The results are compared with other existing theories on the correlation between elastic modulus and composition of compound materials.

Mit 7 Abbildungen und 6 Tabellen     

Rheology/morphology/flow conditions relationships for polymethylmethacrylate/rubber blend

Viscoelastic behavior, phase morphology and flow conditions relationships in polymer/rubber blends have been investigated. The importance of such correlations is illustrated on polymethylmethacrylate (PMMA)/rubber blends subjected to different flow conditions both under small and large deformations. In small-amplitude oscillatory shear (the morphology does not change during the flow) the elastic modulus G of the concentrated blends shows a secondary plateau, G _p , in the low frequency region. This solid-like behavior appears for rubber particle contents beyond the percolation threshold concentration (15%). Morphological observations revealed that for concentrations higher than 15%, the particles are dispersed in a three-dimensional network-type structure.In capillary flow it was found that the network-type structure was destroyed and replaced by an alignment of particles in the flow direction. This morphological modification resulted in a decrease in both viscosity and post-extrusion swell of the blends. Morphological observations revealed that the ordered structure in the flow direction was concentrated only in the skin region of the extrudate, where the shear stress is higher than the secondary plateau, G _p . A simple kinetic mechanism is proposed to explain the observed morphology.Similarly, steady shear measurements performed in the cone-and-plate geometry revealed alignment of particles in the flow direction for shear stress values higher than G_p.Presented in part at the Symposium Recent Developments in Structured Continua Montréal (Canada) 26–28 May 1993 and at the 45th Canadian Chemical Engineering Conference, Quebec, October 15–18 (1995)     

Experimental investigation of impinging jet arrays

We report on measurements of the velocity field and turbulence fluctuations in a hexagonal array of circular jets, impinging normally on a plane wall, using particle image velocimetry (PIV). Results for mean velocity and turbulent stresses are presented in various horizontal and vertical planes. From the measurements, we have identified some major features of impinging jet arrays and we discuss their mutual interaction, collision on the plate, and consequent backwash, which generate recirculating motion between the jets. The length of the jet core, the production of turbulence kinetic energy, and the model of the exhaust mechanisms for spent fluid are also discussed. The measurements indicated that the interaction between the self-induced cross flow and the wall jets resulted in the formation of a system of horseshoe-type vortices that circumscribe the outer jets of the array. The instantaneous snapshots of the velocity field reveal some interesting features of the flow dynamics, indicating a breakdown of some of the jets before reaching the plate, which may have consequences on the distribution of the instantaneous heat transfer.List of symbols D_m Nozzle diameter in multiple jet array nozzle plate (m) - D_s Pipe diameter in single jet rig (m) - H Distance between nozzle and impingement plate (m) - k Turbulent kinetic energy (m²/s²) - L Pipe length (m) - P_k Production of turbulent kinetic energy (m²/s³) - P_uu , P_vv Normal components of P_k (m²/s³) - P_uv Shear component of P_k (m²/s³) - s Pitch (m) - U_bulk Surface-averaged exit velocity (single jet) (m/s) - U_CL Center line jet exit velocity (jet array), m/s - u, v Mean velocity components in x and y directions (m/s) - u, v, w Instantaneous velocity in x, y, and z directions (m/s) - u, v, w Velocity fluctuation in x, y, and z directions (m/s) - u², v², w² Reynolds normal stress components (m²/s²) - uv Reynolds shear stress component (m²/s²) - x, z Coordinates parallel to impingement plate (m) - y Coordinate perpendicular to impingement plate (m)     

Die swell of filled polymer melts

The Barus effect in polypropylene and polystyrene blended with a variety of fillers at various concentrations was investigated using a capillary extrusion rheometer. If the die swell is defined as the square of the ratio of the extrudate diameterd to the die diameterD, it is found to depend on the apparent shear stress _W . Below a certain value of _w the relation =B _B ^A applies. The die swell, _M , of a filled polymer depends on the type, size and volume fraction of the filler. In particular,A increases as the volume fraction increases and is largest for powders, smaller for flakes and smallest for fibres, whereasB shows the opposite trend but to a lesser extent.